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At least 307 records · Page 17

Regulatory Decision-Making Process Using 'Weight of Evidence: An Evidence Integration Approach' by the State of Washington at the Hanford Site - 20163

Performance Assessment and Environmental Impact Statement Modeling, Human and Ecological Risk Assessments are the tools used by the Washington State Department of Ecology (Ecology) to make regulatory decisions for permitting and cleanup. These efforts all inherently have large amounts of uncertainty no matter how many alternative approaches are attempted. Professional feedback from tribal governments, stakeholders, federal and state regulators, the public and independent peer review groups are taken into account in this process of informed decision making. The process also includes full evaluation of the comments and the associated reviews made by the various peer review groups such as the Low -Level Waste Disposal Facility Federal Review Group (DOE order 435.1) and the Nuclear Regulatory Commission (NRC). The evolution of technology has produced quicker and more efficient fate and transport modeling tools with related quantification of uncertainties and their significance. Groundwater and vadose zone models have been expanded across the entire Hanford site. Many of the technical approaches identified in the Washington State Regulations are updated using current knowledge to better understand the complexities of the Hanford Site using the latest state of the art tools for risk assessment and modeling. More emphasis and time are directed on defining uncertainty and then managing the uncertainty. One added tool is to run sensitivity cases based on informed decision making. The weight of evidence approach considers all relevant information in an integrative assessment that takes into account the kinds of evidence available, the quality and quantity, the uncertainty and error associated with each type, and how they fit together. Evidence of integration involves looking at systematic reviews and evaluating their strengths and weaknesses. In conclusion, Ecology, Washington State's lead regulatory agency at the Hanford site, has had to modify its site closure approach compared to the rest of the state. A more holistic approach dealing with the Hanford site as an integrated system has evolved leading to a defensible informed approach for regulatory closure decisions. (authors)

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A risk-informed assessment tool to support review of license amendment requests for spent nuclear fuel dry cask storage systems

We report that while risk-informed safety evaluations are common methodologies used by the U.S. Nuclear Regulatory Commission (NRC), their application in the field of commercial spent nuclear fuel (SNF) dry storage has received limited attention. For instance, license amendment requests (LARs) for SNF dry cask storage systems (DCSSs) are evaluated according to U.S. NRC standard review plans (SRPs). However, risk-informed LAR review strategies could improve the understanding of critical system modifications, and lead to more predictable, efficient, and consistent LAR review processes. A methodology to develop a risk-informed LAR review tool is presented. Although focused on DCSSs, this methodology can be used to develop similar tools for a broad spectrum of safety-relevant systems. The end product (i.e., the tool) includes a tree diagram to help visualize the review risk significances assigned to a predefined set of system modifications and supporting rationale documentation. Instructions support correct tool application and provide the user with a path to incorporate currently unevaluated modifications in the tool structure. The demonstration of the methodology leads to the conclusion that risk-informed reviews of DCSS LARs are possible, although the tool precision could benefit from additional risk information. Further, the results indicate that many typical LARs involve low-risk or medium-risk modifications.

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An Intelligent Garbage Sorting System Based on Edge Computing and Visual Understanding of Social Internet of Vehicles

In order to enable Social Internet of Vehicles devices to achieve the purpose of intelligent and autonomous garbage classification in a public environment, while avoiding network congestion caused by a large amount of data accessing the cloud at the same time, it is therefore considered to combine mobile edge computing with Social Internet of Vehicles to give full play to mobile edge computing features of high bandwidth and low latency. At the same time, based on cutting-edge technologies such as deep learning, knowledge graph, and 5G transmission, the paper builds an intelligent garbage sorting system based on edge computing and visual understanding of Social Internet of Vehicles. First of all, for the massive multisource heterogeneous Social Internet of Vehicles big data in the public environment, different item modal data adopts different processing methods, aiming to obtain a visual understanding model. Secondly, using the 5G network, the model is deployed on the edge device and the cloud for cloud-side collaborative management, aiming to avoid the waste of edge node resources, while ensuring the data privacy of the edge node. Finally, the Social Internet of Vehicles devices is used to make intelligent decision-making on the big data of the items. First, the items are judged as garbage, and then the category is judged, and finally the task of grabbing and sorting is realized. The experimental results show that the system proposed in this paper can efficiently process the big data of Social Internet of Vehicles and make valuable intelligent decisions. At the same time, it also has a certain role in promoting the promotion of Social Internet of Vehicles devices.

