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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Compressive Creep of Polymer Electrolyte Membranes: A Case Study for Electrolyzers

For proton-exchange membrane (PEM) water electrolyzers to be commercially feasible, PEMs must perform over long lifetimes in liquid environments under compression while maintaining mechanical stability. A hydrated environment, while inherent for operation and conductivity, undermines PEM stability. Mechanical stability of PEMs is commonly characterized in tension, which is not applicable to electrolyzers, wherein PEMs could undergo high pressures. In this study, a compression creep procedure is developed using a custom-designed setup to monitor creep response of hydrated PEMs. Furthermore, our results show that PEMs exhibit continuous creep response under compression over 24 h, with a dependence on the applied pressure and hydration state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Adsorptive behavior of poly (vinylidene fluoride) membranes for the recovery of lignin-derived hydrophobic deep eutectic solvents

Abstract Recently, membrane technology has gained significant traction as an energy-efficient alternative to traditional thermal processes for solvent recovery. Deep eutectic solvents (DESs) have emerged as sustainable alternatives to conventional organic solvents, yet a systematic methodology for selecting compatible membrane materials for their recovery remains underdeveloped. This study established a predictive framework for membrane material selection in hydrophobic DES applications using Hansen Solubility Parameters (HSP) with inverted criteria targeting materials with relative energy difference (RED) values greater than 1.0. Flat sheet membranes were fabricated via the non-solvent induced phase separation (NIPS) technique. Four NIPS fabricated polymer membranes were evaluated: polysulfone, cellulose acetate, polyvinylidene fluoride (PVDF) fabricated with polyethylene glycol (PEG) as a pore-forming agent, and polybenzimidazole (PBI). The HSP approach successfully predicted membrane-solvent compatibility, with polysulfone (RED = 0.6) and cellulose acetate (RED = 0.9) dissolving completely within 24 h, while PVDF (RED = 1.9) and PBI (RED = 1.1) maintained structural integrity throughout a 7-day exposure period. Furthermore, PVDF demonstrated superior performance with minimal weight gain (3.0%), hydrophobic surface characteristics (122° water contact angle), and enhanced mechanical properties following DES exposure. Comprehensive chemical and morphological characterization confirmed PVDF’s chemical stability and revealed a surface-selective interaction mechanism involving simultaneous PEG (pore-forming agent) extraction and DES component adsorption. Adsorption kinetics followed pseudo-first-order behavior with reversible characteristics, best described by the Temkin isotherm model (R² = 0.9987). PVDF membranes-maintained separation functionality with average lignin rejection (75.2 ± 7.69%) and demonstrated filtration permeability of 2.0 ± 0.34 LMH/bar. This methodology provides a rational approach for membrane selection in emerging solvent systems, contributing to the advancement of sustainable separation technologies for DES-based biomass processing applications.

Science & Technology - Other Topics↗
DOE OSTI2024

A high-throughput and data-driven computational framework for novel quantum materials

Two-dimensional layered materials, such as transition metal dichalcogenides (TMDs), possess an intrinsic van der Waals gap at the layer interface, allowing for remarkable tunability of the optoelectronic features via external intercalation of foreign guests such as atoms, ions, or molecules. Herein, we introduce a high-throughput, data-driven computational framework for the design of novel quantum materials derived from intercalating planar conjugated organic molecules into bilayer transition metal dichalcogenides and dioxides. By combining first-principles methods, material informatics, and machine learning, we characterize the energetic and mechanical stability of this new class of materials and identify the fifty (50) most stable hybrid materials from a vast configurational space comprising ∼105 materials, employing intercalation energy as the screening criterion.

Kastuar, Srihari M. (ORCID:0000000279001561)↗
DOE OSTI2023

Large-scale cascading of first-order FBG array in a highly multimode coreless fiber using femtosecond laser for distributed thermal sensing

