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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2011

Status and Outlook for the U.S. Non-Automotive Fuel Cell Industry: Impacts of Government Policies and Assessment of Future Opportunities

Fuel cells (FCs) are considered essential future energy technologies by developed and developing economies alike. Several countries, including the United States, Japan, Germany, and South Korea have established publicly funded R&D and market transformation programs to develop viable domestic FC industries for both automotive and non-automotive applications. Important non-automotive applications include large scale and small scale distributed combined heat and electrical power, backup and uninterruptible power, material handling and auxiliary power units. The U.S. FC industry is in the early stages of development, and is working to establish sustainable markets in all these areas. To be successful, manufacturers must reduce costs, improve performance, and overcome market barriers to new technologies. U.S. policies are assisting via research and development, tax credits and government-only and government-assisted procurements. Over the past three years, the industry has made remarkable progress, bringing both stack and system costs down by more than a factor of two while improving durability and efficiency, thanks in part to government support. Today, FCs are still not yet able to compete in these markets without continued policy support. However, continuation or enhancement of current policies, such as the investment tax credit and government procurements, together with continued progress by the industry, appears likely to establish a viable domestic industry within the next decade.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2011

Intergovernmental Advanced Stationary PEM Fuel Cell System Demonstration (Final Report)

A program to complete the design, construction and demonstration of a PEMFC system fuelled by Ethanol, LPG or NG for telecom applications was initiated in October 2007. Early in the program the economics for Ethanol were shown to be unfeasible and permission was given by DOE to focus on LPG only. The design and construction of a prototype unit was completed in Jun 2009 using commercially available PEM FC stack from Ballard Power Systems. During the course of testing, the high pressure drop of the stack was shown to be problematic in terms of control and stability of the reformer. Also, due to the power requirements for air compression the overall efficiency of the system was shown to be lower than a similar system using internally developed low pressure drop FC stack. In Q3 2009, the decision was made to change to the Plug power stack and a second prototype was built and tested. Overall net efficiency was shown to be 31.5% at 3 kW output. Total output of the system is 6 kW. Using the new stack hardware, material cost reduction of 63% was achieved over the previous Alpha design. During a November 2009 review meeting Plug Power proposed and was granted permission, to demonstrate the new, commercial version of Plug Power's telecom system at CERL. As this product was also being tested as part of a DOE Topic 7A program, this part of the program was transferred to the Topic 7A program. In Q32008, the scope of work of this program was expanded to include a National Grid demonstration project of a micro-CHP system using hightemperature PEM technology. The Gensys Blue system was cleared for unattended operation, grid connection, and power generation in Aug 2009 at Union College in NY state. The system continues to operate providing power and heat to Beuth House. The system is being continually evaluated and improvements to hardware and controls will be implemented as more is learned about the system's operation. The program is instrumental in improving the efficiency and reducing costs of PEMFC based power systems using LPG fuel and continues to makes steps towards meeting DOE's targets. Plug Power would like to thank DOE for their support of this program.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2012

Advanced Cathode Catalysts and Supports for PEM Fuel Cells (Final Report)

The principal objectives of the program were development of a durable, low cost, high performance cathode electrode (catalyst and support), that is fully integrated into a fuel cell membrane electrode assembly with gas diffusion media, fabricated by high volume capable processes, and is able to meet or exceed the 2015 DOE targets. Work completed in this contract was an extension of the developments under three preceding cooperative agreements/grants Nos. DE-FC-02-97EE50473, DE-FC-99EE50582 and DE-FC36- 02AL67621 which investigated catalyzed membrane electrode assemblies for PEM fuel cells based on a fundamentally new, nanostructured thin film catalyst and support system, and demonstrated the feasibility for high volume manufacturability.

