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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

All sources NASA NTRS DOE OSTI

DOE OSTI2016

A new deflection technique applied to an existing scheme of electrostatic accelerator for high energy neutral beam injection in fusion reactor devices

A scheme of a neutral beam injector (NBI), based on electrostatic acceleration and magneto-static deflection of negative ions, is proposed and analyzed in terms of feasibility and performance. The scheme is based on the deflection of a high energy (2 MeV) and high current (some tens of amperes) negative ion beam by a large magnetic deflector placed between the Beam Source (BS) and the neutralizer. This scheme has the potential of solving two key issues, which at present limit the applicability of a NBI to a fusion reactor: the maximum achievable acceleration voltage and the direct exposure of the BS to the flux of neutrons and radiation coming from the fusion reactor. In order to solve these two issues, a magnetic deflector is proposed to screen the BS from direct exposure to radiation and neutrons so that the voltage insulation between the electrostatic accelerator and the grounded vessel can be enhanced by using compressed SF{sub 6} instead of vacuum so that the negative ions can be accelerated at energies higher than 1 MeV. By solving the beam transport with different magnetic deflector properties, an optimum scheme has been found which is shown to be effective to guarantee both the steering effect and the beam aiming.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2016

Positive direct current corona discharges in single wire-duct electrostatic precipitators

This paper is aimed to study the characteristics of the positive dc corona discharges in single wire-duct electrostatic precipitators. Therefore, the corona discharges were formed inside dry air fed single wire-duct reactor under positive dc voltage at the normal atmospheric conditions. The corona current-voltage characteristics curves have been measured in parallel with the ozone concentration generated inside the reactor under different discharge conditions. The corona current-voltage characteristics curves have agreed with a semi empirical equation derived from the previous studies. The experimental results of the ozone concentration generated inside the reactor were formulated in the form of an empirical equation included the different parameters that were studied experimentally. The obtained equations are valid to expect both the current-voltage characteristics curves and the corresponding ozone concentration that generates with the positive dc corona discharges inside single wire-duct electrostatic precipitators under any operating conditions in the same range of the present study.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2016

Computing dispersive, polarizable, and electrostatic shifts of excitation energy in supramolecular systems: PTCDI crystal

The gas-to-crystal-shift denotes the shift of electronic excitation energies, i.e., the difference between ground and excited state energies, for a molecule transferred from the gas to the bulk phase. The contributions to the gas-to-crystal-shift comprise electrostatic as well as inductive polarization and dispersive energy shifts of the molecular excitation energies due to interaction with environmental molecules. For the example of 3,4,9,10-perylene-tetracarboxylic-diimide (PTCDI) bulk, the contributions to the gas-to-crystal shift are investigated. In the present work, electrostatic interaction is calculated via Coulomb interaction of partial charges while inductive and dispersive interactions are obtained using respective sum over states expressions. The coupling of higher transition densities for the first 4500 excited states of PTCDI was computed using transition partial charges based on an atomistic model of PTCDI bulk obtained from molecular dynamics simulations. As a result it is concluded that for the investigated model system of a PTCDI crystal, the gas to crystal shift is dominated by dispersive interaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Atomistic insight into the effects of electrostatic fields on hydrocarbon reaction kinetics

Reactive Molecular Dynamics (MD) and Density Functional Theory (DFT) computations are performed to provide insight into the effects of external electrostatic fields on hydrocarbon reaction kinetics. By comparing the results from MD and DFT, the suitability of the MD method in modeling electrodynamics is first assessed. Results show that the electric field-induced polarization predicted by the MD charge equilibration method is in good agreement with various DFT charge partitioning schemes. Then, the effects of oriented external electric fields on the transition pathways of non-redox reactions are investigated. Results on the minimum energy path suggest that electric fields can cause catalysis or inhibition of oxidation reactions, whereas pyrolysis reactions are not affected due to the weaker electronegativity of the hydrogen and carbon atoms. MD simulations of isolated reactions show that the reaction kinetics is also affected by applied external Lorentz forces and interatomic Coulomb forces since they can increase or decrease the energy of collision depending on the molecular conformation. In addition, electric fields can affect the kinetics of polar species and force them to align in the direction of field lines. These effects are attributed to energy transfer via intermolecular collisions and stabilization under the external Lorentz force. The kinetics of apolar species is not significantly affected mainly due to the weak induced dipole moment even under strong electric fields. The dynamics and reaction rates of species are studied by means of large-scale combustion simulations of n-dodecane and oxygen mixtures. Results show that under strong electric fields, the fuel, oxidizer, and most product molecules experience translational and rotational acceleration mainly due to close charge transfer along with a reduction in their vibrational energy due to stabilization. This study will serve as a basis to improve the current methods used in MD and to develop novel methodologies for the modeling of macroscale reacting flows under external electrostatic fields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

