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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Using Separation-Enhanced Isotope Ratio Mass Spectrometry to Enable Increased Renewable Carbon Content in Transportation Fuels (CRADA 525)

Stable isotope ratio measurements of carbon atoms using isotope ratio mass spectrometry (IRMS) can be an effective tool for quantifying biogenic carbon in co-processed fuels, with results approaching the precision and accuracy of accelerator mass spectrometry (AMS). The lower cost of an IRMS may enable deployment to refineries, improving access and analysis turnaround times (≤2 hours), and, by extension, provide data that can allow process optimization to maximize renewable carbon in desired refinery products. This project explored the integration of chemical separation with IRMS analyses to enable highly detailed tracking of biogenic carbon into fuel product streams separated by boiling point range, chemical class, or specific compound. Forty-nine fuels and fuel components of fossil and biogenic origin, spanning gasoline and diesel boiling point ranges, were received from three refiners and were analyzed for their δ 13 C values via IRMS. Results spanned a 13 C range from ca. 10‰ to 44‰ and reflect materials derived from sustainable sources (e.g., C4 or C3 plants, animal-based pathways, syngas) or from fossil-derived fuels. Common ranges are approximately 18‰ to 9‰ and approximately 30‰ to 20‰ for C4 and C3 plants, respectively, and approximately 34‰ to 24‰ and approximately 70‰ to 33‰ for petroleum-derived fuels and methane, respectively. Fuel-like standards were developed and tested using direct-injection elemental analyzer (EA) IRMS for liquid fuels. This method was compared with the published methods, yielding statistically similar results. Four blend curve sets were produced ranging from 0% to 100% of a fuel containing biogenic carbon, focusing on 0% to 10% biogenic carbon. Linear fits were the most applicable for two of the four blend curve sets; however, two sets were found to exhibit slightly quadratic behavior, which was more pronounced in low biogenic blend samples, necessitating second-order fits. The origin of the slight quadratic behavior remains unclear; however, the discussion points to possible interpretations. CanmetENERGY thoroughly characterized a majority of the samples using one- and two-dimensional gas chromatography (GC and GC×GC, respectively) and other analyses. Selected samples were subjected to solid phase extraction (SPE) for saturate, olefin, aromatic, and polar (SOAP) analysis, and the resulting solvent-diluted fractions containing saturates and aromatics were returned to Pacific Northwest National Laboratory (PNNL), where the solvent was removed via evaporation or physical separation using GC techniques. Characterization and separations provided an understanding of saturate and aromatic content, as well as boiling point ranges for each sample and sample fraction. Samples resulting from SPE were examined using EA-IRMS and gas chromatography combustion IRMS (GC-C-IRMS) analyses. Both approaches suggest that the range in values between end-members can be increased by selecting the paraffinic or aromatic fraction of the end-member or by selecting among individual compounds resulting from GC separation of the paraffinic fractions. Considerable work remains to put these approaches into practice and statistically validate the benefit for using a fraction or individual compound over bulk analysis of a sample. However, initial results suggest that separations provide advantages for samples having blend ratios of less than 10% biogenic blendstocks. 13 C results showed statistically similar biofuel blend results to those obtained at PNNL, although additional work is needed to obtain better reproducibility. Select samples were sent to Los Alamos National Laboratory (LANL) for IRMS measurements and Beta Analytics for AMS measurements. This work suggests that IRMS and AMS yield closely comparable results and in some circumstances, IRMS could serve as a surrogate for AMS. While additional work is needed to better resolve statistical advantages for separations and better show the comparable nature of IRMS and AMS in both the biogenic carbon analysis of bulk chemical classes, initial results from this study suggest that these should be pursued in order to proliferate this approach for quantifying biogenic carbon in transportation fuels to the refinery level, thereby potentially enabling process optimization in co-processing scenarios.