08 HYDROGEN↗
DOE OSTI2012

Alternate Fuel Cell Membranes for Energy Independence

The overall objective of this project was the development and evaluation of novel hydrocarbon fuel cell (FC) membranes that possess high temperature performance and long term chemical/mechanical durability in proton exchange membrane (PEM) fuel cells (FC). The major research theme was synthesis of aromatic hydrocarbon polymers of the poly(arylene ether sulfone) (PAES) type containing sulfonic acid groups tethered to the backbone via perfluorinated alkylene linkages and in some cases also directly attached to the phenylene groups along the backbone. Other research themes were the use of nitrogen-based heterocyclics instead of acid groups for proton conduction, which provides high temperature, low relative humidity membranes with high mechanical/thermal/chemical stability and pendant moieties that exhibit high proton conductivities in the absence of water, and synthesis of block copolymers consisting of a proton conducting block coupled to poly(perfluorinated propylene oxide) (PFPO) blocks.

08 HYDROGEN↗
DOE OSTI2013

Low-Cost Illumination-Grade LEDs

Solid State Lighting is a cost-effective, energy-conserving technology serving a rapidly expand- ing multi-billion dollar market. This program was designed to accelerate this lighting revolution by reducing the manufacturing cost of Illumination-Grade LEDs. The technical strategy was to investigate growth substrate alternatives to standard planar sapphire, select the most effective and compatible option, and demonstrate a significant increase in Lumen/$ with a marketable LED. The most obvious alternate substrate, silicon, was extensively studied in the first two years of the program. The superior thermal and mechanical properties of Si were expected to improve wavelength uniformity and hence color yield in the manufacture of high-power illumination- grade LEDs. However, improvements in efficiency and epitaxy uniformity on standard c-plane sapphire diminished the advantages of switching to Si. Furthermore, the cost of sapphire decreased significantly and the cost of processing Si devices using our thin film process was higher than expected. We concluded that GaN on Si was a viable technology but not a practical option for Philips Lumileds. Therefore in 2012 and 2013, we sought and received amendments which broadened the scope to include other substrates and extended the time of execution. Proprietary engineered substrates, off-axis (non-c-plane) sapphire, and c-plane patterned sapphire substrates (PSS) were all investigated in the final 18 months of this program. Excellent epitaxy quality was achieved on all three candidates; however we eliminated engineered substrates and non-c-plane sapphire because of their higher combined cost of substrate, device fabrication and packaging. Ultimately, by fabricating a flip-chip (FC) LED based upon c-plane PSS we attained a 42% reduction in LED manufacturing cost relative to our LUXEON Rebel product (Q1-2012). Combined with a flux gain from 85 to 102 Lm, the LUXEON Q delivered a 210% increase in Lm/$ over this time period. The technology was commercialized in our LUXEON Q product in Sept., 2013. Also, the retention of the sapphire increased the robustness of the device, enabling sales of low-cost submount-free chips to lighting manufacturers. Thus, blue LED die sales were initiated in the form of a PSS-FC in February, 2013.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2015

Ultra-sensitive Magnetic Microscopy with an Atomic Magnetometer

The PowerPoint presentation focused on research goals, specific information about the atomic magnetometer, response and resolution factors of the SERF magnetometer, FC+AM systems, tests of field transfer and resolution on FC, gradient cancellation, testing of AM performance, ideas for a multi-channel AM, including preliminary sensitivity testing, and a description of a 6 channel DAQ system. A few ideas for future work ended the presentation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

Faraday's Cup Design and Testing

The main purpose of the Faraday’s Cup (FC) device is to stop and measure the beam charge. Three such FC’s are installed: Two in the Linac area at the end of the transport lines and one at the Booster to storage ring transport line.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Developing an Energy-Conscious Traffic Signal Control System for Optimized Fuel Consumption in Connected Vehicle Environments

