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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

An Ecosystem Simulation Model for Methane Production and Emission from Wetlands

Previous experimental studies suggest that methane emission from wetland is influenced by multiple interactive pathways of gas production and transport through soil and sediment layers to the atmosphere. The objective of this study is to evaluate a new simulation model of methane production and emission in wetland soils that was developed initially to help identify key processes that regulate methanogenesis and net flux of CH4 to the air, but which is designed ultimately for regional simulation using remotely sensed inputs for land cover characteristics. The foundation for these computer simulations is based on a well-documented model (CASA) of ecosystem production and carbon cycling in the terrestrial blaspheme. Modifications to represent flooded wetland soils and anaerobic decomposition include three new sub-models for: (1) layered soil temperature and water table depth (WTD) as a function of daily climate drivers, (2) CH4 production within the anoxic soil layer as a function of WTD and CO2 production under poorly drained conditions, and (3) CH4 gaseous transport pathways (molecular diffusion, ebullition, and plant vascular transport) as a function of WTD and ecosystem type. The model was applied and tested using climate and ecological data to characterize tundra wetland sites near Fairbanks, Alaska studied previously by Whalen and Reeburgh. Comparison of model predictions to measurements of soil temperature and thaw depth, water-table depth, and CH4 emissions over a two year period suggest that inter-site differences in soil physical conditions and methane fluxes could be reproduced accurately for selected periods. Day-to-day comparison of predicted emissions to measured CH4 flux rates reveals good agreement during the early part of the thaw season, but the model tends to underestimate production of CH4 during the months of July and August in both test years. Important seasonal effects, including that of falling WTD during these periods, are apparently overlooked in the model formulation. Nevertheless, reasonably close agreement was achieved between the model's mean daily and seasonal estimates of CH4 flux and observed emission rates for northern wetland ecosystems. Several features of the model are identified as crucial to more accurate prediction of wetland methane emission, including the capacity to incorporate influences of localized topographic and hydrologic features on site-specific soil temperature and WTD dynamics, and mechanistic simulation of methane emission transport pathways from within the soil profile.

Potter, C. S.↗
NASA NTRS2003

Methane Clathrate Hydrate Prospecting

A method of prospecting for methane has been devised. The impetus for this method lies in the abundance of CH4 and the growing shortages of other fuels. The method is intended especially to enable identification of subpermafrost locations where significant amounts of methane are trapped in the form of methane gas hydrate (CH4(raised dot)6H2O). It has been estimated by the U.S. Geological Survey that the total CH4 resource in CH4(raised dot) 6H2O exceeds the energy content of all other fossil fuels (oil, coal, and natural gas from non-hydrate sources). Also, CH4(raised dot)6H2O is among the cleanest-burning fuels, and CH4 is the most efficient fuel because the carbon in CH4 is in its most reduced state. The method involves looking for a proxy for methane gas hydrate, by means of the combination of a thermal-analysis submethod and a field submethod that does not involve drilling. The absence of drilling makes this method easier and less expensive, in comparison with prior methods of prospecting for oil and natural gas. The proposed method would include thermoprospecting in combination with one more of the other non-drilling measurement techniques, which could include magneto-telluric sounding and/or a subsurface-electrical-resistivity technique. The method would exploit the fact that the electrical conductivity in the underlying thawed region is greater than that in the overlying permafrost.

