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At least 325 records · Page 18

Engineering models of the Venus atmosphere.

Engineering models of the Venus atmosphere are presented for use in spacecraft design and mission planning. The models are developed from (1) data measured by the U.S. Mariner 5 and USSR Venera spacecraft, (2) earth-based measurements, and (3) theory which best satisfies the observations. The models include a most probable model and models for extremes of molecular mass and solar activity. In addition to the basic engineering models, other atmospheric characteristics and parameters affecting the models are discussed including planetary radius, atmospheric composition and clouds.

Noll, R. B.↗

Synthesis of improved phenolic and polyester resins

Thirty-seven cured phenolic resin compositions were prepared and tested for their ability to provide improved char residues and moisture resistance over state of the art epoxy resin composite matrices. Cyanate, epoxy novolac and vinyl ester resins were investigated. Char promoter additives were found to increase the anaerobic char yield at 800 C of epoxy novolacs and vinyl esters. Moisture resistant cyanate and vinyl ester compositions were investigated as composite matrices with Thornel 300 graphite fiber. A cyanate composite matrix provided state of the art composite mechanical properties before and after humidity exposure and an anaerobic char yield of 46 percent at 800 C. The outstanding moisture resistance of the matrix was not completely realized in the composite. Vinyl ester resins showed promise as candidates for improved composite matrix systems.

Delano, C. B.↗

Rapid adhesive bonding concepts

Adhesive bonding in the aerospace industry typically utilizes autoclaves or presses which have considerable thermal mass. As a consequence, the rates of heatup and cooldown of the bonded parts are limited and the total time and cost of the bonding process is often relatively high. Many of the adhesives themselves do not inherently require long processing times. Bonding could be performed rapidly if the heat was concentrated in the bond lines or at least in the adherends. Rapid adhesive bonding concepts were developed to utilize induction heating techniques to provide heat directly to the bond line and/or adherends without heating the entire structure, supports, and fixtures of a bonding assembly. Bonding times for specimens are cut by a factor of 10 to 100 compared to standard press bonding. The development of rapid adhesive bonding for lap shear specimens (per ASTM D1003 and D3163), for aerospace panel bonding, and for field repair needs of metallic and advanced fiber reinforced polymeric matrix composite structures are reviewed.

Stein, B. A.↗

Fracture modes in notched angleplied composite laminates

The Composite Durability Structural Analysis (CODSTRAN) computer code is used to determine composite fracture. Fracture modes in solid and notched, unidirectional and angleplied graphite/epoxy composites were determined by using CODSTRAN. Experimental verification included both nondestructive (ultrasonic C-Scanning) and destructive (scanning electron microscopy) techniques. The fracture modes were found to be a function of ply orientations and whether the composite is notched or unnotched. Delaminations caused by stress concentrations around notch tips were also determined. Results indicate that the composite mechanics, structural analysis, laminate analysis, and fracture criteria modules embedded in CODSTRAN are valid for determining composite fracture modes.

Irvine, T. B.↗

Addition polymers from 1,4,5,8-tetrahydro-1,4;5,8-diepoxyanthracene and Bis-dienes: Processable resins for high temperature application

1,4,5,8-Tetrahydro-1,4;5,8-diepoxyanthracene reacts with various anthracene endcapped polyimide oligomers to form Diels-Alder cycloaddition copolymers. The polymers are soluble in common organic solvents, and have molecular weights of approximately 21,000 to 32,000. Interestingly, these resins appear to be more stable in air then in nitrogen. This is shown to be due to a unique dehydration (loss of water ranges from 2 to 5 percent) at temperatures of 390 to 400 C to give thermo-oxidatively stable pentiptycene units along the polymer backbone. Because of their high softening points and good thermo-oxidative stability, the polymers have potential as processible, matrix resins for high temperature composite applications.

