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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Alumina-supported Pd-Ag catalysts for low-temperature CO and methanol oxidation

Pd-Ag bimetallic catalysts, supported on gamma-Al2O3, have been evaluated as exhaust catalysts for methanol-fueled vehicles. Laboratory studies have shown that a 0.01% Pd-5% Ag catalyst has greater CO and CH3OH oxidation activity than either 0.01% Pd or 5% Ag catalysts alone. Moreover, Pd and Ag interact synergistically in the bimetallic catalyst to produce greater CO and CH3OH oxidation rates and lower yields of methanol partial oxidation products than expected from a mixture of the single-component catalysts. The Pd-Ag synergism results from Pd promoting the rate of O2 adsorption and reaction with CO and CH3OH on Ag. Rate enhancement by the bimetallic catalyst is greatest at short reactor residence times where the oxygen adsorption rate limits the overall reaction rate.

Mccabe, R. W.↗
NASA NTRS1987

Characterization of Pt/SnO2 catalysts for CO oxidation

Results are presented of surface characterization of 2% and 1% (w/w) Pt on SnO2 catalysts which are being used in promoting the oxidation of CO in pulsed CO2 lasers. The N2 adsorption BET surface area for both catalysts is 6.9 sq m/g. The CO chemisorbed area at 313K is 0.17 sq m/g and 0.062 sq m/g for the 2% and 1% catalysts, respectively. Monitoring the reaction between CO and O2 by the same technique, at the same temperature yields a turn-over frequency (TOF) for the 2% catalyst of 2.7 x 100 molecules of CO2/site/s and for the 1% catalyst a value of 1.2 x 100. The ratio of the TOFs for the two catalysts is 2.2 which is approximately the ratio of the Pt loading.

Brown, K. G.↗
NASA NTRS1987

Detection of CO (J=1-0) in the dwarf elliptical galaxy NGC 185

The detection of CO (J = 1-0) emission in the dwarf elliptical galaxy NGC 185 is reported. The presence of massive molecular clouds in this early-type galaxy supports the idea of recent or ongoing stellar formation indicated by the population of blue stars in the center. The CO was detected in two positions in the galaxy, the center, and a prominent dustcloud. The emission profile has two peaks, roughly centered around the systemic velocity. It is found that NGC 185 is overluminous in blue light for its CO luminosity compared with Sc galaxies. This might indicate a higher star-formation efficiency for NGC 185 than for the late-type galaxies.

Wiklind, Tommy↗
NASA NTRS1986

A search for the millimeter-wave transitions of CO(+) in Comet P/Halley

Although no detection was obtained in the present search for the N = 2-1, J = 5/2-3/2, and J = 3/2-1/2 mm-wave transitions of CO(+) in Comet P/Halley, a 2-sigma upper limit of 8 x 10 to the 11th/sq cm was determined for the beam-averaged column density of this specie. Upon comparison of this upper limit estimate with model predictions involving the variation of such parameters as the chemical composition and ionization mechanisms, it appears that H2O may be the main nucleus constituent of the comet. If, in addition, photodissociation ionization is active in the coma, then the origin of the CO(+) is more likely to be in CO2 than in CO.

Baum, S.↗
NASA NTRS1987

Carbon Dioxide Observational Platform System (CO-OPS), feasibility study

The Carbon Dioxide Observational Platform System (CO-OPS) is a near-space, geostationary, multi-user, unmanned microwave powered monitoring platform system. This systems engineering feasibility study addressed identified existing requirements such as: carbon dioxide observational data requirements, communications requirements, and eye-in-the-sky requirements of other groups like the Defense Department, the Forestry Service, and the Coast Guard. In addition, potential applications in: earth system science, space system sciences, and test and verification (satellite sensors and data management techniques) were considered. The eleven month effort is summarized. Past work and methods of gathering the required observational data were assessed and rough-order-of magnitude cost estimates have shown the CO-OPS system to be most cost effective (less than $30 million within a 10 year lifetime). It was also concluded that there are no technical, schedule, or obstacles that would prevent achieving the objectives of the total 5-year CO-OPS program.

Bouquet, D. L.↗
NASA NTRS1987

IOS and ECS line coupling calculation for the CO-He system - Influence on the vibration-rotation band shapes

Line coupling coefficients resulting from rotational excitation of CO perturbed by He are computed within the infinite order sudden approximation (IOSA) and within the energy corrected sudden approximation (ECSA). The influence of this line coupling on the 1-0 CO-He vibration-rotation band shape is then computed for the case of weakly overlapping lines in the 292-78 K temperature range. The IOS and ECS results differ only at 78 K by a weak amount at high frequencies. Comparison with an additive superposition of Lorentzian lines shows strong modifications in the troughs between the lines. These calculated modifications are in excellent quantitative agreement with recent experimental data for all the temperatures considered. The applicability of previous approaches to CO-He system, based on either the strong collision model or exponential energy gap law, is also discussed.

