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At least 325 records · Page 18

The Benefits of Incorporating Shipping Containers into the Climate Change Adaption Plans at NASA Wallops Flight Facility

The National Aeronautics and Space Administration has several centers and facilities located near the coast that are undoubtedly susceptible to climate change. One of those facilities is Wallops Flight Facility on the Eastern Shore of Virginia which is separated into three areas: Main Base, Mainland, and the Island. Wallops Island has numerous buildings and assets that are vulnerable to flood inundation, intense storms, and storm surge. The shoreline of Wallops Island is prone to beach erosion and is slated for another beach replenishment project in 2019. In addition, current climate projections for NASAs centers and facilities, conducted by the Climate Adaptation Science Investigators, warn of inevitable increases in annual temperature, precipitation, sea level rise, and extreme events such as heat waves. The aforementioned vulnerabilities Wallops Island faces in addition to the projections of future climate change reveal an urgency for NASA to adjust how new buildings at its centers and facilities near the coast are built to adapt to the inevitable effects of climate change. Although the agency has made strides to mitigate the effects of climate change by incorporating L.E.E.D. into new buildings that produce less greenhouse gas, the strides for the agency to institute clear climate adaptation policies for the buildings at its centers and facilities near the coast seem to lag behind. As NASA continues to formulate formidable climate change adaptation plans for its centers and facilities, an architectural trend that should be examined for its potential to replace several old buildings at Wallops Island is shipping containers buildings. Shipping containers or Intermodal Steel Building Units offer an array of benefits such as strength, durability, versatility, modular, and since they can be upcycled, they are also eco-friendly. Some disadvantages of shipping containers are they contain harmful chemicals, insulation must be added, fossil fuels must be used to transport them to the site, and multiple ISBUs are needed. However, the benefits of shipping container buildings could be utilized at NASA centers or facilities near the coast such as Wallops Island on new buildings that are designed to adapt to the impending effects of climate change. Thus, this Masters Research Project will explore how those benefits can be incorporated into the climate change adaptation plans at Wallops Island and make recommendations for policy guidelines and shipping container buildings specific to Wallops Island.

Sustainable Design↗

Testing and certification of the SAVY 4000 nuclear material container for DOT Type A liquid transport - 15636

Los Alamos National Laboratory has contracted with Nuclear Filter Technology, Inc. to perform testing and certification of the SAVY 4000 container for DOT Type A liquid transport. The container was originally designed to meet DOE M441.1-1 requirements for safe storage of nuclear material, and it is currently being used for storage at Los Alamos National Laboratory, Livermore National Laboratory, Idaho National Laboratory and Nevada National Security Site. The SAVY 4000 container is manufactured from 316L stainless steel in a range of sizes from 1 quart to 10 gallon capacity, it can be opened and closed easily by hand, it is sealed with a Viton{sup R} O-Ring, and the filter retains particulates and resists liquid water entry while allowing hydrogen gas to escape. Finite element analysis has been used to guide the development of a testing regime that includes a 30 foot drop, bar penetration, vibration, water spray and stacking for the 5 quart capacity container. The results of the tests will be compared with the finite element analysis to validate the model. The validated model is being used to extend the Type A certification to the other container sizes. This poster will describe the results of the Type A liquid testing, the finite element analysis, and the benefits of broadening the use and versatility of the container. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Polymer Lifetime in Plutonium Storage Containers - 18508

The plutonium facility at Los Alamos National Laboratory utilizes stainless steel containers for interim storage of plutonium compounds, metals, alloys, and process residues. Various polymer materials are used in these containers, including neoprene rubber gaskets, Viton O-rings, polytetrafluoroethylene membranes, and polyvinyl chloride bags. The DOE Manual, M441.1-1, requires storage containers to have a technically justified design life, and these polymer components play a key role in the determination of the overall design life for the containers. The capabilities at Los Alamos for monitoring degradation and estimating the design life of polymer materials used in plutonium storage containers will be described, along with the results of the lifetime determination studies for the polymer components used in SAVY-4000 and Hagan containers and some proposed alternatives. (authors)

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Demonstration of Passive Phoretic Decontamination by Accident Simulation in a Scaled Reactor Containment