Duxbury, N.↗
NASA NTRS2014

Model Analysis of the Factors Regulating Trends and Variability of Methane, Carbon Monoxide and OH: 1. Model Validation

Methane (CH4) is the second most important anthropogenic greenhouse gas (GHG). Its 100-year global warming potential (GWP) is 25 times larger than that for carbon dioxide. The 100-yr integrated GWP of CH4 is sensitive to changes in OH levels. Methane's atmospheric growth rate was estimated to be more than 10 ppb yr(exp -1) in 1998 but less than zero in 2001, 2004 and 2005 (Kirschke et al., 2013). Since 2006, the CH4 is increasing again. This phenomena is yet not well understood. Oxidation of CH4 by OH is the main loss process, thus affecting the oxidizing capacity of the atmosphere and contributing to the global ozone background. Current models typically use an annual cycle of offline OH fields to simulate CH4. The implemented OH fields in these models are typically tuned so that simulated CH4 growth rates match that measured. For future and climate simulations, the OH tuning technique may not be suitable. In addition, running full chemistry, multi-decadal CH4 simulations is a serious challenge and currently, due to computational intensity, almost impossible.

OH↗
NASA NTRS2015

Optical Parametric Technology for Methane Measurements

Atmospheric methane (CH4) is the second most important anthropogenic greenhouse gas, with approximately 25 times the radiative forcing of carbon dioxide (CO2) per molecule. Yet, lack of understanding of the processes that control CH4 sources and sinks and its potential release from stored carbon reservoirs contributes significant uncertainty to our knowledge of the interaction between carbon cycle and climate change. At Goddard Space Flight Center (GSFC) we have been developing the technology needed to remotely measure CH4 from orbit. Our concept for a CH4 lidar is a nadir viewing instrument that uses the strong laser echoes from the Earth's surface to measure CH4. The instrument uses a tunable, narrow-frequency light source and photon-sensitive detector to make continuous measurements from orbit, in sunlight and darkness, at all latitudes and can be relatively immune to errors introduced by scattering from clouds and aerosols. Our measurement technique uses Integrated Path Differential Absorption (IPDA), which measures the absorption of laser pulses by a trace gas when tuned to a wavelength coincident with an absorption line. We have already demonstrated ground-based and airborne CH4 detection using Optical Parametric Amplifiers (OPA) at 1651 nm using a laser with approximately 10 microJ/pulse at 5kHz with a narrow linewidth. Next, we will upgrade our OPO system to add several more wavelengths in preparation for our September 2015 airborne campaign, and expect that these upgrades will enable CH4 measurements with 1% precision (10-20 ppb).

oscillator↗
NASA NTRS2015

Ammonia and Methane Dairy Emission Plumes in the San Joaquin Valley of California from Individual Feedlot to Regional Scales

Agricultural ammonia (NH3) emissions are highly uncertain, with high spatiotemporal variability and a lack of widespread in situ measurements. Regional NH3 emission estimates using mass balance or emission ratio approaches are uncertain due to variable NH3 sources and sinks as well as unknown plume correlations with other dairy source tracers. We characterize the spatial distributions of NH3 and methane (CH4) dairy plumes using in situ surface and airborne measurements in the Tulare dairy feedlot region of the San Joaquin Valley, California, during the NASA Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality 2013 field campaign. Surface NH3 and CH4 mixing ratios exhibit large variability with maxima localized downwind of individual dairy feedlots. The geometric mean NH3:CH4 enhancement ratio derived from surface measurements is 0.15 +/- 0.03 ppmv ppmv−1. Individual dairy feedlots with spatially distinct NH3 and CH4 source pathways led to statistically significant correlations between NH3 and CH4 in 68% of the 69 downwind plumes sampled. At longer sampling distances, the NH3:CH4 enhancement ratio decreases 20-30%, suggesting the potential for NH3 deposition as a loss term for plumes within a few kilometers downwind of feedlots. Aircraft boundary layer transect measurements directly above surface mobile measurements in the dairy region show comparable gradients and geometric mean enhancement ratios within measurement uncertainties, even when including NH3 partitioning to submicron particles. Individual NH3 and CH4 plumes sampled at close proximity where losses are minimal are not necessarily correlated due to lack of mixing and distinct source pathways. Our analyses have important implications for constraining NH3 sink and plume variability influences on regional NH3 emission estimates and for improving NH3 emission inventory spatial allocations.

