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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Development of sputtering process to deposit stoichiometric zirconia coatings for the inside wall of regeneratively cooled rocket thrust chambers

Thermal barrier coatings of yttria stabilized zirconia and zirconia-ceria mixtures were deposited by RF reactive sputtering. Coatings were 1-2 mils thick, and were deposited on copper cylinders intended to simulate the inner wall of a regeneratively cooled thrust chamber. Coating stoichiometry and adherence were investigated as functions of deposition parameters. Modest deposition rates (approximately 0.15 mil/hr) and subambient sustrate temperatures (-80 C) resulted in nearly stoichiometric coatings which remained adherent through thermal cycles between -196 and 400 C. Coatings deposited at higher rates or substrates temperatures exhibited greater oxygen deficiences, while coatings deposited at lower temperatures were not adherent. Substrate bias resulted in structural changes in the coating and high krypton contents; no clear effect on stoichiometry was observed.

Busch, R.↗
NASA NTRS1977

The Response of a Quartz Crystal Microbalance to a Liquid Deposit

A theory was developed for predicting the loss of response of a QCM (Quartz Crystal Microbalance) to a liquid deposit due to viscous effects in the deposit. The loss of response is expressed by a response factor, equal to the response of the QCM to a liquid film divided by its response to a solid film of the same mass per unit area. The theory assumes a droplet-type deposit morphology, and considers the influence of droplet distribution parameters. Experiments were conducted to examine the validity of the theory, using DC 704 silicone oil as the subject deposit material. Experiments were made in two series: one with constant deposit mass and variable temperature, the other with variable deposit mass and constant temperature. Interpretation of the data using the theory has enabled information on droplet area coverage and number density to be deduced.

Glassford, A. P. M.↗
NASA NTRS1979

Particle deposition due to turbulent diffusion in the upper respiratory system

Aerosol deposition in the upper respiratory system (trachea to segmental bronchi) is considered and the importance of turbulent diffusion as a deposition mechanism is evaluated. It is demonstrated that for large particles (diameter greater than about 5 microns), turbulent diffusion is the dominant deposition mechanism in the trachea. Conditions under which turbulent diffusion may be important in successive generations of the pulmonary system are determined. The probability of particle deposition is compared with probabilities of deposition, as determined by the equations generally used in regional deposition models. The analysis is theoretical; no new experimental data is presented.

Hamill, P.↗
NASA NTRS1979

Multispectral mapping of the Apollo 15-Apennine region - The identification and distribution of regional pyroclastic deposits

Multispectral mapping of the Apollo 15-Apennine region has allowed the identification of numerous dark mantle deposits of probable pyroclastic origin. The deposits display a low albedo, appear to mantle and slightly subdue subjacent terrain, are spectrally distinct on the multispectral maps (high in the infrared but low in the ultraviolet) and generally exhibit a weak depolarized 3.8 cm radar echo. These characteristics are consistent with an origin by pyroclastic eruption. The regional dark mantle deposits are commonly associated with vents along marginal fractures and faults near the base of the Apennines, thereby emphasizing the role of basin-controlled weaknesses in providing channels for the upward migration of magma generated at depth. The spectral properties of the pyroclastic deposits are incompatible with those of Apollo 15 green glass but the deposits may be composed of material similar to the Apollo 15 brown or yellow glass. If so, the widespread distribution of the deposits suggest that mare basalts genetically related to the brown or yellow glass may occur in the Apollo 15 region. Moreover, pyroclastic volcanic activity has apparently been a more important and widespread process in the Apollo 15-Apennine region than has previously been thought.

Hawke, B. R.↗
NASA NTRS1980

Deposition and material response from Mach 0.3 burner rig combustion of SRC 2 fuels

Collectors at 1173K (900 C) were exposed to the combustion products of a Mach 0.3 burner rig fueled with various industrial turbine liquid fuels from solvent refined coals. Four fuels were employed: a naphtha, a light oil, a wash solvent and a mid-heavy distillate blend. The response of four superalloys (IN-100, U 700, IN 792 and M-509) to exposure to the combustion gases from the SRC-2 naphtha and resultant deposits was also determined. The SRC-2 fuel analysis and insights obtained during the combustion experience are discussed. Particular problems encountered were fuel instability and reactions of the fuel with hardware components. The major metallic elements which contributed to the deposits were copper, iron, chromium, calcium, aluminum, nickel, silicon, titanium, zinc, and sodium. The deposits were found to be mainly metal oxides. An equilibrium thermodynamic analysis was employed to predict the chemical composition of the deposits. The agreement between the predicted and observed compounds was excellent. No hot corrosion was observed. This was expected because the deposits contained very little sodium or potassium and consisted mainly of the unreactive oxides. However, the amounts of deposits formed indicated that fouling is a potential problem with the use of these fuels.