Shen, Xuehao↗

Work Smarter, Not Harder: Improving Energy Efficiency and Safety through Smarter Ventilation: Preprint

Ventilation is a key component to maintaining healthy, safe indoor air quality. Especially important in laboratories, ventilation is the first line of defense against airborne hazards produced during research activities. Though a vital component, laboratory ventilation systems are often victim to ineffective operation, posing a risk to the most important asset - the researchers. Furthermore, system inefficiencies can lead to up to 50% wasted energy. To improve both energy efficiency and safety in laboratories, we present the Smart Labs Toolkit - a resource developed by the U.S. Department of Energy Federal Energy Management Program and the International Institute for Sustainable Laboratories that guides laboratory stakeholders through a straight-forward, holistic approach to achieve dynamic, high-performance laboratories. Smart Labs enable safe and efficient world class science to occur in laboratories through high-performance methods. A Smart Labs program employs a combination of physical, administrative, and management techniques to assess, optimize, and manage high performance laboratories. We will focus on a central component of the Smart Labs approach - the Laboratory Ventilation Risk Assessment, a systematic process for identifying risk due to airborne hazards to inform the operation of dynamic ventilation that optimizes safety and efficiency. Case studies of organizations who have successfully implemented Smart Labs ventilation management programs will also be shared. In learning ventilation strategies successful in critical laboratory environments, learn the tools and resources needed to successfully manage energy in any building through smarter, safer ventilation.

buildings↗

Effect of Evaporation on Vapor Space Flammability in DWPF Process Vessels - 20278

The Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) processes liquid high-level waste (HLW) and encapsulates it in glass within stainless-steel containers suitable for safe, long-term storage and disposal. Radiolytic and chemical decomposition of the liquid waste generates hydrogen and other flammable gases creating a hazard. The rate of flammable gas generation increases by an order of magnitude as temperature increases from sub-boiling to boiling. DWPF controls this hazard in process tanks by ensuring a minimum purge flow through each tank's head space. The minimum purge flow rate is established assuming dry air and neglecting evaporation. However, this study determined that steam from boiling in a representative process tank is sufficient to dilute flammable gases and, thereby, preclude flammability. For sub-boiling, water vapor is an insufficient diluent considering hydrogen's lower flammable limit (LFL) in air. However, the upper and lower flammable limits approach each other in a hydrogen-air-water-vapor environment as the water vapor concentration increases. This effect may preclude flammable conditions if water vapor concentration is about 60 volume percent or higher. A saturated, constant-pressure air-water system would achieve 60 volume percent water vapor at 86 deg. C. (authors)

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Experimental Analysis of Salt Hydrate Latent Heat Thermal Energy Storage System With Porous Aluminum Fabric and Salt Hydrate as Phase Change Material With Enhanced Stability and Supercooling

Phase change materials (PCMs), especially salt hydrates possess high volumetric energy storage capacity in their transition temperature range. These materials are used in applications where it is necessary to store thermal energy due to temporary load shift between demand and availability. Thus, possible applications are HVAC, recovery of waste heat, and defense thermal management. Despite salt hydrates potential, the practical feasibility of latent heat storage with salt hydrates is limited due to low power rating, supercooling, phase segregation, and long-term stability. Its low power rating and long-term stability limits its application in most applications. This work experimentally validates the stability and thermal performance of a compact heat exchanger charged with salt hydrate during melting and freezing. The compact heat exchanger was designed with fins on both the heat transfer fluid (HTF) and salt hydrate PCM side. The thermal performance of the latent heat thermal energy storage system (LHTESS) was evaluated for various operating conditions. The results show that LHTESS could achieve an average heat transfer coefficient of 124 and 87 W/(m2 K) during melting and solidification, respectively. The stability of the system in suppressing supercooling was validated over 800 cycles with nucleating agent and active homogenous nucleation techniques. The supercooling was reduced to 3 °C with zinc hydroxyl nitrate as nucleating agent and less than 1 °C with the active homogenous nucleation technique. The LHTESS showed less than 6% degradation in energy storage capacity over 800 cycles.