Miller, David J.↗
NASA NTRS2015

Airborne Observations of Carbon Dioxide and Methane Emission Ratios from the Yosemite Rim Wildfire, California

This paper presents airborne in situ measurements of carbon dioxide (CO2) and methane (CH4) downwind of an exceptionally large wildfire, the Rim Fire, near Yosemite, California, during two flights. Data analyses are discussed in terms of emission ratios (ER) and emission factors (EF) and are compared to previous studies. CH4 ER’s were 7.5-7.9 parts per billion (ppb) CH4 for every 1 part per million (ppm) of CO2 (ppb CH4 (ppm CO2)(exp.-1)) on 29 August 2013 and 14.2-16.7 ppb CH4 (ppm CO2)(exp. -1) on 10 September 2013. This study measured only CO2 and CH4; however, estimated emission factors (EEF’s) are used as rough estimates of EF’s of CO2 and CH4 and are in close agreement with EF’s reported in previous studies. In the western US, wildfires dominate over prescribed fires, contributing to atmospheric trace gas budgets and regional and local air pollution. Limited sampling of emissions from wildfires means western US emission estimates rely largely on data from prescribed fires, which may not be a suitable proxy for wildfire emissions. Given the magnitude of the Yosemite Rim wildfire, the impacts it had on regional air quality and the limited sampling of wildfire emissions in the western US to date, this study provides a valuable measurement dataset and may have important implications for forestry and regional air quality management.

Yates, Emma L.↗
DOE OSTI2024

ELM-Wet: Inclusion of a wetland landunit with sub-grid representation of eco-hydrological patches and hydrological forcing in E3SM Land Model (ELM)

Wetlands emit the most biogenic methane (CH4) and present the greatest uncertainty in the global CH4 budget. Modeling these emissions is challenging due to the temporal and spatial variability in wetland structure and CH4 flux rates, along with complex interactions among hydrological, ecological, meteorological, and microbial processes that govern CH4 dynamics. To address these issues, we aim to enhance the accuracy of wetland representation in the U.S. Department of Energy’s Exascale Earth System Model (E3SM) Land Model, ELM. This effort led to the development of ELM-Wet, which incorporates a dedicated wetland landunit with subgrid representation of eco-hydrological patch types. We implement wetland-specific hydrology by imposing site-specific constraints on surface water levels, thereby allowing different patches to sustain varying depths of inundation. Additionally, we refined the calculation of aerenchyma transport diffusivity based on observed conductance across different vegetation types. We validated these enhancements through site-specific simulations of a coastal freshwater wetland, the Salvador WMA Freshwater Marsh (Ameriflux, site ID US-LA2), located in the coast of Louisiana (29.85N,90.29W) at an elevation of 0 m. The site was simulated with ELM-Wet and the default version ELMv1. We use Bayesian Optimization to parameterize CO2 and CH4 fluxes. Eddy covariance observations of CO2 and CH4 fluxes from 2012-2013 were used to train the model and data from 2021 were used for validation. In this repository, we include all the output of all the simulations performed using different versions of ELMv1 and ELM-Wet, all input required to the model, and the Matlab scripts we used to processed the output data. ELM-Wet_flmd.csv includes a detailed description of the datasets files.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1976

Scattering of high-velocity He and Ar beams by methane, silane, and germane

Fast He and Ar beams have been scattered by room-temperature CH4, SiH4, and GeH4 to obtain average atom-molecule potentials for He-CH4, He-SiH4, He-GeH4, Ar-CH4, and Ar-GeH4. Somewhat unexpectedly, the potential for He-GeH4 was intermediate between He-CH4 and He-SiH4; this apparent discrepancy, however, correlates with the bond polarities. The potential for Ar-CH4 can be satisfactorily predicted from that for He-CH4 by means of simple potential models and combination rules. The analogous prediction for Ar-GeH4 is unsatisfactory; reasons for the discrepancy are discussed.

