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At least 325 records · Page 18

Categorization of Used Nuclear Fuel Inventory in Support of a Comprehensive National Nuclear Fuel Cycle Strategy - 13575

A technical assessment of the current inventory [∼70,150 metric tons of heavy metal (MTHM) as of 2011] of U.S.-discharged used nuclear fuel (UNF) has been performed to support decisions regarding fuel cycle strategies and research, development and demonstration (RD and D) needs. The assessment considered discharged UNF from commercial nuclear electricity generation and defense and research programs and determined that the current UNF inventory can be divided into the following three categories: 1. Disposal - excess material that is not needed for other purposes; 2. Research - material needed for RD and D purposes to support waste management (e.g., UNF storage, transportation, and disposal) and development of alternative fuel cycles (e.g., separations and advanced fuels/reactors); and 3. Recycle/Recovery - material with inherent and/or strategic value. A set of key assumptions and attributes relative to the various disposition options were used to categorize the current UNF inventory. Based on consideration of RD and D needs, time frames and material needs for deployment of alternative fuel cycles, characteristics of the current UNF inventory, and possible uses to support national security interests, it was determined that the vast majority of the current UNF inventory should be placed in the Disposal category, without the need to make fuel retrievable from disposal for reuse or research purposes. Access to the material in the Research and Recycle/Recovery categories should be retained to support RD and D needs and national security interests. This assessment does not assume any decision about future fuel cycle options or preclude any potential options, including those with potential recycling of commercial UNF. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Advanced Light-Duty SI Engine Fuels Research: Multiple Optical Diagnostics of Well-mixed and Stratified Operation.

Ever tighter fuel economy standards and concerns about energy security motivate efforts to improve engine efficiency and to develop alternative fuels. This project contributes to the science base needed by industry to develop highly efficient direct injection spark ignition (DISI) engines that also beneficially exploit the different properties of alternative fuels. Here, the emphasis is on lean operation, which can provide higher efficiencies than traditional non-dilute stoichiometric operation. Since lean operation can lead to issues with ignition stability, slow flame propagation and low combustion efficiency, the focus is on techniques that can overcome these challenges. Specifically, fuel stratification is used to ensure ignition and completeness of combustion but this technique has soot and NOx emissions challenges. For ultra-lean well-mixed operation, turbulent deflagration can be combined with controlled end-gas autoignition to render mixed-mode combustion for sufficiently fast heat release. However, such mixed-mode combustion requires very stable inflammation, motivating studies on the effects of near-spark flow and turbulence, and the use of small amounts of fuel stratification near the spark plug.

33 ADVANCED PROPULSION SYSTEMS↗

Impact of Oxygen Storage Components in Prototype Pd-Based Three-Way Catalysts under Exhaust Conditions Relevant to Propane Engines

With increasing concerns about global warming, the push for sustainable and eco-friendly fuels is accelerating. Propane, recognized as liquefied petroleum gas or LPG, has garnered research interest as an alternative fuel due to its notable advantages, including a high-octane rating, reduced greenhouse gas emissions, and potential cost-effectiveness. However, to realize its full potential as an alternative fuel it is essential to develop catalysts that efficiently handle emissions at low temperatures. In our research, we investigated three distinct palladium (Pd)-based three-way catalyst (TWC) formulations (PdRh, Pd-only, and Pd-OSC) to investigate the influence of typical TWC components rhodium (Rh) and oxygen storage components (OSC) in exhaust scenarios relevant to propane-fueled engines. Among these, the formulation containing oxygen storage components (Pd-OSC) showed the highest reactivity for both NO and C 3 H 8 while minimizing performance degradation from hydrothermal aging (HTA). Notably, the temperature of 50% conversion (T50) for propane in the Pd-OSC fresh and HTA sample was lower by 30 °C and 13 °C, respectively, compared to the Pd-only sample, highlighting the role of oxygen storage materials in enhancing catalyst performance, even without dithering. Additionally, N 2 physisorption showed that the PdOSC sample has a higher surface area and increased pore volume. This underscores the idea that OSC materials not only augment the catalyst’s porosity but also optimize reactant accessibility to active sites, thus elevating catalytic efficiency. In addition to evaluating performance, we further explored the performance and characteristics of the catalysts using catalytic probe reactions, such as water–gas shift and steam reforming reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Alternative Compliance Annual Reporting

This document helps state and alternative fuel provider fleets determine what data they need to report to meet their Energy Policy Act (EPAct) requirements using the Alternative Compliance method under the U.S. Department of Energy's Alternative Fuel Transportation Program.