09 BIOMASS FUELS↗

Search for muon neutrino disappearance with multi-topologically splitted Inclusive events at SBN

The Short-Baseline Neutrino (SBN) program at Fermilab searches for signatures of sterile neutrinos with mass-squared splittings at the O(1) eV2 scale, motivated by anomalies previously reported by the LSND and MiniBooNE experiments. We present a search for such signatures using the muon neutrino disappearance channel. This analysis exploits the large statistics of fully inclusive charged-current interactions collected by the SBND and ICARUS detectors to maximize sensitivity. The inclusive samples in both detectors are further subdivided into multiple exclusive topological channels, a strategy designed to enhance sensitivity by isolating differences in interaction-mode composition and reconstructed energy response. This multi-topology approach represents a novel analysis technique within SBN, enabling improved constraints on systematic uncertainties arising from neutrino flux, interaction modeling, and detector response. We will present comparisons of data with detailed predictions incorporating a comprehensive treatment of systematic uncertainties and constraints on the systematics obtained by the multi-topology method.

Yadav, Shweta [Texas U., Arlington]↗

Developing Confidence Limits For Reliability Of Software

Technique developed for estimating reliability of software by use of Moranda geometric de-eutrophication model. Pivotal method enables straightforward construction of exact bounds with associated degree of statistical confidence about reliability of software. Confidence limits thus derived provide precise means of assessing quality of software. Limits take into account number of bugs found while testing and effects of sampling variation associated with random order of discovering bugs.

Hayhurst, Kelly J.↗

Three-dimensional hard X-ray ptychographic reflectometry imaging on extended mesoscopic surface structures

Many nanodevices and quantum devices, with their sizes often spanning from millimeters down to sub-nanometer, have intricate low-dimensional, non-uniform, or hierarchical structures on surfaces and interfaces. Since their functionalities are dependent on these structures, high-resolution surface-sensitive characterization becomes imperative to gain a comprehensive understanding of the function–structure relationship. We thus developed hard x-ray ptychographic reflectometry imaging, a new technique that merges the high-resolution two-dimensional imaging capabilities of hard x-ray ptychography for extended objects, with the high-resolution depth profiling capabilities of x-ray reflectivity for layered structures. The synergy of these two methods fully leverages both amplitude and phase information from ptychography reconstruction to not only reveal surface topography and localized structures, such as shapes and electron densities, but also yields statistical details, such as interfacial roughness that is not readily accessible through coherent imaging solely. The hard x-ray ptychographic reflectometry imaging is well-suited for three-dimensional imaging of mesoscopic samples, particularly those comprising planar or layered nanostructures on opaque supports, and could also offer a high-resolution surface metrology and defect analysis on semiconductor devices, such as integrated nanocircuits and lithographic photomasks for microchip fabrications.

47 OTHER INSTRUMENTATION↗

Supersonic Free-Flight Dynamics Testing in the Stratosphere

A new technique for obtaining stratospheric free-flight dynamics data for atmospheric entry capsules is described. The Stratospheric Projectile Experiment of Entry Dynamics (SPEED) represents a new approach to characterizing the free-flight dynamics of vehicles in the supersonic and transonic regime of flight. The SPEED test architecture leverages a stratospheric balloon and 3D-printed flight system in a novel two-stage configuration to deliver test articles to supersonic conditions in the atmosphere which achieve dynamic similitude with a full-scale vehicle. Designed to address the limitations of existing test facilities, SPEED captures the complete time evolution of a vehicle’s dynamic state while producing a statistically significant number of observed flight trajectories to address the stochastic nature of the wake-driven dynamic stability phenomenon. SPEED was developed over two years at NASA Ames Research Center. The inaugural flight of the SPEED test platform was conducted in the summer of 2024 where scaled capsules of the Mars Sample Return Earth Entry System and Dragonfly entry vehicle were tested. This paper describes the motivation for a new test architecture, operational constraints and achievable flight test envelopes, the design and development of the SPEED concept, and results from the demonstration flight. Techniques for estimating the dynamic aerodynamic characteristics and atmospheric conditions for each test article individually and as a collective are also discussed.