Reactor containment performance is a critical defense-in- depth barrier for the prevention of radioactive release in the event of a nuclear accident. One of the functions of the containment is to assist in the decontamination of aerosolized radioactive particles through both 'passive' or natural processes and 'active' or mechanical processes. Current United States Nuclear Regulatory Commission (NRC) guidance (Reg. guide 1.183) allows the use of aerosol natural deposition correlations to quantify postaccident nuclear containment decontamination factors. Large Light Water Reactor (LLWR) correlations have previously been developed to quantify the contribution of natural phenomena to post-accident aerosol decontamination. Specific correlations must similarly be developed to support the safety analyses of Small Modular Reactors (SMRs). For LLWR plants, decontamination is achieved 'actively' by mechanical systems such as containment sprays and 'passively' via natural phenomena such as gravitational settling, condensation, impaction, thermophoresis, diffusiophoresis and hygroscopic effects. Integrated pressurized water reactor (iPWR) SMR designs do not have containment sprays; therefore, they rely primarily on passive natural phenomena for decontamination in the integrated reactor vessel. Analytical studies and inferences from LLWR test data suggest that the smaller containment vessel volume to surface area ratio, coupled with the thermal hydraulic properties of iPWR plants, would significantly enhance decontamination factors for these smaller designs. The research aims to quantify the amount of decontamination from natural phenomena for the range of iPWR physical and thermal hydraulic characteristics. A preliminary assessment has shown that diffusiophoresis, thermophoresis and hygroscopic effects are the major areas with a research gap for iPWR plants; hence these areas are the foci of the research. These first-of-a-kind experiments will be described and preliminary analytical results will be presented that show the expected effects of SMR-specific correlations on passive decontamination of aerosolized radionuclides.

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Influence of Emissions and Aqueous Processing on Particles Containing Black Carbon in a Polluted Urban Environment: Insights From a Soot Particle-Aerosol Mass Spectrometer

Inorganic and organic coatings on black carbon (BC) particles can enhance light absorption and affect atmospheric lifetimes of BC-containing particles and thus have significant implications for climate. To study the physical and chemical characteristics of atmospheric BC and BC-associated coatings, a soot particle-aerosol mass spectrometer was deployed during the winter of 2014–2015 in Fresno, a city located in the San Joaquin Valley of California, to selectively analyze BC-containing particles. Comparing soot particle-aerosol mass spectrometer measurements to those from the collocated single-particle soot photometer (SP2) and high-resolution aerosol mass spectrometer, we found that 17% of total submicrometer aerosol mass was associated with BC-containing particles, suggesting that a majority of the fine particles in Fresno contained no BC. Most BC-containing particles appeared to be associated with residential wood burning and vehicular traffic. These particles typically had a bulk-average mass ratio of coating to BC (R coat/rBC ) less than 2. However, during periods of persistent fog larger R coat/rBC values were observed, with the coatings primarily composed of secondary inorganic and organic components that likely resulted from aqueous-phase processing. Specifically, compared to periods with less fog, the BC coating increased in concentration and contained a larger fraction of nitrate and oxidized organic matter. The size distributions of BC and associated organic coating were generally centered around 300 nm in vacuum aerodynamic diameter. However, during foggy periods BC had an additional peak at ~400 nm and organics and nitrate displayed a prominent mode in the accumulation size range.

54 ENVIRONMENTAL SCIENCES↗

Predicting cost-effective carbon fiber precursors: Unraveling the functionalities of oxygen and nitrogen-containing groups during carbonization from ReaxFF simulations