Santoro, G. J.↗
NASA NTRS1982

Deposit formation in hydrocarbon fuels

The hydrocarbon fuels RP-1, commercial-grade propane, JP-7 and chemically pure propane were subjected to tests in a high pressure fuel coking apparatus in order to evaluate their thermal decomposition limits and carbon deposition rates in heated copper tubes. A fuel thermal stability parametric evaluation was conducted at 136-340 atmospheres, bulk fuel velocities of 6-30 m/sec, and tube wall temperatures of 422-811 K, and the effect of inside wall material on deposit formation was evaluated in tests using nickel-plated tubes. Results show RP-1 deposit formation at wall temperatures between 600 and 800 K, with peak deposit formation near 700 K. Substitution of deoxygenated JP-7 for RP-1 showed no improvement, and the carbon deposition rates for propane fuels were found to be higher than those of either of the kerosene fuels. Nickel plating of the tube walls significantly reduced RP-1 carbon deposition rates.

Roback, R.↗
NASA NTRS1982

Present wind activity on Mars - Relation to large latitudinally zoned sediment deposits

The relation of present Martian winds to large latitudinally zoned sediment deposits has been investigated using global wind streak data and mapping of large sand and dust deposits. Dune sand deposits occur primarily in three latitude belts: north polar (74-85 degrees North), low latitude (5 degrees North-20 degrees South), and south polar (40-80 degrees South). Comparison with wind streak data shows the high-latitude dunes to be in areas of seasonally reversing winds. The present winds can form latitudinal dune belts from a variety of initial dune distributions, including uniform distribution and a polar source. The presence of dune sand within the polar layered deposits, the erosional state of the deposits, and the present surface wind flow away from the poles indicate that both polar dune concentrations have been derived from erosion of the layered deposits. The low-latitude dunes are topographically confined in canyons and craters; they are probably subject to long-term reversal of orientations with climate cycles.

Thomas, P.↗
NASA NTRS1983

Ionized cluster beam deposition

Ionized Cluster Beam (ICB) deposition, a new technique originated by Takagi of Kyoto University in Japan, offers a number of unique capabilities for thin film metallization as well as for deposition of active semiconductor materials. ICB allows average energy per deposited atom to be controlled and involves impact kinetics which result in high diffusion energies of atoms on the growth surface. To a greater degree than in other techniques, ICB involves quantitative process parameters which can be utilized to strongly control the characteristics of films being deposited. In the ICB deposition process, material to be deposited is vaporized into a vacuum chamber from a confinement crucible at high temperature. Crucible nozzle configuration and operating temperature are such that emerging vapor undergoes supercondensation following adiabatic expansion through the nozzle.

Kirkpatrick, A. R.↗
NASA NTRS1986

UV laser deposition of metal films by photogenerated free radicals

A novel photochemical method for liquid-phase deposition of metal films is described. In the liquid phase deposition scheme, a metal containing compound and a metal-metal bonded carbonyl complex are dissolved together in a polar solvent and the mixture is irradiated using a UV laser. The optical arrangement consists of a HeCd laser which provides 7 mW of power at a wavelength of 325 nm in the TEM(OO) mode. The beam is attenuated and may be expanded to a diameter of 5-20 mm. Experiments with photochemical deposition of silver films onto glass and quartz substrates are described in detail. Mass spectrometric analysis of deposited silver films indicated a deposition rate of about 1 A/s at incident power levels of 0.01 W/sq cm. UV laser-induced copper and palladium films have also been obtained. A black and white photograph showing the silver Van Der Pauw pattern of a solution-deposited film is provided.