This research focuses on the performance analysis and characterization of a fiber Bragg gratings (FBGs) array, consisting of 10 first-order FBGs inscribed by a femtosecond (FS) laser in a highly multimode coreless fiber. The study evaluates the FBG array's ability to function as a distributed thermal sensing (DTS) platform, with the coreless fiber chosen as the sensing element due to its immunity to dopant migration at high temperatures. The design of a large cascaded first-order FBG array effectively eliminates unwanted harmonic peaks across a wide spectrum range. In contrast, higher-order FBGs introduce limitations due to the overlapping of Bragg peaks with harmonics. The FBG array's performance is evaluated by measuring the reflection spectrum of each grating at different temperatures, showing a high temperature sensitivity of 15.05 pm/°C at a Bragg wavelength of 1606.3 nm, with a linear response in the temperature range of 24 - 1100 °C. The FBG array was designed for a spatial resolution of 5 mm. A mode scrambler in the sensing network is employed, which suppresses multimodal interference, characterizes FBG peak visibility, and stabilizes the interference spectrum. The stability of the FBG array is also assessed over 24 hrs at 1100 °C, and it is observed to be stable during thermal treatment. Heat treatment at 1100°C improves the signal to noise ratio of the FBG array, demonstrating the robustness and suitability of the proposed FBG array on highly multimode coreless fiber as a potential sensing platform for DTS applications in harsh environmental conditions, overcoming the issues of dopant migration presented by dopes silica optical fibers at high temperatures.

47 OTHER INSTRUMENTATION↗
NASA NTRS1989

Simulation of electrostatic ion instabilities in the presence of parallel currents and transverse electric fields

A spatially two-dimensional electrostatic PIC simulation code was used to study the stability of a plasma equilibrium characterized by a localized transverse dc electric field and a field-aligned drift for L is much less than Lx, where Lx is the simulation length in the x direction and L is the scale length associated with the dc electric field. It is found that the dc electric field and the field-aligned current can together play a synergistic role to enable the excitation of electrostatic waves even when the threshold values of the field aligned drift and the E x B drift are individually subcritical. The simulation results show that the growing ion waves are associated with small vortices in the linear stage, which evolve to the nonlinear stage dominated by larger vortices with lower frequencies.

Nishikawa, K.-I.↗
NASA NTRS1989

State-of-the-art fiber optics for short distance frequency reference distribution

A number of recently developed fiber-optic components that hold the promise of unprecedented stability for passively stabilized frequency distribution links are characterized. These components include a fiber-optic transmitter, an optical isolator, and a new type of fiber-optic cable. A novel laser transmitter exhibits extremely low sensitivity to intensity and polarization changes of reflected light due to cable flexure. This virtually eliminates one of the shortcomings in previous laser transmitters. A high-isolation, low-loss optical isolator has been developed which also virtually eliminates laser sensitivity to changes in intensity and polarization of reflected light. A newly developed fiber has been tested. This fiber has a thermal coefficient of delay of less than 0.5 parts per million per deg C, nearly 20 times lower than the best coaxial hardline cable and 10 times lower than any previous fiber-optic cable. These components are highly suitable for distribution systems with short extent, such as within a Deep Space Communications Complex. Here, these new components are described and the test results presented.

Lutes, G. F.↗
NASA NTRS1990

Simulation of electrostatic turbulence due to sheared flows parallel and transverse to the magnetic field

A spatially two-dimensional electrostatic particle simulation code is used to examine the stability of a plasma equilibrium characterized by a localized transverse dc electric field and a magnetic-field-aligned electron drift for L much less than Lx, where Lx is the simulation length in the x direction and L is the scale length associated with the dc electric field. It is found that the dc electric field and the field-aligned current can together play a synergistic role to enable the excitation of electrostatic waves even when the threshold values of the field-aligned drift and the E x B drift are individually subcritical. The simulation results indicate that a broadband turbulence is associated with such an equilibrium.

Nishikawa, K.-I.↗
NASA NTRS1993

Upper Atmosphere Research Satellite attitude disturbances during shadow entry and exit

The Upper Atmosphere Research Satellite (UARS), as with the Landsat-4 and Landsat-5 spacecraft, experiences large attitude disturbances when entering and exiting the Earth's shadow. Previous investigations have provided some evidence linking these disturbances to rapid bending of the solar array but have also raised questions. For example, the magnitudes of the roll attitude disturbances have shown an unmolested asymmetry, and the timing of the disturbances at sunrise appears to disagree with the modeled timing. A better understanding of this phenomenon is important in assessing the implications for UARS science gathering and for future mission design analysis. To this end, UARS attitude, sensor, and actuator data are used to evaluate the disturbances as they vary with solar beta angle and solar array drive angle. The attitude data are examined during specific periods of interest, such as the month in which the solar array was parked in its high-noon position, and are also tracked from the beginning of the mission to determine any trends that may result from changing mass properties due to cryogen boiloff and propellant usage. Attitude rate and torque profiles are derived from inertial reference until data and related to the disturbances seen in the attitude data. The timing of the disturbances with respect to spacecraft sunset and sunrise is characterized to allow event predictions. Stability during the disturbances is discussed in terms of science instrument requirements. Finally, the results are compared with the behavior predicted by models that are based on solar array bending.