The project titled “Developing an Energy-Conscious Traffic Signal Control System for Optimized Fuel Consumption in Connected Vehicle Environments” addresses energy-related challenges associated with adaptive traffic control systems by integrating connected vehicles (CV) and connected infrastructure (CI). The system developed in this project, a CV-based adaptive traffic control system, aims to improve fuel consumption in mixed traffic environments by capitalizing on emerging CV and CI communication technologies, as well as leveraging recent advances in Artificial Intelligence (AI), optimization, and edge computing. The system was tested at the MLK Smart Corridor, an urban testbed managed by the University of Tennessee at Chattanooga (UTC) and the City of Chattanooga. The system was validated through extensive simulations, both Software-in-the-Loop (SILS) and Hardware-in-the-Loop (HILS), and was further implemented and tested in real-world conditions at several intersections along the corridor. The Fuel Consumption Performance Index (FC-PI) and the Ecological Performance Index (Eco-PI) were developed as the key components for evaluating the system’s impact on fuel consumption and emissions. These metrics provided a comprehensive means of understanding the impact of traffic signal control optimization in mixed traffic environments. The report presents an in-depth analysis of the Eco-PI, FC-PI, adaptive traffic control system integration, and the testing and field implementation of the system. The results demonstrate significant reductions in fuel consumption and emissions, showcasing the system’s capability to contribute to more sustainable urban traffic management. The report also documents the challenges encountered and recommendations for scaling and further improving the system.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Effects of N -glycans on the structure of human IgA2

The transition of IgA antibodies into clinical development is crucial because they have the potential to create a new class of therapeutics with superior pathogen neutralization, cancer cell killing, and immunomodulation capacity compared to IgG. However, the biological role of IgA glycans in these processes needs to be better understood. This study provides a detailed biochemical, biophysical, and structural characterization of recombinant monomeric human IgA2, which varies in the amount/locations of attached glycans. Monomeric IgA2 antibodies were produced by removing the N-linked glycans in the CH1 and CH2 domains. The impact of glycans on oligomer formation, thermal stability, and receptor binding was evaluated. In addition, we performed a structural analysis of recombinant IgA2 in solution using Small Angle X-Ray Scattering (SAXS) to examine the effect of glycans on protein structure and flexibility. Our results indicate that the absence of glycans in the Fc tail region leads to higher-order aggregates. SAXS, combined with atomistic modeling, showed that the lack of glycans in the CH2 domain results in increased flexibility between the Fab and Fc domains and a different distribution of open and closed conformations in solution. When binding with the Fcα-receptor, the dissociation constant remains unaltered in the absence of glycans in the CH1 or CH2 domain, compared to the fully glycosylated protein. These results provide insights into N-glycans’ function on IgA2, which could have important implications for developing more effective IgA-based therapeutics in the future.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2016

Immunophenotype Discovery, Hierarchical Organization, and Template-Based Classification of Flow Cytometry Samples

We describe algorithms for discovering immunophenotypes from large collections of flow cytometry samples and using them to organize the samples into a hierarchy based on phenotypic similarity. The hierarchical organization is helpful for effective and robust cytometry data mining, including the creation of collections of cell populations’ characteristic of different classes of samples, robust classification, and anomaly detection. We summarize a set of samples belonging to a biological class or category with a statistically derived template for the class. Whereas individual samples are represented in terms of their cell populations (clusters), a template consists of generic meta-populations (a group of homogeneous cell populations obtained from the samples in a class) that describe key phenotypes shared among all those samples. We organize an FC data collection in a hierarchical data structure that supports the identification of immunophenotypes relevant to clinical diagnosis. A robust template-based classification scheme is also developed, but our primary focus is in the discovery of phenotypic signatures and inter-sample relationships in an FC data collection. This collective analysis approach is more efficient and robust since templates describe phenotypic signatures common to cell populations in several samples while ignoring noise and small sample-specific variations. We have applied the template-based scheme to analyze several datasets, including one representing a healthy immune system and one of acute myeloid leukemia (AML) samples. The last task is challenging due to the phenotypic heterogeneity of the several subtypes of AML. However, we identified thirteen immunophenotypes corresponding to subtypes of AML and were able to distinguish acute promyelocytic leukemia (APL) samples with the markers provided. Clinically, this is helpful since APL has a different treatment regimen from other subtypes of AML. Core algorithms used in our data analysis are available in the flowMatch package at www.bioconductor.org. It has been downloaded nearly 6,000 times since 2014.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Structural Characterization of Linker Shielding in ADC Site-Specific Conjugates

