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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2011

Phase Separation and Pattern Formation in a Binary Bose-Einstein Condensate

The miscibility-immiscibility phase transition in binary Bose-Einstein condensates (BECs) can be controlled by a coupling between the two components. Here we propose a new scheme that uses coupling-induced pattern formation to test the Kibble-Zurek mechanism (KZM) of topological-defect formation in a quantum phase transition. For a binary BEC in a ring trap we find that the number of domains forming the pattern scales as a function of the coupling quench rate with an exponent as predicted by the KZM. For a binary BEC in an elongated harmonic trap we find a different scaling law due to the transition being spatially inhomogeneous. We perform a ''quantum simulation'' of the harmonically trapped system in a ring trap to verify the scaling exponent.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Data for "Adsorptive Separation and Recovery of Triacetic Acid Lactone from Fermentation Broth"

Triacetic acid lactone (TAL) can be microbially produced and further chemically upgraded to several high-value chemicals. In this work, several acidic and basic ion-exchange resins and activated charcoal were evaluated for their ability to adsorb microbially produced TAL. Activated charcoal and a weak base resin, Dowex 66, showed similar TAL adsorption capacity of 0.18 ± 0.002 g/g. At 15% w/v activated charcoal, about 98% of TAL present in fermentation broth could be adsorbed. Further, ethanol washing allowed recovery of 72% of adsorbed TAL. A biorefinery producing TAL from sucrose was designed, simulated, and evaluated (through technoeconomic analysis) under uncertainty, for an estimated TAL minimum product selling price (MPSP) of $4.27/kg [$3.71−4.94/kg; 5th-95th percentiles] for the current state of technology and $2.83/kg [$2.46–3.29/kg] following potential near-term improvements to fermentation. Thus, this work provides an adsorptive process to recover microbially produced TAL that can be chemically upgraded to several industrial products.

Bioproducts↗
DOE OSTI2019

Performance of the Gemini Planet Imager Non-redundant Mask and Spectroscopy of Two Close-separation Binaries: HR 2690 and HD 142527

The Gemini Planet Imager (GPI) contains a 10-hole non-redundant mask (NRM), enabling interferometric resolution in complement to its coronagraphic capabilities. The NRM operates both in spectroscopic (integral field spectrograph, henceforth IFS) and polarimetric configurations. NRM observations were taken between 2013 and 2016 to characterize its performance. Most observations were taken in spectroscopic mode, with the goal of obtaining precise astrometry and spectroscopy of faint companions to bright stars. We find a clear correlation between residual wavefront error measured by the adaptive optic system and the contrast sensitivity by comparing phase errors in observations of the same source, taken on different dates. We find a typical 5σ contrast sensitivity of (2–3) × 10 –3 at $~λ/D$. We explore the accuracy of spectral extraction of secondary components of binary systems by recovering the signal from a simulated source injected into several data sets. We outline data reduction procedures unique to GPI's IFS and describe a newly public data pipeline used for the presented analyses. We demonstrate recovery of astrometry and spectroscopy of two known companions to HR 2690 and HD 142527. NRM+polarimetry observations achieve differential visibility precision of σ ~ 0.4% in the best case. We discuss its limitations on Gemini-S/GPI for resolving inner regions of protoplanetary disks and prospects for future upgrades. We summarize lessons learned in observing with NRM in spectroscopic and polarimetric modes.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1973

Electrophoresis separator combining centrifugal separation

Centrifugal force causes buffer, chosen to be denser than particles, to move outward and particles to move inward. Electrophoresis force can be made to equal centrifugal force. System tends not to be affected by convection and other disturbances that are so troublesome in conventional electrophoresis systems.

Semon, H. W.↗
DOE OSTI2016

Process for fabricating PBI hollow fiber asymmetric membranes for gas separation and liquid separation

The invention provides methods for preparing an asymmetric hollow fiber, the asymmetric hollow fibers prepared by such methods, and uses of the asymmetric hollow fibers. One method involves passing a polymeric solution through an outer annular orifice of a tube-in-orifice spinneret, passing a bore fluid though an inner tube of the spinneret, dropping the polymeric solution and bore fluid through an atmosphere over a dropping distance, and quenching the polymeric solution and bore fluid in a bath to form an asymmetric hollow fiber.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Efficient Mesofluidic Separation of Large Particles in nuclear slurries - 20408