33 ADVANCED PROPULSION SYSTEMS↗

Study of research and development requirements of small gas-turbine combustors

A survey is presented of the major small-engine manufacturers and governmental users. A consensus was undertaken regarding small-combustor requirements. The results presented are based on an evaluation of the information obtained in the course of the study. The current status of small-combustor technology is reviewed. The principal problems lie in liner cooling, fuel injection, part-power performance, and ignition. Projections of future engine requirements and their effect on the combustor are discussed. The major changes anticipated are significant increases in operating pressure and temperature levels and greater capability of using heavier alternative fuels. All aspects of combustor design are affected, but the principal impact is on liner durability. An R&D plan which addresses the critical combustor needs is described. The plan consists of 15 recommended programs for achieving necessary advances in the areas of liner thermal design, primary-zone performance, fuel injection, dilution, analytical modeling, and alternative-fuel utilization.

Demetri, E. P.↗

FY2017 Technology Integration Annual Progress Report

The 2017 Technology Integration Annual Progress Report covers 27 multi-year projects funded by the Vehicle Technologies Office. The report includes information on 20 competitively awarded projects, ranging from training on alternative fuels and vehicles for first responders, to safety training and design for maintenance facilities housing gaseous fuel vehicles, to electric vehicle community partner programs. It also includes seven projects conducted by several of VTO’s national laboratory partners, Argonne National Laboratory, Oak Ridge National Laboratory and the National Renewable Energy Laboratory. These projects range from a Technical Assistance project for business, industry, government and individuals, to the EcoCar 3 Student Competition, and the Fuel Economy Information Project.

33 ADVANCED PROPULSION SYSTEMS↗

The long term energy problem and aeronautics

The projected increase in energy consumption by transportation in general and civil aviation in particular is directly opposed to the dwindling supplies of natural petroleum crude oil currently used to produce aircraft fuels. This fact dictates the need to develop even more energy conservative aircraft and propulsion systems than are currently available and to explore the potential of alternative fuels to replace the current petroleum derived hydrocarbons. Advances in technology are described in the areas of improved component efficiency, aircraft and engine integration, control systems, and advanced lightweight materials that are needed to maximize performance and minimize fuel usage. Also, improved turbofan and unconventional engine cycles which can provide significant fuel usage reductions are described. These advancements must be accomplished within expected environmental constraints such as noise and pollution limits. Alternative fuels derived from oil shale and coal are described, and the possible technological advancements needed to use these fuels in aircraft engines are discussed and evaluated with relation to potential differences in fuel characteristics.

Rudey, R. A.↗

Experimental and kinetic modeling study of the low- temperature and high-pressure combustion chemistry of straight chain pentanol isomers: 1-, 2- and 3-Pentanol