Blends of polyacrylonitrile (PAN) and poly(p-phenylene-2,6-benzobisoxazole) (PBO) as precursors may offer an opportunity to reduce the cost of carbon fiber (CF) production. The all-carbon ring formations and volatile gas production during the heating and carbonization for 9 PAN/PBO blend precursors with varying mixing ratios are studied via the ReaxFF reactive molecular dynamics simulations. Evolutions of oxygen-containing (O-containing) and nitrogen-containing (N-containing) groups are detailed, in order to reveal the reaction mechanisms of the O and N-based CF precursors. Particularly, the O-containing groups are identified to be more efficient for initiating the carbonization, whereas N-containing groups are far longer retained in the graphitic materials and play a key role in capturing and converting carbon radical species into the graphitic networks. Additionally, the PAN/PBO blend precursor with a mole ratio of 1:1 is compared with the pre-oxidized PAN, PAN, and PBO. As a result, it is found that the PAN/PBO blends could be a promising alternative for the cost-effective PAN-based CF precursors, since they can decrease the cost of the CF production by means of: (a) eliminating the pre-oxidation process, (b) having considerable all-carbon ring formations within a short period, and (c) having a relatively fast conversion rate, reaching 95% 6-membered carbon ring formation.

42 ENGINEERING↗

The HPC Container Experience on the Summit Supercomputer

Containers are seeing widespread use in the world of High Performance Computing, with many HPC Centers either providing their own containerization solution or adopting existing ones like Singularity and Apptainer. The demand for containerization options come from users who want to take advantage of the portability and reproducibility containers can provide, as well as being able to build and use applications that are only distributed in container form or are otherwise unsuited to natively run in an HPC environment. The users served by the Oak Ridge Leadership Computing Facility are no exception. We go over the past and current containerization offerings at the Oak Ridge Leadership Computing Facility, mainly focusing on the Summit supercomputer. We arrive at using a combination of Podman and Singularity to allow users to build and run containers directly on Summit, without requiring external resources or hardware for any step of the process. We look at a couple of projects running on Summit that greatly benefited from being able to use containers on Summit. And we compare benchmarks running natively and in containers on Summit at different scales, observing minimal performance difference and consistent behavior across all tests.

Abraham, Subil↗

Thermal dissipation studies and Pu238/Li source simulation (MCNP) of the K2 containers (COWS)

The six K2 containers (COWS) have been proposed to be shipped to WIPP in the configuration depicted in Figure 1. Currently, the containers reside in the water bath storage and have not been opened since LANL received them. The K2 containers containing the mound scrap material each have their own unique dose rate and thermal loading. 3 The properties of each container are listed below in Table 1. The problem with loading the K2 container into the proposed configuration is the thermal load the package will experience. Each component within the package has a thermal working limit that should not be exceeded. 2 However, the package must also maintain enough shielding to lower the measured dose rate at the surface of the drum to be accepted by WIPP. Testing the current configuration through simulation LANL can prove heat will not compromise any components and dose can be reduced to a safe configuration.

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Coupon Container Pressure Test

A total of six containers were tested to verify the Maximum Allowed Working Pressure (MAWP) rating of 100 psi. Three Inner Container Pressure Test Assemblies (1006759387-AA) and three Outer Container Pressure Test Assemblies (1006729168-AA) were tested. The container serial numbering is the drawing number followed by the serial number (i.e.,1006759387-###). The test procedure was performed as follows: 1. Pressurize to 50 psi and hold for 5 minutes. 2. Increase pressure to 100 psi and hold for 5 minutes. 3. Increase pressure to 150 psi and hold for a minimum of 20 minutes. A container is considered to pass if the pressure drops less than 1% at the end of the 20 minutes. All six containers passed the test.

42 ENGINEERING↗

Thermal Evaluation of the SAVY-4000 1 Quart Container at High Heat Loads

The SAVY-4000 Safety Analysis Report (SAR) was published in 2013 which established the design life of the container series through physical testing that meets applicable requirements from DOE M 441.1-1, Nuclear Material Packaging Manual. One critical requirement in DOE M 441.1-1 is to set a maximum heat load for the entire series to ensure that throughout the lifetime of the container, each of the components still performs within manufacture specifications. The original maximum decay heat limit has been defined within the SAVY-4000 SAR, which was accomplished by completing a series of tests that heat loaded the SAVY-4000 series and measured the steady state temperature and graded it against manufacture specifications. The container series is comprised of a corrosion resistant 316L stainless steel containment boundary, ceramic composite filter for the prevention of radiological particulate release and a chemically stable O-ring made of Viton ® . Currently, the SAVY 4000 maximum decay heat load is set at 25 Watts and the heat load expected during normal handling and storage is considered sufficient that the SAVY 4000 container requirements will not be the limiting factor for storage of most common material in use at TA-55, e.g. weapons grade oxide, americium, Pu-238 oxide and encapsulated heat sources. The SAVY 4000 lifetime was originally set as 5 years within the SAVY-4000 SAR, but in July 2019 the lifetime was extended to 15 years through a technical basis justification approved by the Department of Energy (DOE) Los Alamos Field Office. The 25 Watt limit applies to all SAVY 4000 container sizes; 1-quart, 2-quart, 3-quart, 5-quart, 8-quart, 12-quart, 5-gallon, and 10-gallon.

