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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Energy impact of short-haul STOL systems

An analysis has been made to evaluate the impact on fuel requirements of a segregated short-haul system. A comparison has been made between two alternate scenarios: one with STOL, and the other without STOL. For the New York to Washington, D.C. city pair the results show: (1) the modal efficiency approach, while indicating the with STOL scenario requires more fuel than the without STOL scenario, is of questionable validity because it does not account for various effects which exist in realistic scenarios; (2) evaluation of fuel requirements based on more detailed modeling indicates that while a STOL scenario requires more fuel than without STOL when an idealized CTOL system is postulated, the STOL scenario requires less fuel than without STOL when the CTOL system has even moderate delays. These results are due to a combination of effects: the closer and more convenient locations of STOL ports to the traveler, congestion at the CTOL airports, and the impact of the through passenger traffic. Sensitivity of results to STOL aircraft block fuel and to CTOL congestion delays are considered.

Stewart, E. C.↗
NASA NTRS1974

Liquid-metal atomization for hot working preforms

Rapid quenching of a liquid metal by atomization or splat cooling overcomes the major limitation of most solidification processes, namely, the segregation of alloying elements, impurities, and constituent phases. The cooling rates of different atomizing processes are related to the dendrite arm spacings and to the microstructure of the atomized powders. The increased solubility limits and the formation of metastable compounds in splat-cooled alloys are discussed. Consolidation of the powders by hot isostatic compaction, hot extrusion, or hot forging and rolling processes yields billets with properties equivalent to or better than those of the wrought alloys. The application of this powder processing technology to high-performance alloys is reviewed.

Grant, N. J.↗
NASA NTRS1974

Liquid phase sintered compacts in space

A model that will explain the effect of gravity on liquid phase sintering was developed. Wetting characteristics and density segregation which are the two important phenomena in liquid phase sintering are considered in the model development. Experiments were conducted on some selected material combinations to study the gravity effects on liquid phase sintering, and to verify the validity of the model. It is concluded that: (1) The surface tension forces acting on solid particles in a one-g environment are not appreciably different from those anticipated in a 0.00001g/g sub 0 (or lower) environment. (2) The capillary forces are dependent on the contact angle, the quantity of the liquid phase, and the distance between solid particles. (3) The pores (i.e., bubbles) do not appear to be driven to the surface by gravity-produced buoyancy forces. (4) The length of time to produce the same degree of settling in a low-gravity environment will be increased significantly. (5) A low gravity environment would appear to offer a unique means of satisfactorily infiltrating a larger and/or complex shaped compact.

Mookherji, T. K.↗
NASA NTRS1975

Effects of alloy composition in alleviating embrittlement problems associated with the tantalum alloy T-111

The causes of aging embrittlement in T-111 (Ta-8W-2Hf) and the effect of alloy modification were investigated. Results show that T-111 possesses a critical combination of tungsten and hafnium that leads to loss in ductility at -196 C after aging near 1040 C. It was found that this occurs because tungsten enhances hafnium segregation to grain boundaries, which also leads to increased susceptibility to hydrogen embrittlement. Aging embrittlement was not observed in tantalum alloys with reduced tungsten or hafnium contents; most of the alloys studied have lower strengths than T-111 and exhibit susceptibility to hydrogen embrittlement.

Stephens, J. R.↗
NASA NTRS1975

Dependence of resistivity on the doping level of polycrystalline silicon

The electrical resistivity of polycrystalline silicon films has been studied as a function of doping concentration and heat treatment. The films were grown by the chemical vapor decomposition of silane on oxidized silicon wafers. The resistivity of the as-deposited films was widely scattered but independent of dopant atom concentration at the lightly doped levels and was strong function of dopant level in the more heavily doped regions. Postdeposition heat treatments in an oxidizing atmosphere remove scatter in the data. The resultant resistivity for dopant levels less than 10 to the 16th atoms/per cu cm was approximately equal to that of intrinsic silicon. In the next 2 orders of magnitude increase in dopant level, the resistivity dropped 6 orders of magnitude. A model, based on high dopant atom segregation in the grain boundaries, is proposed to explain the results.