Pentanols have received significant attention as a potential alternative fuel or fuel additive owing to their high energy densities and low vapor pressure. The development of robust chemical kinetic models for alternative fuels which can provide accurate and efficient predictions of combustion performance across a wide range of engine relevant conditions is important in developing cleaner, more efficient combustors. Although the high temperature oxidation kinetics of pentanol isomers has been researched considerably, their low temperature combustion chemistry needs further investigation. While previously proposed low temperature mechanisms for 1-pentanol based on analogy and rate rules need further refinement, the low temperature oxidation kinetics of 2-pentanol and 3-pentanol has not been studied previously by any means, experimentally or theoretically. A newly developed kinetic mechanism is presented in this work for the three straight chain pentanol isomers: 1-, 2- and 3-pentanol. Low temperature kinetics is based on a recent study by Lockwood et al., 2022 [20] involving theoretical calculations at the CCSD(T)/cc-pV∞Z level of theory for the oxidation pathways involving alcohol peroxy radicals. Rate of production analyses performed in this study highlight the importance of the newly added pressure-dependent reactions of the α-alcohol peroxy radical forming an RO 2 adduct. While the α-alcohol fuel radical reacts with O 2 to directly decompose via a chemically activated pathway at low pressures, the formation of the RO 2 adduct is favored at high pressures. Furthermore, the detailed model is comprehensively validated against new ignition experiments at low temperature and high pressure, together with the wide range of data available in the literature. Both qualitative and quantitative predictions of the experimental data using the proposed kinetic model are satisfactory for all three pentanol isomers studied here.

1-pentanol↗

Technology Integration 2018 Annual Progress Report

The FY 2018 Technology Integration Annual Progress Report covers 28 multi-year projects funded by the Vehicle Technologies Office. The report includes information on 21 competitively awarded projects, ranging from training on alternative fuels and vehicles for first responders, to safety training and design for maintenance facilities housing gaseous fuel vehicles, to electric vehicle community partner programs. It also includes seven projects conducted by several of VTO’s national laboratory partners, Argonne National Laboratory, Oak Ridge National Laboratory and the National Renewable Energy Laboratory. These projects range from a Technical Assistance project for business, industry, government and individuals, to the EcoCar 3 Student Competition, and the Fuel Economy Information Project.

33 ADVANCED PROPULSION SYSTEMS↗

The Impact of LPG Composition on Performance, Emissions, and Combustion Characteristics of a Pre-mixed Spark-Ignited CFR Engine

Research on alternative fuels has made significant progress as demands for cleaner and more efficient engine operation intensifies. Liquefied petroleum gas (LPG) can offer a potential alternative fuel route in the Diesel fuel dominated heavy-duty transportation sector due to its low cost, high anti-knock limit relative to gasoline, and reduced emission levels. In this work, experimental investigations are performed to study the effects of LPG compositions on performance, emissions, and combustion behavior of a spark-ignited (SI) cooperative fuel research (CFR) engine under stoichiometric conditions. Four LPG blends (chemically pure propane, a representative US blend, HD-5, and a representative European blend) representing the present LPG market are chosen. The impact of fuel composition is studied under different compression ratios (CR), ranging from 7:1 to 10:1 with one-unit increments, and at constant engine speed, intake manifold air pressure (IMAP) and 50% burn crank angle (CA50). The results show that fuel composition has minimal effect on engine efficiency over the CR range 7:1 to 10:1. Engine-out emissions are substantially affected by fuel compositions with the representative European blend indicating higher unburned hydrocarbon (UHC) emissions, particularly at higher CR. The representative US blend emits the lowest brake specific CO (bsCO) averaged over the tested CR range. With the increase of CR, end-gas autoignition intensifies for all blends and the representative European blend demonstrates the highest knock intensity of all tested blends, due to the presence of the more reactive fuel component, n-butane.

Fosudo, Toluwalase↗

FY2020 Technology Integration Annual Progress Report

The 2020 Technology Integration Annual Progress Report covers 46 multi-year projects funded by the Vehicle Technologies Office. The report includes information on competitively awarded projects, ranging from rural shared mobility demonstration projects to medium- and heavy-duty electric vehicle deployment to statewide alternative fuel resiliency planning. It also includes projects conducted by several of the Vehicle Technologies Office’s (VTO) National Laboratory partners, Argonne National Laboratory, Oak Ridge National Laboratory and the National Renewable Energy Laboratory. These projects range from a Technical Assistance project for business, industry, government and individuals, to the EcoCar Advanced Vehicle Technology Competition, and the Fuel Economy Information Project.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

ParaChoice Model.