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Using containers to speed up development, to run integration tests and to teach about distributed systems

GlideinWMS is a workload manager provisioning resources for many experiments including CMS and DUNE. The software is distributed both as native packages and specialized production containers. Following an approach used in other communities like web development we built our workspaces, system-like containers to ease development and testing. Developers can change the source tree or check out a different branch and quickly reconfigure the services to see the effect of their changes. In this paper, we’ll talk about what differentiates workspaces from other containers. We’ll describe our base system composed of three containers. A one-node cluster including a compute element and a batch system. A GlideinWMS Factory controlling pilot jobs. And a scheduler and Frontend, to submit jobs and provision resources. Additional containers can be used for optional components. This system can easily run on a laptop and we’ll share our evaluation of different container runtimes, with an eye for ease of use and performance. Finally, we’ll talk about our experience as developers and with students. The GlideinWMS workspaces are easily integrated with IDEs like VS Code, simplifying debugging and allowing development and testing of the system also when offline. They simplified the training and onboarding of new team members and Summer interns. And they were useful in workshops where students could have first-hand experience with the mechanisms and components that, in production, run millions of jobs.

Mambelli, Marco↗

Full Submersion Water Testing of SAVY-4000 Nuclear Material Storage Containers

SAVY-4000 (SAVY) containers are the primary container used at Technical Area (TA) TA-55 plutonium facility for the prevention of water ingress to mitigate against a criticality event. The basis for water resistance of these containers has long been attributed to the Polytetrafluoroethylene (PTFE) membrane that is assembled on the outermost surface of the filter assembly. On August 22nd a test of a container used inside of a glovebox was performed that brought into question this long-standing-basis. This test was performed by inverting a SAVY-lid onto a specialized piece of equipment for evaluating the integrity of the PTFE membrane. During the test water was observed passing through the filter indicating that the filter membrane was no longer preventing the ingress of water through the filter. The assumption after making this observation was that alpha-particles were rapidly degrading the membrane creating a leak path through the underlying aluminosilicate media (Fiberfrax®). The apparatus used was designed to only test the lid rather than the entire SAVY assembly. A test plan, PA-PLAN-01921, was developed to investigate whether a fully assembled container with a fully degraded PTFE membrane would be capable of meeting the criteria defined in PA-RD-1009 of not allowing more than 200 ml of water to enter the container with a water column of 6-inches applied over a 2-hour period. This report provides the results of the testing performed against PA-PLAN-01921.

36 MATERIALS SCIENCE↗

ALARA Review for Venting of Flanged Tritium Waste Containers (FTWCs) at TA-54

This project will vent headspace hydrogen and oxygen from specialized high-pressure storage vessels called flanged tritium waste containers (FTWCs). There are four of these containers located in Los Alamos National Laboratory’s (LANL’s) Technical Area 54 (TA-54), Building 1028. This building is in the southwest corner of LANL’s Material Disposal Area G. The vented headspace gas is expected to contain tritium in the form of water vapor, elemental hydrogen or a combination of both. The venting operation is expected to take place in 2025. There will be a series of operational readiness reviews prior to venting activities commencing. The FTWCs at TA-54 contain tritium-contaminated metal parts and molecular sieve media, which is a pebble-like material used to absorb water vapor from the air. This molecular sieve media inside the FTWCs is contained in metal canisters, along with some loose media material in bags. Over time, tritiated water vapor that had been adsorbed onto the media can become liberated into the FTWC headspace gas. Radiolysis can cause separation of the water vapor into its hydrogen and oxygen components, resulting in the potentially hazardous gas mixture within the FTWC. LANL has determined that continued tritium storage in these containers can pose an unsafe condition due to possible hydrogen and oxygen gas buildup within the FTWCs with a potential for explosion if sparks are generated within the FTWCs. To mitigate this hazard, the FTWCs will be stabilized by venting them in-place to remove hazardous gases.