Boissoles, J.↗
NASA NTRS1988

Detection of H I, OH, CO, and optical imaging of the distant galaxy IRAS 12112 + 0305

The detection of H I absorption and OH and CO emission from the galaxy IRAS 12112 + 0305, which is receding from the sun at about 7 percent of the speed of light is reported. This galaxy, which appears to be an ongoing merger, radiates about 2 x 10 to the 12th solar luminosities in the infrared. The H I, OH, and CO spectra are indicative of large turbulent motions. From the millimeter wave CO observations, a total mass of molecular gas of 4 x 10 to the 10th solar masses is inferred. The OH emission in the 1667 MHz line is the most luminous extragalactic OH maser reported so far, with an isotropic luminosity of 1800 solar luminosities.

Mirabel, I. F.↗
NASA NTRS1988

The photodissociation of CO in circumstellar envelopes

The CO photodissociation rate for the unshielded ISM is calculated using recent laboratory results which confirm that photodissociation occurs by way of line absorption. A value of 2.0 x 10 to the -10th/s, an order of magnitude higher than the rate used in the past, is obtained. The new rate and a treatment of the radiative transfer and shielding are used to develop a theory for the CO abundance in the circumstellar envelopes of cool, evolved stars, and results are presented on the spatial variation of CO, C, and C(+). It is shown that these distributions play important roles in determining the observational properties of circumstellar envelopes.

Mamon, G. A.↗
NASA NTRS1988

The effect of Co alloying content on the kinetics of reaction zone growth in tungsten fiber reinforced superalloy composites

A Co-free modified superalloy similar in composition to Waspaloy is investigated in an effort to understand the effect of Co on reaction zone growth kinetics and verify the chemistry dependence of reaction zone growth in the matrix of tungsten fiber reinforced superalloy composites. The values of the parabolic rate constant, characterizing the kinetics of reaction zone growth, for the Waspaloy matrix and the C-free alloy as well as five other alloys from a previous study confirm the dependence of reaction zone growth kinetics on cobalt content of the matrix. The Co-free alloy composite exhibits the slowest reaction zone growth among all tungsten fiber reinforced composites studied to date.

Rodriguez, A.↗
NASA NTRS1989

Heterodyne spectroscopy of the J = 17-16 CO line in Orion

High-resolution spectra of the 153 micron J = 17-16 CO line in the BN-KL region of Orion using a laser heterodyne spectrometer are obtained. The line shows broad wings characteristic of the plateau emission as well as a narrower component probably associated with the quiescent gas in the molecular ridge. From an analysis of the plateau emission together with that observed in lower J CO transitions, an excitation temperature of 180 + or - 50 K and minimum column density of 1 x 10 to the 18th /sq cm are derived for CO in this component, which constitutes 80 percent of the total integrated intensity of the J = 17-16 line near BN. The peak intensity of the narrower component observed at 0.8 km/s resolution increases relative to that of the plateau component toward theta 1C and away from BN, while the width decreases from 10 to 4 km/s (FWHM).

Boreiko, R. T.↗
NASA NTRS1989

Photodissociation of CO in the thermosphere of Venus

Recent investigations of CO photoabsorption demonstrate that photodissociation longward of the ionization threshold at 88.5 nm occurs primarily through line absorptions rather than continuous processes. High-resolution photoabsorption cross sections for CO at rotational temperatures near 250 K have been constructed from the improved data on dissociating transitions. The effects of the new cross sections on the rate of solar photodissociation of CO in the thermosphere of Venus are examined, and the results are compared to values obtained with the lower resolution cross sections available previously. It is found that the photodissociation profile peaks slightly higher in the atmosphere and the peak value and integrated total rate both decrease by about a factor of two.

Fox, J. L.↗
NASA NTRS1990

Alternative catalysts for low-temperature CO-oxidation

MnO sub x, Ag/MnO sub x, Cu/MnO sub x, Pt/MnO sub x, Ru/MnO sub x, Au/CeO sub x, and Au/Fe2O3 were synthesized and tested for CO oxidation activity in low concentrations of stoichiometric CO and O2 at 30 to 75 C. Catalytic activity was measured for periods as long as 18000 minutes. At 75 deg Au/MnO sub x is most active sustaining nearly 100 percent CO conversion for 10000 minutes. It also retains high activity at 50 and 30 C with negligible decay in activity. A direct comparison between an unpretreated 10 percent Au/MnO sub x catalyst and an optimized 19.5 percent Pt/SnO sub 2 (pretreated) catalyst shows that the Au/MnO sub x catalyst exhibits much higher catalytic activity and far superior decay characteristics. Other catalysts including Au/CeO sub x and Au/Fe2O3 also perform well. The Cu/MnO sub x exhibits a high initial activity which decays rapidly. After the decay period the activity remains very stable making Cu/MnO sub x a potential candidate for long-term applications such as CO2 lasers in space.

