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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Vapor Pressures of RDX and HMX Explosives Measured at and Near Room Temperature: 1,3,5-Trinitro-1,3,5-triazinane and 1,3,5,7-Tetranitro-1,3,5,7-tetrazocane

Knowing accurate saturated vapor pressures of explosives at ambient conditions is imperative to provide realistic boundaries on available vapor for ultra-trace detection. In quantifying vapor content emanating from low-volatility explosives, we observed discrepancies between the quantity of explosive expected based on literature vapor pressure values and the amount detected near ambient temperatures. Most vapor pressure measurements for low-volatility explosives, such as RDX (1,3,5-trinitro-1,3,5-triazinane) and HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocane), have been made at temperatures far exceeding 25 °C and linear extrapolation of these higher temperature trends appears to underestimate vapor pressures near room temperature. Our goal was to measure vapor pressures as a function of temperature closer to ambient conditions. We used saturated RDX and HMX vapor sources at controlled temperatures to produce vapors that were then collected and analyzed via atmospheric flow tube-mass spectrometry (AFT-MS). The parts-per-quadrillion (ppqv) sensitivity of AFT-MS enabled measurement of RDX vapor pressures at temperatures as low as 7 °C and HMX vapor pressures at temperatures as low as 40 °C for the first time. Furthermore, these vapor pressures were corroborated with analysis of vapor generated by nebulizing low concentration solutions of RDX and HMX. We report updated vapor pressure values for both RDX and HMX. Based on our measurements, the vapor pressure of RDX at 25 °C is 3 ± 1 x 10-11 atm (i.e. 30 parts per trillion by volume, pptv), the vapor pressure of HMX is 1.0 ± 0.6 x 10-14 atm (10 ppqv) at 40 °C and, with extrapolation, HMX has a vapor pressure of 1.0 ± 0.6 x 10-15 atm (1.0 ppqv) at 25 °C.

RDX, HMX, explosives, vapor pressure, vapor detect↗
DOE OSTI2022

Detecting Large Explosions With Machine Learning Models Trained on Synthetic Infrasound Data

Explosions produce low-frequency acoustic (infrasound) waves capable of propagating globally, but the spatio-temporal variability of the atmosphere makes detecting events difficult. Machine learning (ML) is well-suited to identify the subtle and nonlinear patterns in explosion infrasound signals, but a previous lack of ground-truth data inhibited training of generalized models. We introduce a physics-based method that propagates infrasound sources through realistic atmospheres to create 28,000 synthetic events, which are used to train ML classifiers. A simple artificial neural network and modern temporal convolutional network discriminate synthetic events from background noise with >90% accuracy and, more importantly, successfully identify the majority of real-world explosion signals recorded during the Humming Road Runner experiment. ML models trained entirely on physics-based synthetics advance explosion detection capabilities and make ML more viable to related fields lacking training data.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2014

Communication: Determining the structure of the N{sub 2}Ar van der Waals complex with laser-based channel-selected Coulomb explosion

We experimentally reconstructed the structure of the N{sub 2}Ar van der Waals complex with the technique of laser-based channel-selected Coulomb explosion imaging. The internuclear distance between the N{sub 2} center of mass and the Ar atom, i.e., the length of the van der Waals bond, was determined to be 3.88 Å from the two-body explosion channels. The angle between the van der Waals bond and the N{sub 2} principal axis was determined to be 90° from the three-body explosion channels. The reconstructed structure was contrasted with our high level ab initio calculations. The agreement demonstrated the potential application of laser-based Coulomb explosion in imaging transient molecular structure, particularly for floppy van der Waals complexes, whose structures remain difficult to be determined by conventional spectroscopic methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Contributed Review: Quantum cascade laser based photoacoustic detection of explosives

Detecting trace explosives and explosive-related compounds has recently become a topic of utmost importance for increasing public security around the world. A wide variety of detection methods and an even wider range of physical chemistry issues are involved in this very challenging area. Optical sensing methods, in particular mid-infrared spectrometry techniques, have a great potential to become a more desirable tools for the detection of explosives. The small size, simplicity, high output power, long-term reliability make external cavity quantum cascade lasers (EC-QCLs) the promising spectroscopic sources for developing analytical instrumentation. This work reviews the current technical progress in EC-QCL-based photoacoustic spectroscopy for explosives detection. The potential for both close-contact and standoff configurations using this technique is completely presented over the course of approximately the last one decade.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2016

