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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Photoelectrode Durability in Two- versus Three-Electrode Configurations: Understanding the Impact of Circuit Configuration on Water-Splitting Stability

Device durability remains a significant challenge in photoelectrochemical (PEC) water splitting under ambient conditions. Yet, a lack of understanding of the test configuration and applied bias effects continue to hinder progress. In this study, we differentiate two-electrode (2E) and three-electrode (3E) configurations for evaluating PEC material durability, focusing particularly on their impacts on photoabsorber solid-state operating conditions. Our results underscore the fallacy of inferring 2E device stability from durability measurements performed solely in 3E configurations. Unmeasured and often misunderstood total circuit bias in 3E tests moderates material degradation, leading to the overestimation of photoelectrode stability compared to short-circuit operation. We demonstrate how the photoabsorber's operating voltage critically governs charge separation, surface stability, and degradation mechanisms during PEC operation. With these findings, we propose a standardized framework for conducting more reliable 3E durability experiments that simulate unassisted performance to help accelerate the development of robust, stable materials for solar-driven water splitting.

08 HYDROGEN↗

Enhancing Short-Term Flexibility through Characterization of HVDC Transmission Systems

Efficient power grid operation hinges on maintaining safety and reliability through adaptable system flexibility standards. However, in a future power grid characterized by extensive renewable energy integration, conventional system flexibility and predetermined requirements may falter under extreme conditions. This paper addresses the formidable challenge of sustaining secure and dependable power grid operations under these circumstances, emphasizing the role of controllable high voltage direct current (HVdc) transmission systems in amplifying overall system flexibility and tackling operational complexities. To quantitatively assess short-term flexibility and its associated economic benefits from HVdc within specific regions, we propose a Power Flow Distribution Factors (PTDFs) based approach. This methodology takes into account both dispatchable generators and HVdc systems, pinpointing their contributions. Through an analysis of the Western Electricity Coordinating Council (WECC) system, we demonstrate the practical application of this approach to scrutinize the impacts of existing and future HVdc lines.

Operational Flexibility, Multi-terminal HVdc, tran↗

Binary pseudorandom array test standard optimized for characterization of large field-of-view optical interferometers

Recently, a technique for calibrating the modulation transfer function (MTF) of a broad variety of metrology instrumentation has been demonstrated. This technique is based on test samples structured as one-dimensional binary pseudo-random (BPR) sequences and two-dimensional BPR arrays (BPRAs). The inherent power spectral density of BPR gratings (sequences) and arrays has a deterministic white-noise-like character that allows direct determination of the MTF with uniform sensitivity over the entire spatial frequency range and field-of-view of an instrument. As such, the BPR samples satisfy the characteristics of a test standard: functionality, ease of specification and fabrication, reproducibility, and low sensitivity to manufacturing error. Here we discuss our recent developments directed to the optimization of the sample design, fabrication, application, and data processing procedures, suitable for thorough characterization of large aperture optical interferometers. Compared with the previous coded-aperture based design, the improved, 'highly randomized' BPRA pattern of the new test standard provides better accuracy and reliability of instrument MTF and aberration characterization, and enables operation optimization of large aperture optical interferometers. We describe the pattern generation algorithm and tests to verify the compliance to desired BPRA topography. The data acquisition and analysis procedures for different applications of the technique are also discussed.

Yashchuk, Valeriy V.↗

Experimental Benchmarking for High-Reproducibility, Cross-Institutional Evaluation of Iron Redox Electrochemistry

We present a practical case study standardizing experimental protocols between collaborators with the goal of understanding ferrous iron (Fe 2+ ) chemistry and improving the iron deposition reaction for energy-efficient, electrochemical iron production. The study of iron reactions can be difficult, as aqueous iron electrolytes exhibit complex behaviors that can lead to differing interpretation of ostensibly similar experiments. The question we want to answer: are we studying the same chemistry? Our protocols address inherent challenges such as the tendency for Fe 2+ to spontaneously oxidize to ferric iron (Fe 3+ ) and the production of hydrogen at the potentials of interest. Our standardized protocol, executed by four collaborators in different labs and institutions, yields high-reproducibility results, and identified glassy carbon electrode surface quality and Fe 3+ impurities in the salt as key factors with outsized effects on cyclic voltammetry measurements. The process of developing the protocols helped to troubleshoot underlying issues that created poorer reversibility and reproducibility. This study highlights the fact that even nominally straightforward electrochemical systems can yield vastly different outcomes due to small differences in experimental preparation and serves as a useful example for creating transparent and achievable standards for the generation of reliable datasets that can be widely used and shared.

Ketter, Benjamin [Argonne National Laboratory (ANL↗

Modified Inverse First Order Reliability Method (I-FORM) for Predicting Extreme Sea States.