Background/Objectives: Antibody–Drug Conjugates (ADCs) have rapidly evolved from early, rudimentary conjugates to highly targeted and precisely engineered molecules. Despite notable clinical successes, ADCs continue to face significant challenges, including aggregation and high hydrophobicity driven by high drug-to-antibody ratios (DARs), premature payload release, dose-limiting toxicities, and suboptimal pharmacokinetics. While site-specific linker–payload conjugation has improved ADC homogeneity and stability, the structural basis of antibody–linker interactions at specific sites remains underexplored. Methods: In this work, we present the crystal structures of trastuzumab Fab and Fc domains site-specifically conjugated with a cleavable linker–payload. Results: Our findings suggest that pockets within both Fab and Fc regions may interact with and shield the linker portion of the conjugate. Conclusions: These insights highlight the previously underappreciated potential of structure-based design to drive the optimization of ADC linker chemistry and facilitate the co-design of bespoke linker–payloads tailored to individual antibody conjugation sites.

Jaime-Garza, Maru [Discovery Chemistry, Merck & Co↗
DOE OSTI2019

A comprehensive characterization of ice nucleation by three different types of cellulose particles immersed in water

Abstract. We present the laboratory results of immersion freezing efficiencies of cellulose particles at supercooled temperature ( T ) conditions. Three types of chemically homogeneous cellulose samples are used as surrogates that represent supermicron and submicron ice-nucleating plant structural polymers. These samples include microcrystalline cellulose (MCC), fibrous cellulose (FC) and nanocrystalline cellulose (NCC). Our immersion freezing dataset includes data from various ice nucleation measurement techniques available at 17 different institutions, including nine dry dispersion and 11 aqueous suspension techniques. With a total of 20 methods, we performed systematic accuracy and precision analysis of measurements from all 20 measurement techniques by evaluating T -binned (1  ° C) data over a wide T range ( - 36  ° C  < T < - 4   ° C). Specifically, we intercompared the geometric surface area-based ice nucleation active surface site (INAS) density data derived from our measurements as a function of T , n s,geo ( T ) . Additionally, we also compared the n s,geo ( T ) values and the freezing spectral slope parameter ( Δ log ( n s , geo ) / Δ T ) from our measurements to previous literature results. Results show all three cellulose materials are reasonably ice active. The freezing efficiencies of NCC samples agree reasonably well, whereas the diversity for the other two samples spans ≈  10  ° C. Despite given uncertainties within each instrument technique, the overall trend of the n s,geo ( T ) spectrum traced by the T -binned average of measurements suggests that predominantly supermicron-sized cellulose particles (MCC and FC) generally act as more efficient ice-nucleating particles (INPs) than NCC with about 1 order of magnitude higher n s,geo ( T ) .

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Bayesian performance evaluation of evapotranspiration models based on eddy covariance systems in an arid region

Abstract. Evapotranspiration (ET) is a major component of the land surface processinvolved in energy fluxes and energy balance, especially in the hydrologicalcycle of agricultural ecosystems. While many models have been developed aspowerful tools to simulate ET, there is no agreement on which model bestdescribes the loss of water to the atmosphere. This study focuses on twoaspects, evaluating the performance of four widely used ET models andidentifying parameters, and the physical mechanisms that havesignificant impacts on the model performance. The four tested models arethe Shuttleworth–Wallace (SW) model, Penman–Monteith (PM) model,Priestley–Taylor and Flint–Childs (PT–FC) model, and advection–aridity (AA)model. By incorporating the mathematically rigorous thermodynamicintegration algorithm, the Bayesian model evidence (BME) approach is adoptedto select the optimal model with half-hourly ET observations obtained at aspring maize field in an arid region. Our results reveal that the SW model has thebest performance, and the extinction coefficient is not merely partitioningthe total available energy into the canopy and surface but also includingthe energy imbalance correction. The extinction coefficient is wellconstrained in the SW model and poorly constrained in the PM model but notconsidered in PT–FC and AA models. This is one of the main reasons that theSW model outperforms the other models. Meanwhile, the good fitting of SWmodel to observations can counterbalance its higher complexity. In addition,the detailed analysis of the discrepancies between observations and modelsimulations during the crop growth season indicate that explicit treatmentof energy imbalance and energy interaction will be the primary way offurther improving ET model performance.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1975

On sound transmission into a thin cylindrical shell under 'flight conditions'

