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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Development of Principal Design Criteria of the Fast Modular Reactor

General Atomics Electromagnetic Systems (GA-EMS) is developing a 50-megawatt electric (MWe) helium-cooled Fast Modular Reactor (FMR). The project has been selected by the U.S. Department of Energy (DOE) for Advanced Reactor Concepts-20 (ARC-20). The long-term goal of the project is to design, license, and commercialize the FMR plant by the mid-2030s. Early engagement with the U.S. Nuclear Regulatory Commission (NRC) is an important step for the developers to license the advanced reactors including the FMR. As an effort to support the design and the preapplication regulatory engagement plan, GA-EMS is developing Principal Design Criteria (PDC) applicable to the FMR design.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2021

Receiving flat bands near the Fermi level in 1T-VSe2 by using angle resolved photoemission spectroscopy

Here, we study the surface electronic structure of 1T-VSe 2 by means of angle resolved photoemission spectroscopy and uncover a dispersion-less emission located in the vicinity of the Fermi level. Its crystal momentum dependency reveals that it occupies large portions of the Brillouin zone (BZ), where no bulk band is expected. Upon electron doping (deposition of Rb-atoms), the system evolves in a surprising way. Besides the expected down-shifting of the bands, a splitting of both bulk and dispersion-less emission is observed. This peculiar behavior strongly suggests the intrinsic nature of the dispersion-less emission. Its characterization may therefore be relevant to a deeper understanding of the physics of transition metal dichalcogenides.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Exploring New Diamond Surfaces with Precision Chemistry and Quantum Spectroscopy

Point defects in diamond known as color centers are a promising platform for quantum sensing. As atom-like systems, they can exhibit excellent spin coherence and can be manipulated with light. As solid-state defects, they can be produced at high densities and be incorporated into scalable devices. Diamond is a uniquely excellent host; it has a large band gap, can be synthesized with sub-ppb impurity concentrations, and can be isotopically purified to eliminate magnetic noise from nuclear spins. Specifically, the nitrogen vacancy (NV) center has been demonstrated to be a highly sensitive, non-invasive magnetic probe capable of resolving the magnetic field of a single electron spin with nanometer spatial resolution. However, the development of NV centers and other color centers in diamond as a quantum platform crucially relies on developing methods to functionalize and process diamond surfaces. Diamond is the hardest material, making polishing and processing challenging, and diamond surfaces are inert and sterically hindered, making them notoriously difficult to chemically terminate and functionalize. Our approach is to discover new surface chemistries for diamond by combining multimodal surface spectroscopy with NV-based quantum spectroscopy to carefully characterize the diamond surface. We have developed a suite of techniques for characterizing the diamond surface using rapid tools for reaction screening and detailed surface spectroscopy tools for definitive identification of the surface bonding.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Post-Irradiation Examination to Quantify Irradiation-Induced Bowing of SiGA® Silicon Carbide Composite Structures (Final CRADA Report – NFE-23-09937)

As part of the SiC-based material development at General Atomics Electromagnetic Systems (GA-EMS), this project involved the first-of-a-kind experimental post-irradiation examination of the irradiation-induced bowing response in SiC composite structures under a neutron flux gradient. The SiC composite miniature channel specimen was provided by GA-EMS for the irradiation experiment. To quantify the irradiation-induced bowing of the channel specimen, a series of visual and dimensional inspections were conducted using the unique capabilities at Oak Ridge National Laboratory (ORNL), including a custom profilometry rig. The post-irradiation examination results of this project will assist GA-EMS in validating their fuel performance model for SiC-based core structures in neutron irradiation environments.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Atoms-to-devices models for post-irradiation annealing kinetics in III-V semiconductors

