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At least 307 records · Page 17

Thermophysical properties data on graphite/polyimide composite materials

Experimental data for the thermal conductivity, thermal expansion, specific heat, and emittance of laminates of HTS/NR 150B2 and HTS/PMR 15 are presented. Measurements were made over the temperature range 116 K to 588 K. Results for the two materials were similar with some differences attributable to laminate quality. Higher expansion coefficients for the HTS/PMR 15 specimens in the resin-dominated directions indicate a higher coefficient for PMR 15 than NR 150B2.

Campbell, M. D.↗

Thermophysical properties data on graphite/polyimide composite materials

Experimental data for the thermal conductivity, thermal expansion, specific heat, and emittance of laminates of HTS/NR 150B2 and HTS/PMR 15 are presented. Measurements were made over the temperature range 116 K to 588 K. Results for the two materials were similar with some differences attributable to laminate quality. Higher expansion coefficients for the HTS/PMR 15 specimens in the resin-dominated directions indicate a higher coefficient for PMR 15 than NR 150B2. Previously announced in STAR as N80-14197

Campbell, M. D.↗

Thin film coatings for space electrical power system applications

This paper examines some of the ways in which thin film coatings can play a role in aerospace applications. Space systems discussed include photovoltaic and solar dynamic electric power generation systems, including applications in environmental protection, thermal energy storage, and radiator emittance enhancement. Potential applications of diamondlike films to both atmospheric and space based systems are examined. Also, potential uses of thin films of the recently discovered high-temperature superconductive materials are discussed.

Gulino, Daniel A.↗

Thin film coatings for space electrical power system applications

This paper examines some of the ways in which thin film coatings can play a role in aerospace applications. Space systems discussed include photovoltaic and solar dynamic electric power generation systems, including applications in environmental protection, thermal energy storage, and radiator emittance enhancement. Potential applications of diamondlike films to both atmospheric and space based systems are examined. Also, potential uses of thin films of the recently discovered high-temperature superconductive materials are discussed.

Gulino, Daniel A.↗

Enrichment and heating of the intracluster medium by ejection from galaxies

Results of N-body + hydrodynamic simulations designed to model the formation and evolution of clusters of galaxies and intracluster gas are presented. Clusters of galaxies are the largest bound, relaxed objects in the universe. They are strong x-ray emitters; this radiation originates through thermal bremsstrahlung from a diffuse plasma filling the space between cluster galaxies, the intracluster medium or ICM. From observations, one can infer that the mass of the ICM is comparable to or greater than the mass of all the galaxies in the cluster, and that the ratio of mass in hot gas to mass in galaxies, M(sub ICM)/M(sub STARS), increases with the richness of the cluster. Spectroscopic studies of cluster x-ray emission show heavy element emission lines. While M(sub ICM)/M(sub STARS) is greater than or equal to 1 implies that most of the ICM is primordial in nature, the discovery of heavy elements indicates that some of the gas must have been processed through galaxies. Galaxy evolution thus directly impacts cluster evolution.

Metzler, Chris↗

Variable Emittance Coatings

Variable emittance coatings (VECs) can reduce thermal control system mass and power by passively changing radiator heat rejection according to spacecraft and environment heat loads. VECs make establishing a lunar presence easier since this technology helps overcome challenges with harsh thermal environments on the lunar surface and in transit. This CIF focuses on creating testing capabilities to assess VECs from collaborators in academia and industry. Two main testing capabilities were created. First, a set of temperature dependent Fourier Transform Infrared Spectroscopy (FTIR) measurement accessories were designed, fabricated, and used to measure samples received from collaborators. These accessories are capable of measuring the transmittance and reflectance of semi transparent and opaque samples. Second, a vacuum calorimetry experiment was designed and built to assess the variable heat rejection of larger coupons.

Sydney Taylor↗

Geometric-Optical Modeling of Directional Thermal Radiance for Improvement of Land Surface Temperature Retrievals from MODIS, ASTER, and Landsat-7 Instruments

The general objectives of this project were to improve understanding of the directional emittance properties of land surfaces in the thermal infrared (TIR) region of the electro-magnetic spectrum. To accomplish these objectives our research emphasized a combination of theoretical model development and empirical studies designed to improve land surface temperature (LST) retrievals from space-borne remote sensing instruments. Following the proposal, the main tasks for this project were to: (1) Participate in field campaigns; (2) Acquire and process field, aircraft, and ancillary data; (3) Develop and refine models of LST emission; (4) Develop algorithms for LST retrieval; and (5) Explore LST retrieval methods for use in energy balance models. In general all of these objectives were addressed, and for the most part achieved. The main results from this project are described in the publications arising from this effort. We summarize our efforts related to each of the objectives.

