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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Data-Driven Discovery of Linear Molecular Probes with Optimal Selective Affinity for PFAS in Water

Approaches to tackle the wide and growing variety of highly persistent per- and polyfluoroalkyl substances (PFAS) are of pressing global need because of their detrimental human health effects, such as cancer, birth defects, and hormone imbalance. Sensitive, selective, and easy-to-use real-time sensors to monitor and detect PFAS and sorbents to extract them are critical to meeting government-mandated environmental concentrations. In this work, we combine all-atom molecular dynamics simulations, enhanced sampling, deep representational learning, and Bayesian optimization to perform high-throughput virtual screening for highly sensitive and selective molecular probes. Our molecular design space consists of 3850 linear hydrocarbon chains with varying degrees of halogenation with and without amine- and phosphine-based headgroups. By employing a data-driven search process, we efficiently explore the molecular design space to optimize the sensitivity to perfluorooctanesulfonic acid (PFOS) as a prototypical PFAS analyte and selectivity relative to a sodium dodecyl sulfate (SDS) interferent. We calculate 504 Gibbs free energies of probe-analyte and probe-interferent interactions and identify probes with PFOS association free energies of up to (-ΔG PFOS ) = 9.8 ± 0.2 kJ/mol and selectivities relative to SDS of (-ΔΔG PFOS–SDS ) = 3.1 ± 1.5 kJ/mol. A C 11 Br 23 P(CH 3 ) 2 probe containing 11 backbone brominated carbons and a tertiary phosphine headgroup possesses the most sensitive binding constant to PFOS within the defined search space of K b PFOS = 177.4 ± 12.7, and a semibrominated probe C 5 H 11 C 7 Br 14 N(CH 3 ) 2 containing 12 backbone carbons and a tertiary amine headgroup possesses the highest selectivity relative to SDS of K b PFOS /K b SDS = 4.6 ± 1.7. A retrospective analysis of our data to extract interpretable design rules reveals that the sensitivity of linear hydrogenated probes increases by approximately 1 kJ/mol per C–C bond. The addition or removal of halogen atoms and amine or phosphine headgroups produces nonmonotonic changes in both sensitivity and selectivity with changes to the sensitivity of up to 2.5 kJ/mol. Finally, this work places empirical limitations on the performance of a wide range of linear probes for PFOS detection and offers a generic strategy for high-throughput computational screening to promote selective and sensitive binding.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Deep drilling in the time domain with DECam: survey characterization

ABSTRACT This paper presents a new optical imaging survey of four deep drilling fields (DDFs), two Galactic and two extragalactic, with the Dark Energy Camera (DECam) on the 4-m Blanco telescope at the Cerro Tololo Inter-American Observatory (CTIO). During the first year of observations in 2021, >4000 images covering 21 deg2 (seven DECam pointings), with ∼40 epochs (nights) per field and 5 to 6 images per night per filter in g, r, i, and/or z have become publicly available (the proprietary period for this program is waived). We describe the real-time difference-image pipeline and how alerts are distributed to brokers via the same distribution system as the Zwicky Transient Facility (ZTF). In this paper, we focus on the two extragalactic deep fields (COSMOS and ELAIS-S1) characterizing the detected sources, and demonstrating that the survey design is effective for probing the discovery space of faint and fast variable and transient sources. We describe and make publicly available 4413 calibrated light curves based on difference-image detection photometry of transients and variables in the extragalactic fields. We also present preliminary scientific analysis regarding the Solar system small bodies, stellar flares and variables, Galactic anomaly detection, fast-rising transients and variables, supernovae, and active Galactic nuclei.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2018

Small Spacecraft for Planetary Atmospheric, Surface, and Interior Structure Using Radio Links