Gardner, Steven D.↗
NASA NTRS1990

Effect of pretreatment on a platinized tin oxide catalyst used for low-temperature CO-oxidation

A commercial platinized tin oxide catalyst used for low-temperature CO oxidation has been characterized using ion scattering spectroscopy (ISS), Auger electron spectroscopy (AES) and Electron Spectroscopy for Chemical Analysis (ESCA) before and after reduction in 40 Torr of CO for 1 hour at various temperatures from 75 to 175 C. The reduction results in loss of surface oxygen, formation of metallic tin, conversion of platinum oxides to Pt-O-Sn and Pt(OH)2 and a small amount of metallic Pt which alloys with the tin. These results should be useful in understanding how the pretreatment temperature affects the catalytic activity of platinized tin oxide toward CO oxidation.

Drawdy, Jean E.↗
NASA NTRS1989

Large-scale transport of a CO-enhanced air mass from Europe to the Middle East

On November 14, 1981, the shuttle-borne Measurement of Air Pollution from Satellites (MAPS) experiment observed a carbon monoxide (CO) enhanced air mass in the middle troposphere over the Middle East. The primary source of this polluted air was estimated by constructing adiabatic isentropic trajectories backwards from the MAPS measurement location over a 36 h period. The isentropic diagnostics indicate that CO-enhanced air was transported southeastward over the Mediterranean from an organized synoptic-scale weather regime, albeit of moderate intensity, influencing central Europe on November 12. Examination of the evolving synoptic scale vertical velocity and precipitation patterns during this period, in conjuction with Meteosat visible, infrared, and water vapor imagery, suggests that the presence of this disturbed weather system over Europe may have created upward transport of CO-enhanced air between the boundary-layer and midtropospheric levels, and subsequent entrainment in the large-scale northwesterly jet stream flow over Europe and the Mediterranean.

Connors, V. S.↗
NASA NTRS1990

Aperture synthesis CO observations of the inner disk of NGC 1068

NGC 1068 is probably the nearest galaxy with both a high rate of star formation and a high luminosity active nucleus. About one-half of the total IR luminosity originates in a disk approximately 30 seconds in size, which has been taken as evidence for a high rate of massive star formation (Telesco et al. 1984). Previous CO line observations have shown the existence of a ring at the outer boundary of the inner disk (Myers and Scoville 1987). Although these observations have proved that this ring is extremely rich in molecular gas (as suggested by Scoville et al. 1983), the angular resolution (approx. 6 seconds) was not high enough to resolve its structure. New aperture synthesis observations of the CO (J=1 to 0) emission in the inner disk of NGC 1068 have been carried out with the Owens Valley Radio Observatory (OVRO) mm Interferometer. The new receivers installed for the 88/89 season have allowed researchers to obtain a high sensitivity map of the CO emission. The molecular cloud ring has been resolved and continuum as well as line emission from the nucleus of the galaxy have been detected.

Planesas, P.↗
NASA NTRS1990

A relationship between the integrated CO intensity and the radio continuum emission in spiral galaxies

In an effort to determine the role played by cosmic ray electrons and interstellar radiation fields on the collapse of molecular clouds, a survey was begun to investigate the relationship between the radio continuum brightness emission and the integrated CO intensity in spiral galaxies. The investigation was done on two scales; a global galaxy to galaxy comparison of integrated disk values, and a ring-averaged study over the disks of individual galaxies. For the large-scale survey, radio continuum flux densities integrated over the full disk at 1.49 GHz were taken from Condon (1987) and the total CO fluxes were taken from Verter (1985). The galaxies with values included in the two catalogs are displayed. It can be seen that a good correlation exists between the integrated CO emission and radio continuum emission.

Adler, D. S.↗
NASA NTRS1991

CO fundamental bands in late-type stars. II - Spectrum simulations for F-K stars

The procedure of Ayres and Wiedemann (1989) was applied to a range of stellar-atmosphere models to study the CO Delta-v = 1 spectrum and to establish its use as a remote sensor of thermal conditions in late-type stars. Spectra were computed to examine the sensitivity of the CO Delta-v = 1 to fundamental stellar parameters and to assess the errors introduced into the spectrum intepretation by uncertain input parameters and non-LTE effects. Results of the sensitivity study demonstrate that CO fundamental spectra are useful probes for the temperature structure of the outer layers of cool stellar atmospheres, but that their value is limited by the uncertainties introduced by non-LTE effects. However, in stars with surface gravities of log g of about 1.5 and greater, the values of these uncertainties are reasonably small.

Wiedemann, Guenter↗
NASA NTRS1990

A composite large-scale CO survey at high Galactic latitudes in the second quadrant

Surveys of the second quadrant of the Galaxy undertaken with the CfA 1.2-m telescope have been combined to produce a map of approximately 620 sq deg in the 2.6-mm CO (J = 1-0) line at high Galactic latitudes. CO was detected over about 13 percent of the region surveyed, an order of magnitude more gas by area than previously estimated. In contrast, only 26 percent of the area predicted by Desert et al. (1988) to contain molecular gas actually reveals CO, and about two-thirds of the clouds detected are not listed in their catalog of IR excess clouds.

Heithausen, A.↗