42 ENGINEERING↗

Hanford low-activity waste glass composition-temperature-melt viscosity relationships

This study developed a model for predicting viscosity of alkali-alumino-borosilicate glass melts as functions of composition and temperature. The model is based on a total of 3935 viscosity-temperature data from 574 glasses with viscosity values ranging from 2.53 to 7260 Poise (P) in the temperature range of 900–1260°C. Several different model forms were surveyed, including those based on Arrhenius, Vogel-Fulcher-Tammann, Avramov-Milchev, and Mauro-Yue-Ellison-Gupta-Allen. For each of these models, combinations of the temperature-independent parameters were fitted to composition. It was found that generally fitting more than one temperature-independent parameter as functions of composition resulted in overfitting. The Avramov-Milchev-based model was found to best represent the Hanford low-activity waste glass melt viscosity data based on model fit and validation statistics. A 21-term partial quadratic mixture model was recommended for use. This model predicts melt viscosity with a root-mean square error of .1736 ln(P), which is similar to the error in viscosity measurements from replicate glass analyses of .1383 ln(P). Viscosity was found to be most increased by SiO 2 > Al 2 O 3 > ZrO 2 > SnO 2 and most decreased by Li 2 O > Na 2 O > B 2 O 3 > CaO > K 2 O > MgO, at temperatures from 900 to 1260°C.

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Hydraulic Properties Data Package for the E-Area Soils, Cementitious Materials, and Waste Zones–Update

Hydraulic property estimates for the soils, cementitious materials, and waste zones associated with the E-Area low-level radioactive waste disposal units have been provided to support the Performance Assessments (PA) for the E-Area Low-Level Waste Facility (LLWF). Nominal or “best estimate” hydraulic property values for use in the deterministic modeling are provided along with representations of the hydraulic property value uncertainty for use in sensitivity and uncertainty modeling. The hydraulic properties provided for each of the E-Area materials include: porosity ( η ), dry bulk density ( ρ b ), particle density (ρ p ), saturated hydraulic conductivity ( K sat ), characteristic curves (suction head, saturation, and relative permeability), and effective diffusion coefficient ( D e ). A representation of the uncertainty associated with each property, except for the characteristic curves, is provided for each material, except for the E-Area waste zones. These nominal parameter values for each of the E-Area soils, cementitious materials, and waste zones, and, where indicated, parameter uncertainty representations, are based upon the following in order of priority: Site-specific field data, Site-specific laboratory data, Similarity to material with site-specific field or laboratory data, and Literature data. Additionally, a methodology to represent long-term concrete degradation is provided. Finally, because much of the nominal hydraulic property values and uncertainty representations for the E-Area soils, cementitious materials, and waste zones are based on similarity to other materials or literature data, a methodology to prioritize additional work to better define these values and representations is outlined. Prioritization should be based on the importance of the material and/or property to the results of deterministic, sensitivity, and uncertainty modeling. This prioritization should be established through a process of sensitivity modeling. This report supersedes the previous hydraulic properties data package. Revision 1 contains clarifications, updates and corrections to text, figures and tables in a number of places in the report along with some minor editing.

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Abstract for CRADA between NETL and Rivalia Chemical Co