A self-consistent electrostatic electrified shallow water model for charged liquid surface dynamics

The dynamics of an electrified liquid surface are investigated using a shallow water model that is self-consistently coupled with an electrostatic solver. To account for the spatiotemporal variation of a curved liquid surface, the electric field on curved surfaces is calculated by solving a two-dimensional electrostatic equation using the weighted least squares (WLSQ) interpolation method. First, the WLSQ implementation is verified with analytical theory obtained from a Laplace solution assuming a half-cylinder liquid surface profile. Then, the coupled electrified shallow water model is used to study the instability of liquid surface perturbation as a function of the potential drop between an electrode and conducting liquid, surface tension, and gravity. We present a linear dispersion theory of liquid surface instability for long-wavelength perturbations, including the effects of liquid viscosity. Furthermore, the effects of multiple sinusoidal surface perturbations on the electrified liquid surface instability are investigated.

Capillary waves↗

DOE OSTI2021

Enhancing ion transport in charged block copolymers by stabilizing low symmetry morphology: Electrostatic control of interfaces

Recently, the interest in charged polymers has been rapidly growing due to their uses in energy storage and transfer devices. Yet, polymer electrolyte-based devices are not on the immediate horizon because of the low ionic conductivity. In the present study, we developed a methodology to enhance the ionic conductivity of charged block copolymers comprising ionic liquids through the electrostatic control of the interfacial layers. Unprecedented reentrant phase transitions between lamellar and A15 structures were seen, which cannot be explained by well-established thermodynamic factors. X-ray scattering experiments and molecular dynamics simulations revealed the formation of fascinating, thin ionic shell layers composed of ionic complexes. The ionic liquid cations of these complexes predominantly presented near the micellar interfaces if they had strong binding affinity with the charged polymer chains. Therefore, the interfacial properties and concentration fluctuations of the A15 structures were crucially dependent on the type of tethered acid groups in the polymers. Overall, the stabilization energies of the A15 structures were greater when enriched, attractive electrostatic interactions were present at the micellar interfaces. Contrary to the conventional wisdom that block copolymer interfaces act as “dead zone” to significantly deteriorate ion transport, this study establishes a prospective avenue for advanced polymer electrolyte having tailor-made interfaces.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2017

Electrostatic interaction of macroparticles in a plasma in the strong screening regime

We have studied the electrostatic interaction of spherical particles in an equilibrium plasma or an electrolyte in the moderate and strong screening regimes when the macroparticle size is comparable with or much larger than the Debye screening radius. We have developed an approximate theory of the electrostatic interaction of macroparticles in the case of constant potentials of their surfaces in the weak or moderate screening regimes. In this theory, the charges of macroparticles with a fixed spacing between them are determined using vacuum capacitive coefficients, which are corrected taking into account the plasma screening effects. The force of interaction with the resultant charges is calculated based on the solution of the problem of interaction in a homogeneous dielectric (vacuum) and is multiplied by the plasma factor. We have also obtained an approximate solution to the problem in the strong screening regime. Comparison with the exact solution has demonstrated high accuracy of the proposed methods of calculation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2019

Microscopy of Electrostatic Field Effect in Novel Quantum Materials (Final Report)

In this DOE Early Career project “Microscopy of Electrostatic Field Effect in Novel Quantum Materials”, the PI’s group explored the nanoscale electronic properties when charge carriers are electrostatically modulated in functional materials. Using a microwave impedance microscope (MIM), the team probed the spatial evolution of local conductivity in various field-effect transistors (FETs) ranging from traditional metal-oxide-semiconductor FETs, sketched oxide-interface FETs, to ferroelectric FETs and electric double-layer transistors (EDLTs). Specifically, the work has led to a deep understanding on the electrical inhomogeneity and conductive edge channels in atomically thin transition metal dichalcogenides and their heterostructures, which is of fundamental importance for their applications in electronics and photonics. The unique sub-surface imaging capability also enables the first-time report of ferroelectric field effect on Ge substrates due to the polarization switching of an epitaxial BaTiO 3 layer, as well as the visualization of sketched nanostructures in the LaAlO 3 /SrTiO 3 interface. Using a cryogenic MIM, the local channel conductance in ion-gel-gated oxide EDLTs has been successfully imaged, resolving a major challenge in the EDLT research to study electronic fluctuations in the devices. Finally, a new tuning-fork-based MIM has been developed to perform quantitative conductivity imaging on back-gated FETs. The research supported by this DOE grant is significant for understanding the nanoscale uniformity in technologically important materials towards energy applications.