Entry Vehicle↗

Priors on red galaxy stochasticity from hybrid effective field theory

ABSTRACT We investigate the stochastic properties of typical red galaxy samples in a controlled numerical environment. We use halo occupation distribution (HOD) modelling to create mock realizations of three separate bright red galaxy samples consistent with data sets used for clustering and lensing analyses in modern galaxy surveys. Second-order Hybrid Effective Field Theory (HEFT) is used as a field-level forward model to describe the full statistical distribution of these tracer samples, and their stochastic power spectra are directly measured and compared to the Poisson shot-noise prediction. While all of the galaxy samples we consider are hosted within haloes with sub-Poisson stochasticity, we observe that the galaxy samples themselves possess stochasticities that range from sub-Poisson to super-Poisson, in agreement with predictions from the halo model. As an application of our methodology, we place priors on the expected degree of non-Poisson stochasticity in cosmological analyses using such samples. We expect these priors will be useful in reducing the complexity of the full parameter space for future analyses using second-order Lagrangian bias models. More generally, the techniques outlined here present the first application of HEFT methods to characterize models of the galaxy–halo connection at the field level, revealing new connections between once-disparate modelling frameworks.

79 ASTRONOMY AND ASTROPHYSICS↗

A finite element technique for non-deterministic thermal deformation analyses including temperature dependent material properties

A technique utilizing the finite element displacement method is developed for the static analysis of structures subjected to non-deterministic thermal loading in which the material properties, assumed isotropic, are temperature dependent. Matrix equations are developed for the first two statistical moments of the displacements using a third order series expansion for the displacements in terms of the random temperatures. Sample problems are included to demonstrate the range of applicability of the third order series solutions. These solutions are compared with results from Monte Carlo analyses and also, for some problems, with solutions obtained by numerically integrating equations for the statistical properties of the displacements. In general, it is shown that the effect of temperature dependent material properties can have a significant effect on the covariances of the displacements.

Case, W. R., Jr.↗

Sea surface temperature anomalies, planetary waves, and air-sea feedback in the middle latitudes

Current analytical models for large-scale air-sea interactions in the middle latitudes are reviewed in terms of known sea-surface temperature (SST) anomalies. The scales and strength of different atmospheric forcing mechanisms are discussed, along with the damping and feedback processes controlling the evolution of the SST. Difficulties with effective SST modeling are described in terms of the techniques and results of case studies, numerical simulations of mixed-layer variability and statistical modeling. The relationship between SST and diabatic heating anomalies is considered and a linear model is developed for the response of the stationary atmosphere to the air-sea feedback. The results obtained with linear wave models are compared with the linear model results. Finally, sample data are presented from experiments with general circulation models into which specific SST anomaly data for the middle latitudes were introduced.

Frankignoul, C.↗

Stochastic estimation of coherent structures in turbulent boundary layers

The stochastic estimation technique is described as well as its extension to two-point and space-time conditional estimates. Based on the experimental data of Guezennec (1985), a comparison is made between the stochastic estimates and the conventional ensemble averaging results. As only the normal velocity and streamwise components were measured at each point on the sampling grid, the assumption of statistical symmetry in the spanwise direction about the centerline was used and the spanwise velocity component was reconstructed by integrating the continuity equation from the centerline outward.

Guezennec, Y. G.↗

In Situ Mg/Ca Measurements on Foraminifera: Comparison Between Laser Ablation Inductively Coupled Plasma Mass Spectrometry and Wavelength-Dispersive X-Ray Spectroscopy by Electron Probe Microanalyzer

We present a comparison of two different techniques: Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) and wavelength-dispersive X-Ray Spectroscopy by electron probe microanalyzer (EPMA) for obtaining Mg/Ca ratios in individual foraminifera shells. The goal is to assess the use of EPMA as an alternative technique for Mg/Ca analyses of single foraminiferal calcite shells. Foraminifera obtained from sediments (benthic, Uvigerina spp.) and from plankton tows (planktonic, Orbulina universa) were analyzed. All specimens were prepared in epoxy mounts and exposed in cross-section such that multiple high-resolution analyses could be completed on the shells using both techniques. We examined our data using statistical methods designed for the assessment and comparison of measurement techniques. In the case of Uvigerina, the mean difference for ratios obtained using EPMA and LA-ICP-MS is very small (−0.046 mmol mol−1) and scale independent. The Limits of Agreement (LoA, the standard deviation of the bias plus the mean bias) is [−0.315, 0.223] mmol mol−1. For samples with ratios lower than 13 mmol mol−1, we found a mean EPMA–LA-ICP-MS bias of −2.44 mmol mol−1 and a corresponding LoA of [−3.85, −1.04] mmol mol−1. For ratios higher than 13 mmol mol−1, there appears to be a scale dependent bias, meaning that the EPMA measured ratios become progressively larger than those of LA-ICP-MS as the Mg/Ca ratio increases, so the mean bias and LoA metrics are not meaningful. Results indicate that it is possible to use EPMA to collect Mg/Ca data, if the ratios are lower than ∼13 mmol mol−1.

