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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Minimum time and fuel flight profiles for an F-15 airplane with a Highly Integrated Digital Electronic Control (HIDEC) system

A simulation study was conducted to optimize minimum time and fuel consumption paths for an F-15 airplane powered by two F100 Engine Model Derivative (EMD) engines. The benefits of using variable stall margin (uptrim) to increase performance were also determined. This study supports the NASA Highly Integrated Digital Electronic Control (HIDEC) program. The basis for this comparison was minimum time and fuel used to reach Mach 2 at 13,716 m (45,000 ft) from the initial conditions of Mach 0.15 at 1524 m (5000 ft). Results were also compared to a pilot's estimated minimum time and fuel trajectory determined from the F-15 flight manual and previous experience. The minimum time trajectory took 15 percent less time than the pilot's estimate for the standard EMD engines, while the minimum fuel trajectory used 1 percent less fuel than the pilot's estimate for the minimum fuel trajectory. The F-15 airplane with EMD engines and uptrim, was 23 percent faster than the pilot's estimate. The minimum fuel used was 5 percent less than the estimate.

Haering, E. A., Jr.↗
NASA NTRS1986

F-106 data summary and model results relative to threat criteria and protection design analysis

The NASA F-106 has acquired considerable data on the rates-of-change of electromagnetic parameters on the aircraft surface during 690 direct lightning strikes while penetrating thunderstorms at altitudes ranging from 15,000 to 40,000 feet. These in-situ measurements have provided the basis for the first statistical quantification of the lightning electromagnetic threat to aircrat appropriate for determining lightning indirect effects on aircraft. The data are presently being used in updating previous lightning criteria and standards developed over the years from ground-based measurements. The new lightning standards will, therefore, be the first which reflect actual aircraft responses measured at flight altitudes. The modeling technique developed to interpret and understand the direct strike electromagnetic data acquired on the F-106 provides a means to model the interaction of the lightning channel with the F-106. The reasonable results obtained with the model, compared to measured responses, yield confidence that the model may be credibly applied to other aircraft types and uses in the prediction of internal coupling effects in the design of lightning protection for new aircraft.

Pitts, F. L.↗
NASA NTRS1988

Surface flow visualization of separated flows on the forebody of an F-18 aircraft and wind-tunnel model

A method of in-flight surface flow visualization similar to wind-tunnel-model oil flows is described for cases where photo-chase planes or onboard photography are not practical. This method, used on an F-18 aircraft in flight at high angles of attack, clearly showed surface flow streamlines in the fuselage forebody. Vortex separation and reattachment lines were identified with this method and documented using postflight photography. Surface flow angles measured at the 90 and 270 degrees meridians show excellent agreement with the wind tunnel data for a pointed tangent ogive with an aspect ratio of 3.5. The separation and reattachment line locations were qualitatively similar to the F-18 wind-tunnel-model oil flows but neither the laminar separation bubble nor the boundary-layer transition on the wind tunnel model were evident in the flight surface flows. The separation and reattachment line locations were in fair agreement with the wind tunnel data for the 3.5 ogive. The elliptical forebody shape of the F-18 caused the primary separation lines to move toward the leeward meridian. Little effect of angle of attack on the separation locations was noted for the range reported.

Fisher, David F.↗
NASA NTRS1995

An overview of integrated flight-propulsion controls flight research on the NASA F-15 research airplane

The NASA Dryden Flight Research Center has been conducting integrated flight-propulsion control flight research using the NASA F-15 airplane for the past 12 years. The research began with the digital electronic engine control (DEEC) project, followed by the F100 Engine Model Derivative (EMD). HIDEC (Highly Integrated Digital Electronic Control) became the umbrella name for a series of experiments including: the Advanced Digital Engine Controls System (ADECS), a twin jet acoustics flight experiment, self-repairing flight control system (SRFCS), performance-seeking control (PSC), and propulsion controlled aircraft (PCA). The upcoming F-15 project is ACTIVE (Advanced Control Technology for Integrated Vehicles). This paper provides a brief summary of these activities and provides background for the PCA and PSC papers, and includes a bibliography of all papers and reports from the NASA F-15 project.