Fripp, A. L.↗
NASA NTRS1975

On the 'Seyfert Sextet', VV 115

Radial velocity observations and red shift determinations of some galaxies east of the Seyfert Sextet are discussed. It is suggested that the Sextet may be a condensation in an extended group of galaxies. The velocities of galaxies in this region are segregated into three main groups, corresponding to the redshifts of the Hercules cluster, the group including the Seyfert Sextet, and a third group as indicated by the velocities of NGC 6035 and Mark 294.

Chincarini, G.↗
NASA NTRS1975

Superconducting properties of Pb-Sn-In alloys directionally solidified aboard Skylab

Superconducting alloys of Pb-Sn-In were directionally solidified in the absence of gravity-induced convection and segregation by processing in a near weightless condition aboard Skylab. Lead-rich and tin-rich lamellar structures were obtained with both high and low G/R (temperature gradient/solidification rate) samples processed at 0-g and at 1-g in a ground-based laboratory. Thinner, higher density lamellae were found with the 0-g specimens. Magnetization curves at 4.2 K showed hysteresis effects with large areas under the curves indicating magnetic flux pinning by the normal state tin-rich phase.

Anderson, W. T., Jr.↗
NASA NTRS1974

A study of Pb-204 partition in lunar samples using terrestrial and meteoritic analogues

Pb-204, Bi, Tl, and Zn have been measured in Apollo 16 samples and Apollo 17 orange soil. These data in addition to already reported Apollo 14 and 15 Pb-204 results and literature data are used to support the Pb-204-metallic phase coherence. The partition of Pb-204 into very fine metallic grains appears to be the result of an impact process rather than metal segregation in a magma.

Allen, R. O., Jr.↗
NASA NTRS1975

Origin of titaniferous lunar basalts

Delineation of low pressure phase equilibria in the composition space relevant to titaniferous lunar basalts demonstrates a significant degree of control by those equilibria on the compositions of the basalts. The existence of two distinct chemical groups of basalts (high and low K) which cannot be related one to the other by fractional crystallization at any pressure, suggests that melting is responsible for the two groups. Consideration of the pressure shift required to produce the differences between groups constrains magma segregation to have occurred in the outer 150 km of the moon. It is difficult to relate low-Ti and high-Ti basalts to the same source region. The preferred source region of high-Ti basalts, based on phase equilibrium considerations, is a late ilmenite-rich cumulate produced from the residual liquid of the primordial differentiation of the outer portions of the moon. This ilmenite-rich layer is sandwiched between the lunar feldspathic crust and a complementary mafic cumulate.

Walker, D.↗
NASA NTRS1975

A study of reactive turbulent mixing

This paper describes the development of a probe to study turbulent reactive mixing of two hypergolic streams of gas. The streams contain CO and O2 respectively and are mixed at 1400 K. The probe is a water cooled sonic orifice probe followed by a Fanno duct. Tests showed that it rapidly quenched the reaction, and that time-average, ingested gas composition accurately reflected the time-average composition at the sampling point. A new way to measure mixedness to the molecular level in a reactive flow situation is described, based on time-average compositions at the probe. This definition is compared to the definition of intensity of segregation which can be used for unreactive mixing situations. Finally, the probe is used to examine centerline composition in a confined coaxial mixing situation.

Roler, M. A.↗
NASA NTRS1976

Growing crystals from eutectic melts

Inverted Bridgman Method yields crystals of higher homogeneity and better structure than those grown by ordinary Bridgman method. Process controls thermotransport by holding molten alloy in known temperature for known period of time. Rapid cooling quenches in state of segregation. Method is applicable to other eutectiferous systems where thermotransport is appreciable.

Bhat, B. N.↗
NASA NTRS1976

The metal to metal interface and its effect on adhesion and friction

The nature of the interface, adhesion and friction properties of noble metals, platinum metals, Group IV (B) metals and transition metals were considered. The surface chemical activity of the noble and platinum metals is shown to effect metal to metal interfaces as does a valance bonding in the transition metals. With the Group IV (B) metals the degree of metallic nature of the elements is shown to effect interfacial behavior. The effect of surface segregation of alloy constituents such as silicon in iron and its influence on the metal to metal interface is discussed. In addition the effect of alloy constituents on changes in bulk properties such as transformations in tin are shown to effect interfacial adhesion and friction behavior.