Montgomery, R. K.↗
NASA NTRS1987

Carbon deposition model for oxygen-hydrocarbon combustion, volume 1

Presented are details of the design, fabrication, and testing of subscale hardware used in the evaluation of carbon deposition characteristics of liquid oxygen and three hydrocarbon fuels for both main chamber and preburner/gas generator operating conditions. In main chamber conditions, the deposition of carbon on the combustion chamber wall was investigated at mixture ratios of 2.0 to 4.0 and at pressures of 1000 to 1500 psia. No carbon deposition on the chamber walls was detected at these main chamber mixture ratios. In preburner/gas generator operating conditions, the deposition of carbon on the turbine simulator tubes was evaluated at mixture ratios of 0.20 to 0.60 and at chamber pressures of 720 to 1650 psia. The results of the tests showed carbon deposition rate to be a strong function of mixture ratio and a weak function of chamber pressure. Further analyses evaluated the operational consequences of carbon deposition on preburner/gas generator performance. The report is in two volumes, of which this is Volume 1 covering the main body of the report plus Appendixes A through D.

Hernandez, R.↗
NASA NTRS1987

Carbon Deposition Model for Oxygen-Hydrocarbon Combustion, Volume 2

Presented are details of the design, fabrication, and testing of subscale hardware used in the evaluation of carbon deposition characteristics of liquid oxygen and three hydrocarbon fuels for both main chamber and preburner/gas generator operating conditions. In main chamber conditions, the deposition of carbon on the combustion chamber wall was investigated at mixture ratios of 2.0 to 4.0 and at chamber pressures of 1000 to 1500 psia. No carbon deposition on chamber walls was detected at these main chamber mixture ratios. In preburner/gas generator operating conditions, the deposition of carbon on the turbine simulator tubes was evaluated at mixture ratios of 0.20 to 0.60 and at chamber pressures of 720 to 1650 psia. The results of the tests showed carbon deposition rate to be a strong function of mixture ratio and a weak function of chamber pressure. Further analyses evaluated the operational concequences of carbon deposition on preburner/gas generator performance. This is Volume 2 of the report, which contains data plots of all the test programs.

Hernandez, R.↗
NASA NTRS1990

Color and albedo of the south polar layered deposits on Mars

Five color/albedo units, including polar frost, have been recognized and mapped in the southern layered deposits on Mars. Atmospheric dust scattering was measured in shadows and modeled in order to remove the component of brightness in Mars images due to the atmosphere and quantify the albedo and color of the surface. The layered deposits appear to be mantled by red dust, except where eolian stripping has exposed the underlying bedrock. Dark material has been deposited in topographic depressions in much of the south polar region, including the layered deposits. The available observational data suggest that the layered deposits are composed of bright dust, ice, and a small amount of dark material. If the dark material is sand, a periodic change in polar winds seems required in order to transport the sand poleward into the layered terrain. In any case, the observations are not consistent with the layered deposits being composed only of bright dust and ice.

Herkenhoff, Ken E.↗
NASA NTRS1990

Silicon carbon alloy thin film depositions using electron cyclotron resonance microwave plasmas

Amorphous and microcrystalline silicon carbon films (a-SiC:H, micro-c-SiC:H) have been deposited using SiH4, CH4 and H2 mixed gas ECR (electron cyclotron resonance) plasmas. The optical bandgap of a-SiC:H films is not dependent on the hydrogen dilution in the ECR plasma. The deposition rate of a-SiC:H films is found to be strongly dependent on the ECR magnetic field and the hydrogen dilution. The hydrogen dilution effect on the deposition rate indicates that the etching in ECR hydrogen plasmas plays an important role in the deposition of a-SiC:H films. The optical constants n and k of ECR-deposited a-SiC:H films in the wavelength region of 0.4 to 1.0 micron are determined to be 2.03-1.90 and 0.04-0.00, respectively. The microstructures of ECR-deposited micro-c-SiC:H films are shown by X-ray diffraction and SEM (scanning electron microscopy) to be composed of 1000-A alpha-SiC microcrystallites and amorphous network structures.

Shing, Y. H.↗
NASA NTRS1991

Remote sensing of regional pyroclastic deposits on the north central portion of the lunar nearside

High-resolution 3.0-cm radar data for the Rima Bode regional pyroclastic deposit and a number of UV-visible reflectance spectra for regional pyroclastic deposits on the north-central portion of the lunar nearside are analyzed and compared to existing data. The data obtained indicate that small craters in this deposit excavated loose unwelded pyroclastic particles, suggesting that welded layers or lenses do not exist at depths within the deposit's core area. The 70-cm radar data indicate that the Roma Bode deposit is thinner than the pyroclastic unit on the Aristarchus Plateau. The surfaces of all these regional pyroclastic deposits are dominated by ilmenite-rich black spheres, and contamination by low-Ti, nonpyroclastic debris appears to be minimal. The fine-grained block-free uncontaminated Rima Bode would be ideal for lunar mining operations and for rapidly covering lunar base modules with an adequate thickness of shielding material for protection from meteorite impact and space radiation.