Meador, Mary Ann B.↗

A proposed comet nucleus penetrator for the Comet Rendezvous Asteroid Flyby mission

The importance of the study of comets has led NASA to plan a mission to rendezvous with comet Tempel 2 in 1997. Critical to the understanding of comets will be measurements of the nucleus material to determine its elemental and isotopic composition, its mechanical properties, and its thermal state and properties. this paper describes a proposal for a Comet Nucleus Penetrator to accomplish these measurement goals. The Comet Nucleus Penetrator will implant instruments into the comet's nucleus beneath a probable volatile-depleted surface mantle into material more representative of the bulk composition of the nucleus.

Swenson, B. L.↗

High-temperature processing of oxide superconductors and superconducting oxide-silver oxide composite

High temperature processing was found to partially convert the green 211 phase oxide to 123 phase. High Tc superconductivity was observed in Bi-Sr-Cu-O and Y-Sr-Cu-O systems prepared using the same heat treatment process. High temperature processing presents an alternative synthetic route in the search for new high Tc superconductors. An unusual magnetic suspension with enhancement in critical current density was observed in the 123 and AgO composite.

Wu, M. K.↗

Composite laminate tailoring with probabilistic constraints and loads

A reliability-based structural synthesis procedure was developed to tailor laminates to meet reliability-based (ply) strength requirements and achieve desirable laminate responses. The main thrust is to demonstrate how to integrate the optimization technique in the composite laminate tailoring process to meet reliability design requirements. The question of reliability arises in fiber composite analysis and design because of the inherent scatter that is observed in the constituent (fiber and matrix) material properties during experimentation. Symmetric and asymmetric composite laminates subject to mechanical loadings are considered as application examples. These application examples illustrate the effectiveness and ease with which reliability considerations can be integrated in the design optimization model for composite laminate tailoring.

Thanedar, P. B.↗

Processable, high temperature polymers from 1,4,5,8-tetrahydro-1,4;5,8-diepoxyanthracene and bis-dienes

1,4,5,8-tetrahydro-1,4;5,8-diepoxyanthracene reacts with various anthracene end-capped polyimide oligomers to form Diels-Alder cycloaddition copolymers. The polymers are soluble in common organic solvents, and have molecular weights of approximately 21,000 to 32,000. These resins exhibit lower weight loss in air than in nitrogen. This is suggested to be due to dehydration (loss of water ranges from 2 to 5 percent) at temperatures of 390 to 400 C to give thermooxidatively stable pentiptycene units along the polymer backbone. Because of their high softening points and good thermooxidative stability, the polymers have potential as processable, matrix resins for high temperature composite applications.

Meador, Mary Ann B.↗

Composite laminate tailoring with probabilistic constraints and loads

A reliability-based structural synthesis procedure was developed to tailor laminates to meet reliability-based (ply) strength requirements and achieve desirable laminate responses. The main thrust is to demonstrate how to integrate the optimization technique in the composite laminate tailoring process to meet reliability design requirements. The question of reliability arises in fiber composite analysis and design because of the inherent scatter that is observed in the constituent (fiber and matrix) material properties during experimentation. Symmetric and asymmetric composite laminates subject to mechanical loadings are considered as application examples. These application examples illustrate the effectiveness and ease with which reliability considerations can be integrated in the design optimization model for composite laminate tailoring.

Thanedar, P. B.↗

Structure-to-property relationships in addition cured polymers. 4: Correlations between thermo-oxidative weight losses of norbornenyl cured polyimide resins and their composites

Relationships are identified between the thermo-oxidative stability (TOS) at 316 C of a wide variety of PMR (polymerization of monomeric reactants) addition cured polyimide resins and their corresponding graphite fiber composites. Weight loss results at 316 C confirmed the expected relationship of increasing aliphatic endcap content with decreasing TOS. Moreover, the resin TOS study also showed an unexpected linear correlation of decreasing weight loss to increasing ratio of benzylic diamine to aliphatic endcap in the range of the stoichiometries studied. Only after long term 316 C aging does the dianhydride used with the benzylic diamines become an additional factor in influencing the amount of PMR resin and composite weight losses. Also, the benzylic systems consistently showed much lower resin and composite weight losses at 316 C than the corresponding nonbenzylic norbornenyl resins and composites, except when the nonbenzylic diamine monomer does not contain a connecting group. Instead, this diamine resulted in a 316 C resin and composite weight loss that was only competitive with benzylic type diamines. Results show excellent correlation between TOS of all graphite fiber PMR composites and resins.