EPMA↗

Strangeness enhancement at its extremes: multiple (multi-)strange hadron production in pp collisions at \(\sqrt{s}=5.02\) TeV

The probability to observe a specific number of strange and multi-strange hadrons (nS), denoted as P(nS), is measured by ALICE at midrapidity (|y| < 0.5) in $$\sqrt{s}=5.02$$ TeV proton-proton (pp) collisions, dividing events into several multiplicity-density classes. Exploiting, for the first time, a technique based on counting the number of strange-particle candidates event-by-event, this measurement allows one to extend the study of strangeness production beyond the mean of the distribution. This constitutes a new test bench for production mechanisms, probing events with a large imbalance between strange and non-strange content. The analysis of a large-statistics data sample makes it possible to extract P(nS) up to a maximum nS of 7 for $${\text{K}}_{\text{S}}^{0}$$, 5 for Λ and $$\overline{\Lambda }$$, 4 for Ξ− and $${\overline{\Xi } }^{+}$$, and 2 for Ω− and $${\overline{\Omega } }^{+}$$. From this, the probability of producing strange hadron multiplets per event is calculated, thereby enabling the extension of the study of strangeness enhancement to extreme situations where several strange quarks hadronize in a single event at midrapidity. Moreover, comparing hadron combinations with different u and d quark compositions and equal overall s quark content, the contribution to the enhancement pattern coming from non-strangeness related mechanisms is isolated. The results are compared with state-of-the-art phenomenological models implemented in commonly used Monte Carlo event generators, including PYTHIA 8 Monash 2013, PYTHIA 8 with QCD-based Color Reconnection and Rope Hadronization (QCD-CR + Ropes), and EPOS LHC, which incorporates both partonic interactions and hydrodynamic evolution. These comparisons show that the new approach dramatically enhances the sensitivity to the different underlying physics mechanisms modeled by each generator.