2D materials↗

NASA NTRS1965

Development of electrostatic sensors for scout systems evaluation vehicle, 131r

In the course of a Scout vehicle mission, a static charge may build up on the vehicle and reach sufficiently high values to become potentially dangerous to the vehicle mission. The development of electrostatic sensors for monitoring the potential build-up on a Scout vehicle is discussed in this report. The investigation and studies, which produced the theories tor the electrostatic sensor concepts, are also discussed. The sensors were designed, fabricated and installed on Scout vehicle 131R. Results of the sensor development program are discussed in full; however, at the time this report was completed, the flight experiment had not been accomplished.

Scout Project↗

NASA NTRS2009

Electrostatic Switching in Vertically Oriented Nanotubes for Nonvolatile Memory Applications

We have demonstrated electrostatic switching in vertically oriented nanotubes or nanofibers, where a nanoprobe was used as the actuating electrode inside an SEM. When the nanoprobe was manipulated to be in close proximity to a single tube, switching voltages between 10 V - 40 V were observed, depending on the geometrical parameters. The turn-on transitions appeared to be much sharper than the turn-off transitions which were limited by the tube-to-probe contact resistances. In many cases, stiction forces at these dimensions were dominant, since the tube appeared stuck to the probe even after the voltage returned to 0 V, suggesting that such structures are promising for nonvolatile memory applications. The stiction effects, to some extent, can be adjusted by engineering the switch geometry appropriately. Nanoscale mechanical measurements were also conducted on the tubes using a custom-built anoindentor inside an SEM, from which preliminary material parameters, such as the elastic modulus, were extracted. The mechanical measurements also revealed that the tubes appear to be well adhered to the substrate. The material parameters gathered from the mechanical measurements were then used in developing an electrostatic model of the switch using a commercially available finite-element simulator. The calculated pull-in voltages appeared to be in agreement to the experimentally obtained switching voltages to first order.

plasma-enhanced chemical vapor deposition (PECVD).↗

NASA NTRS2018

Development of the Electrostatic Precipitator (ESP) for Mars and Electrodynamic Dust Shield (EDS)

Kennedy Space Center's Swamp Works is a fast-paced and diverse technology development laboratory that aims to advance commercial and government capabilities to colonize extraterrestrial environments. As a part of Swamp Works, the Electrostatic and Surface Physics Laboratory (ESPL) is currently developing new technologies that will further NASA's capabilities to colonize lunar and Martian environments. At the ESPL, the objective of the overall project is to aid in the dust mitigation of robotic and human exploration missions to the moon and Mars. The moon and Mars are covered with layers of dust, which can make long-term exploration missions very difficult. The team at the ESPL is developing an electrostatic precipitator (ESP) to aid in the reduction of interference from airborne Martian dust on equipment. The ESP is designed to mitigate the dust in an intake of CO2-rich dusty gas (i.e., the Martian atmosphere). The ESP is essentially a cylindrical tube with a coaxial wire electrode. Applying a high voltage through this electrode induces a corona discharge (a glowing plasma that envelops the electrode), which is used to charge the inflowing dust. The electric field caused by the corona pushes the charged dust to the walls of the precipitator, preventing the dust to flow out of the tube. Environmental dust can make long-term exploration missions very difficult, and settled dust is no exception. Settled lunar or Martian dust can hinder the performance and lifetime of equipment. For example, dust can settle on the solar panels of a lunar or Martian rover, decreasing its performance while increasing its charging time. To address this, the team at the ESPL is also developing an electrodynamic dust shield (EDS), which is designed to remove lunar or Martian dust from the surfaces of equipment. The EDS uses a non-uniform electric field to generate a dielectrophoretic force, which pushes the particles away from the surface of the shield. A number of dust shields will be tested on the exterior of the International Space Station (ISS) via MISSE-11, a flight payload to the ISS that will test the effects of long-term exposure to space on materials. During my internship at the ESPL, I aided in the development of these technologies. For the ESP, I helped characterize the electrical properties of various geometries and helped redesign the hardware of the testbed (the precipitator used to test this technology in the lab). To characterize the electrical properties of the ESP, I ran various tests of the precipitator, which consisted of varying the environmental conditions and geometry of the testbed. Analyzing the electrical properties of the ESP in various environmental conditions is necessary to characterize its collection efficiency, since it will be used in the dusty Martian environment. For the EDS, I helped analyze the dielectric strength of the surface of the shield via high-voltage testing. A dielectrically strong surface will help the shield survive the harsh environment of space, which will enable it to have both lunar and Martian applications.

Corona Discharge↗

NASA NTRS2018

Design of a Second Generation Electrostatic Precipitator for Martian Atmospheric Dust Mitigation of ISRU Intakes

A second generation electrostatic precipitator for use in the Martian environment has been developed by the Electrostatics and Surface Physics Laboratory (ESPL) at NASA Kennedy Space Center (KSC). This new system was designed to be modular and has three interchangeable test sections, each with a variety of replaceable high voltage electrodes, enabling optimization of the dust collection efficiency of the precipitator. It has the ability to maintain an increased atmospheric flow rate and provide more accurate dust delivery into the test section than was available in the previous prototypes. A majority of the controls for the system are provided by a software package developed to maintain a constant flow rate, low pressure, and electrode current to enable long duration performance characterization. This allows for testing of the technology in a relevant environment similar to those expected to be found in an atmospheric In-Situ Resource Utilization (ISRU) plant on Mars.