Efficient and effective particle separation is essential to cleanup of many nuclear wastes. For example, particle separation may be used to accelerate settle-decant bottlenecks that limit the throughput necessary to achieve the U.S. Department of Energy waste cleanup mission in a timely manner. Particle separation may be used to protect downstream processing equipment from pulses of solids that may be encountered near (within a few feet of) liquid-solid interfaces during waste transfer operations, thereby preventing work stoppages. Effective particle separation may permit efficient sludge washing. These are only a few of the ways in which particle separation is important. Yet, efficient and effective particle separation in nuclear processing environments remains challenging. For example, settle-decant operations permit larger and heavier particles to settle, leaving smaller, lighter particles suspended. However, settle-decant operations are slow, convection currents may resuspend solids, hindered settling of multicomponent slurries remains incompletely understood, and predictive models for settling in graduated cylinders fail to match limited observations of settling in large waste tanks. Additionally, pumping operations can cause turbulent resuspension of particles when the pump intake is close to the settled solids layer. Filtration techniques that use membranes or partially permeable barriers retain larger particles, permitting smaller particles to permeate. However, filters, including dead-end filtration, are prone to clogging and caking, operate at elevated pressures due to minimal void volume, and increase in pressure during operations, which require more control systems. Therefore, the need for high throughput particle separation techniques that operate with modest pressure drops persists. A novel mesofluidic separator presents the opportunity to effectively and efficiently accelerate the waste cleanup mission. The separator separates large particles from process streams across a broad range of particle sizes and has no moving parts or media to replace, regenerate, or clean. This separator design has an unusually large void volume, permitting operation at much higher flow rates (and lower pressures) than traditional filtration (e.g., dead-end filtration). Industrial-scale flow rates have been demonstrated. In performance testing, mesofluidic separators operate at might flow rates (>90 gpm (0.0006 m{sup 3}/s) in piping 3 inches (0.08 m) in diameter; Re>10{sup 5}), with modest pressure drop (∼25 psi (170 KPa) in testing). In complex, aggregating waste simulants, the separator loses <25% of flow projected over months without back pulsing or chemical cleaning. Mesofluidic separation presents infrastructure advantages, reduces risk, and provides mission impact. Infrastructure advantages include implementation within existing transfer systems, plug and play without facility modifications to safety systems, and operation at low pressures. The separator is flexible in location, may be positioned within or outside of waste tanks, and may replace or augment dead-end and cross-flow filters. Mesofluidic separation reduces risk by minimizing waste (no media to replace or regenerate and no cleaning chemicals to handle and dispose) and by minimizing filter change-out consistent with as low as reasonably achievable (ALARA) exposure to workers. The potential mission impact of these separators is substantial. The separator has potential to support, simplify, and accelerate in-farm transfers and waste feed delivery. Furthermore, the separator can free up settling and holding tanks in the Direct Feed Low-Activity Waste (DFLAW) mission by reducing or eliminating post-transfer settling and wait times with the potential to free up 1 Mgal (4000 m{sup 3}) of double-shell tank space. This paper quantitatively compares mesofluidic separation to dead-end filtration, discusses scale-up results, and considers the separator's potential to efficiently and effectively reduce the long-term environmental ability of particulate-rich nuclear wastes. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Low-Cost Production of Lithium-Ion Separator Membranes w/ Improved Safety