Environmental contours describing extreme sea states are generated as the input for numerical or physical model simulation s as a part of the stand ard current practice for designing marine structure s to survive extreme sea states. Such environmental contours are characterized by combinations of significant wave height ( ) and energy period ( ) values calculated for a given recurrence interval using a set of data based on hindcast simulations or buoy observations over a sufficient period of record. The use of the inverse first - order reliability method (IFORM) i s standard design practice for generating environmental contours. In this paper, the traditional appli cation of the IFORM to generating environmental contours representing extreme sea states is described in detail and its merits and drawbacks are assessed. The application of additional methods for analyzing sea state data including the use of principal component analysis (PCA) to create an uncorrelated representation of the data under consideration is proposed. A reexamination of the components of the IFORM application to the problem at hand including the use of new distribution fitting techniques are shown to contribute to the development of more accurate a nd reasonable representations of extreme sea states for use in survivability analysis for marine struc tures. Keywords: In verse FORM, Principal Component Analysis , Environmental Contours, Extreme Sea State Characteri zation, Wave Energy Converters

Eckert-Gallup, Aubrey Celia↗

Measuring the x-ray irradiated degradation of PMMA through FTIR and 2D-COS analysis

To combat issues arising from polymer aging studies which include wasting valuable time and resources, Two-Dimensional Correlation Spectroscopy (2D-COS) has been observed to identify accelerated aging conditions in materials in a very short timeframe. This study is attempting to validate 2D-COS as a viable technique for aging studies by measuring the degradation of PMMA via x-ray radiation. PMMA has been previously observed to degrade via main chain scission under x-ray radiation, and similar results have possibly been seen in this study. More work needs to be done to collect reliable data, including finalizing a standard operating procedure and normalizing raw data so that noise is not recognized as spectral change by the extremely sensitive 2D-COS software.

36 MATERIALS SCIENCE↗

NREL Hydrogen Sensor Testing Laboratory and Smart Hydrogen Wide Area Monitoring

The NREL Hydrogen sensor laboratory aims to ensure that hydrogen sensor technology is available to meet end-user needs and to foster the proper use of sensors by advancing next generation sensing and analysis techniques, supporting codes and standards development, and improving component reliability systems.

08 HYDROGEN↗

PIP-II LLRF Master Oscillator and Precision Reference Line - Station Level Design and Testing

The PIP-II superconducting linac at Fermilab requires a highly stable RF Reference Line to maintain phase syn- chronization throughout the accelerator. Temperature- induced changes in the electrical length of long coaxial cables can introduce phase drift and measurement errors. The reference-line architecture mitigates these effects by phase averaging the forward and reflected RF signals, while a phase-locked loop anchors the system to the mas- ter oscillator. This work focuses on the characterization, validation, and mechanical integration of station-level RF assemblies using CAD modeling, vector network analyzer measurements, and spectrum analyzer testing. PID-controlled thermal plates will stabilize critical RF components and further reduce temperature-dependent phase and amplitude variations. These methods sup- port repeatable, standardized designs that can be reliably integrated across the different reference-line stations.

Mosher, Alexander [U. Illinois, Chicago]↗

Predictive Analytics for Hydropower Fleet Intelligence

A primary challenge in hydropower industry is the ability to maintain cost-competitiveness, reliability, and security of hydropower assets through evolving power system contexts and aging of the fleet. Maintaining cost-effective and reliable operations under these conditions is expected to require new modernization and maintenance paradigms for changing contexts. Changes in existing practices for O&M will require an understanding of the current state and health of hydropower assets, and the impact of changing paradigms on asset health and reliability. The Hydropower Fleet Intelligence project is developing and evaluating standardized methodologies and analysis tools for data-driven asset reliability and management technologies for hydropower, leading to eventual predictive maintenance planning, repair/replacement decision making, and asset-reliability and cost-optimized operations. A key question is the feasibility of using existing data sets at hydropower facilities to perform assessments of asset reliability. This document uses data from hydropower facilities to assess the potential for using available analytics methods for asset reliability estimates. In addition to reliability assessments, the feasibility of using existing analytics techniques for several other potential applications is discussed. Finally, a case study that a data-driven model is trained to learn nominal operations via vibration data from an asset of a certain plant, and then utilized to identify anomalies on a similar asset from a different plant, highlighting the generic use of proposed Prognostics and Health Management (PHM) approaches.

Yucesan, Yigit↗

Improved relay chatter detector

Detector provides go/no-go sensing of momentary relay or contact opening during vibration testing. Device compares duration of unwanted openings to calibrated standard and lights indicator if standard is exceeded. Stability and reliability are higher than in any other comparable device.