The National Energy Technology Laboratory (NETL) will assist Rivalia Chemical Co (Participant) with system analyses to aid the Participant with setting priorities and securing funding. The Participant is an early-stage startup pioneering new chemical extraction technology to solve two important problems: critical mineral scarcity and coal ash waste management. The U.S. generates coal fly ash from coal combustion for power generation and has amassed over two billion metric tons of ash, which contains valuable rare earth elements. The ash is often stored in unlined ponds and frequently contaminates the local environment. The Participant’s patent-pending process harvests rare earths from ash, then transforms the residual ash for use in green concrete, providing an economic pathway for utilities to empty and remediate the ash ponds. Founder Laura Stoy created the company in July 2022 after developing the core intellectual property during her Ph.D. at the Georgia Institute of Technology. Stoy is currently participating in the Chain Reactions Innovations (CRI) program at the U.S. Department of Energy (DOE) Argonne National Laboratory (ANL) where she will be optimizing the core technology and scaling from bench scale to demonstration scale. The technology has been validated at bench scale (TRL3); the goal is to approach TRL5 by the conclusion of the CRI program and prepare to raise capital investment for a pilot facility. NETL and the Participant will develop an updated technoeconomic analysis (TEA) and identify key sustainability performance parameters to inform ’s research and development priorities and de-risk the technology. NETL will also provide the Participant with guidance to prepare a more detailed life cycle assessment (LCA), and a narrative on the Participant’s product markets. These tools will aid the Participant with the next steps of commercialization.

01 COAL, LIGNITE, AND PEAT↗

Study of Waste Generated by Retrieval of Fuel Debris at Fukushima Daiichi Nuclear Power Station - 20178

As a member of International Research Institute for Nuclear Decommissioning (IRID), we organized information on waste generated from the fuel debris retrieval, and considered containment, transport and storage processes. An important safety function to consider for these wastes is not only the handling of ordinary high-dose waste, but also the prevention of diffusion of fuel component contamination and the countermeasures against hydrogen gas generation. In order to satisfy these safety functions, we considered guideline for waste generated from the fuel debris retrieval, and proposed an example of handling process that includes generation of waste, container storage, on-site transfer and storage in a storage building. (authors)

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Reduced Temperature Cesium Removal from AP-107 Using Crystalline Silicotitanate

The Tank Side Cesium Removal (TSCR) system is currently being constructed to process Hanford tank waste supernates for vitrification. TSCR incorporates a filtration system and cesium (Cs) removal system using columns filled with crystalline silicotitanate (CST) ion exchanger, produced by Honeywell UOP, LLC (product IONSIV™ R9140-B).

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Simulations of Water Flow in Relation to a Steady Criticality in an Unsaturated Alluvial Repository

Oak Ridge National Laboratory (ORNL) is examining the conditions under which a criticality event could be ruled out for large packages placed in an unsaturated alluvial repository. This work specifically examines the water level in a stylized waste package that is assumed (1) to fail on the top, and (2) to empty as water is driven away—not by boiling—but by fluid flow phenomena driven by thermal gradients. This analysis uses the PFLOTRAN code package. Specifically, this year’s work includes examination of the heat rate at which water is driven away for various percolation rates using the same assumptions listed in the 2022 annual report. The STANDARDS (formerly UNF-ST&DARDS) package has predicted dual-purpose canister (DPC) neutron multiplication factors (k-effectives) ranging above 1.1 (unitless) with failed components. The DPC designs were not created with the intent to use for disposal purposes. Emplacing such packages may be worth consideration if it can be shown that criticality is either extremely unlikely or of very low consequence to the repository’s safety case. This work aims to help establish hydrologic boundary conditions for a highly hypothetical, highly stylized subsurface criticality event. The approach to critical is assumed to be slow, producing steady heating rates under a few kilowatts. For a DPC containing capillary media, the simulated power required for dry-out was proportional to the percolation rate but was unaffected by the size of a large breech on top of the DPC. Results for single cases with no capillary media in the DPC suggest that higher infiltration rates may be required in those cases to cause flooding. Bounding mechanisms and assumptions must be identified and characterized further by performing additional perturbations to various input parameters to demonstrate robustness of the results. This might be accomplished by examining responses to power pulses to determine the system transfer function required to enable a reduced order feedback model.

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I2SL Phil Wirdzek Leadership Award

I’m nominating Shannon Blair from Los Alamos National Laboratory’s (LANL) Sustainability Program and Michael Moss from LANL’s Pollution Prevention Program for the Phil Wirdzek Leadership Award for their efforts in reducing sulfur hexafluoride (SF 6 ) emissions at LANL and creating a system of accounting for improved tracking of SF 6 emissions in the future.