Abualrob, I J↗

DEEPEN Global Standardized Categorical Exploration Datasets for Magmatic Plays

DEEPEN stands for DE-risking Exploration of geothermal Plays in magmatic ENvironments. As part of the development of the DEEPEN 3D play fairway analysis (PFA) methodology for magmatic plays (conventional hydrothermal, superhot EGS, and supercritical), weights needed to be developed for use in the weighted sum of the different favorability index models produced from geoscientific exploration datasets. This was done using two different approaches: one based on expert opinions, and one based on statistical learning. This GDR submission includes the datasets used to produce the statistical learning-based weights. While expert opinions allow us to include more nuanced information in the weights, expert opinions are subject to human bias. Data-centric or statistical approaches help to overcome these potential human biases by focusing on and drawing conclusions from the data alone. The drawback is that, to apply these types of approaches, a dataset is needed. Therefore, we attempted to build comprehensive standardized datasets mapping anomalies in each exploration dataset to each component of each play. This data was gathered through a literature review focused on magmatic hydrothermal plays along with well-characterized areas where superhot or supercritical conditions are thought to exist. Datasets were assembled for all three play types, but the hydrothermal dataset is the least complete due to its relatively low priority. For each known or assumed resource, the dataset states what anomaly in each exploration dataset is associated with each component of the system. The data is only a semi-quantitative, where values are either high, medium, or low, relative to background levels. In addition, the dataset has significant gaps, as not every possible exploration dataset has been collected and analyzed at every known or suspected geothermal resource area, in the context of all possible play types. The following training sites were used to assemble this dataset: - Conventional magmatic hydrothermal: Akutan (from AK PFA), Oregon Cascades PFA, Glass Buttes OR, Mauna Kea (from HI PFA), Lanai (from HI PFA), Mt St Helens Shear Zone (from WA PFA), Wind River Valley (From WA PFA), Mount Baker (from WA PFA). - Superhot EGS: Newberry (EGS demonstration project), Coso (EGS demonstration project), Geysers (EGS demonstration project), Eastern Snake River Plain (EGS demonstration project), Utah FORGE, Larderello, Kakkonda, Taupo Volcanic Zone, Acoculco, Krafla. - Supercritical: Coso, Geysers, Salton Sea, Larderello, Los Humeros, Taupo Volcanic Zone, Krafla, Reyjanes, Hengill. **Disclaimer: Treat the supercritical fluid anomalies with skepticism. They are based on assumptions due to the general lack of confirmed supercritical fluid encounters and samples at the sites included in this dataset, at the time of assembling the dataset. The main assumption was that the supercritical fluid in a given geothermal system has shared properties with the hydrothermal fluid, which may not be the case in reality. Once the datasets were assembled, principal component analysis (PCA) was applied to each. PCA is an unsupervised statistical learning technique, meaning that labels are not required on the data, that summarized the directions of variance in the data. This approach was chosen because our labels are not certain, i.e., we do not know with 100% confidence that superhot resources exist at all the assumed positive areas. We also do not have data for any known non-geothermal areas, meaning that it would be challenging to apply a supervised learning technique. In order to generate weights from the PCA, an analysis of the PCA loading values was conducted. PCA loading values represent how much a feature is contributing to each principal component, and therefore the overall variance in the data.

15 GEOTHERMAL ENERGY↗

Bayesian Framework For Bioburden Density Calculations To Perform Planetary Protection Probabilistic Risk Assessment

The planetary protection discipline aims to minimize the microbial contamination on spacecraft to prevent the inadvertent contamination of other planetary bodies, known as forward planetary protection (PP). Planetary protection probabilistic risk assessment (PRA) relies on two core methodologies-the contamination probability event tree analysis and statistical parameter estimation. Planetary protection engineers combine several techniques to estimate the bioburden present on spacecraft components. A direct assay to enumerate CFU (colony forming units) is the preferred methodology, but given a similar processing environment the bioburden present on certain components is inferred using: (1) a NASA defined bioburden estimate based upon the biological cleanliness of the manufacturing/assembly environment or (2) sampled data from a similar spacecraft component. The paper presents an empirical Bayesian framework to systematically treat bioburden estimation and its uncertainties on different levels starting with measurement procedures to combining different components to subsystems and whole spacecraft. It is shown that the Bayesian approach can effectively handle estimations and their uncertainties at different levels and produce a reliable estimate for bioburden to be used to evaluate the probability of contamination.

Seuylemezian, Arman↗

An Evaluation of Advanced Tools for Distributed Wind Turbine Performance Estimation

We evaluate various classes of distributed wind turbine performance tools across two sites in the United States. The class of tools ranges from the simple mass conservation model to the coupled Reynolds-averaged Navier-Stokes model, all initiated by the WIND Toolkit data set. The resource estimation at the site is evaluated against measured data at the mast location. Taking a sample 100-kW wind turbine and constant losses, we evaluate Openwind, Continuum, and WindNinja tools and document annual energy production (AEP) and time-series statistics associated with the performance estimation of the wind turbine. Using a methodology that is consistent and unbiased across the three options currently available in the industry, we elaborate results at the two sample locations and discuss the probable sources of discrepancy in the AEP estimates. Two main sources of the discrepancy come from the input WIND Toolkit data and the spatial modeling techniques of the tools to capture atmospheric physics. The discussion includes additional values that these tools may bring into the energy assessment process to enhance the owners' confidence over the distributed wind power systems.