The purpose of this Cooperative Research and Development Agreement (CRADA) between Oak Ridge National Laboratory (ORNL) and Porous Power Technologies, LLC (PPT) was to validate the performance, durability, and safety of a new type of reinforced, composite lithium ion battery separator produced as either a free-standing product or by a method of direct coating after electrode fabrication. ORNL’s primary roles were to develop novel separator thermophysical and mechanical property characterization methods and assist with fundamental understanding of SYMMETRIX® HPX and HPX-F product line chemical makeup and microstructure. PPT’s primary roles were to implement the understanding gained from the ORNL developed characterization methods into a refined product line featuring nonwoven-reinforced, ceramic-filled composite HPX-F separators for the lithium ion battery industry and quantify long-term cell performance improvements associated with HPX-F separators. Over the course of this CRADA, the product line of PPT was expanded from a pure polyvinylidene fluoride (PVDF) HP and polyester nonwoven-reinforced HPX separator platform to one that includes a variety of ceramic-filled HPX-F separators. In addition, the laminating and direct coating technologies for HPX and HPX-F separators are now more developed and moving towards commercial licensing. PPT’s SYMMETRIX® production process will revolutionize the production of lithium ion batteries by eliminating one of the most expensive components (the free-standing separator membrane) while improving performance and safety. The performance and safety improvements are due primarily to replacement of the conventional polyethylene/polypropylene (PE/PP) separator material with polyvinylidene fluoride (PVDF), and to ceramic materials added to the PVDF to form a short-resistant, thermally-stable composite structure. Ultimately, lithium ion battery manufacturers will be able to produce PPT separators in-house through the laminating or direct coating methods such as those based on the SYMMETRIX® product line, giving them higher performance cells at a fraction of the cost required to purchase separators from existing vendors. Direct coating of separators onto electrodes eliminates the cost of a downstream thermal lamination step and requires little or no change to existing equipment. It is a clear path for lithium ion battery manufacturers to reach the <$1/m2 separator price target set by the U.S. Advanced Battery Consortium (USABC). The technology enabled by this project will have a substantial impact on energy efficiency required to produce cells and is anticipated to save up to $1B annually by 2014 in reduced manufacturing costs. In addition, it will contribute significantly to production energy savings associated with transporting free-standing polyolefin (PE/PP) separators from the vendor to the cell manufacturer locations. SYMMETRIX® separators have shown increased cell capacity, improved thermal stability, and longer cycle life over their PE/PP counterparts and have been repeatedly demonstrated to improve nearly all aspects of lithium ion battery performance Prior to the start of this CRADA, widespread adoption has been limited by three factors: 1) difficulty in handling the material on high-speed processing equipment due to lower tensile strength than oriented PE/PP materials; 2) cost concerns associated with the higher expense of PVDF as a raw material; and 3) questions regarding short resistance and durability. The first factor was addressed through thorough mechanical (ultimate tensile strength and dynamic mechanical analysis, etc.) property characterization of HPX and HPX-F materials against the commercial polyolefin baselines. The second factor was address by shifting the focus of PPT’s product line towards the HPX-F materials with low-PVDF (high ceramic filler) content to reduce overall separator cost. Concerns associated with the third factor were alleviated by evaluating the internal shorting resistance of the separators using a custom developed ORNL measurement method and obtaining long-term cycling data of the new HPX-F separator formulations. A materials emphasis was placed on polyester fiber mats for the nonwoven reinforcement (to boost overall separator tensile strength) and proprietary metal oxides for the HPX-F fillers (to improve thermomechanical properties of the separator and make it more resistant to overcharge and internal shorting).

batteries↗
NASA NTRS1994

Control of flow separation in airfoil/wing design applications

Existing aerodynamic design methods have generally concentrated on the optimization of airfoil or wing shapes to produce a minimum drag while satisfying some basic constraints such as lift, pitching moment, or thickness. Since the minimization of drag almost always precludes the existence of separated flow, the evaluation and validation of these design methods for their robustness and accuracy when separated flow is present has not been aggressively pursued. However, two new applications for these design tools may be expected to include separated flow and the issues of aerodynamic design with this feature must be addressed. The first application of the aerodynamic design tools is the design of airfoils or wings to provide an optimal performance over a wide range of flight conditions (multipoint design). While the definition of 'optimal performance' in the multipoint setting is currently being hashed out, it is recognized that given a wide enough range of flight conditions, it will not be possible to ensure a minimum drag constraint at all conditions, and in fact some amount of separated flow (presumably small) may have to be allowed at the more demanding flight conditions. Thus a multipoint design method must be tolerant of the existence of separated flow and may include some controls upon its extent. The second application is in the design of wings with extended high speed buffet boundaries of their flight envelopes. Buffet occurs on a wing when regions of flow separation have grown to the extent that their time varying pressures induce possible destructive effects upon the wing structure or adversely effect either the aircraft controllability or the passenger comfort. A conservative approach to the expansion of the buffet flight boundary is to simply expand the flight envelope of nonseparated flow under the assumption that buffet will also thus be alleviated. However, having the ability to design a wing with separated flow and thus to control the location, extent, and severity of the separated flow regions may allow aircraft manufacturers to gain an advantage in the early design stages of an aircraft, when configuration changes are relatively inexpensive to make. Continuing the work begun last year, an airfoil design package has been modified to provide some control over the existence and extent of flow separation. This package consists of a 2-D Navier-Stokes flow solver which is coupled to the CDISC (constrained direct/iterative surface curvature) design method. The first modification is a prediction method for determining whether separation is likely based solely upon a given pressure distribution. If separation is predicted but is undesirable, the new routines will modify the pressure distribution to alleviate the problem. This new pressure distribution is then used in the design method to generate a new aerodynamic shape. Since separation may be acceptable in some cases, particularly if the separation does not extend to the trailing edge, another added logic estimates the extent of separation based upon a correlation with calculated separated flow cases. If the flow behind a shock induced separation is not predicted to reattach before the trailing edge, the logic weakens the shock strength and otherwise alters the pressure distribution in order to promote reattachment. This later addition is as yet unreliable due to secondary separation effects, but additional work is being pursued to improve the method.