Burcham, Frank W., Jr.↗
NASA NTRS2002

University Nanosatellite Program ION-F Constellation

The Space Engineering program at Utah State University has developed a small satellite, known as USUSat, under funding from AFOSR, AFRL, NASA and Utah State University's Space Dynamics Laboratory. This satellite was designed and significantly manufactured by students in the Mechanical and Aerospace Engineering and the Electrical and Computer Engineering Departments within the College of Engineering. USUSat is one of three spacecraft being designed for the Ionospheric Observation Nanosatellite Formation (ION- F). This formation comprises three 15 kg. spacecraft designed and built in cooperation by Utah State University, University of Washington, and Virginia Polytechnic Institute. The ION-F satellites are being designed and built by students at the three universities, with close coordination to insure compatibility for launch, deployment, and the formation flying mission. The JON-F mission is part of the U.S. Air Force Research Laboratory (AFRL) University Nanosatellite Program, which provides technology development and demonstrations for the TechSat2l Program. The University Nanosatellite Program involves 10 universities building nanosatellites for a launch in 2004 on two separate space shuttle missions. Additional support for the formation flying demonstration has been provided by NASA's Goddard Space Flight Center.

NANOSATS (NANOSATELLITES)↗
NASA NTRS1999

The Integration of Delta Prime (f)in a Multidimensional Space

Consideration is given to the thickness noise term of the Ffowcs Williams-Hawkings equation when the time derivative is taken explicitly. An interpretation is presented of the integral I = function phi(x)delta-prime(f) dx, where it is initially assumed that the absolute value of Del-f is not equal to 1 on the surface f = 0.

Farassat, F.↗
NASA NTRS2010

The Relation Between Magnetospheric State Parameters and the Occurrence of Plasma Depletion Events in the Night-Time Mid-Latitude F-Region

Studies using all-sky imagers have revealed the presence of various ionospheric irregularities in the night-time mid-latitude F-region. The most prevalent and well known of these are the Medium Scale Traveling Ionospheric Disturbances (MSTIDs) that usually occur when the geomagnetic activity is low, and mid-latitude spread-F plumes that are often observed when the geomagnetic activity is high. The inverse and direct relations between geomagnetic activity (particularly Kp) and the occurrence rate of MSTIDs and midlatitude plumes, respectively, have been observed by several studies using different instruments. In order to understand the underlying causes of these two relations, it is illuminating to better characterize the occurrence of MSTIDs and plumes using multiple magnetospheric state parameters. Here we statistically compare multiple geomagnetic driver and response parameters (such as Kp, AE, Dst, and solar wind parameters) with the occurrence rates of night-time MSTIDs and plumes observed using an all-sky imager at Arecibo Observatory (AO) between 2003 and 2008. The results not only allow us to better distinguish MSTIDs and plumes, but also shed further light on the generation mechanism and electrodynamics of these two different phenomena occurring at night-time in the mid-latitude F-region.

Seker, Ilgin↗
NASA NTRS2011

Characterization of Volume F Trash from Four Recent STS Missions: Weights, Categorization, Water Content

The fate of space-generated solid wastes, including trash, for future missions is under consideration by NASA. Several potential treatment options are under consideration and active technology development. Potential fates for space-generated solid wastes are: Storage without treatment; storage after treatment(s) including volume reduction, water recovery, sterilization, and recovery plus recycling of waste materials. Recycling might be important for partial or full closure scenarios because of the prohibitive costs associated with resupply of consumable materials. For this study, we determined the composition of trash returned from four recent STS missions. The trash material was 'Volume F' trash and other trash, in large zip-lock bags, that accompanied the Volume F trash. This is the first of two submitted papers on these wastes. This one will cover trash content, weight and water content. The other will report on the microbial Characterization of this trash. STS trash was usually made available within 2 days of landing at KSC. The Volume F bag was weighed, opened and the contents were catalogued and placed into one of the following categories: food waste (and containers), drink containers, personal hygiene items - including EVA maximum absorbent garments (MAGs)and Elbow packs (daily toilet wipes, etc), paper, and packaging materials - plastic firm and duct tape. Trash generation rates for the four STS missions: Total wet trash was 0.602 plus or minus 0.089 kg(sub wet) crew(sup -1) d(sup -1) containing about 25% water at 0.154 plus or minus 0.030 kg(sub water) crew(sup -1) d(sup -1) (avg plus or minus stdev). Cataloguing by category: personal hygiene wastes accounted for 50% of the total trash and 69% of the total water for the four missions; drink items were 16% of total weight and 16% water; food wastes were 22% of total weight and 15% of the water; office waste and plastic film were 2% and 11% of the total waste and did not contain any water. The results can be used by NASA to determine requirements and criteria for Waste Management Systems on future missions.