Lambertson, M.↗
NASA NTRS1999

Superconductor-Magnet Bearings With Inherent Stability and Velocity-Independent Drag Torque

A hybrid superconductor magnet bearing system has been developed based on passive magnetic levitation and the flux pinning effect of high-temperature superconductivity. The rationale lies in the unique capability of a high-temperature superconductor (HTS) to enhance system stability passively without power consumption. Characterization experiments have been conducted to understand its dynamic behavior and to estimate the required motor torque for its driving system design. These experiments show that the hybrid HTS-magnet bearing system has a periodic oscillation of drag torque due mainly to the nonuniform magnetic field density of permanent magnets. Furthermore, such a system also suffers from a small superimposed periodic oscillation introduced by the use of multiple HTS disks rather than a uniform annulus of HTS material. The magnitude of drag torque is velocity independent and very small. These results make this bearing system appealing for high-speed application. Finally, design guidelines for superconducting bearing systems are suggested based on these experimental results.

Lee, Eun-Jeong↗
NASA NTRS2000

Space Environmentally Stable Polyimides and Copolyimides

Polyimides with a unique combination of properties including low color in thin films, atomic oxygen (AO), ultra-violet (UV) radiation resistance, solubility in organic solvents in the imide form, high glass transition (T(sub g)) temperatures and high thermal stability have been prepared and characterized. The polymers were prepared by reacting a novel aromatic diamine with aromatic dianhydrides in a polar aprotic solvent. The solubility of the polymers in the imide form as well as the color density of thin films were dependent upon the chemical structure of the dianhydride. Several thin films (25-50 mm thick) prepared by solution casting of amide acid or imide solutions exhibited very low color and high optical transparency (approximately 90%) as determined by UV/visible spectroscopy. The polymers exhibited T(sub g)s >200 C depending upon the structure of the dianhydride and temperatures of 5% weight loss approximately 500C in air as determined by dynamic thermogravimetric analysis. Thin films coated with silver/inconel were exposed to a high fluence of AO and 1000 equivalent solar hours of UV radiation. The effects of these exposures on optical properties were minor. These space environmentally durable polymers are potentially useful in a variety of applications on spacecraft such as thin film membranes on antennas, second-surface mirrors, thermal/optical coatings and multi-layer thermal insulation (MLI) blanket materials. The chemistry, physical and mechanical properties of the polymers as well as their responses to AO and UV exposure will be discussed.

Watson, Kent A.↗
NASA NTRS2008

NASA Tech Briefs, June 2008

Topics covered include: Charge-Control Unit for Testing Lithium-Ion Cells; Measuring Positions of Objects Using Two or More Cameras; Lidar System for Airborne Measurement of Clouds and Aerosols; Radiation-Insensitive Inverse Majority Gates; Reduced-Order Kalman Filtering for Processing Relative Measurements; Spaceborne Processor Array; Instrumentation System Diagnoses a Thermocouple; Chromatic Modulator for a High-Resolution CCD or APS; Commercial Product Activation Using RFID; Cup Cylindrical Waveguide Antenna; Aerobraking Maneuver (ABM) Report Generator; ABM Drag_Pass Report Generator; Transformation of OODT CAS to Perform Larger Tasks; Visualization Component of Vehicle Health Decision Support System; Mars Reconnaissance Orbiter Uplink Analysis Tool; Problem Reporting System; G-Guidance Interface Design for Small Body Mission Simulation; DSN Scheduling Engine; Replacement Sequence of Events Generator; Force-Control Algorithm for Surface Sampling; Tool for Merging Proposals Into DSN Schedules; Micromachined Slits for Imaging Spectrometers; Fabricating Nanodots Using Lift-Off of a Nanopore Template; Making Complex Electrically Conductive Patterns on Cloth; Special Polymer/Carbon Composite Films for Detecting SO2; Nickel-Based Superalloy Resists Embrittlement by Hydrogen; Chemical Passivation of Li+-Conducting Solid Electrolytes; Organic/Inorganic Polymeric Composites for Heat-Transfer Reduction; Composite Cathodes for Dual-Rate Li-Ion Batteries; Improved Descent-Rate Limiting Mechanism; Alignment-Insensitive Lower-Cost Telescope Architecture; Micro-Resistojet for Small Satellites; Using Piezoelectric Devices to Transmit Power through Walls; Miniature Latching Valve; Apparatus for Sampling Surface Contamination; Novel Species of Non-Spore-Forming Bacteria; Chamber for Aerosol Deposition of Bioparticles; Hyperspectral Sun Photometer for Atmospheric Characterization and Vicarious Calibrations; Dynamic Stability and Gravitational Balancing of Multiple Extended Bodies; Simulation of Stochastic Processes by Coupled ODE-PDE; Cluster Inter-Spacecraft Communications; Genetic Algorithm Optimizes Q-LAW Control Parameters; Low-Impact Mating System for Docking Spacecraft; Non-Destructive Evaluation of Materials via Ultraviolet Spectroscopy; Gold-on-Polymer-Based Sensing Films for Detection of Organic and Inorganic Analytes in the Air; and Quantum-Inspired Maximizer.