Hawke, B. R.↗
NASA NTRS1991

Lunar western limb pyroclastic deposits

It has become increasingly evident that the lunar pyroclastic volcanism played an important role in the formation and resurfacing of many areas of the Moon. On-going analysis of lunar Orbiter and Apollo photographs continues to locate and identify pyroclastic deposits and suggests that they just may be more ubiquitous than once thought. Located near mare/highland boundaries, many of these deposits formed contemporaneously with effusive mare volcanism. The mantling deposits formed as products of fire-fountaining. Probable source vents for these deposits include irregular depressions at the head of associated sinuous rilles and/or along irregular fractures in the floors of ancient craters. Here, researchers provide a brief synopsis of the nature of the dark mantling deposits and briefly discuss several newly identified deposits on the western limb.

Coombs, Cassandra R.↗
NASA NTRS1992

Polar deposits of Mars

Layered deposits unique to the poles of Mars indicate long-term winter deposition of ice and sediment modulated by periodic climate change. The layered deposits contain at least two kinds of nonvolatile materials: one that is similar to the bright red dust raised in Martian dust storms, and one similar to dark sand dune materials observed at low and mild latitudes. The ice fraction of the deposits remains unknown. Because the present polar dust and ice budgets are poorly constrained, correlation of layer thicknesses with specific astronomical cycles remains very uncertain. Layered deposits in both polar regions appear to have been slightly more widespread in the past. Other sediments near the poles, and the estimated ages of the layered deposits, suggest that the polar sedimentary regime has evolved over the geologic history of Mars. Acquisition of good data on the vertical sequence of layer characteristics and better crater retention ages should allow revealing comparisons with astronomically driven cycles and secular atmospheric changes.

Thomas, P.↗
NASA NTRS1993

Mass spectrometric studies of SiO2 deposition in an indirect plasma enhanced LPCVD system

Reaction pathways for the low temperature deposition of SiO2 from silane and indirect plasma-excited oxygen-nitrogen mixtures are proposed based on experimental evidence gained from mass spectrometry in an indirect plasma enhanced chemical vapor deposition chamber. It was observed that about 80-85 percent of the silane was oxidized to byproduct hydrogen and only about 15-20 percent to water. Such conversion levels have led us to interpret that silanol (SiH3OH) could be the precursor for SiO2 film deposition, rather than siloxane /(SiH3)2O/ which has generally been cited in the literature. From mass spectrometry, we have also shown the effects of the plasma, and of mixing small amounts of N2 with the oxygen flow, in increasing the deposition rate of SiO2. Free radical reaction of nitric oxide, synthesized from the reaction of oxygen and nitrogen in the plasma chamber, and an *ncrease in atomic oxygen concentration, are believed to be the reasons for these SiO2 deposition rate increases. Through mass spectrometry we have, in addition, been able to identify products, presumably originating from terminating reactions, among a sequence of chemical reactions proposed for the deposition of SiO2.

Iyer, R.↗
NASA NTRS1993

Mars: New evidence for origin of some Valles Marineris layered deposits

The discovery of layered deposits in the walls of a deep trough in Lunae Planum has implications for the origin of similar-appearing deposits in some canyons of Valles Marineris. Although layering is visible in the competent, cliff-forming upper walls of the canyons, the dissimilarity in appearance between canyon walls and soft rounded hills of layered deposits on canyon floors, as well as their contrasting patterns of erosion, has been considered strong evidence that their modes of origin were different. Most workers agree that the wall rocks are volcanic flows derived from fissure vents and other volcanic sources in the region. However, several hypotheses have been advanced to account for the softer-appearing stratified floor deposits. Chief among them is the proposal that the floor deposits are waterlaid sediments that accumulated in large lakes within the canyons and include materials eroded from canyon walls, eolian deposits, and subaqueous volcanic eruptives.

Scott, David H.↗