Scaled experiments of explosions in cavities

Consequences of an explosion inside an air-filled cavity under the earth's surface are partly duplicated in a laboratory experiment on spatial scales 1000 smaller. The experiment measures shock pressures coupled into a block of material by an explosion inside a gas-filled cavity therein. The explosion is generated by suddenly heating a thin foil that is located near the cavity center with a short laser pulse, which turns the foil into expanding plasma, most of whose energy drives a blast wave in the cavity gas. Variables in the experiment are the cavity radius and explosion energy. Measurements and GEODYN code simulations show that shock pressuresmeasured in the block exhibit a weak dependence on scaled cavity radius up to ~25 m/kt 1/3 , above which they decrease rapidly. Possible mechanisms giving rise to this behavior are described. As a result, the applicability of this work to validating codes used to simulate full-scale cavityexplosions is discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2016

A novel method for the measurement of the von Neumann spike in detonating high explosives

We present detonation wave profiles measured in T2 (97 wt. % TATB) and TX1 (52 wt. % TATB and 45 wt. % HMX) high explosives. The experiments consisted in initiating a detonation wave in a 15 mm diameter cylinder of explosive using an explosive wire detonator and an explosive booster. Free surface velocity wave profiles were measured at the explosive/air interface using a Photon Doppler Velocimetry system. We demonstrate that a comparison of these free surface wave profiles with those measured at explosive/window interfaces in similar conditions allows to bracket the von Neumann spike in a narrow range. For T2, our measurements show that the spike pressure lies between 35.9 and 40.1 GPa, whereas for TX1, it lies between 42.3 and 47.0 GPa. The numerical simulations performed in support to these measurements show that they can be used to calibrate reactive burn models and also to check the accuracy of the detonation products equation of state at low pressure.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Development of an FPGA-based multipoint laser pyroshock measurement system for explosive bolts

Pyroshock can cause failure to the objective of an aerospace structure by damaging its sensitive electronic equipment, which is responsible for performing decisive operations. A pyroshock is the high intensity shock wave that is generated when a pyrotechnic device is explosively triggered to separate, release, or activate structural subsystems of an aerospace architecture. Pyroshock measurement plays an important role in experimental simulations to understand the characteristics of pyroshock on the host structure. This paper presents a technology to measure a pyroshock wave at multiple points using laser Doppler vibrometers (LDVs). These LDVs detect the pyroshock wave generated due to an explosive-based pyrotechnical event. Field programmable gate array (FPGA) based data acquisition is used in the study to acquire pyroshock signals simultaneously from multiple channels. This paper describes the complete system design for multipoint pyroshock measurement. The firmware architecture for the implementation of multichannel data acquisition on an FPGA-based development board is also discussed. An experiment using explosive bolts was configured to test the reliability of the system. Pyroshock was generated using explosive excitation on a 22-mm-thick steel plate. Three LDVs were deployed to capture the pyroshock wave at different points. The pyroshocks captured were displayed as acceleration plots. The results showed that our system effectively captured the pyroshock wave with a peak-to-peak magnitude of 303 741 g. The contribution of this paper is a specialized architecture of firmware design programmed in FPGA for data acquisition of large amount of multichannel pyroshock data. The advantages of the developed system are the near-field, multipoint, non-contact, and remote measurement of a pyroshock wave, which is dangerous and expensive to produce in aerospace pyrotechnic tests.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Shock initiation of the HMX-based explosive PBX 9012: Experiments, uncertainty analysis, and unreacted equation-of-state

In this study, shock initiation experiments have been carried out on the polymer-bonded explosive PBX 9012 [nominally 90% octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazine (HMX), 10% vinylidene–hexafluoropropylene copolymer (Viton A) by weight] in order to provide calibration data for the explosive’s unreacted equation-of-state (EOS) and shock-to-detonation transition for reactive burn rate calibration. The input pressures covered the range of 1.86–4.43 GPa. This provided run-to-detonation depths ranging from > 22.3 mm for the lowest pressure shot to 4.91 mm at the highest pressure. The relative shock sensitivity of PBX 9012 is compared to other HMX-explosives in terms of the Pop-plot, showing that the studied explosive is more sensitive than other similar HMX-based counterparts (with notable exceptions). The uncertainty in the shock velocity determinations from the shock tracker measurements are also investigated, yielding new uncertainty measures in the generated Hugoniot data and run-to-detonation coordinates. Finally, the unreacted equation-of-state is determined using a linear U s – u p Mie–Grüneisen relation and the Davis reactants EOS analytical form, the latter being more suited for reactive burn modeling.