Source record↗
NASA NTRS2008

WRATS Integrated Data Acquisition System

The Wing and Rotor Aeroelastic Test System (WRATS) data acquisition system (DAS) is a 64-channel data acquisition display and analysis system specifically designed for use with the WRATS 1/5-scale V-22 tiltrotor model of the Bell Osprey. It is the primary data acquisition system for experimental aeroelastic testing of the WRATS model for the purpose of characterizing the aeromechanical and aeroelastic stability of prototype tiltrotor configurations. The WRATS DAS was also used during aeroelastic testing of Bell Helicopter Textron s Quad-Tiltrotor (QTR) design concept, a test which received international attention. The LabVIEW-based design is portable and capable of powering and conditioning over 64 channels of dynamic data at sampling rates up to 1,000 Hz. The system includes a 60-second circular data archive, an integrated model swashplate excitation system, a moving block damping application for calculation of whirl flutter mode subcritical damping, a loads and safety monitor, a pilot-control console display, data analysis capabilities, and instrumentation calibration functions. Three networked computers running custom-designed LabVIEW software acquire data through National Instruments data acquisition hardware. The aeroelastic model (see figure) was tested with the DAS at two facilities at NASA Langley, the Transonic Dynamics Tunnel (TDT) and the Rotorcraft Hover Test Facility (RHTF). Because of the need for seamless transition between testing at these facilities, DAS is portable. The software is capable of harmonic analysis of periodic time history data, Fast Fourier Transform calculations, power spectral density calculations, and on-line calibration of test instrumentation. DAS has a circular buffer archive to ensure critical data is not lost in event of model failure/incident, as well as a sample-and-hold capability for phase-correct time history data.

Piatak, David J.↗
NASA NTRS2005

Diode-Laser-Based Spectrometer for Sensing Gases

A diode-laser-based spectrometer has been developed for measuring concentrations of gases and is intended particularly for use in analyzing and monitoring combustion processes under microgravitational conditions in a drop tower or a spacecraft. This instrument is also well suited for use on Earth in combustion experiments and for such related purposes as fire-safety monitoring and monitoring toxic and flammable gases in industrial settings. Of the gas-sensing spectrometers available prior to the development of this instrument, those that were sensitive enough for measuring the combustion gases of interest were too large, required critical optical alignments, used far too much electrical power, and were insufficiently rugged for use under the severe conditions of spacecraft launch and space flight. In contrast, the present instrument is compact, consumes relatively little power, and is rugged enough to withstand launch vibrations and space flight. In addition, this instrument is characterized by long-term stability, accuracy, and reliability. The diode laser in this spectrometer is operated in a wavelength-modulation mode. Different gases to be measured can be selected by changing modular laser units. The operation of the laser is controlled by customized, low-power electronic circuitry built around a digital signal-processor board. This customized circuitry also performs acquisition and analysis of data, controls communications, and manages errors.