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3013 Baseline Inner Container Report: Description, Imaging, and Analysis

This report presents consolidated findings from three microscopy studies of baseline Bagless Transfer Containers (BTCs), which are the inner containers used in DOE Standard 3013-compliant plutonium storage packages. The studies were conducted by Los Alamos National Laboratory (LANL), Savannah River National Laboratory (SRNL), and DNV, a subcontractor specializing in corrosion science. The baseline BTCs examined had not been exposed to corrosive environments, serving as control samples for comparison with destructively examined (DE) containers. Additionally, the Background section provides an overview of the BTC design, including manufacturing methods, material properties, and container configurations that may influence corrosion behavior. The primary objective of the LANL and SRNL studies was to establish reference characteristics of BTCs to distinguish manufacturing artifacts from corrosion-induced features observed in DE containers. Both laboratories used advanced microscopy techniques, including Wide Area Microscopy (WAMS), Laser Confocal Microscopy (LCM), Scanning Electron Microscopy (SEM), and Focused Ion Beam (FIB), to reveal that most surface anomalies were shallow and attributable to flow-forming processes, not corrosion. Subsurface impurities, identified as non-metallic inclusions, were also observed. DNV’s investigation focused on characterizing the mechanical and chemical properties of the BTC material to support crack growth modeling. Their findings indicate higher hardness and strength but reduced ductility—consistent with flow-formed 304L stainless steel and a higher-than-expected martensite content, in contrast to manufacturer claims. Ongoing and future studies, including Electron Backscatter Diffraction (EBSD), aim to further understand the microstructural factors influencing crack initiation and propagation. The combined studies provide a crucial baseline for distinguishing corrosion effects in DE containers, contributing to the safe and reliable long-term storage of plutonium-bearing materials.

36 MATERIALS SCIENCE↗

Test Report: Glovebox Test Fire for Evaluation of Effects on Containers and Windows

This test report describes a designed Glovebox (GB) fire to identify target environmental conditions that GB containers and windows are subject to such fires. The fire was designed by representatives from the Los Alamos National Laboratory (LANL) to replicate a realistic worst-case fire scenario at LANL. Key results of these experiments include: • The GB fire was active for more than 30 minutes. • Thermocouples were placed at multiple points in the GB were measured, including one on top of the container. Temperatures at varied widely as a function of location during the fires, as might be expected and as a function of proximity to fire, elevation in the GB, and in relation airflow present during the test, which constantly introduces room-temperature air into the GB. The maximum temperature recorded by a thermocouple was slightly less than 500°F at the elevation of the highest gloveports and near, but not in contact with the GB wall. • A thermographic camera imaged the region of the GB container during the fire. These data report container temperatures of up to approximately 900°F (482°C) over a period of several minutes. • Four kilograms of lead shot were held in the container. The majority of the shot melted during the course of the fire (lead melting point: 621°F/327°C). • Multiple windows fractured during the test. In some cases, the polymer interlayer of the laminated GB window glass appears to have sustained damage due to thermal breakdown of the polymer, though the interlayer of the laminated GB window glass appears to have remained intact in all cases. • The one window with an attached thermocouple was less affected by the fire. The attached thermocouple measured up to approximately 150°F. • Other thermocouples along (but not in contact with) the GB wall and closer to the fire (and cracked windows) reported up to approximately 200°C (392° F). These finding suggest that subjecting containers to 500°C for 45 minutes is bounding and representative for fires of this type. It should also be noted that 500°C (932°F) has been previously used as a test criterion for related work. Similarly, 200°C may be a reasonable target temperature for GB windows subjected to fires of this type.