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Drop Analysis of Department of Energy Standard Canister with Fort Saint Vrain SNF

DOE manages over 300 types of SNF, most of which are located at the INL site. The Idaho Cleanup Project and INL are collaborating on the Road-Ready Capability Demonstration Project, which will develop and demonstrate the designs, technology, processes, and regulatory framework for packaging DOE-managed SNF at the INL site for ?road-ready dry storage?. ?Road-ready dry storage? is a SNF management concept where SNF is packaged into dry and sealed canisters, which are then placed in on-site storage in anticipation of later transportation. The forward-looking goal of the Demonstration is establishing the foundation for a large-scale road-ready dry storage program at the INL site. The Demonstration will first package Fort Saint Vrain SNF currently stored at INL into several DOE Standard Canisters. These Standard Canisters will then be loaded into another commercial transportation or storage containment system (e.g., storage cask or transportation package). The Standard Canister is a class of standardized canisters designed for containing the large variety of DOE-managed SNF during interim storage, transportation and/or disposal at a geological repository. One critical aspect of road-ready dry storage is the ability to license the DOE Standard Canisters and its associated transportation package to 10 CFR 71. Depending on the SNF and transportation strategy, the Standard Canisters may have to maintain structural integrity under normal conditions of transport and hypothetical accident scenarios (i.e., drop events). The Standard Canisters have been tested and analyzed under various SNF loading configurations and accident drop events in support of the Idaho Spent Fuel Facility and other DOE programs. However, no analysis has been completed to support the recent Demonstration. This analysis will consider the Ø0.5 m × 5.1 m Standard Canister under drop scenario(s) considered in previous INL tests and analyses, including the 9 m drop at 80 degree off vertical. However, this analysis will consider the more recent Fort Saint Vrain loading configurations proposed for the Demonstration. This analysis will performed using strain-based acceptance criteria established by the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, Section III, Division 3. It will be compared to previous analyses and form the foundation of further formal calculations that will be used to support licensing efforts of the road-ready dry storage system at INL.

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Qualification of Processing Batches for Tank Closure Cesium Removal Through In-Tank Batch Contact Testing - 20470

The Tank Closure Cesium Removal (TCCR) process at the Savannah River Site (SRS) is currently processing waste from Tank 10H, generating decontaminated salt solution that is sent to Tank 11H. Transfers out of Tank 11H are then disposed of on site as a grout wasteform in the SRS Saltstone Processing Facility. This is a full-scale demonstration of the use of Crystalline Silicotitanate (CST) for the decontamination of aqueous nuclear waste supernate. CST primarily removes cesium from the high sodium alkaline feed, but also adsorbs strontium, actinides, and some other trace metals. The TCCR unit is an at-tank set of four ion exchange columns, with two typically being operated in series during waste processing. Tank 10H is serving a dual function as both the salt dissolution tank as well as the feed tank for the TCCR system. Prior to operation of TCCR, Tank 10H must undergo dissolution campaigns, dissolving the salt cake to form an aqueous salt solution (supernate). After each dissolution campaign, the supernate created must be qualified prior to processing through the TCCR system. Qualification includes detailed characterization of the supernate as well as in-tank batch contact tests to determine the equilibrium loading of Cs-137 on the CST ion exchange media (IONSIV{sup TM} R9120-Ba). In support of the in-tank batch contact testing, Savannah River National Laboratory (SRNL) developed a CST sample holder, also referred to as a 'tea-bag', to hold a measured amount (∼0.1 grams) of pretreated CST between stainless steel screens. The tea-bag fits within a standard stainless steel sample vial that has been modified to allow the flow of supernate to the CST. This sample holder is then immersed in the waste tank allowing free contact between the CST beads and the surrounding liquid, at an effectively infinite liquid-to-solid phase ratio. A pair of tea-bags are deployed in the tank for a period of 10 days for each batch, after which the CST is recovered, digested, and analyzed to determine the loading of cesium isotopes on the CST. This result then supports the TCCR column thermal loading limits for processing as part of the TCCR safety basis. This paper will discuss the design and testing of the CST sample holder, as well as results from the first few batches of waste qualified and subsequently processed through the TCCR system. In addition, results from analyses of Tank 11H samples, showing decontamination of the product will be included. (authors)