36 MATERIALS SCIENCE↗
DOE OSTI2023

A study of explosive-induced fracture in polymethyl methacrylate (PMMA)

The fracture response of geologic materials is of interest for applications, including geothermal energy harnessing and containment of underground explosions. To better understand the explosively induced fracture response of geomaterials, polymethyl methacrylate (PMMA) was used as a transparent rock surrogate to allow imaging of internal shock propagation and fracture growth processes. Experiments were conducted using high-speed shadowgraphy and photon Doppler velocimetry (PDV), which were compared to numerical simulations. Experiments measured fractures produced in 304.8mm × 304.8mm × 304.8mm PMMA cubes with two simultaneously initiated detonators. The cubes were subjected to varying amounts and directions of externally applied uniaxial stresses, including no stress, 2 MPa stress, and 20 MPa stress. The fracture radius as a function of time was extracted from the high-speed videos. Post-test images of the PMMA cubes aided in the determination of three-dimensional effects not directly imaged by the cameras. The surface velocity history and the shock response captured in PDV and the high-speed videos were compared to the simulated explosive-induced shock response. The simulation results indicate that the shock drives the fracture for the first 20 μs corresponding to a fracture radius of approximately 15 mm in the experiments. The gas-driven fracture extent was estimated analytically using an equilibrium stress distribution calculated after the shock wave propagation through the sample. Reduction in the gas pressure due to the leakage of the explosive products through the crack as a function of time was accounted for. In conclusion, the estimated fracture lengths were in agreement with the experimentally observed fracture lengths.

15 GEOTHERMAL ENERGY↗
DOE OSTI2011

GRAVITATIONAL WAVE SIGNATURES OF MAGNETOHYDRODYNAMICALLY DRIVEN CORE-COLLAPSE SUPERNOVA EXPLOSIONS

By performing a series of two-dimensional, special relativistic magnetohydrodynamic (MHD) simulations, we study signatures of gravitational waves (GWs) in the MHD-driven core-collapse supernovae. In order to extract the gravitational waveforms, we present a stress formula including contributions both from magnetic fields and special relativistic corrections. By changing the precollapse magnetic fields and initial angular momentum distributions parametrically, we compute 12 models. As for the microphysics, a realistic equation of state is employed and the neutrino cooling is taken into account via a multiflavor neutrino leakage scheme. With these computations, we find that the total GW amplitudes show a monotonic increase after bounce for models with a strong precollapse magnetic field (10{sup 12} G) and with a rapid rotation imposed. We show that this trend stems both from the kinetic contribution of MHD outflows with large radial velocities and also from the magnetic contribution dominated by the toroidal magnetic fields that predominantly trigger MHD explosions. For models with weaker initial magnetic fields, the total GW amplitudes after bounce stay close to zero because the contribution from the magnetic fields cancels with the contribution from the hydrodynamic counterpart. These features can be clearly understood with a careful analysis of the explosion dynamics. We point out that the GW signals with the increasing trend, possibly visible to the next-generation detectors for a Galactic supernova, would be associated with MHD explosions with explosion energies exceeding 10{sup 51} erg.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

COMPACT REMNANT MASS FUNCTION: DEPENDENCE ON THE EXPLOSION MECHANISM AND METALLICITY

The mass distribution of neutron stars and stellar-mass black holes provides vital clues into the nature of stellar core collapse and the physical engine responsible for supernova explosions. A number of supernova engines have been proposed: neutrino- or oscillation-driven explosions enhanced by early (developing in 10-50 ms) and late-time (developing in 200 ms) convection as well as magnetic field engines (in black hole accretion disks or neutron stars). Using our current understanding of supernova engines, we derive mass distributions of stellar compact remnants. We provide analytic prescriptions for both single-star models (as a function of initial star mass) and for binary-star models-prescriptions for compact object masses for major population synthesis codes. These prescriptions have implications for a range of observations: X-ray binary populations, supernova explosion energies, and gravitational wave sources. We show that advanced gravitational radiation detectors (like LIGO/VIRGO or the Einstein Telescope) will be able to further test the supernova explosion engine models once double black hole inspirals are detected.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Simultaneous observation of a hot explosion by NST and IRIS