Scientific studies using spacecraft radio links have been conducted on almost every Solar System exploration mission in the past five decades and have led to numerous discoveries. Radio Science experiments have elucidated the thermal history of the Moon from high resolution gravitational field measurements, unveiled the interiors of Titan, Enceladus, Mercury, Phobos, Vesta and Ceres providing key evidence for identifying subsurface oceans on icy moons; sounded Titan, Saturn, and Pluto’s atmospheres, and refined models for the atmospheres, surfaces, and interior structure of Mars and Venus. A Juno experiment is in progress measuring the gravitational field of Jupiter to reveal its interior structures, as did a similar recent Cassini experiment with Saturn. Experiments at Mercury, the Jovian system, and other targets, are in development or planning phases. Over the next 30 years, significant advances in radio and laser link-science technologies, including nearly one order of magnitude improvement achievable in range-rate and range accuracy, could enable many new scientific breakthroughs. Future exploration concepts in many cases focus on applications of small spacecraft and can include spacecraft constellations for studies of atmospheric dynamics, interior structures, and surface properties. A set of science-enabling radio link technologies specific to small spacecraft instrumentation on future solar system missions are under study and development. Examples include field tests of radio scattering to determine soil properties, smallsat constellations for dense geographic and temporal atmospheric probing, small science-quality software-defined transponders, miniature ultra-stable oscillators, and advanced radio-metric calibrations at the Deep Space Network. This paper describes many of these technologies and their scientific applications.

Elliott, Harvey↗
NASA NTRS2016

Sylph: Life Detection Probe for a Europa Plume

Jupiter’s Galilean satellite Europa likely contains a vast, global, subsurface salt-water ocean. A singular telescope observation in 2012 indicated possible plume activity, in some ways similar to the continuous plume activity seen at Enceladus. If a Europan plume does expel ocean water into space, its vapor, ice grains, and dust grains could be analyzed by a spacecraft equipped with high-resolution mass spectrometers. Such plume measurements would be sufficient to measure the contextual habitability profile of the ocean, and to detect multiple signatures of life, should it exist in the ocean. Instrumented with MASPEX (Mass Spectrometer for Planetary Exploration) and SUDA (Surface Dust Analyzer), NASA’s planned Europa Mission now in development could theoretically conduct this investigation. However, the mission’s closest flyby altitude would be 25 km; due to Europa’s large gravity, frozen ocean spray containing non-volatile molecular species critical to biosignature detection can be sampled only within 5 km of the surface. The Europa Mission would not fly this low. Sylph is a concept for a complementary, free-flyer smallsat probe, about the same size as an office water-cooler bottle, that could be deployed by the Europa Mission as it conducts a plume fly-through. Sylph would execute a single ~2 km altitude plume pass below the main spacecraft. With a mass of 40 kg and a 24-hr life, the probe would autonomously navigate its low-altitude pass, and carry a dualchannel Mini-SUDA impact ionization mass spectrometer that would measure the composition of large grains, complementing the main spacecraft’s measurements of small grains and gas. Sylph is a novel smallsat concept: purpose-built configuration optimized for both the harsh Jovian environment and for Europan planetary-protection requirements, and built with advanced manufacturing methods from both deep space and smallsat components. For $80M (~4% marginal cost), the Europa Mission could buy a Sylph “insurance policy,” hedging the possibility that it does discover ocean plumes upon arrival in 2028. At less than 85 kg for probe and accommodations, the mission could carry two or three of the probes.

Sherwood, Brent↗
DOE OSTI2022

AtomAI framework for deep learning analysis of image and spectroscopy data in electron and scanning probe microscopy

Over the past several decades, electron and scanning probe microscopes have become critical components of condensed matter physics, materials science and chemistry research. At the same time, the infrastructure for establishing a connection between microscopy observations and materials behaviour over a broader parameter space is lacking. In this work, we introduce AtomAI, an open-source software package bridging instrument-specific Python libraries, deep learning and simulation tools into a single ecosystem. AtomAI allows direct applications of deep neural networks for atomic and mesoscopic image segmentation converting image and spectroscopy data into class-based local descriptors for downstream tasks such as statistical and graph analysis. For atomically resolved imaging data, the output is types and positions of atomic species, with an option for subsequent refinement. AtomAI further allows the implementation of a broad range of image and spectrum analysis functions, including invariant variational autoencoders for disentangling structural factors of variation and im2spec type of encoder–decoder models for mapping structure–property relationships. Finally, our framework allows seamless connection to the first principles modelling with a Python interface on the inferred atomic positions.