Understanding atomic displacement damage and propagating this understanding into validated defect-aware radiation damage models is a critical step toward achieving predictive, atoms-to-systems assessment of radiation vulnerabilities of microelectronics. These models are essential for evaluating the performance and reliability of nuclear stockpile components or space-based electronics (satellites). The goal of this project was to bridge a fundamental science gap between defect spectroscopies and atomistic modeling of radiation-induced defects on the one hand, and simulations of device response on the other hand, to develop predictive defect-aware damage models for high-fidelity device simulations of radiation-damaged III-V semiconductors.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Quadrupole Effects in the Photoionisation of Sodium 3s in the Vicinity of the Dipole Cooper Minimum

A procedure to obtain relativistic expressions for photoionisation angular distribution parameters using the helicity formulation is discussed for open-shell atoms. Electric dipole and quadrupole transition matrix elements were considered in the present work, to study the photoionisation dynamics of the 3s electron of the sodium atom in the vicinity of the dipole Cooper minimum. We studied dipole–quadrupole interference effects on the photoelectron angular distribution in the region of the dipole Cooper minimum. Interference with quadrupole transitions was found to alter the photoelectron angular distribution, even at rather low photon energies. The initial ground and final ionised state discrete wavefunctions of the atom were obtained in the present work using GRASP, and we employed RATIP with discrete wavefunctions, to construct continuum wavefunctions and to calculate transition amplitudes, total cross-sections and angular distribution asymmetry parameters.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Nuclear responses with neural-network quantum states

We introduce a variational Monte Carlo framework that combines neural-network quantum states with the Lorentz integral transform technique to compute the dynamical properties of self-bound quantum many-body systems in continuous Hilbert spaces. While broadly applicable to various quantum systems, including atoms and molecules, in this initial application we focus on the photoabsorption cross section of light nuclei, where benchmarks against numerically exact techniques are available. Our accurate theoretical predictions are complemented by robust uncertainty quantification, enabling meaningful comparisons with experiments. We demonstrate that a simple nuclear Hamiltonian, based on a leading-order pionless effective field theory expansion and known to accurately reproduce the ground-state energies of nuclei with $A\leq 20$ nucleons also provides a reliable description of the photoabsorption cross section.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1972

Absolute frequency of an atomic hydrogen maser clock

An accurate determination was made of the unperturbed atomic hydrogen ground state hyperfine transition frequency (F=1,m=0 - F=0,m=0) in reference to present world wide realizations of internationally defined time interval. In relation to the international atomic time system, the composite value is 1,420,405,751.7755 plus or minus 0.0031 HZ.

Peters, H. E.↗
NASA NTRS1973

Selective reabsorption leading to multiple oscillations in the 8446-A atomic-oxygen laser.

Laser oscillation of atomic oxygen at 8446 A occurs in four closely spaced lines with peculiar intensity ratios, all detuned from the atomic center frequencies of the three fine-structure transitions. These anomalies are caused by the selective reabsorption of resonance radiation from the lower laser level by ground-state oxygen atoms. The selectivity results from the fact that the velocity distribution of the laser levels is considerably wider than that of the ground state, because of the dissociative mode of production of excited oxygen atoms. Possible extension of this mechanism to the atomic-hydrogen system is discussed.

Feld, M. S.↗
NASA NTRS1974

Theoretical investigations on plasma processes in the Kaufman thruster

An analysis of the sputtering of metal surfaces and grids by ions of medium energies is given and it is shown that an exact, nonlinear, hyperbolic wave equation for the temperature field describes the transient transport of heat in metals. Quantum statistical and perturbation theoretical analysis of surface sputtering by low energy ions are used to develop the same expression for the sputtering rate. A transport model is formulated for the deposition of sputtered atoms on system components. Theoretical efforts in determining the potential distribution and the particle velocity distributions in low pressure discharges are briefly discussed.

Wilhelm, H. E.↗
NASA NTRS1984

Kinetics of the reaction O + ClO yields Cl + O2

The bimolecular rate constant for the reaction O + ClO yields Cl + O2 has been measured over the temperature range 236-422 K in a discharge flow system using atomic oxygen resonance fluorescence at 130 nm to monitor the decay of O in an excess of ClO. The results are found to be independent of the method used to produce the ClO radical. At 296 K, the rate constant is given by (3.6 + or - 0.7) x 10 to the -11th cu cm/sec and the temperature dependence expressed in Arrhenius form by k2 = (5.0 + or - 1.0) x 10 to the -11th exp-(96 + or - 20)/T cu cm/sec. The results are compared with earlier values, and the implications for stratospheric chemistry are discussed briefly.