Amdur, I.↗
NASA NTRS1983

Ethane ocean on Titan

Voyager I radio occultation data is employed to develop a qualitative model of an ethane ocean on Titan. It is suggested that the ocean contains 25 percent CH4 and that the ocean is in dynamic equilibrium with an N2 atmosphere. Previous models of a CH4 ocean are discounted due to photolysis rates of CH4 gas. Tidal damping of Titan's orbital eccentricity is taken as evidence for an ocean layer approximately 1 km deep, with the ocean floor being covered with a solid C2H2 layer 100 to 200 m thick. The photolytic process disrupting the CH4, if the estimates of the oceanic content of CH4 are correct, could continue for at least one billion years. Verification of the model is dependent on detecting CH4 clouds in the lower atmosphere, finding C2H6 saturation in the lower troposphere, or obtaining evidence of a global ocean.

Lunine, J. I.↗
NASA NTRS1985

Methane emissions to the atmosphere through aquatic plants

The movement of methane (CH4) from anaerobic sediments through the leaves, stems, and flowers of aquatic plants and into the atmosphere was found to provide a significant pathway for the emission of CH4 from the aquatic substrates of flooded wetlands. Methane concentrations well above the surrounding ambient air levels were found in the mesophyll of 16 varies of aquatic plants and are attributed to transpiration, diffusion, and pressure-induced flow of gaseous CH4 from the roots when they are embedded in CH4-saturated anaerobic sediments. Methane emissions from the emergent parts of aquatic plants were measured using floating chamber techniques and by enclosing the plants in polyethylene bags of known volume. Concentration changes were monitored in the trapped air using syringes and gas chromatographic techniques. Vertical profiles of dissolved CH4 in sediment pore water surrounding the aquatic plants' rhizomes were obtained using an interstitial sampling technique. Methane emissions from the aquatic plants studied varied from 14.8 mg CH4/d to levels too low to be detectable. Rooted and unrooted freshwater aquatic plants were studied as well as saltwater and brackish water plants. Included in the experiment is detailed set of measurements on CH4 emissions from the common cattail (Typha latifolia). This paper illustrates that aquatic plants play an important gas exchange role in the C cycle between wetlands and the atmosphere.

Sebacher, D. I.↗
NASA NTRS1988

Methane emissions to the troposphere from the Amazon floodplain

The magnitudes of CH4 emissions to the troposphere from the Amazon River floodplain and the mechanism of these emissions were investigated using the data of 94 individual flux measurements made along a 1700-km stretch of the river during July/August 1985. The overall average rate of CH4 emission from wetlands was found to be 390 mg CH4/sq m per day, with the highest emissions (590 mg CH4/sq m per day) attributed to the water surfaces covered by aquatic macrophytes. Ebullition was the dominant mechanism of emission, accounting for 85 percent of the total. Surface-water CH4 concentrations were highly supersaturated, averaging 6.4 micromolar. The annual emission of CH4 from the Amazon Basin to the troposphere, estimated from the area and the known emission rate, is about 10 CH4 Tg/yr, indicating the importance of the area in the global atmospheric CH4 cycle.

Devol, Allen H.↗
NASA NTRS1988

Seasonal variations of D/H and C-13/C-12 ratios of microbial methane in surface sediments

Appreciable seasonal and spatial variation has been found in the delta D and delta C-13 of gas-phase microbial CH4 produced in the marine sediments of Cape Lookout Bight (CLB), North Carolina. The observations provide indirect evidence that the CLB CH4 delta variation reflects variation in the relative contributions of the main CH4 precursors, acetate and CO2/H2. The delta D-CH4 and delta C-13-CH4 are inversely correlated, indicating that microbial consumption is not responsible for the delta variation. While CLB is not strictly representative of wetlands in general, some of the key microbial processes and environmental characteristics that appear largely responsible for the observed CLB CH4 delta variation are probably similar in typical temperate and high-latitude wetlands.