36 MATERIALS SCIENCE↗
NASA NTRSDate not supplied

Agent-based modeling of microbes in space

Space is tough on organisms. Microorganisms traveling to space experience stress from environmental features such as ionizing radiation and lack of normal microgravity; however, much remains unknown about the mechanisms by which those environmental features affect microbial physiology. Microbes experience changes in gravity not directly but rather through changes in their fluid environment, and deep-space particle radiation causes cell damage that is complex but rare. Computational modeling at the single-cell level (agent-based modeling) can allow us to probe the spatially heterogeneous processes that characterize space stresses, to gain insight into the relationships of microbial cells with their environments and with each other. Here we present two software packages for simulating microbial population dynamics in space conditions: CAMDLES and AMMPER. Microbes growing in liquid culture medium in the microgravity of an orbital space station experience a quiescent, poorly-mixed fluid environment. CAMDLES (CFD-DEM Artificial Microgravity Developments for Living Ecosystem Simulation) simultaneously simulates biological, chemical, and mechanical processes to predict microbial ecological dynamics in microgravity, and in the rotating culture vessels used to create an artificial microgravity environment in the lab. Initial results demonstrate that the growth of a cross-feeding microbial consortium, dependent on the exchange of soluble metabolites, is sensitive to the initial spatial distribution of cells, and grows differently in real versus artificial microgravity. Microbial populations exposed to deep-space radiation experience spatially and temporally heterogeneous damage from the traversal of high-energy particles. AMMPER (Agent-Based Model for Microbial Populations Exposed to Radiation) pairs a 3d model of energy deposition along a radiation particle track with a microbial population growth and damage model to predict the effects of localized radiation damage on population-level responses. It includes a user-friendly graphical interface. AMMPER results agree with experimental data indicating that indirect effects of radiation (reactive oxygen species generation, metabolic impairment) have a greater impact on microorganisms than direct effects (DNA damage).

Jessica A Lee↗
NASA NTRS2022

Agent-Based Modeling of Microbes in Space

Space is tough on organisms. Microorganisms traveling to space experience stress from environmental features such as ionizing radiation and lack of normal gravity, and much remains unknown about the mechanisms by which those environmental features affect microbial physiology. Microbes experience changes in gravity not directly but rather through changes in their fluid environment, and deep-space particle radiation causes cell damage that is complex but rare. Computational modeling at the single-cell level (agent-based modeling) can allow us to probe the spatially heterogeneous processes that characterize space stresses, to gain insight into the relationships of microbial cells with their environments and with each other. Here we present two software packages for simulating microbial population dynamics in space conditions: CAMDLES and AMMPER. Microbes growing in liquid culture medium in the microgravity of an orbital space station experience a quiescent, poorly-mixed fluid environment. CAMDLES (CFD-DEM Artificial Microgravity Developments for Living Ecosystem Simulation) simultaneously simulates biological, chemical, and mechanical processes to predict microbial ecological dynamics in microgravity, and in the rotating culture vessels used to create an artificial microgravity environment in the lab. Initial results demonstrate that the growth of a cross-feeding microbial consortium, dependent on the exchange of soluble metabolites, is sensitive to the initial spatial distribution of cells, and grows differently in real versus artificial microgravity. Microbial populations exposed to deep-space radiation experience spatially and temporally heterogeneous damage from the traversal of high-energy particles. AMMPER (Agent-Based Model for Microbial Populations Exposed to Radiation) pairs a 3d model of energy deposition along a radiation particle track with a microbial population growth and damage model to predict the effects of localized radiation damage on population-level responses. It includes a user-friendly graphical interface. AMMPER growth curves recapitulate experimental results, and allow comparison between direct effects (DNA damage) and indirect effects (reactive oxygen species generation, metabolic impairment) of radiation.

microbiology↗
NASA NTRS2000

The Mars Microprobe Mission: Advanced Micro-Avionics for Exploration Surface

The Mars Microprobe Mission is the second spacecraft developed as part of the New Millennium Program deep space missions. The objective of the Microprobe Project is to demonstrate the applicability of key technologies for future planetary missions by developing two probes for deployment on Mars. The probes are designed with a single stage entry, descent, and landing system and impact the Martian surface at speeds of approximately 200 meters per second. The microprobes are composed of two main sections, a forebody section that penetrates to a depth below the Martian surface of 0.5 to 2 meters, and an aftbody section that remains on the surface. Each probe system consists of a number of advanced technology components developed specifically for this mission. These include a non-erosive aeroshell for entry into. the atmosphere, a set of low temperature batteries to supply probe power, an advanced microcontroller to execute the mission sequence, collect the science data, and react to possible system fault conditions, a telecommunications subsystem implemented on a set of custom integrated circuits, and instruments designed to provide science measurements from above and below the Martian surface. All of the electronic components have been designed and fabricated to withstand the severe impact shock environment and to operate correctly at predicted temperatures below -100 C.