We present the first simultaneous observations of so-called “hot explosions” in the cool atmosphere of the Sun made by the New Solar Telescope (NST) of Big Bear Solar Observatory and the Interface Region Imaging Spectrograph (IRIS) in space. The data were obtained during the joint IRIS-NST observations on 2014 July 30. The explosion of interest started around 19:20 UT and lasted for about 10 minutes. Our findings are as follows: (1) the IRIS brightening was observed in three channels of slit-jaw images, which cover the temperature range from 4000 to 80,000 K; (2) during the brightening, the Si iv emission profile showed a double-peaked shape with highly blue and redshifted components (−40 and 80 km s{sup −1}); (3) wing brightening occurred in Hα and Ca ii 8542 Å bands and related surges were observed in both bands of the NST Fast Imaging Solar Spectrograph (FISS) instrument; (4) the elongated granule, seen in NST TiO data, is clear evidence of the emergence of positive flux to trigger the hot explosion; (5) the brightening in Solar Dynamics Observatory/Atmospheric Imaging Assembly 1600 Å images is quite consistent with the IRIS brightening. These observations suggest that our event is a hot explosion that occurred in the cool atmosphere of the Sun. In addition, our event appeared as an Ellerman bomb (EB) in the wing of Hα, although its intensity is weak and the vertical extent of the brightening seems to be relatively high compared with the typical EBs.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Statistical analysis of correlations in the x-ray induced Coulomb explosion of iodopyridine

Coulomb explosion imaging is a promising experimental tool to study individual molecules. Here, in this work simulation data for the x-ray induced Coulomb explosion of 2-iodopyridine is analyzed and the involved fragmentation dynamics are described. It is found that particular final ion momenta show correlations that reflect a collision of two atoms during the explosion. Variations of the proton kinetic energies can be associated with variations in the charge build-up time. Covariances of the forces during the explosion can be utilized to simplify the description of the dynamics in reduced dimensionality using only four collective coordinates.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2012

Residual Stress Measurements of Explosively Clad Cylindrical Pressure Vessels

Tantalum refractory liners were explosively clad into cylindrical pressure vessels, some of which had been previously autofrettaged. Using explosive cladding, the refractory liner formed a metallurgical bond with the steel of the pressure vessel at a cost of induced strain. Two techniques were employed to determine the residual stress state of the clad steel cylinders: neutron diffraction and mechanical slitting. Neutron diffraction is typically nondestructive; however, due to attenuation along the beam path, the cylinders had to be sectioned into rings that were nominally 25 mm thick. Slitting is a destructive method, requiring the sectioning of the cylindrical samples. Both techniques provided triaxial stress data and useful information on the effects of explosive cladding. The stress profiles in the hoop and radial directions were similar for an autofrettaged, nonclad vessel and a clad, nonautofrettaged vessel. The stress profiles in the axial direction appeared to be different. Further, the data suggested that residual stresses from the autofrettage and explosive cladding processes were not additive, in part due to evidence of reverse yielding. The residual stress data are presented, compared and discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Rapid clay precipitation in explosion-induced fractures

Fractures within the earth control rock strength and fluid flow, but their dynamic nature is not well understood. As part of a series of underground chemical explosions in granite in Nevada, we collected and analyzed microfracture density data sets prior to, and following, individual explosions. Our work shows an ~4-fold increase in both open and filled microfractures following the explosions. Based on the timing of core retrieval, filling of some new fractures occurs in as little as 6 wk after fracture opening under shallow (<100 m) crustal conditions. These results suggest that near-surface fractures may fill quite rapidly, potentially changing permeability on time scales relevant to oil, gas, and geothermal energy production; carbon sequestration; seismic cycles; and radionuclide migration from nuclear waste storage and underground nuclear explosions.