42 ENGINEERING↗

Evaluation of Technologies to Mitigate the Presence of Gaseous Elemental Mercury in Waste Disposal Containers

A study was conducted to evaluate sorbent technologies that can mitigate the presence of elemental mercury (Hg⁰) in waste containers for mercury-contaminated debris (MCD). Decontamination and demolition (D&D) activities at the Y-12 National Security Complex (Y-12) and other U.S. Department of Energy (DOE) Oak Ridge Reservation (ORR) facilities generate MCD requiring offsite disposal. The debris is packaged in appropriate waste containers and may be temporarily stored onsite prior to transport for treatment and/or disposal. During transportation of loads that had no visible liquid Hg at the point of origin, temperature changes can cause Hg⁰ to evaporate, condense, and form droplets on container walls. Furthermore, vibration during transportation could cause beads of Hg to be released from the debris, container walls, and ceiling, resulting in pools of liquid Hg⁰ on the container floor. Waste acceptance criteria (WAC) limitations for commercial disposal facilities, the Nevada National Security Site (NNSS), and ORR mixed low-level waste landfills prohibit the presence of any free liquids in containers identified as a solid waste form. Potential solutions to mitigate the presence of residual liquids that could be formed through vapor condensation include the use of sorbents or similar materials to capture and stabilize volatile Hg⁰ vapors and thus ensure compliance with landfill WAC requirements. This report summarizes data from small-scale laboratory experiments conducted to evaluate sorbent materials for Hg⁰ vapor suppression and sorption of liquid Hg⁰ that could form under relevant transportation and disposal conditions. A series of experiments was conducted to evaluate commercial sorbent materials and their effectiveness for Hg⁰ sorption across a temperature range from 19.4°C to 60°C. The impact of residual moisture on sorption was investigated under relevant conditions, and leaching tests were performed to assess the stability of Hg⁰ captured sorbent materials. The results provide estimates for sorbent quantities needed for a given Hg⁰ mass loading based on experimental results exposing sorbents to gaseous and liquid Hg⁰ at various mass ratios. Overall, sorbents that were most effective for Hg⁰ vapor suppression were brominated activated carbons, mackinawite-based sorbents coated on vermiculite, and sulfur-modified granular activated carbon. Elevated temperatures and moisture conditions did not result in significant increases of Hg⁰ headspace concentrations, and the materials also demonstrated high sorption capacities for the sorption of liquid Hg⁰.

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Technical Basis SAVY-4000® Series, 5.5G Container (Rev. 1)

The 5.5 Gallon (5.5G) SAVY-4000® nuclear material storage container is the latest in the SAVY-4000® series. The 5.5G is similar to that of a 1or 2Qt container in functionality with the exception of a larger volume deep drawn and spun form body achieved through increases in the depth and diameter of the container. Here, a technical basis using engineering equivalency analysis, calculation, and test data is presented to establish that the 5.5G SAVY-4000® Container is a DOE Manual 441.1-1 compliant container at a drop height of 9 feet (rather than the typical 12 ft of the other SAVY-4000® containers) and that a twenty-five year design life (as with the currently approved SAVY-4000® series) is justified.

99 GENERAL AND MISCELLANEOUS↗

Using Containers to Speed Up Development, to Run Integration Tests and to Teach About Distributed Systems

GlideinWMS is a workload manager provisioning resources for many experiments, including CMS and DUNE. The software is distributed both as native packages and specialized production containers. Following an approach used in other communities like web development, we built our workspaces, system-like containers to ease development and testing. Developers can change the source tree or check out a different branch and quickly reconfigure the services to see the effect of their changes. In this paper, we will talk about what differentiates workspaces from other containers. We will describe our base system, composed of three containers: a one-node cluster including a compute element and a batch system, a GlideinWMS Factory controlling pilot jobs, and a scheduler and Frontend to submit jobs and provision resources. Additional containers can be used for optional components. This system can easily run on a laptop, and we will share our evaluation of different container runtimes, with an eye for ease of use and performance. Finally, we will talk about our experience as developers and with students. The GlideinWMS workspaces are easily integrated with IDEs like VS Code, simplifying debugging and allowing development and testing of the system even when offline. They simplified the training and onboarding of new team members and summer interns. And they were useful in workshops where students could have first-hand experience with the mechanisms and components that, in production, run millions of jobs.

Mambelli, Marco [Fermilab] (ORCID:0000000294892681↗