Blue, Randel↗
NASA NTRS1985

A comparison of 8.415-, 32.0- and 565646-GHz deep space telemetry links

An economic and performance comparison is made of spacecraft telecommunication links at 8.415, 32.0, and 565646 GHz (0.53-micron wavelength) for the return of 3.43 x 10 to the 11th power bits from a Saturn Orbiter/Titan Probe mission in year 2000. Technical performance and costs for both ends of the links are included. Spacecraft antenna or telescope efficiencies, pointing losses, ground-based or Earth-orbiting relay terminals efficiencies, noise temperatures, recurring and nonrecurring engineering, and maintenance and operations costs are modeled. Weather effects, dc-to-RF or laser power conversion efficiencies, gravity and other environment distortions gain reductions, and the cost of pointing and tracking are analyzed. The effort is focused primarily on the microwave frequency links. There are large uncertainties in the cost results, but conclusions indicate that for a mid-1990's launch, the Ka-band system is as cost effective as X-band. The Ka-band system has a data rate advantage as compared to the X-band system for the same dc power input to the spacecraft. The magnitude of the advantage is a complex function of the weather at the DSN stations and the elevation angle of the ground antenna. A simple numerical comparison of the advantage is difficult and curves are provided. The optical frequency link is more costly based on the launch-to-orbit costs for the orbiting terminal. A more detailed study of the optical system is recommended to quantify astrometric tracking benefits and improve the accuracy of the cost estimate.

Dickinson, R. M.↗
NASA NTRS1991

Trade studies for nuclear space power systems

As visions of space applications expand and as probes extend further and further out into the universe, the need for power also expands, and missions evolve which are enabled by nuclear power. A broad spectrum of missions which are enhanced or enabled by nuclear power sources are defined. These include earth orbital platforms, deep space platforms, planetary exploration and extraterrestrial resource exploration. The recently proposed Space Exploration Initiative (SEI) to the moon and Mars has more clearly defined these missions and their power requirements. This paper presents results of recent studies of radioisotope and nuclear-reactor energy sources combined with various energy-conversion devices for earth orbital applications, SEI lunar/Mars rover and surface power, and planetary exploration.

Smith, John M.↗
NASA NTRS1979

Voyager telecommunications - The broadcast from Jupiter

The means by which the data collected by the Voyager 1 mission to Jupiter were returned to earth are presented. Radio links between the earth and the spacecraft are used for the transmission of both imaging and nonimaging telemetry from the spacecraft and commands from the earth and for radiometric observations of the spacecraft and its environment. Features which have lead to vast improvements in the capability of the Voyager telecommunications system over that of previous space probes include the use of X-band rather than S-band telemetry, a dual power X-band traveling wave tube amplifier, a 3.7 m spacecraft antenna and a single channel telemetry system with concatenated coding. Communications equipment at the three ground complexes of the Deep Space Network for telemetry reception includes 64 m steerable antennas, cryogenic maser preamplifiers and a phase-lock loop receiver. Voyager 1 has met or exceeded all of its telecommunications requirements, providing a 98% data return and a total of 2 x 10 to the 11th data bits during the Jupiter encounter.

Edelson, R. E.↗
NASA NTRSDate not supplied

Applications of Nuclear Thermal Propulsion Systems for Deep Space Science Missions

Nuclear thermal propulsion (NTP) systems occupy a unique area in the space propulsion technology landscape due to their ability to combine moderate-to-high thrust systems normally seen in chemical propulsion systems with specific impulses that are closer to those observed in some electric propulsion systems. Consequently, NTP systems have the potential to greatly expand access to deep space and can enable a variety of missions that achieve the science goals outlined in NASA’s decadal surveys. This paper leverages previous analysis performed to show the applicability of NTP systems for notional science missions, expanding the analyzed portfolio to encompass additional science mission profiles and demonstrating how the use of NTP affects various mission parameters, such as trip time and delivered mass. This paper also outlines efforts to improve the fidelity of the existing NTP design concepts and vehicles that are utilized by leveraging previous work on nuclear propulsion systems for human-Mars missions. The fidelity of the analysis in this work is improved over previous studies, permitting commensurate improvements in the analyses of previous mission concept studies –the Triton lander, the solar polar orbiter, and the interstellar medium probe missions.