Precipitator↗

NASA NTRS2018

Dust Mitigation on Mars Using an Electrostatic Precipitator

The Martian atmosphere contains large amounts of dust, which are lofted by dust devils and dust storms. Some of this dust, particles on the order of 2-4 m, never settle and are constantly present in the atmosphere. Therefore, in order to utilize the planet's atmosphere for production of consumables, like oxygen and methane, this dust must be removed before the commodity production can begin. The electrostatic precipitator is currently being studied at Kennedy Space Center as a realistic option for removing this dust. This project covers the results, to date, of the dust flow initiation, control, and analysis inside the electrostatic precipitator, which is to be modelled after various dusty Martian atmospheric conditions.

electrostatic precipitator↗

NASA NTRSDate not supplied

Electrostatic Charging of the Lunar Surface

Lunar regolith dust particles accumulate charge and interact electrostatically with rover wheels, astronaut boots, and equipment. We have developed instrumentation for in situ measurements of the electrostatic charge developed by the interactions of lunar regolith dust with the space-rated materials on these devices. This instrument is also capable of measuring the distribution of electric fields on or near the lunar surface and the ion currents present near the lunar surface. We also report on our efforts to characterize the charging behavior of lunar dust in low gravity environments. This behavior is nonintuitive due to complex interactions between individual dust grains. We are developing an experiment to study this interaction in a microgravity vacuum environment. Better understanding of this interaction will allow for improved dust mitigation on the lunar surface.

electrostatics↗

NASA NTRSDate not supplied

Electrostatic charging of the lunar regolith

electrostatics↗

NASA NTRS2023

Effect of the Electrostatic Field due to the Surface Monolayer Metal Atoms on the Dissociation of Homonuclear Diatomic Gases in Gas-Metal Surface Reactions

The present paper examines the role of an electrostatic field generated by the outermost monolayer of metal ions prior to gas adsorption in aiding the dissociation of homonuclear diatomic gas molecules. The interaction of five homonuclear diatomic gases, Cl 2 , F 2 , H 2 , N 2 and O 2 , with several pure metals are examined using Coulomb’s law to calculate the attractive and repulsive forces between the electrons or ions in the gas molecule and the free surface metallic electrons or ions assuming a Bohr model. These calculations demonstrate that the total energy of the electrostatic fields from the metals can exceed the molecular binding energies of Cl 2 , F 2 , and O 2 at some distance from the metallic surface thereby suggesting that these gases interact primarily with the metallic surface in their atomic states after molecular bond dissociation prior to reaction. In contrast, H 2 and N 2 gases do not dissociate prior to reaching the metal surface due to the fact that the effective charge of the gas ions is less than the total electron charge at the outermost electronic shell. The present results correlate linearly with the electrochemical series standard reduction potential as well as with the Pauling electronegativity for several metals.

Gas-metal reactions↗

DOE OSTI2017

Cation Translocation around Single Polyoxometalate-Organic Hybrid Cluster Regulated by Electrostatic and Cation-π Interactions

We report herein an interesting dynamic translocation process of countercations around one polyoxometalate(POM)–organic hybrid anionic cluster at various concentrations and temperatures. It was found that both electrostatic interactions and cation–π interactions regulate the position of small countercations around single clusters. The dynamic geometry and the symmetry of the hybrid macroions are largely affected by the type of counterions, as shown by nuclear magnetic resonance (NMR) spectroscopy studies and all–atom molecular dynamics simulation. It is also shown that electrostatic interactions dominate over cation–π interactions in determining the locations of the counterions in the current system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2017

Electrostatic‐Assisted Liquefaction of Porous Carbons

Abstract Porous liquids are a newly developed porous material that combine unique fluidity with permanent porosity, which exhibit promising functionalities for a variety of applications. However, the apparent incompatibility between fluidity and permanent porosity makes the stabilization of porous nanoparticle with still empty pores in the dense liquid phase a significant challenging. Herein, by exploiting the electrostatic interaction between carbon networks and polymerized ionic liquids, we demonstrate that carbon‐based porous nanoarchitectures can be well stabilized in liquids to afford permanent porosity, and thus opens up a new approach to prepare porous carbon liquids. Furthermore, we hope this facile synthesis strategy can be widely applicated to fabricate other types of porous liquids, such as those (e.g., carbon nitride, boron nitride, metal–organic frameworks, covalent organic frameworks etc.) also having the electrostatic interaction with polymerized ionic liquids, evidently advancing the development and understanding of porous liquids.

Li, Peipei↗