Burke, Roger A., Jr.↗
NASA NTRS1990

Methane overtone absorption by intracavity laser spectroscopy

Interpretation of planetary methane (CH4) visible-near IR spectra, used to develop models of planetary atmospheres, has been hampered by a lack of suitable laboratory spectroscopic data. The particular CH4 spectral bands are due to intrinsically weak, high overtone-combination transitions too complex for classical spectroscopic analysis. The traditional multipass cell approach to measuring spectra of weakly absorbing species is insufficiently sensitive to yield reliable results for some of the weakest CH4 absorption features and is difficult to apply at the temperatures of the planetary environments. A time modulated form of intracavity laser spectroscopy (ILS), has been shown to provide effective absorption pathlengths of 100 to 200 km with sample cells less than 1 m long. The optical physics governing this technique and the experimental parameters important for obtaining reliable, quantitative results are now well understood. Quantitative data for CH4 absorption obtained by ILS have been reported recently. Illustrative ILS data for CH4 absorption in the 619.7 nm and 681.9 nm bands are presented. New ILS facilities at UM-St. Louis will be used to measure CH4 absorption in the 700 to 1000 nm region under conditions appropriate to the planetary atmospheres.

Obrien, James J.↗
NASA NTRS1990

A two-component volatile atmosphere for Pluto. I - The bulk hydrodynamic escape regime

The seasonal effects on Pluto's atmosphere of a simplified system of CH4 and N2 saturated over a solid solution are investigated, and the results are compared with previous CH4 models. It is found that bulk escape occurs for CH4 mole fractions less than 0.7 of Pluto's volatile reservoir. Greater CH4 abundance leads to diffusive separation during the escape of both species and an atmospheric mixing ratio of about Xc(0). If Xc(0) is in the range 0.02-0.10, Pluto's atmosphere remains largely intact at aphelion rather than virtually freezing out as it does for Xc(0) greater than 0.3 or less than 0.001, or form an atmosphere with only a single volatile gas. An upper limit for the CH4 mixing ratio is about 0.07 if N2 is the second gas. On the other hand, CH4 is the dominant surface constituent of the volatile deposit if Xc(0) is greater than 0.0001.

Trafton, L.↗
NASA NTRS1993

Mid- and far-infrared spectroscopy of ices - Optical constants and integrated absorbances

Laboratory spectra through the mid-infrared (4000 to 500/cm (2.5-20 microns) have been used to calculate the optical constants (n and k) and integrated absorption coefficients (A) for a variety of pure and mixed molecular ices of relevance to astrophysics. The ices studied were H2O, CH3OH, CO2, OCS, CH4, CO2 + CH4, CO2 + OCS, CO + CH4, CO + OCS, O2 + CH4, O2 + OCS, N2 + CH4, N2 + OCS, H2O + CH4, H2O + OCS, and H2O + CH3OH + CO + NH3. In addition, the measurements have been extended through the far-infrared (500 to 50/cm (20-200 microns) for the H2O, CH3OH, and H2O + CH3OH + CO + NH3 ices.