Leu, M.-T.↗
NASA NTRS1986

Effects on optical systems from interactions with oxygen atoms in low earth orbits

Modifications of material surface properties due to interactions with ambient atomic oxygen have been observed on surfaces facing the orbital direction in low earth orbits. Some effects are very damaging to surface optical properties while some are more subtle and even beneficial. Most combustible materials are heavily etched, and some coatings, such as silver and osmium, are seriously degraded or removed as volatile oxides. The growth of oxide films on metals and semiconductors considered stable in dry air was measured. Material removal, surface roughness, reflectance, and optical densities are reported. Effects of temperature, contamination, and overcoatings are noted.

Peters, P. N.↗
NASA NTRS1986

Theoretical studies of diatomic and triatomic systems containing the group IB atoms Cu, Ag, and Au

Selected portions of the ground state potential energy surfaces of the Cu3, Ag3, AgCu2, and AuCu2 trimers are studied at the single-reference singles plus doubles configuration interaction and couple pair functional levels correlating 33 electrons. The calculations use the effective core potentials of Hay and Wadt (1985) to replace the deep core levels. The Cu3 and Ag3 molecules are found to have 2B2 obtuse-angled ground states, with low-lying 2A1 acute-angled excited states. The AgCu2 and AuCu2 molecules have 2A1 acute-angled ground states. The Cu3 molecule has a smaller 3d population than Ag3, and Cu3 has a smaller s electron density in the open-shell orbital than does Ag3, in agreement with recent ESR experiments.

Walch, Stephen P.↗
NASA NTRS1993

MIL-STDS and PTTI: What's available and what needs to be done

The systems developer who needs Precise Time and Time Interval (PTTI) capability has relatively little guidance in the form of military standards, particularly for systems using atomic clocks or other sources of very precise time and frequency. The existing standards, including MIL-STD-188-115, MIL-F-2991(EC), and DOD-STD-1399 are discussed. These documents were written several years ago and do not always reflect current practice or take advantage of more recent technology improvements. User needs have also changed over the years and some of those needs such as more detailed time codes are not being met. We will summarize what's available and what's good and bad about it. The second part will make suggestions about what should be done in the future to promote and facilitate good PTTI design practice. Topics will include clock performance parameters, environmental considerations, time codes, signal isolation, and time dissemination.

Murray, James A.↗
NASA NTRS1996

Computational Modeling of Multi-Phase/Multi-Species Flows with Applications to Liquid Rocket Engines

Accurate prediction of all physical phenomena in a combustion chamber is essential for better understanding of the system performance. Atomization, evaporation, combustion, chemical kinetics, and turbulence are those processes of great importance that need to be well understood. Processes involving the liquid phase in a combustion chamber will be further complicated under supercritical conditions. More advanced and accurate numerical techniques are required to extend our understanding of the above phenomena. A computer program for multi-species/multi-phase flow was developed for NASA/MSFC in 1992. This code, called Liquid Thrust Chamber Performance (LTCP) program takes an Eulerian- Eulerian approach and is based on the Total Variation Diminishing (TVD) technique with Lax-Friedrichs upwind method. Under the NASA/ASEE SFFP the LTCP code was used to predict the performance characteristics of several engines that were of particular interest to NASA. This code was also successful in a combustion detonation study. Converting the program to the PC platform was accomplished which extends usability and makes it available to a wider range of users. The Eulerian formulation of the liquid phase provides a suitable model that can be extended to include combustion modeling under supercritical conditions. The results have been compared against the ones of other codes and available measured data. The algorithm proved to be robust and efficient for problems with stiff source terms.

Navaz, Homayun K.↗