Li, Xiaowen↗

Manufacturing, Characterization and Terrestrial Passive Radiative Cooling Performance of Nanofibrous PTFR-PEO Composite Thermal Coatings

Passive heat management is desirable in many applications since it can reduce the energy expended for cooling, for example, in buildings and automobiles. Specifically, materials with wavelength-dependent reflectance and emittance can manage incident solar fluxes while enabling passive radiative cooling by thermal emission. This study demonstrates the use of polymeric nanofibers, specifically polytetrafluoroethylene (PTFE) and polyethylene oxide (PEO) composite, as thermal coatings for passive temperature control. Employing the electrospinning fabrication process, we engineer nano and micro-scale fibrous structures, studying the influence of fabrication parameters, such as precursor material concentration and rotating collector speed, on fiber geometry and optical properties. To understand the role of material and fiber geometry on optical performance, we characterize various samples' spectral reflectance, absorptance, and transmittance using spectrophotometers interfaced with integrating spheres. The results show the potential of nanofabricated PTFE-PEO coatings as promising candidates for passive thermal control. We highlight their competitive edge by comparing their solar reflectance and emittance values to existing passive radiative thermal control materials. In essence, this study contributes to advancing passive heat management technologies, offering insights into optimizing material composition and fabrication techniques for enhanced performance in various applications.

Chieloka Ibekwe↗

Deterministic fabrication of highly reproducible monochromatic quantum emitters in hexagonal boron nitride

Quantum emitters in hexagonal boron nitride are important room temperature single-photon sources. However, conventional fabrication methods yield quantum emitters with dispersed and inconsistent spectral profiles, limiting their potential for practical quantum applications, which demand reproducible high quality single-photon sources. Here, we report the deterministic creation of highly reproducible monochromatic quantum emitters by applying carbon-ion implantation on freestanding hexagonal boron nitride flakes, while a carbon mask with suitable thickness was adapted to optimize the implantation results. Quantum emitters fabricated using this approach exhibited thermally limited monochromaticity, with an emission center wavelength of 590.7 ± 2.7 nm, a narrow full width at half maximum of 7.1 ± 1.7 nm, an emission rate of 1 MHz without optical engineering, and exceptional stability under ambient conditions. Density functional theory calculations and scanning transmission electron microscopy suggest that these emitters are comprised of boron centered carbon tetramers. This method provides a reliable single-photon source for optical quantum computing and potential future industry-scale applications.

Hua, Muchuan [Argonne National Laboratory (ANL), A↗

Correlation of Predicted and Observed Optical Properties of Multilayer Thermal Control Coatings

Thermal control coatings on spacecraft will be increasingly important, as spacecraft grow smaller and more compact. New thermal control coatings will be needed to meet the demanding requirements of next generation spacecraft. Computer programs are now available to design optical coatings and one such program was used to design several thermal control coatings consisting of alternating layers of WO3 and SiO2. The coatings were subsequently manufactured with electron beam evaporation and characterized with both optical and thermal techniques. Optical data were collected in both the visible region of the spectrum and the infrared. Predictions of solar absorptance and infrared emittance were successfully correlated to the observed thermal control properties. Functional performance of the coatings was verified in a bench top thermal vacuum chamber.

Jaworske, Donald A.↗

Infrared Radiative Properties of Yttria-Stabilized Zirconia Thermal Barrier Coatings

The infrared (IR) transmittance and reflectance of translucent thermal barrier coatings (TBCs) have important implications for both the performance of these coatings as radiation barriers and emitters as well as affecting measurements of TBC thermal conductivity, especially as TBCs are being pushed to higher temperatures. In this paper, the infrared spectral directional-hemispherical transmittance and reflectance of plasma-sprayed 8wt% yttria-stabilized zirconia (8YSZ) TBCs are reported. These measurements are compared to those for single crystal YSZ specimens to show the effects of the plasma-sprayed coating microstructure. It is shown that the coatings exhibit negligible absorption at wavelengths up to about 5 micrometers, and that internal scattering rather than surface reflections dominates the hemispherical reflectance. The translucent nature of the 8YSZ TBCs results in the absorptance/emittance and reflectance of TBC-coated substrates depending on the TBC thickness, microstructure, as well as the radiative properties of the underlying substrate. The effects of these properties on TBC measurements and performance are discussed.

Eldridge, Jeff I.↗

Temperature-dependent spectral emittance of bauxite and silica particle beds

Bauxite and silica particles are candidate materials for solar thermal energy storage at high temperatures. The temperature-dependent emittance of packed beds with bauxite and silica particles was measured using a newly upgraded emissometer at wavelengths 2 μm ≤ λ ≤ 16 μm and temperatures up to ~730 K. The room-temperature emittance was obtained from the measured directional-hemispherical reflectance. A fused silica disc was used to test the emissometer by comparing the measured spectral emittance with the calculated emittance from a fitted Lorentz oscillator model. For the polycrystalline silica particles and the fused silica disc, the measured emittance increases with temperature in the mid-infrared region. The underlying mechanism is interpreted as the temperature-dependent damping coefficient in the Lorentz oscillator model. Two types of bauxite particles with different compositions and sizes were investigated. For λ > 10 μm, the measured emittance at elevated temperatures is higher than that at room temperature. In the region 2 μm < λ < 6 μm, the temperature dependence varies for different types of particles. The total emittance of bauxite particle beds was calculated by spectral integration using Planck’s distribution at the prescribed temperature. As a result, the calculated total emittance is between 0.89 and 0.96, but it does not change monotonically with temperature.