Strayer, Richard F.↗
NASA NTRS2011

Relation Between Magnetospheric State Parameters and the Occurrence of Plasma Depletion Events in the Nighttime Midlatitude F Region

Studies using all-sky imagers have revealed the presence of various ionospheric irregularities in the nighttime midlatitude F region. The most prevalent and well known of these are the medium-scale traveling ionospheric disturbances (MSTIDs) that usually occur when the geomagnetic activity is low and midlatitude spread F plumes that are often observed when the geomagnetic activity is high. The inverse and direct relations between geomagnetic activity and the occurrence rate of MSTIDs and midlatitude plumes, respectively, have been observed by several studies using different instruments; however, most of them focus on MSTIDs only and use only Kp to characterize geomagnetic activity. In order to understand the underlying causes of these two relations and to distinguish between MSTIDs and plumes, it is illuminating to better characterize the occurrence of MSTIDs and plumes using multiple magnetospheric state parameters. Here we statistically compare multiple geomagnetic driver and response parameters (such as Kp, AE, Dst, and solar wind parameters) with the occurrence rates of nighttime MSTIDs and plumes observed using an all ]sky imager at Arecibo Observatory (AO) between 2003 and 2008. We also present seasonal and annual variations of MSTIDs and plumes at AO. The results not only allow us to better distinguish MSTIDs and plumes, but also to shed further light on the generation mechanism and electrodynamics of these two different phenomena occurring at nighttime in the midlatitude F region.

Seker, Ilgin↗
NASA NTRS2012

Three-Dimensional Numerical Simulations of Equatorial Spread F: Results and Observations in the Pacific Sector

A three-dimensional numerical simulation of plasma density irregularities in the postsunset equatorial F region ionosphere leading to equatorial spread F (ESF) is described. The simulation evolves under realistic background conditions including bottomside plasma shear flow and vertical current. It also incorporates C/NOFS satellite data which partially specify the forcing. A combination of generalized Rayleigh-Taylor instability (GRT) and collisional shear instability (CSI) produces growing waveforms with key features that agree with C/NOFS satellite and ALTAIR radar observations in the Pacific sector, including features such as gross morphology and rates of development. The transient response of CSI is consistent with the observation of bottomside waves with wavelengths close to 30 km, whereas the steady state behavior of the combined instability can account for the 100+ km wavelength waves that predominate in the F region.

ALTAIR↗
DOE OSTI2021

A chemical kinetic mechanism for combustion and flame propagation of CH 2 F 2 /O 2 /N 2 mixtures

Here in this work, we compiled and evaluated rate expressions for reactions relevant to the decomposition and combustion of CH 2 F 2 (difluoromethane, refrigerant R-32) in CH 2 F 2 /O 2 /N 2 flames. The recommended values have been used in premixed flame calculations, reported elsewhere, to model experimentally derived burning velocities determined using a constant volume spherical flame method. In this work, we also provide a detailed description of the reaction pathways for decomposition and combustion of CH 2 F 2 . This work is part of a larger effort at NIST to characterize and predict the flammability of new refrigerant working fluids and their blends for consideration as replacements of current refrigerants with high global warming potentials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Itinerant to relocalized transition of f electrons in the Kondo insulator CeRu 4 Sn 6

In this study, the three-dimensional electronic structure and the nature of Ce 4 f electrons of the Kondo insulator CeRu 4 Sn 6 are investigated by angle-resolved photoemission spectroscopy, utilizing tunable photon energies. Our results reveal (i) the three-dimensional k -space nature of the Fermi surface, (ii) the localized-to-itinerant transition of f electrons occurs at a much high temperature than the hybridization gap opening temperature, and (iii) the "relocalization" of itinerant f electrons below 25 K, which could be the precursor to the establishment of magnetic order.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Mastering the synergy between Na 3 V 2 (PO 4 ) 2 F 3 electrode and electrolyte: A must for Na-ion cells

Sodium-ion batteries are emerging as suitable energy storage devices for special applications such as high-power devices with the advantages of being cheaper and more sustainable than the Li-ion equivalents. The sodium ion cells consisting of polyanionic Na 3 V 2 (PO 4 ) 2 F 3 - hard carbon electrodes exhibit high power rate capabilities but limited cycle life, especially at high temperatures. To circumvent this drawback we herein conducted in-depth analyses of the origins of structural degradations occurring in Na 3 V 2 (PO 4 ) 2 F 3 electrodes upon long cycling. Vanadium dissolution with associated parasitic reactions is identified as one of the major reasons for cell failure. Its amount varies depending on the electrolyte, with NaTFSI-based electrolyte showing the least vanadium dissolution as the TFSI - anion decomposes without producing acidic impurities, in contrast to the NaPF 6 -based electrolyte. The dissolved vanadium species undergoes oxidation and reduction processes at the Na 3 V 2 (PO 4 ) 2 F 3 and HC electrodes, respectively, with the electrochemical signature of these processes being used as a fingerprint to identify state of health of the 18650 cells. Here, having found that surface reactivity is the primary cause of vanadium dissolution we provide methods to mitigate it by combining surface coating and optimized electrolyte formulation.