Nuclear thermal propulsion↗
NASA NTRS2017

Aerial Vehicles to Detect Maximum Volume of Plume Material Associated with Habitable Areas in Extreme Environments

Current technologies of exploring habitable areas of icy moons are limited to flybys of space probes. This research project addresses long-term navigation of icy moons by developing a MATLAB adjustable trajectory based on the volume of plume material observed. Plumes expose materials from the sub-surface without accessing the subsurface. Aerial vehicles capable of scouting vapor plumes and detecting maximum plume material volumes, which are considered potentially habitable in inhospitable environments, would enable future deep-space missions to search for extraterrestrial organisms on the surface of icy moons. Although this platform is still a prototype, it demonstrates the potential aerial vehicles can have in improving the capabilities of long-term space navigation and enabling technology for detecting life in extreme environments. Additionally, this work is developing the capabilities that could be utilized as a platform for space biology research. For example, aerial vehicles that are sent to map extreme environments of icy moons or the planet Mars, could also carry small payloads with automated cell-biology experiments, designed to probe the biological response of low-gravity and high-radiation planetary environments, serving as a pathfinder for future human missions.

Vehicles Extreme Environment↗
NASA NTRS1991

Trade studies for nuclear space power systems

As human visions of space applications expand and as we probe further out into the universe, our needs for power will also expand, and missions will evolve which are enabled by nuclear power. A broad spectrum of missions which are enhanced or enabled by nuclear power sources have been defined. These include Earth orbital platforms, deep space platforms, planetary exploration, and terrestrial resource exploration. The recently proposed Space Exploration Initiative (SEI) to the Moon and Mars has more clearly defined these missions and their power requirements. Presented here are results of recent studies of radioisotope and nuclear reactor energy sources, combined with various energy conversion devices for Earth orbital applications, SEI lunar/Mars rovers, surface power, and planetary exploration.

Smith, John M.↗
NASA NTRS2001

Solid-State Power Generating Microdevices for Distributed Space System Architectures

Deep space missions have a strong need for compact, high power density, reliable and long life electrical power generation and storage under extreme temperature conditions. Conventional power generating devices become inefficient at very low temperatures (temperatures lower than 200 K encountered during Mars missions for example) and rechargeable energy storage devices cannot be operated thereby limiting mission duration. At elevated temperatures (for example for planned solar probe or Venus lander missions), thin film interdiffusion destroys electronic devices used for generating and storing power. Solar power generation strongly depends upon the light intensity, which falls rapidly in deep interplanetary missions (beyond 5 AU), and in planetary missions in the sun shadow or in dusty environments (Mars, for example). Radioisotope thermoelectric generators (RTGs) have been successfully used for a number of deep space missions RTGs. However, their energy conversion efficiency and specific power characteristics are quite low, and this technology has been limited to relatively large systems (more than 100 W). The National Aeronautics and Space Administration (NASA) and the Jet Propulsion Laboratory (JPL) have been planning the use of much smaller spacecrafts that will incorporate a variety of microdevices and miniature vehicles such as microdetectors, microsensors, and microrovers. Except for electrochemical batteries and solar cells, there are currently no available miniaturized power sources. Novel technologies that will function reliably over a long duration mission (ten years and over), in harsh environments (temperature, pressure, and atmosphere) must be developed to enable the success of future space missions. It is also expected that such micropower sources could have a wide range of terrestrial applications, in particular when the limited lifetime and environmental limitations of batteries are key factors. Additional information is contained in the original extended abstract.

Fleurial, J.-P.↗
NASA NTRS1966

Venus DSS operations

Venus Deep Space Station experiments involving telemetry with Mariner IV spacecraft in cooperation with Mars Deep Space Station

TELEMETRY↗