Reynolds, R. K.↗

Modularized instrument system for turbojet engine test facilities

A modular instrument system is being developed to handle the many data channels encountered in turbojet engine testing. Each module contains a group of transducers and all the signal conditioning multiplexing, and digitizing electronics necessary for direct interface with a digital computer. The digital interface within each module is the same for all modules; in addition, each module provides a controlled environment for its contents. A minicomputer in the control room gathers the data, performs on-line calculation and display, and interfaces with a shared recording and computing system. The advantages of this system are: (1) reduced manpower for system installation, setup, and checkout; (2) standardized equipment interfaces; (3) increased reliability through automatic system testing and minimization of manual adjustments; and (4) reduced cost through minimization of wiring and simplification of control room display.

Nieberding, W. C.↗

Modularized instrument system for turbojet engine test facilities

A new modular instrument system is being developed to handle the many channels of data commonly encountered in turbojet engine testing. Each module contains a group of transducers and all the signal conditioning, multiplexing, and digitizing electronics necessary for direct interface with a digital computer. The digital interface within each module is the same for all modules. Each module provides a controlled environment for its contents. A minicomputer in the control room gathers the data, performs some on-line calculation and display, and interfaces with a shared recording and computing system. The advantages of this system are (1) reduced manpower for system installation, setup, and checkout; (2) standardized equipment interfaces; (3) increased reliability through automatic system testing and through minimization of manual adjustments; and (4) reduced cost through minimization of wiring and simplification of control room display.

Nieberding, W. C.↗

A class of programmable satellite receivers

The primary purpose of programmable satellite receivers is to provide flexibility in application through digital control of the important functions of the receiver. This permits the acquisition and demodulation of medium to very low data rates in widely varying communications environments and over a wide range of modulation schemes. The first application of the programmable concept is in the high-reliability, low-power NASA Standard Command Detector Unit. A second programmable receiver has been designed and breadboarded for the Jupiter Orbiter Probe or Galileo mission.

Klare, S. W.↗

Space Flight Operations Center local area network

The existing Mission Control and Computer Center at JPL will be replaced by the Space Flight Operations Center (SFOC). One part of the SFOC is the LAN-based distribution system. The purpose of the LAN is to distribute the processed data among the various elements of the SFOC. The SFOC LAN will provide a robust subsystem that will support the Magellan launch configuration and future project adaptation. Its capabilities include (1) a proven cable medium as the backbone for the entire network; (2) hardware components that are reliable, varied, and follow OSI standards; (3) accurate and detailed documentation for fault isolation and future expansion; and (4) proven monitoring and maintenance tools.

Goodman, Ross V.↗

Cesium and Rubidium Frequency Standards Status and Performance on the GPS Program

This paper is an update of the on-orbit operational performance of the frequency standards on the last Block 1 Navstar satellite (GPS-10), the complete Block 2 Navstar satellites (GPS-13 to 21) and the Block 2A Navstar (GPS-22 to 40) satellites. Since the status of the GPS constellation is now at full operational capability (FOC), a minimum of twenty-four satellites are in position with all the necessary tests successfully completed. The evolution of frequency standards on board the GPS vehicles will be presented with corresponding results. Various methods and techniques will be presented to show on-orbit life time, down time, state of health telemetry, on-orbit trending and characterization of all the frequency standards. Other topics such as reliability, stability, clock quirks and idiosyncrasies of each vehicle will be covered.

VanMelle, M. J.↗

Spaceborne Fiber Optic Data Bus (SFODB)

The SFODB is a standardized, gigabit per second, highly reliable, fault tolerant fiber optic network. SFODB was designed to the harsh space environments and real-time, on-board data handling applications of high speed, remote sensing spacecraft.

Bretthauer, Joy W.↗

Laboratory Measurements of the Dielectronic Recombination Satellite Transitions of He-Like FE XXV and H-Like FE XXVI

We present laboratory spectra of dielectronic recombination (DR) satellite transitions attached to the He-like and H-like iron resonance lines obtained with the NASA Goddard Space Flight Center X-ray calorimeter and produced by a thermal plasma simu1ation technique on the EBIT-I electron beam ion trap at the Lawrence Livermore National Laboratory. We demonstrate that the calorimeter has sufficient spectral resolution in the 6-9 keV range to provide reliable measurements not only of standard DR satellite to resonance line intensities but also of DR satellite to DR satellite ratios that can be used to diagnose nonthermal electron distributions. Electron temperatures derived from the measured line intensities are consistent with the temperature of the simulated plasma. Temperature measurements based on DR satellite transitions have significant advantages over those based on collisional ionization equilibrium or continuum shape. Thus, successful demonstration of this method with the X-ray calorimeter is an important step fur its application in X-ray astronomy.

Gu, M. F.↗