Alston, William B.↗

Pyroclastic deposits on the western limb of the moon

A geologic characterization is presented of 17 newly identified localized pyroclastic deposits on the western limb of the moon. The results show that lunar pyroclastic deposits are more pervasive on the western limb of the moon than once thought. The western limb dark-mantle deposits in the proximal zone are probably related to faults and fractures associated with the Cordillera ring of Orientale Basin. All the localized pyroclastic deposits on the western limb for which near-infrared reflectance spectra have been obtained exhibit parameter that allowed them to be assigned to the three spectral groups described elsewhere. Western limb pyroclastic deposits appear to represent various stages in a formational sequence in which an initial explosive phase is followed by varying amounts of mare flooding. In view of their sequential formation, both the pyroclastic and mare materials associated with individual volcanic complexes may be the products of the same parent magmas and have very similar compositions.

Coombs, Cassandra R.↗

Fabrication and Thermo-Optical Properties of the MLS Composite Primary Reflector

The Microwave Limb Sounder (MLS) is a limb-sounding radiometer sensing emissions in the millimeter and sub-millimeter range. MLS will contribute to an understanding of atmospheric chemistry by assessing stratospheric and tropospheric ozone depletion, climate forcings and volcanic effects. The heart of the antenna is the primary reflector, constructed from graphite/cyanate composites in a facesheet/core construction. The reflector has an aperture of one square meter, a mass of 8.7 kilos and final figure accuracy of 4.37 microns rms. The surface is also modified to ensure RF reflectivity, prevent solar concentration and provide thermal balance to the spacecraft The surface is prepared by precision beadblasting, then coated with vapor deposited aluminum (VDA) and finally a layer of silicon suboxide (SiO(x)) to control the infrared emissivity. The resulting surface has a solar absorptance of 0.43 and an absorptance/emittance ratio of 1.3. BRDF analysis shows that 93% of the incident thermal energy is reflected outside a 10 degree angle of cone. For its mass and aperture, we believe this reflector to have the highest figure accuracy yet achieved in a composite antenna construction.

Willis, Paul B.↗

Pt and Hf Additions to NiAl Bond Coats and Their Effect on the Lifetime of Thermal Barrier Coatings

The lifetimes of thermal barrier coatings (TBC's) with various NiAlPt(HfZr) bond coats were determined by cyclic oxidation testing at 1163 C (2125 F). The bond coats were sprayed from powders by low pressure plasma spraying onto Rene N5 superalloy substrates. Yttria stabilized zirconia (8YSZ) top coats were applied by air plasma spraying. Surprisingly, there was not a strong correlation between TBC lifetime and Pt or Hf content although Zr additions decreased lifetimes. TBC failure morphologies and bond coat microstructures were examined and are discussed with respect to the bond coat compositions.

Nesbitt, J. A.↗

Nitrogen Isotopic Anomalies in a Hydrous Interplanetary Dust Particle

Interplanetary dust particles (IDPs) collected in the stratosphere are the fine-grained end member (5 - 50 microns in size) of the meteoritic material available for investigation in the laboratory. IDPs are derived from either cometary or asteroidal sources. Some IDPs contain cosmically primitive materials with isotopic signatures reflecting presolar origins. Recent detailed studies using the NanoSIMS have shown there is a wide variation of isotopic signatures within individual IDPs; grains with a presolar signature have been observed surrounded by material with a solar isotopic composition. The majority of IDPs studied have been anhydrous. We report here results from integrated NanoSIMS/FIB/TEM/Synchrotron IR studies of a hydrous IDP, focused on understanding the correlations between the isotopic, mineralogical and chemical compositions of IDPs.

Smith, J. B.↗