17 WIND ENERGY↗

The H I content of red geyser galaxies

Red geysers are a specific type of quiescent galaxy, denoted by twin jets emerging from their galactic centres. These bisymmetric jets possibly inject energy and heat into the surrounding material, effectively suppressing star formation by stabilizing cool gas. In order to confirm the presence and evolutionary consequences of these jets, this paper discusses the scaling, stacking, and conversion of 21-cm H I flux data sourced from the H I -MaNGA survey into H I gas-to-stellar mass (G/S) spectra. Our samples were dominated by non-detections, or galaxies with weak H I signals, and consequently by H I upper limits. The stacking technique discussed successfully resolved emission features in both the red geyser G/S spectrum and the control sample G/S spectrum. From these stacked spectra, we find that on average, red geyser galaxies have G/S of 0.086 ± 0.011 (random) + 0.029 (systematic), while non-red geyser galaxies of similar stellar mass have a G/S ratio of 0.039 ± 0.018 (random) + 0.013 (systematic). Therefore, we find no statistically significant evidence that the H I content of red geysers is different from the general quiescent population.

79 ASTRONOMY AND ASTROPHYSICS↗

Atmospheric turbulence power spectral measurements to long wavelengths for several meteorological conditions

Use of power spectral design techniques for supersonic transports requires accurate definition of atmospheric turbulence in the long wavelength region below the knee of the power spectral density function curve. Examples are given of data obtained from a current turbulence flight sampling program. These samples are categorized as (1) convective, (2) wind shear, (3) rotor, and (4) mountain-wave turbulence. Time histories, altitudes, root-mean-square values, statistical degrees of freedom, power spectra, and integral scale values are shown and discussed.

Rhyne, R. H.↗

Managing Large Datasets for Atmospheric Research

Since the mid-1980s, airborne and ground measurements have been widely used to provide comprehensive characterization of atmospheric composition and processes. Field campaigns have generated a wealth of insitu data and have grown considerably over the years in terms of both the number of measured parameters and the data volume. This can largely be attributed to the rapid advances in instrument development and computing power. The users of field data may face a number of challenges spanning data access, understanding, and proper use in scientific analysis. This tutorial is designed to provide an introduction to using data sets, with a focus on airborne measurements, for atmospheric research. The first part of the tutorial provides an overview of airborne measurements and data discovery. This will be followed by a discussion on the understanding of airborne data files. An actual data file will be used to illustrate how data are reported, including the use of data flags to indicate missing data and limits of detection. Retrieving information from the file header will be discussed, which is essential to properly interpreting the data. Field measurements are typically reported as a function of sampling time, but different instruments often have different sampling intervals. To create a combined data set, the data merge process (interpolation of all data to a common time base) will be discussed in terms of the algorithm, data merge products available from airborne studies, and their application in research. Statistical treatment of missing data and data flagged for limit of detection will also be covered in this section. These basic data processing techniques are applicable to both airborne and ground-based observational data sets. Finally, the recently developed Toolsets for Airborne Data (TAD) will be introduced. TAD (tad.larc.nasa.gov) is an airborne data portal offering tools to create user defined merged data products with the capability to provide descriptive statistics and the option to treat measurement uncertainty.

Chen, Gao↗

On the measurement of shape: With applications to lunar regolith

With the renewed commitment from NASA and other commercial entities for a presence on the Moon, the importance of understanding the characteristics of lunar regolith and how to utilize it have become the target of increasing scrutiny. Much of what is known about lunar regolith was collected during and immediately after the Apollo program, however, analytical techniques and instrumentation have advanced in leaps and bounds in the subsequent decades. Specifically, dynamic image analysis systems have advanced to the point that millions of particles can have morphological characteristics automatically determined in relatively short time frames. Particle morphological data was collected on several lunar samples and a pair of widely used regolith simulants to ascertain the accuracy of these simulants and to explore statistical analysis methods of these large datasets. It is found that these morphology datasets can vary widely depending on the particle size of the particles, and simple averaging of the data skews the results heavily towards the numerically abundant size ranges, the fines. Different reporting methods are suggested to ameliorate these problems. When applied to the lunar regolith, the particles are noted to be less morphologically complex than initially suspected. Compared to the lunar material, the simulants are found to contain some more morphological variability and angular grains. Such difference is likely due to the wildly different comminution processes that these different powder systems are subjected to.

2D shape↗