25 ENERGY STORAGE↗
DOE OSTI2020

Spectroscopic study and lifetime measurement of the 6d7p 3 F 2 o state of radium

We report a method for the precision measurement of the oscillator strengths and the branching fractions of the decay channels of the 6d7p 3 F 2 o state in 226 Ra. Here, this method exploits a set of metastable states present in Ra, allowing a measurement of the oscillator strengths that does not require knowledge of the number of atoms in the atomic beam. We measure the oscillator strengths and the branching fractions for decays from the 6d7p 3 F 2 o state to the 7s6d 3 D 1 , 7s6d 3 D 2 , and 7s6d 1 D 2 states and constrain the branching fraction to the 7s6d 3 D 3 state to be less than 0.4% (68% confidence limit). The lifetime of the 3 F 2 o state is determined to be 15 ± 4 ns.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

Anhydrous vs Hydrated f-Element Acetate Polymers Dictated by the Stoichiometry of Protic Acidic/Basic Azole Mixtures

Continuing our investigations of ionic liquid (IL) based routes to a library of f-element/soft donor complexes which could be studied crystallographically, we have explored the dissolution of f-element salts in protic imidazole-based ILs containing only soft donors at high temperatures to drive off volatiles, including water and carboxylic or mineral acids. Here we present our results, reacting acidic and basic azoles in 1:3 or 1:1 stoichiometric compositions at elevated temperature, followed by saturation with Nd(OAc) 3 ·xH 2 O or Ce(OAc) 3 ·xH 2 O, which led to 13 new metal–acetate polymeric complexes identified by single-crystal X-ray diffraction. We found that the diversity in coordination modes of the simple acetate ligand that interfere with substitution of the softer N donors led to several readily crystallizable complexes forming two distinct groups with respect to f-element interaction with the ionic liquid precursors. When the acidic/basic azole ratio was 1:3, acetate and a neutral basic azole were found to be coordinated to the metal centers but no water, although in one case (2) water was observed in the secondary coordination sphere: [Ce(μ 2 -OAc) 3 (C 1 im)] n (1, C 1 im = 1-methylimidazole), [Nd(μ 2 -(OAc) 3 (C 1 im)] n ·nH 2 O (2), [Ce(μ 2 -OAc) 3 (C 2 im)] n (3, C 2 im = 1-ethylimidazole), [Ln(μ 2 -OAc) 3 DMF] n (Ln = Nd (4), Ce (5); dimethylformamide (DMF) was substituted for the azole mixture), and [Nd(μ 2 -OAc) 3 (C 4 im)] n (6, C 4 im = 1-butylimidazole). However, when the stoichiometric ratio was 1:1, water was always observed coordinated to the metal ions with the acidic azole included in the structure as a solvate or cocrystal, despite a higher reaction temperature: [Nd(μ 2 -OAc) 3 (OH 2 )] n ·n(1,2,3-Taz) (7, 1,2,3-Taz = 1,2,3-triazole), [Ln(μ 2 -OAc) 3 (OH 2 )] n ·n(4,5-DCim) (Ln = Nd (8), Ce (9), 4,5-DCim = 4,5-dicyanoimidazole), [Ln(μ 2 -OAc) 3 (OH 2 )] n ·n(3,5-diNH 2 -1,2,4-Taz) (Ln = Nd (10), Ce (11), 3,5-diNH 2 -1,2,4-Taz = 3,5-diamino-1,2,4-triazole), [Ce(μ 2 -OAc) 3 (OH 2 )] n ·n(3-NH 2 -1,2,4-Taz) (12, 3-NH 2 -1,2,4-Taz = 3-amino-1,2,4-triazole), and [Nd(μ 2 -OAc) 3 (OH 2 )] n ·n(5-NH 2 -Tz) (13, 5-NH2-Tz = 5-aminotetrazole). All of the compounds retain the Ln:OAc– ratio of 1:3 and form 1D polymeric chains; however, they exhibit a variety of coordination modes affecting the degree of chain condensation. The isolation of both hydrated and anhydrous products revealed different abilities of the investigated soft N-donors to compete with O-donors finding their place in the coordination sphere of the lanthanide or in the crystal lattice.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Hybrid Double Perovskite Containing Helium: [He 2 ][CaZr]F 6