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Sorbmatech{sup R}Cs, an Innovative Highly Selective Cs Sorbent for Wastewater Decontamination - 20065

The treatment of radioactive wastewater from the operating nuclear industry (energy production, reprocessing of spent fuel, decommissioning of shut-down facilities, etc.) or in case of incidental or accidental situation (such as Fukushima Daichii NPP accident) is an important issue requiring constant improvement of the technologies and techniques used to prevent radioactive releases into the environment and/or to reduce the production of secondary waste. CEA, Orano and CTI are collaborating since 2014, with the support of the French government's program 'investments for the future', to develop Sorbmatech{sup R}Cs, an innovative and patented selective sorbent (Grandjean and Barre 2014) to deal with the removal of radioactive {sup 137}Cs, one of the most hazardous isotope to be managed in nuclear waste, highly efficient either in agitated reactor or in column process. Sorbmatech{sup R}Cs sorbent consists of mesoporous silica particles loaded with potassium-copper hexacyanoferrate nanoparticles (KCu-HCF). This peculiar structure enables much faster sorption kinetics compared to denser crystalline structures, such as Silicotitanate or Zeolite sorbents, whose drawback consists in hindering the diffusion process through the material, and whose larger sorbent particles slow down the ion exchange process. The equilibrium of Sorbmatech{sup R}Cs is reached in few minutes, even at high flow rates in a fixed-bed column process (up to 10 m.h{sup -1} Darcy velocity) with low drop pressure. Moreover, Sorbmatech{sup R}Cs can be used over a wide pH range from 2 to 10 and has a very high selectivity towards {sup 137}Cs even in brine solution (saline, mineral or sea water). This new sorbent also has a K{sub d} higher than 10{sup 5} mL.g{sup -1} depending on the salinity of the wastewater, enabling a highly efficient removal of Cs trace in radioactive wastewater compared to Cs selective sorbent such as Zeolites and Silicotitanates. Its radiological resistance enables the treatment of high, medium and low activity wastewater. The CEA-Orano-CTI/ALSYS partnership leads to the development of a simple and low-cost synthetic route, which demonstrated large-scale manufacturing of the product on a batch of 100 kg. Two products have been developed and are ready for short run market introduction so far with grain size well adapted either for column processes or agitated reactors.. Finally, the industrial implementation has been studied and largely benefits from the properties of the sorbent. Indeed, its high sorption kinetics enable high flow rates resulting in a decrease of operation times, unit sizes, and volumes of secondary waste produced. Moreover, Sorbmatech{sup R}Cs is designed to be combined into a full and integrated solution, ranging from preliminary optimization of operating conditions through numerical dimensioning model, industrial implementation and treatment of the wastewater (through cartridge or preconditioned columns systems developed thanks to Orano's extensive expertise), to long-term stabilization of generated waste (under progress). (authors)

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Helium recovery system at IB3A

The growing demand for sustainable cryogenic operations at Fermilab has underscored the need to improve helium management, particularly at the Industrial Building 3A (IB3A) test facility. IB3A characterizes and tests superconductors, cables, and coils for projects such as the HL-LHC AUP and Mu2e, yet currently relies on 500 L Dewars whose boil-off is vented to atmosphere, wasting a critical, non-renewable resource and increasing the cost of testing. A project is therefore under way to link IB3A to an existing purification and liquefaction station in a neighboring building through a dedicated pipeline. Captured helium will be transferred, purified, reliquefied, and returned for reuse, cutting losses and operating costs. This paper details the first two project phases: "Design and Engineering" and "Procurement and Installation." The design phase finalizes pipeline specifications, establishes flow-control requirements, and resolves integration challenges with existing cryogenic infrastructure. The procurement and installation phase covers material sourcing, pipeline construction, and deployment of control and monitoring systems to assure reliable, efficient operation. Key technical hurdles-route optimization, pressure drop mitigation, and interface compatibility-are discussed alongside implemented solutions. Implementing the pipeline and upgrading IB3A will dramatically reduce helium consumption and therefore testing cost, strengthening Fermilab's capacity to support frontier science far into the future.

Porwisiak, D. [Fermilab; Wroclaw Tech. U.]↗