Silver, Joel A.↗
NASA NTRS2017

Free Flight Ground Testing of ADEPT in Advance of the Sounding Rocket One Flight Experiment

The Adaptable Deployable Entry and Placement Technology (ADEPT) project will be conducting the first flight test of ADEPT, titled Sounding Rocket One (SR-1), in just two months. The need for this flight test stems from the fact that ADEPT's supersonic dynamic stability has not yet been characterized. The SR-1 flight test will provide critical data describing the flight mechanics of ADEPT in ballistic flight. These data will feed decision making on future ADEPT mission designs. This presentation will describe the SR-1 scientific data products, possible flight test outcomes, and the implications of those outcomes on future ADEPT development. In addition, this presentation will describe free-flight ground testing performed in advance of the flight test. A subsonic flight dynamics test conducted at the Vertical Spin Tunnel located at NASA Langley Research Center provided subsonic flight dynamics data at high and low altitudes for multiple center of mass (CoM) locations. A ballistic range test at the Hypervelocity Free Flight Aerodynamics Facility (HFFAF) located at NASA Ames Research Center provided supersonic flight dynamics data at low supersonic Mach numbers. Execution and outcomes of these tests will be discussed. Finally, a hypothesized trajectory estimate for the SR-1 flight will be presented.

Smith, B. P.↗
DOE OSTI2020

Green synthesis and characterization of nontoxic L-methionine capped silver and gold nanoparticles

The simple green method for synthesis of stable L-Methionine (L-Met) capped silver (Ag@LM NPs) and gold (Au@LM NPs) nanoparticles (NPs) without adding any additional reduction agent or stabilizer was developed. Colloidal dispersions were characterized by UV–Vis spectrophotometry. The size and spherical shape of NPs were evaluated by transmission electron microscopy. Their surface covering was confirmed by atomic force microscopy, Fourier transform infrared spectroscopy, dynamic light scattering, and zeta potential measurements. Density functional theory calculations pointed that the preferential adsorption mode of L-Met on both Ag and Au surfaces was a vertical binding geometry via –NH2 group, while horizontal binding mode via [sbnd]S[sbnd] and –NH2 groups is also possible. The genotoxicity (evaluated by the micronucleus assay) of NPs, as well as their effects on some oxidative stress parameters (catalase activity, malondialdehyde level), were assessed in vitro using human peripheral blood cells as a model system. The influence of NPs on the morphology of lymphocyte cells studied using atomic force microscopy revealed that the membrane of cells remained unaffected after the treatment with NPs. When considering the effects of NPs on catalase activity and malondialdehyde level, neither particle type promoted oxidative stress. However, the treatment of lymphocytes with Ag@LM NPs induced a concentration-dependent enhancement of the micronuclei incidence and suppression of the cell proliferation while Au@LM NPs promoted cell proliferation, with no significant effects on micronuclei formation. The Ag@LM NPs were more prone to induce DNA damage than Au@LM NPs, which makes the latter type more suitable for further studies in nano-medicine. © 2019.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1989

Effect of control surface mass unbalance on the stability of a closed-loop active control system

An inertial energy approach similar to the aerodynamic energy method for flutter suppression is used to investigate the effects of mass-unbalanced control surfaces on the stability of a closed-loop system. It is demonstrated that a spanwise section for sensor location can be obtained which ensures minimum sensitivity to the mode shapes of the aircraft. Leading-edge control is characterized by a compatibility between inertial stabilization and aerodynamic stabilization that trailing-edge control lacks.

Nissim, E.↗
NASA NTRS1981

The stability of new transparent polymeric materials: The epoxy trimethoxyboroxine system. Part 1: The preparation, characterization and curing of epoxy resins and their copolymers

The effects of resin composition, curing conditions fillers, and flame retardant additives on the flammability of diglycidyl ether of bisphenol-A (DGEBA) as measured by the oxygen index is examined. The oxygen index of DGEBA cured with various curing agents was between 0.198 to 0.238. Fillers and flame retardant additives can increase the oxygen index dependent on the material and the amount used. Changes in the basic cured resin properties can be anticipated with the addition of noncompatible additives. High flame resistant epoxy resins with good stability and mechanical properties are investigated.

Pearce, E.↗
NASA NTRS2023

Performance of an Active Vehicle Stabilization System During Touchdown in the Presence of Propellant Slosh Dynamics

This paper characterizes the effect of propellant slosh on the performance of an active stabilization control system for the two-two-and-over symmetric landing mode during touchdown. Generalized impulse and momenta theory is used to model the instance when the landing leg strikes the ground as an inelastic collision event. For active stabilization, a rate damping controller is used to stabilize the attitude of the vehicle via onboard reaction control system. Simulation results are shown comparing the performance of the control system with and without slosh dynamics.

Jing Pei↗