Perovskites are of great technological and geological importance, in large part, due to their considerable compositional and structural flexibility. However, the formation of perovskites with neutral species on their A-sites is very unusual. The formation, phase transitions and properties of [He 2 ][CaZr]F 6 , which is the first noble gas containing perovskite to be made, are reported. It is likely that a large family of related materials can also be prepared. On compression in neon, the negative thermal expansion (NTE) material CaZrF 6 amorphizes at ~ 0. 5 GPa. However, on compression in helium at room temperature, gas is inserted into the structure to form a perovskite with helium on the A-site. This suppresses the amorphization until > 3 GPa. Volume versus pressure and Raman measurements suggest that filling of the A-site, to give [He 2 ][CaZr]F 6 , is complete at > 1 GPa. The presence of helium on the A-site in this perovskite leads to a reduction in the magnitude of negative thermal expansion when compared to the parent phase CaZrF 6 , likely due to steric impediment of the transverse vibrational motion of fluoride. The helium also leads to considerable stiffening of the structure. At room temperature and ~2.5 GPa, the helium containing hybrid perovskite has a bulk modulus of ~ 47 GPa, whereas CaZrF 6 has a bulk modulus of ~ 40 GPa at ambient. At 15 K, the cubic perovskite [He 2 ][CaZr]F 6 undergoes a structural phase transition, that likely involves a cooperative tilting of framework octahedra to give a lower-symmetry phase, which is tentatively assigned as tetragonal.

36 MATERIALS SCIENCE↗
DOE OSTI2026

NOCI-F Electronic Couplings in Assemblies of Indolonaphthyridine Molecules: From Dimers to the Full Stack

Key electronic processes related to molecular excitonic states of finite stacks of indolonaphthyridine molecules are analyzed via the non-orthogonal configuration interaction with fragments (NOCI-F) method. Indolonaphthyridine is an organic chromophore that can undergo several electronic photoexcitation-related intermolecular processes, such as exciton and electron transfer. The structures studied here are noncrystalline arrangements built as either ordered stacks of indolonaphthyridine or stacks extracted from molecular dynamics simulations including thermal disorder. Taking dimers or trimers from either model, we performed CASSCF and NOCI-F calculations to quantify the intermolecular electronic couplings governing singlet fission, excited singlet and triplet diffusion, and hole and electron diffusion processes. Also, comparing the results for the different models, we studied the effect of structural disorder and distortion on these couplings. Finally, we present a newly developed, advanced postanalysis tool. It takes the NOCI-F data as input to carry out a multifragment full Hamiltonian procedure that involves the complete stack, providing physical information not available from the dimer/trimer models, hence giving access to additional insight into the material’s properties.

coupling reactions↗
DOE OSTI2023

Coupled Cluster Study of the Heats of Formation of UF 6 and the Uranium Oxyhalides, UO 2 X 2 (X = F, Cl, Br, I, and At)

The atomization enthalpies of the U(VI) species UF6 and the uranium oxyhalides UO 2 X 2 (X=F, Cl, Br, I, At) were calculated using a composite relativistic Feller-Peterson-Dixon (FPD) approach based on scalar relativistic DKH3-CCSD(T) with extrapolations to the CBS limit. The inherent multideterminantal nature of the U atom was mitigated by utilizing the singly charged atomic cation in all calculations with correction back to the neutral asymptote via the accurate ionization energy of the U atom. The effects of SO coupling were recovered using full 4-component CCSD(T) with contributions due to the Gaunt Hamiltonian calculated using Dirac-Hartree-Fock. The final atomization enthalpy for UF 6 (752.2 kcal/mol) was within 2.5 kcal/mol of the experimental value, but unfortunately the latter carries a ±2.4 kcal/mol uncertainty that is predominantly due to the experimental uncertainty in the formation enthalpy of U atom. The analogous value for UO 2 F 2 (607.6 kcal/mol) was in nearly exact agreement with experiment, but the latter has a stated experimental uncertainty of ±4.3 kcal/mol. The FPD atomization enthalpy for UO 2 Cl 2 (540.4 kcal/mol) was within the experimental error limits of ±5.5 kcal/mol. FPD atomization energies for the non-U-containing molecules (used for reaction enthalpies) H 2 O and HX (X=F, Cl, Br, I, At) were within at most 0.3 kcal/mol of their experimental values where available. The FPD atomization enthalpies, together with FPD reaction enthalpies for two different reactions, were used to determine heats of formation for all species of this work with estimated uncertainties of ±4 kcal/mol. The calculated heat of formation for UF 6 (-511.0 kcal/mol) is within 2.5 kcal/mol of the accurately-known (±0.45 kcal/mol) experimental value.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