42 ENGINEERING↗

Spectral reflectance and emittance of Apollo 11 and 12 lunar material.

The thermal radiation properties of Apollo 11 and 12 fines (soils) are reviewed and presented as a function of wavelength, angle of illumination, and bulk density. The spectral directional reflectance is presented for wavelengths from 0.6 to 2 microns and for angles of illumination of 10, 20, 30, 45, and 60 deg. The normal emittance is presented for wavelengths from 2.5 to 14.5 microns. The solar albedo and total normal emittance as a function of temperature were calculated from the spectral values. The solar albedo for Apollo 11 fines is 0.099 whereas for Apollo 12 fines is approximately 0.119 for angles of illumination of 10 deg and a density of 1600 kg cu m.

Birkebak, R. C.↗

Emittance Measurements Relevant to a 250 W(sub t) Class RTPV Generator for Space Exploration

A proposed 250 Wt Radioisotope Thermophotovoltaic (RTPV) power system for utilization in lunar exploration and the subsequent exploration of Mars is described. Details of emitter selection are outlined for use in a maintenance free power supply that is productive over a 14-year mission life. Thorough knowledge of a material s spectral emittance is essential for accurate modeling of the RTPV system. While sometimes treated as a surface effect, emittance involves radiation from within a material. This creates a complex thermal gradient which is a combination of conductive and radiative heat transfer mechanisms. Emittance data available in the literature is a valuable resource but it is particular to the test sample s physical characteristics and the test environment. Considerations for making spectral emittance measurements relevant to RTPV development are discussed. Measured spectral emittance data of refractory emitter materials is given. Planned measurement system modifications to improve relevance to the current project are presented.

Wolford, Dave↗

Cross-correlation between the 170 GHz survey map and the COBE differential microwave radiometer first-year maps

This letter describes results of a cross-correlation between the 170 GHz partial-sky survey, made with a 3.8 deg beam balloon-borne instrument, and the COBE DMR 'Fit Technique' reduced galaxy all-sky map with a beam of 7 deg. The strong correlation between the data sets implies that the observed structure is consistent with thermal variations in a 2.7 K emitter. A chi-square analysis applied to the correlation function rules out the assumption that there is no structure in either of the two maps. A second test shows that if the DMR map has structure but the 170 GHz map does not, the probability of obtaining the observed correlation is small. Further analyses support the assumption that both maps have structure and that the 170 GHz-DMR cross-correlation is consistent with the analogous DMR correlation function. Maps containing various combinations of noise and Harrison-Zel'dovich power spectra are simulated and correlated to reinforce the result. The correlation provides compelling evidence that both instruments have observed fluctuations consistent with anisotropies in the cosmic microwave background.

Ganga, Ken↗

Effects of pillar design on the thermal performance of vacuum-insulated glazing

Vacuum-insulated glazing (VIG) with a low-emittance coating has a great market potential as an effective transparent insulator. The thermal insulating performance of VIG is determined by its design, including material selection and configuration of different components. Thermal conductance of the vacuum gap as a transport bottleneck is one of the primary factors controlling the thermal transport across VIG. In particular, because support pillars provide the main thermal transport channels across the vacuum gap, increasing the pillar thermal resistance is a key strategy for creating effective thermal insulation while maintaining the vacuum space. Here, the effects of various pillar design parameters, such as thermal conductivity, geometry, and arrangement, on the VIG thermal performance were comprehensively investigated via the finite element method. In addition, analytical models for thermal transport were examined and thermal conductance across the VIG unit was experimentally measured for validation. The pillar design parameters, especially the height, shape, spacing, and arrangement of the pillars, showed significant effects on the thermal performance of VIG. This research also shows that the smaller contact area for horizontal pillars can effectively decrease the heat loss by more than 30%. Because current VIG analytical equations of thermal performance are only applicable to cylindrical pillars, an analytical equation that can better describe the thermal performance of rectangular parallelepiped pillars is presented, along with a discussion about the mechanism of thermal transfer for different pillar shapes. Thermo-mechanical analyses based on 3D FEM simulations can provide valuable insights into the effect of various design parameters on the overall performance the VIG, allowing for the development of an optimal VIG design.

36 MATERIALS SCIENCE↗