Gally, Thomas A.↗
NASA NTRS2013

Pilot and Controller Evaluations of Separation Function Allocation in Air Traffic Management

Two human-in-the-loop simulation experiments were conducted in coordinated fashion to investigate the allocation of separation assurance functions between ground and air and between humans and automation. The experiments modeled a mixed-operations concept in which aircraft receiving ground-based separation services shared the airspace with aircraft providing their own separation service (i.e., self-separation). Ground-based separation was provided by air traffic controllers without automation tools, with tools, or by ground-based automation with controllers in a managing role. Airborne self-separation was provided by airline pilots using self-separation automation enabled by airborne surveillance technology. The two experiments, one pilot-focused and the other controller-focused, addressed selected key issues of mixed operations, assuming the starting point of current-day operations and modeling an emergence of NextGen technologies and procedures. In the controller-focused experiment, the impact of mixed operations on controller performance was assessed at four stages of NextGen implementation. In the pilot-focused experiment, the limits to which pilots with automation tools could take full responsibility for separation from ground-controlled aircraft were tested. Results indicate that the presence of self-separating aircraft had little impact on the controllers' ability to provide separation services for ground-controlled aircraft. Overall performance was best in the most automated environment in which all aircraft were data communications equipped, ground-based separation was highly automated, and self-separating aircraft had access to trajectory intent information for all aircraft. In this environment, safe, efficient, and highly acceptable operations could be achieved for twice today's peak airspace throughput. In less automated environments, reduced trajectory intent exchange and manual air traffic control limited the safely achievable airspace throughput and negatively impacted the maneuver efficiency of self-separating aircraft through high-density airspace. In a test of scripted conflicts with ground-managed aircraft, flight crews of self-separating aircraft prevented separation loss in all conflicts with detection time greater than one minute. In debrief, pilots indicated a preference for at least five minute's alerting notice and trajectory intent information on all aircraft. When intent information on ground-managed aircraft was available, self-separating aircraft benefited from fewer conflict alerts and fewer required deviations from trajectory-based operations.

Wing, David↗
NASA NTRS2003

Boundary-Layer Separation Control under Low-Pressure Turbine Airfoil Conditions using Glow-Discharge Plasma Actuators

Modem low-pressure turbines, in general, utilize highly loaded airfoils in an effort to improve efficiency and to lower the number of airfoils needed. Typically, the airfoil boundary layers are turbulent and fully attached at takeoff conditions, whereas a substantial fraction of the boundary layers on the airfoils may be transitional at cruise conditions due to the change of density with altitude. The strong adverse pressure gradients on the suction side of these airfoils can lead to boundary-layer separation at the latter low Reynolds number conditions. Large separation bubbles, particularly those which fail to reattach, cause a significant degradation of engine efficiency. A component efficiency drop of the order 2% may occur between takeoff and cruise conditions for large commercial transport engines and could be as large as 7% for smaller engines at higher altitude. An efficient means of of separation elimination/reduction is, therefore, crucial to improved turbine design. Because the large change in the Reynolds number from takeoff to cruise leads to a distinct change in the airfoil flow physics, a separation control strategy intended for cruise conditions will need to be carefully constructed so as to incur minimum impact/penalty at takeoff. A complicating factor, but also a potential advantage in the quest for an efficient strategy, is the intricate interplay between separation and transition for the situation at hand. Volino gives a comprehensive discussion of several recent studies on transition and separation under low-pressure-turbine conditions, among them one in the present facility. Transition may begin before or after separation, depending on the Reynolds number and other flow conditions. If the transition occurs early in the boundary layer then separation may be reduced or completely eliminated. Transition in the shear layer of a separation bubble can lead to rapid reattachment. This suggests using control mechanisms to trigger and enhance early transition. Gad-el-Hak provides a review of various techniques for flow control in general and Volino discusses recent studies on separation control under low-pressure-turbine conditions utilizing passive as well as active devices. As pointed out by Volino, passive devices optimized for separation control at low Reynolds numbers tend to increase losses at high Reynolds numbers, Active devices have the attractive feature that they can be utilized only in operational regimes where they are needed and when turned off would not affect the flow. The focus in the present paper is an experimental Separation is induced on a flat plate installed in a closed-circuit wind tunnel by a shaped insert on the opposite wall. The flow conditions represent flow over the suction surface of a modem low-pressure-turbine airfoil ('Pak-B'). The Reynolds number, based on wetted plate length and nominal exit velocity, is varied from 50,000 to 300,000, covering cruise to takeoff conditions. Low (0.2%) and high (2.5%) Gee-stream turbulence intensities are set using passive grids. A spanwise-oriented phased-plasma-array actuator, fabricated on a printed circuit board, is surface- flush-mounted upstream of the separation point and can provide forcing in a wide frequency range. Static surface pressure measurements and hot-wire anemometry of the base and controlled flows are performed and indicate that the glow-discharge plasma actuator is an effective device for separation control. of active separation control using glow discharge plasma actuators.

Hultgren, Lennart S.↗