Superior Oxygen Electrocatalysis on RuSe x Nanoparticles for Rechargeable Air Cathodes
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Several advanced air separation unit (ASU) designs being considered for use in coal gasification rely on the use of solid state mixed ionic and electronic conductors. Nicrofer-6025HT, a nickel-based alloy, has been identified as a potential manifold material to transport the hot gases into the ASUs. In the current study, isothermal oxidation tests were conducted on Nicrofer-6025HT in the temperature range of 700–900 °C for up to 24 h. The evolution of oxide scale was evaluated using SEM, XRD, and XPS. The composite surface oxide layer that formed consisted of an outer chromia-rich scale and an inner alumina scale. For the longer times at the higher temperatures evaluated, a NiCr2O4 spinel phase was located at the interface between the alumina and chromia. Based on the experimental results a four-step oxidation model was proposed.
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To facilitate the integration of buildings to the power grid, battery-equivalent models have been proposed to characterize and quantify aggregate flexibility from building loads. An analytical method has been proposed to construct such a flexibility model for thermostatically controlled loads. Since this analytical method is derived from a simplified representation of building thermal dynamics, it is necessary to evaluate the resulting flexibility model in a more realistic context. This paper focuses on the validation of this analytical method for estimating aggregate flexibility from residential air conditioning (ACs) systems. A high-fidelity model is first developed to mimic thermal behaviors of a residential AC system through a co-simulation between Modelica and EnergyPlus. A population of virtual residential AC systems is then generated by randomizing parameters of the high-fidelity model. Finally, an aggregate flexibility model is constructed for the residential AC population using the analytical method and validated using results from simulation of the high-fidelity model. It is found that the flexibility estimated using the analytical method is with reasonable accuracy, but can be improved by explicitly incorporating heat gains into the method.
A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JIVIAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H-2/H2O-concentration across various components of the battery are also systematically investigated. (C) 2015 Elsevier B.V. All rights reserved.
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Stable n-doping of WSe{sub 2} using thin films of SiN{sub x} deposited on the surface via plasma-enhanced chemical vapor deposition is presented. Positive fixed charge centers inside SiN{sub x} act to dope WSe{sub 2} thin flakes n-type via field-induced effect. The electron concentration in WSe{sub 2} can be well controlled up to the degenerate limit by simply adjusting the stoichiometry of the SiN{sub x} through deposition process parameters. For the high doping limit, the Schottky barrier width at the metal/WSe{sub 2} junction is significantly thinned, allowing for efficient electron injection via tunneling. Using this doping scheme, we demonstrate air-stable WSe{sub 2} n-MOSFETs with a mobility of ∼70 cm{sup 2}/V s.
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This study was conducted to assess the current impact of natural gas appliances on air quality in California homes. Data were collected via telephone interviews and measurements inside and outside of 352 homes. Passive samplers measured time-resolved CO and time-integrated NO X , NO 2 , formaldehyde, and acetaldehyde over ~6d periods in November 2011 - April 2012 and October 2012 - March 2013. The fraction of indoor NO X and NO 2 attributable to indoor sources was estimated. NO X , NO 2 and highest 1-h CO were higher in homes that cooked with gas and increased with amount of gas cooking. NO X and NO 2 were higher in homes with cooktop pilot burners, relative to gas cooking without pilots. Homes with a pilot burner on a floor or wall furnace had higher kitchen and bedroom NO X and NO 2 compared to homes without a furnace pilot. When scaled to account for varying home size and mixing volume, indoor-attributed bedroom and kitchen NO X and kitchen NO 2 were not higher in homes with wall or floor furnace pilot burners, though bedroom NO 2 was higher. In homes that cooked 4 h or more with gas, self-reported use of kitchen exhaust was associated with lower NO X , NO 2 and highest 1-h CO. Gas appliances were not associated with higher concentrations of formaldehyde or acetaldehyde.
This project integrates hazardous air pollutant (HAP) model outputs with housing/population data for Southeast Texas, then generates hotspot layers and interactive web maps.
The primary objective of this proposed research is to develop an extensive experimental database for the air-ingress phenomenon, which will help better understand the phenomenon as well as provide experimental data for the validation of computational fluid dynamics (CFD) analyses that are currently being performed at the collaborator’s organization. This research is intended to be a separate-effects experimental study. However, a careful scaling analysis will first be performed prior to designing a scaled-down test facility in order to closely tie this research with the real application. The gas turbine-modular helium reactor (GT-MHR) 600 MWth developed by General Atomics, Inc. will be used as a reference design in this study. In the test matrix of the experiments, the temperature and pressure of the helium, and break size, location, shape, and orientation will be varied to simulate deferent scenarios and to identify potential mitigation strategies.
School facilities are often underfunded with aging and poorly maintained HVAC and lighting systems. Most existing school buildings stand to benefit significantly from retrofits in terms of energy, cost, and emissions savings. Ventilation and indoor air quality (IAQ), which are important aspects of a healthy and productive learning environment, can also be enhanced by some energy efficiency measures (EEMs). Packaging energy efficiency and IAQ systems retrofits may represent a golden opportunity to improve performance in this critical building sector.
Hydrocarbon-air combustion gas model for engine cycle computer programs