58 GEOSCIENCES↗
DOE OSTI2018

Laser Simulations of the Destructive Impact of Nuclear Explosions on Hazardous Asteroids

We present the results of preliminary experiments at laser facilities in which the processes of the undeniable destruction of stony asteroids (chondrites) in space by nuclear explosions on the asteroid surface are simulated based on the principle of physical similarity. We present the results of comparative gasdynamic computations of a model nuclear explosion on the surface of a large asteroid and computations of the impact of a laser pulse on a miniature asteroid simulator confirming the similarity of the key processes in the fullscale and model cases. The technology of fabricating miniature mockups with mechanical properties close to those of stony asteroids is described. For mini-mockups 4–10 mm in size differing by the shape and impact conditions, we have made an experimental estimate of the energy threshold for the undeniable destruction of a mockup and investigated the parameters of its fragmentation at a laser energy up to 500 J. The results obtained confirm the possibility of an experimental determination of the criteria for the destruction of asteroids of various types by a nuclear explosion in laser experiments. We show that the undeniable destruction of a large asteroid is possible at attainable nuclear explosion energies on its surface.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Improved Parametric Models for Explosion Pressure Signals Derived From Large Datasets

Accurate recording and characterization of explosion-induced pressure signals are key components of the forensic analysis of explosion events in the atmosphere. Parametric overpressure models based on several key waveform features (peak overpressure, positive pulse duration, and impulse) are widely used to estimate explosion energy in terms of trinitrotoluene equivalent yield. However, those models are often developed by a limited dataset, including only a few events or recordings at relatively short propagation distances. Here, we develop empirical waveform-parameter models based on a regression analysis of a large set of data curated from four chemical explosion experiments including 16 detonations. We measured peak overpressure and impulse for positive and negative phases from 1000 pressure signals recorded at local ranges (<20 km) with scaled distance up to 8000 m/kg 1/3 . Additionally, the measured waveform parameters showed large variation with respect to observing distances indicating the effects of atmospheric propagation. In this study, a second-order polynomial model was used in a least-squares regression to account for those propagation effects and to improve data fitting. In addition to model parameters for waveform features, we also determined range-dependent model uncertainties based on data variance. The model uncertainty represents the prediction error of our models and can be critical to evaluating the uncertainty of yield estimate.

58 GEOSCIENCES↗
DOE OSTI2020

Beirut Explosion Yield and Mushroom Cloud Height - Effects of the Source Environment

I use crater dimensions to estimate the yield of the August 4th, 2020 Beirut explosion to be equivalent to approximately 1.4 kilotons of TNT with a lower bound of about 0.7 kilotons. Based on the amount of ammonium nitrate reported to have been stored at the Beirut harbor, I assume an upper bound for the yield of 2.75 kilotons. However, it is highly likely that the yield was less than 2.75 kilotons, since reported values for TNT equivalence of ammonium nitrate are typically much less than one hundred percent. The crater-size based yield estimates are based on crater radius estimates from satellite imagery and empirical curves and data for scaled crater radius from past chemical and nuclear explosions. I present evidence that suggests that the relatively large crater radius is due to a high degree of coupling of shock wave energy to the surrounding medium and a reduction of the effective stress because of a high level of saturation of the geologic media beneath the explosion. I provide yield estimates based on seismic body-wave magnitude and crater depth as corroborating evidence. I compare preliminary estimates for the maximum debris cloud height, based on cell phone videos/images, with predicted maximum heights for this yield range from empirical formulas and numerical cloud-rise models. Based on a preliminary analysis of cell phone footage, the observed maximum cloud height appears to be approximately 1600 m. This is much lower than that predicted using standard empirical formulas and buoyant cloud rise models. I present results from a modified buoyant cloud rise model that more accurately predicts the maximum cloud height by allowing for the inclusion of a fixed amount of air and/or water into the fireball at the start of cloud rise. The amount of mass that needs to be added at the start, to reproduce the observed maximum cloud height, is relatively small compared to the total mass entrained during cloud rise. A much greater amount of dry air or debris is required, relative to water, for an equivalent reduction in maximum cloud height. The ammonium nitrate is one possible source for water in the fireball since it was being stored in a very humid environment and ammonium nitrate is known to be hygroscopic. The ground beneath the explosion, especially if it were saturated, and the nearby harbor could also have been sources for water or debris in the fireball.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