Hudgins, D. M.↗
NASA NTRS1993

Possible solutions to the problem of channel formation on early Mars

A warm climate on early Mars would provide a natural, although not unique, explanation for the presence of fluvial networks on the ancient, heavily cratered terrains. Explaining how the climate could have been kept warm, however, is not easy. The idea that the global average surface temperature, T(sub s), could have been kept warm by a dense, CO2 atmosphere supplied by volcanism or impacts is no longer viable. It was shown that CO2 cloud formation should have kept T(sub s) well below freezing until approximately 2 b.y. ago, when the Sun had brightened to at least 86 percent of its present value. Warm equatorial regions on an otherwise cold planet seem unlikely because atmospheric CO2 would probably condense out at the poles. Warming by impact-produced dust in the atmosphere seems unlikely because the amount of warming expected for silicate dust particles is relatively small. Greenhouse warming by high altitude CO2 ice clouds seems unlikely because such are poor absorbers of infrared radiation at most wavelengths. Warming by atmospheric NH3 seems unlikely because NH3 is readily photodissociated and because N may have been in short supply as consequence of impact erosion and the high solubility of NH3. A brighter, mass-losing young Sun seems unlikely because stellar winds of the required strength were not observed on other solar-type stars. In short, most of the explanations for a warm Martian paleoclimate that were proposed in the past seem unlikely. One possibility that seems feasible from radiative/photochemical standpoint is that CH4 and associated hydrocarbon gases and particles contributed substantially to the greenhouse effect on early Mars. Methane is photochemically more stable than NH3 and the gases and particles that can be formed from it are all good absorbers of infrared radiation. The idea of a CH4-rich Martian paleoatmosphere was suggested a long time ago but has fallen out of favor because of perceived difficulties in maintaining a CH4-rich atmosphere. In particular, it is not obvious where the CH4 might come from, since volcanic gases (on Earth, at least) contain very little CH4. This difficulty could be largely overcome if early Mars was inhabited by microorganisms. Then, methanogenic bacteria living in sediments could presumably have supplied CH4 to the atmosphere in copious quantities.

Kasting, J. F.↗
NASA NTRS1994

Carbon monoxide and methane over Canada: July - August 1990

Carbon monoxide (CO) and methane (CH4) were measured in the 0.15- to 6-km portion of the troposphere over subarctic and boreal landscapes of midcontinent and eastern Canada during July - August 1990. In the mid-continent region, Arctic air entering the region was characterized by relatively uniform CO concentrations (86-108 parts per billion by volume (ppbv)) and CH4 concentrations (1729-1764 ppbv). Local biomass burning and long-range transport of CO into the area from industrial/urban sources and distant fires did frequently produce enhanced and variable concentrations. Emissions of CH4 from the Hudson Bay lowlands was the primary source for enhanced and variable concentrations, especially at altitudes of 0.15-1 km. In eastern Canada, most of the observed variability in CO and CH4 was similar in origin to the phenomena described for the midcontinent region. However, unexpectedly low concentrations of CO (51 ppbv) and CH4 (1688 ppbv) were measured in the midtroposphere on several flights. Combined meteorological and chemical data indicated that the low CO-CH4 events were the result of long-range transport of tropical Pacific marine air to subarctic latitudes.

Harriss, R. C.↗
NASA NTRS1994

Comment on 'A dramatic decrease in the growth rate of atmospheric methane in the Northern Hemisphere during 1992' by E. J. Dlugokencky et al.

The carefully measured decrease in the growth rate of atmospheric methane (CH4) in 1992 reported by Dlugokencky et al. (1994) is an impressive accomplishment, and testimony for the importance of maintaining high-quality, long-term monitoring of atmospheric composition. The changing growth rate of atmospheric CH4 has important implications for assessing and understanding the potential magnitude and rates of a future greenhouse gas-induced climate change. Furthermore, the CH4 data from the current Climate Monitoring and Diagnostics Laboratory (CMDL) globally-distributed network of cooperative air sampling sites are clearly the best record of global CH4 trends and distribution currently available. However, we argue briefly here that the speculation by Dlugokencky et al. (1994) on possible mechanisms for the decreased growth rate in 1992 is only one scenario of many that could possibly fit with the constraints imposed by the reported data. Our comments are to (1) illustrate the difficulties of deducing small changes in complex, poorly understood, geographically diverse natural and anthropogenic sources of CH4 from measurements at the remotely-located CMDL sampling sites and (2) emphasize that detailed bottoms-up analyses are necessary to really advance the understanding of changes in source strengths; we are not promoting alternative mechanisms to explain the 1992 decrease in atmospheric CH4.

Hogan, Kathleen B.↗