Buckley, D. H.↗
NASA NTRS1975

The solidification under zero gravity conditions of binary alloys exhibiting solid state immiscibility

The solidification behavior of gold-silicon alloys containing up to 25 at. % silicon was studied, and a mathematical model of gravity segregation during solidification was developed. A background of knowledge is provided which can be used in the design of zero gravity solidification experiments to be carried out in the 300-ft drop tower, in Aerobee rockets and in future space missions. Such experiments are needed to develop the basic scientific knowledge required for the design of economically viable space manufacturing processes. Some preliminary zero gravity experiments were carried out on a gold-25 at. % silicon alloy using the drop tower facility.

Johnson, A. A.↗
NASA NTRS1976

M551 metals melting experiment

The Metals Melting Skylab Experiment consisted of selectively melting, in sequence, three rotating discs made of aluminum alloy, stainless steel, and tantalum alloy. For comparison, three other discs of the same three materials were similarly melted or welded on the ground. The power source of the melting was an electron beam unit. Results are presented which support the concept that the major difference between ground base and Skylab samples (i.e., large elongated grains in ground base samples versus nearly equiaxed and equal sized grains in Skylab samples) can be explained on the basis of constitutional supercooling, and not on the basis of surface phenomena. Microstructural observations on the weld samples and present explanations for some of these observations are examined. In particular, ripples and their implications to weld solidification were studied. Evidence of pronounced copper segregation in the Skylab A1 weld samples, and the tantalum samples studied, indicates a weld microhardness (and hence strength) that is uniformly higher than the ground base results, which is in agreement with previous predictions. Photographs are shown of the microstructure of the various alloys.

Li, C. H.↗
NASA NTRS1976

Mechanical testing - In situ fracture device for Auger electron spectroscopy

An in situ fracture device for Auger spectroscopy is described. The device is designed to handle small tensile specimens or small double-cantilever beam specimens and is fully instrumented with load and displacement transducers so that quantitative stress-strain measurements can be made directly. Some initial test results for specimens made from 4130 and 1020 steel are presented. Results indicate that impurity segregation at interfaces other than grain boundary may play a significant role in the mechanism of ductile fracture.

Moorhead, R. D.↗
NASA NTRS1976

Implications of an internal dynamo for the thermal history of Mercury

Constraints placed on the thermal evolution of Mercury by the dynamo model of the planet's magnetic field are investigated. It is assumed that Mercury is a differentiated planet possessing an iron-nickel core with a radius approximately three-fourths of the planetary radius, that the mantle is made of silicates with thermal and rheological properties similar to those of earth's upper mantle, and that differentiation was a global process which resulted in the removal of radioactive heat sources from the core and the upward segregation of heat sources in the mantle. These assumptions are found to lead to the conclusion that the existence of a molten core requires the retention of a minimum concentration of heat sources throughout the mantle, the value being comparable to the mantle-wide average concentration for earth. Thus, it is suggested that the differentiation of Mercury could not have resulted in the complete removal of heat sources from the mantle into a crust near the planet's surface.

Cassen, P.↗
NASA NTRS1976

The metal to metal interface and its effect on adhesion and friction

The paper considers the interface between two bulk metals and the effect of this interface on adhesive bonding, resistance to tangential displacements, friction and the interfacial transport from one surface to another. Using Auger emission spectroscopy, field ion microscopy, and low energy electron diffraction techniques, the influence of surface orientation, lattice registry, crystal lattice structure and defects, metal surface chemistry and alloying on the characteristics of the interface was studied for noble, platinum, transition, and Group 4B metals. With dissimilar metals in contact, epitaxial transfer of the cohesively weaker to the cohesively stronger metal has been observed. Surface chemical activity of the noble and platinum metals is shown to affect interfacial behavior as does a valence bonding in the transition metals, and the degree of metallic nature in the Group 4B elements. Alloying elements, e.g., Si and Fe, can alter interfacial behavior by segregation to the surface of metals or by altering bulk properties such as crystal transformation kinetics.

Buckley, D. H.↗