Analysis with the ParaChoice model addresses three barriers from the VTO Multi-Year Program Plan: availability of alternative fuels and electric charging station infrastructure, availability of AFVs and electric drive vehicles, and consumer reluctance to purchase new technologies. In this fiscal year, we first examined the relationship between the availability of alternative fuels and station infrastructure. Specifically, we studied how electric vehicle charging infrastructure affects the ability of EVs to compete with vehicles that rely on mature, conventional petroleum-based fuels. Second, we studied how the availability of less costly AFVs promotes their representation in the LDV fleet. Third, we used ParaChoice trade space analyses to help inform which consumers are reluctant to purchase new technologies. Last, we began analysis of impacts of alternative energy technologies on Class 8 trucks to isolate those that may most efficaciously advance HDV efficiency and petroleum use reduction goals.

33 ADVANCED PROPULSION SYSTEMS↗

Well-to-Wheels Analysis of Compressed Natural Gas and Ethanol from Municipal Solid Waste

The amount of municipal solid waste (MSW) generated in the United States was estimated at 254 million wet tons in 2013, and around half of that generated waste was landfilled. There is a huge potential in recovering energy from that waste, since around 60% of landfilled material is biomass-derived waste that has high energy content. In addition, diverting waste for fuel production avoids huge fugitive emissions from landfills, especially uncontrolled CH 4 emissions, which are the third largest anthropogenic CH 4 source in the United States. Lifecycle analysis (LCA) is typically used to evaluate the environmental impact of alternative fuel production pathways. LCA of transportation fuels is called well-to-wheels (WTW) and covers all stages of the fuel production pathways, from feedstock recovery (well) to vehicle operation (wheels). In this study, the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET ® ) model developed by Argonne National Laboratory is used to evaluate WTW greenhouse gas (GHG) emissions and fossil fuel consumption of waste-derived fuels. Two waste-to-energy (WTE) pathways have been evaluated – one for compressed natural gas (CNG) production using food waste via anaerobic digestion, and the other for ethanol production from yard trimmings via fermentation processes. Because the fuel production pathways displace current waste management practices (i.e., landfilling waste), we use a marginal approach that considers only the differences in emissions between the counterfactual case and the alternative fuel production case.

03 NATURAL GAS↗

VISION Model Description and User's Guide: Model Used to Estimate the Impacts of Highway Vehicle Technologies and Fuels on Energy Use and Carbon Emissions to 2100

The VISION model has been developed by the US Department of Energy (DOE) to provide estimates of the potential energy use, oil use, and carbon emission impacts to the year 2100 of advanced light- and heavy-duty highway vehicle technologies and alternative fuels. DOE supports research of advanced transportation technologies (including fuels) and is frequently asked to provide estimates of the potential impacts of successful market penetration of these technologies, sometimes on a relatively-quick turnaround basis. VISION is a spreadsheet model that was created in Microsoft Excel® that can be used to respond rapidly to quick-turnaround requests, as well as for longer-term analyses. It uses vehicle survival and age-dependent usage characteristics to project total light- and heavy-truck stock, total vehicle miles traveled (VMT), and total energy use by technology and fuel type by year, given market penetration and vehicle energy efficiency assumptions developed exogenously. Total carbon emissions for on-highway vehicles by year are also estimated because life-cycle carbon coefficients for various fuels are included in VISION. VISION is not a substitute for the transportation component of the US Energy Information Administration’s (EIA’s) National Energy Modeling System (NEMS). NEMS incorporates a consumer choice model to project market penetration of advanced vehicles and alternative fuels. The projections are made within the context of the entire US economy. However, the NEMS model requires more time to execute and only makes projections to 2040. VISION complements NEMS with its relative ease of use and by extending the time frame of potential analysis beyond 2040. VISION has been used for a wide variety of purposes. For illustration, we have listed some of its most recent and current uses in Table 1. Figures 1 through 4 illustrate the results of some of those runs. These graphs are not actual model outputs, but they are based on model results. Aside from these, the National Petroleum Council and National Academies used VISION in their recent scenario studies. The original VISION model description and user guide were written in 2004 and 2006, respectively. Since then, the VISION model has been upgraded with new features and functions. Based on the previous two documents, this report describes the 2013 version including all of the new features that have been added since 2006. The main body of this report describes VISION’s methodology and data sources. The methodology and data sources used in the light- and heavy-vehicle portions of the model are discussed separately. Some suggestions for future improvements to the model are made.