A mathematical model for sound transmission into a thin cylindrical shell is used to study sound transmission under flight conditions, i.e., under conditions of external air flow past a pressurized cylinder at flight altitude. Numerical results for different incidence angles are presented for a typical narrow-bodied jet in cruising flight at 10,660 m with interior pressure at 2440 m. A comparison is made between no-flow sound transmission at standard conditions on the ground to sound transmission under flight conditions. It is shown that at M = 0, the cylinder transmission loss (TL) has dips at the cylinder ring frequency (fR) and the critical frequency (fc) for a flat panel of same material and thickness as shell. Between fR and fc, cylinder TL follows a mass-law behavior. Flow provides a modest increase in TL in the mass-law region, and strongly interacts with the cylinder resonances below fR.

Koval, L. R.↗
NASA NTRS1982

An experimental study of heat induced surface-tension driven flow

Laser Doppler anemometry, radiation thermometry, and time-lapse photography have been used to study heat induced surface-tension driven flows in silicone oil and Fluorinert FC-43 in large open containers. For silicone oil, the effect of the surface tension gradient on the velocity field was not apparent enough to be detected. Because of its high viscosity, the oil was insensitive to outside disturbances, and the flow was steady. In the case of FC-43, the fluid was noticeably influenced by outside disturbances, and the flow was unsteady. The work reported here is part of an effort to develop experimental techniques and select test fluids for future space experiments on fluid motion in materials processing.

Kamotani, Y.↗
NASA NTRS1990

Smooth radio emission and a new emission at Neptune

The Planetary Radio Astronomy (PRA) experiment Warwick et al., (1977) on the spacecraft Voyager 2 observed three types of smooth emission: (1) numerous recurrent episodes are modeled by filled emission cones from midlatitude conjugate sources; (2) an 'equatorial' feature seen soon after closest approach includes electron cyclotron harmonic emission above the upper hybrid resonance, as well as smooth recurrent emission, its strange appearance is a result of rapid change in Voyager's magnetic latitude and; (3) unique 'high-latitude' emission is seen near closest approach during Voyager's single excursion to high north (+) magnetic latitude when fc, the electron cyclotron frequency at the spacecraft, lies in the observable range. The stronger component covers a broad band of frequencies above 2fc; its sensitivity to magnetic field identifies it as extraordinary (X) mode. The weaker component extends smoothly through f = fc and is identified as ordinary (O) mode. At each frequency f the observed sense of polarization reverses when f = 2fc.

Sawyer, C.↗
NASA NTRS1991

Single element magnetic suspension actuator

The invention, a single element magnetic suspension actuator with bidirectional force capability along a single axis, includes an electromagnet and a nonmagnetic suspended element. A permanent magnet mounted on the suspended element interacts with a magnetic field established by the electromagnet to produce bidirectional forces in response to a variable force command voltage V (sub FC) applied to the electromagnet. A sensor measures the position of the suspended element on the single axis which is a function of force command voltage V (sub FC).

Groom, Nelson J.↗
NASA NTRS1991

The optimum shape for a rigid rotating shell enclosing an isotropic spherical planetary mass

Analysis of the Dyson Sphere, an extremely advanced civilization's hypothetical construct entirely surrounding a star, shows that new stress inward to the star increases to maxima at the poles if the sphere is rotating. This is because the centrifugal force in the rotating frame of reference vanishes at zero rotational radius, which occurs at the poles. There is less of the centrifugal force at high latitudes than low to offset the star's gravity. A form is derived for a thin, rigid, rotating shell, surrounding a large pointlike mass and/or charge, which will experience the least possible net stress at every point upon it - a shape on which every point not on the shell's equator is as near as possible to being in orbit. In orbit, whose plane passes through the primary body's center of mass or of charge, F(grav), or Fg, is exactly opposite in direction to F(centrif), or Fc, and is equal in amount. At all points not on the equator, Fc will not entirely offset Fg, because of Fg's vector decomposition. However, both forces are always constrained to be equal in absolute amount everywhere on the shell, equator included. The derived shape, given by the figure of revolution around the x-axis of x = square root (y-1-72), will prove useful in large-scale space construction. Also, various engineering problems are discussed.

Covington, Tatiana↗