Zhou, Yan↗

Free-spray characteristics and spray-wall interactions of methanol on a gasoline direct injector under flash-boiling and non-flash-boiling conditions

Methanol is considered a promising alternative fuel for internal combustion engines (ICEs) due to its high-octane number, fast laminar flame speed, and elevated latent heat of vaporization, all of which support higher compression ratios and improved thermal efficiency. However, its substantial latent heat of vaporization also poses cold-start challenges, such as misfire and fuel film deposition. This study aims to investigate methanol spray morphology and spray-wall interaction using the Spray M injector from the Engine Combustion Network within a constant-pressure flow vessel. A recently developed unified numerical framework capable of modeling both flash and non-flash boiling sprays is validated against experimental liquid volume fraction data acquired via 3-D computed tomography. Here, the results reveal that flash boiling significantly alters the spray morphology, leading to smaller droplets and spray collapse due to enhanced air-entrainment-induced turbulence. Quantitative agreement between experiments and simulations confirms this behavior. Coupled 0-D equilibrium and 3-D computational fluid dynamics analyses show that flash boiling accelerates evaporation and reduces fuel residence time, while non-flash conditions maintain a persistent liquid core more susceptible to wall wetting. Wall temperature diagnostics reveal that spray collapse alters heat transfer patterns by shifting cooling effects. Mixture fraction analysis indicates that evaporation is primarily governed by shear-layer turbulence, though deviations from adiabatic equilibrium mixing emerge under low-turbulence conditions. Finally, increasing fuel, ambient, and wall temperatures reduces wall wetting and film thickness, mitigating cold-start risks. These findings enhance the understanding of methanol sprays’ behavior and support its adoption as a viable, alternative fuel for ICEs.

Engine Combustion Network↗

Sustainable Transportation: Accelerating Widespread Adoption of Energy Efficient Vehicles & Fuels (Brochure)

While energy efficient transportation strategies have the potential to simultaneously slash oil consumption and reduce greenhouse gas (GHG) emissions, a truly sustainable solution will require more than just putting drivers behind the wheels of new fuel-efficient cars. As the only national laboratory dedicated 100% to renewable energy and energy efficiency, the National Renewable Energy Laboratory (NREL) accelerates widespread adoption of high-performance, low-emission, energy-efficient passenger and freight vehicles, as well as alternative fuels and related infrastructure. Researchers collaborate closely with industry, government, and research partners, using a whole-systems approach to design better batteries, drivetrains, and engines, as well as thermal management, energy storage, power electronic, climate control, alternative fuel, combustion, and emission systems. NREL's sustainable transportation research, development, and deployment (RD&D) efforts are not limited to vehicles, roads, and fueling stations. The lab also explores ways to save energy and reduce GHGs by integrating transportation technology advancements with renewable energy generation, power grids and building systems, urban planning and policy, and fleet operations.

25 ENERGY STORAGE↗

Heavy Duty Vehicle Futures Analysis.

This report describes work performed for an Early Career Research and Development project. This project developed a heavy-duty vehicle (HDV) sector model to assess the factors influencing alternative fuel and efficiency technology adoption. This model builds on a Sandia light duty vehicle sector model and provides a platform for assessing potential impacts of technological advancements developed at the Combustion Research Facility. Alternative fuel and technology adoption modeling is typically developed around a small set of scenarios. This HDV sector model segments the HDV sector and parameterizes input values, such as fuel prices, efficiencies, and vehicle costs. This parameterization enables sensitivity and trade space analyses to identify the inputs that are most associated with outputs of interest, such as diesel consumption and greenhouse gas emissions. Thus this analysis tool enables identification of the most significant HDV sector drivers that can be used to support energy security and climate change goals.

Askin, Amanda Christine↗