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At least 307 records · Page 17

Ship-based Observations and Climate Model Simulations of Cloud Phase over the Southern Ocean

The Southern Ocean (SO) clouds exert a significant influence on the Earth’s radiation budget. Here we analyzed ship-based remote sensing observations of SO clouds over a five-month long DOE ARM Measurements of Aerosols, Radiation and Clouds over the Southern Oceans (MARCUS) field campaign to better understand cloud phase variability. We developed a method to classify eight categories of hydrometeors (ice, liquid, mixed phase, rain, drizzle, snow, aerosols, and clear sky) based on measurements of lidar, radar and radiosondes. Cloud thermodynamic phases (liquid, ice and mixed phase) at coarser scales were further derived to compare with the DOE Energy Exascale Earth System Model version 1 (E3SMv1) simulation and the Earth Model Column Collaboratory (EMC 2 ) instrument simulator. For a scale-aware comparison with climate model simulations, we found that spatially averaging the raw remote sensing data (e.g., backscatter, reflectivity) results in increased cloud cover and cloud liquid, whereas, directly averaging cloud phase from higher to lower resolution maintains clear air regions and is thus recommended for in-cloud frequency comparisons. For cloud thermodynamic phases in stratiform clouds, the E3SM underestimates cloud ice and overestimates cloud liquid at temperatures between -40 and 0°C. When latitudes increase, both observations and simulations show a transition of dominant phase from liquid to ice for cloud tops as well as for the entire cloud columns, but the model underestimation of ice phase is more severe at higher latitudes. Such model bias is unlikely caused by spatial scale differences or lack of heterogeneity in cloud vertical structure in the simulation.

54 ENVIRONMENTAL SCIENCES↗

3D characterisation and quantification of an offshore freshened groundwater system in the Canterbury Bight

Although offshore freshened groundwater (OFG) systems have been documented in numerous continental margins worldwide, their geometry, controls and emplacement dynamics remain poorly constrained. Here we integrate controlled-source electromagnetic, seismic reflection and borehole data with hydrological modelling to quantitatively characterise a previously unknown OFG system near Canterbury, New Zealand. The OFG system consists of one main, and two smaller, low salinity groundwater bodies. The main body extends up to 60 km from the coast and a seawater depth of 110 m. We attribute along-shelf variability in salinity to permeability heterogeneity due to permeable conduits and normal faults, and to recharge from rivers during sea level lowstands. A meteoric origin of the OFG and active groundwater migration from onshore are inferred. However, modelling results suggest that the majority of the OFG was emplaced via topographically-driven flow during sea level lowstands in the last 300 ka. Global volumetric estimates of OFG will be significantly revised if active margins, with steep coastal topographies like the Canterbury margin, are considered.

54 ENVIRONMENTAL SCIENCES↗

Planck 2018 results - IV. Diffuse component separation

We present full-sky maps of the cosmic microwave background (CMB) and polarized synchrotron and thermal dust emission, derived from the third set of Planck frequency maps. These products have significantly lower contamination from instrumental systematic effects than previous versions. The methodologies used to derive these maps follow closely those described in earlier papers, adopting four methods (Commander, NILC, SEVEM, and SMICA) to extract the CMB component, as well as three methods (Commander, GNILC, and SMICA) to extract astrophysical components. Our revised CMB temperature maps agree with corresponding products in the Planck 2015 delivery, whereas the polarization maps exhibit significantly lower large-scale power, reflecting the improved data processing described in companion papers; however, the noise properties of the resulting data products are complicated, and the best available end-to-end simulations exhibit relative biases with respect to the data at the few percent level. Using these maps, we are for the first time able to fit the spectral index of thermal dust independently over 3° regions. We derive a conservative estimate of the mean spectral index of polarized thermal dust emission of β d = 1.55 ± 0.05, where the uncertainty marginalizes both over all known systematic uncertainties and different estimation techniques. For polarized synchrotron emission, we find a mean spectral index of β s = -3.1 ± 0.1, consistent with previously reported measurements. We note that the current data processing does not allow for construction of unbiased single-bolometer maps, and this limits our ability to extract CO emission and correlated components. The foreground results for intensity derived in this paper therefore do not supersede corresponding Planck 2015 products. For polarization the new results supersede the corresponding 2015 products in all respects.

79 ASTRONOMY AND ASTROPHYSICS↗

Spatially-resolved measurements of spin valley polarization in MOCVD-grown monolayer WSe 2

Time-resolved Kerr rotation microscopy is used to generate and measure spin valley polarization in MOCVD-grown monolayer tungsten diselenide (WSe 2 ). The Kerr signal reveals bi-exponential decay with time constants of 100 ps and 3 ns. Measurements are performed on several triangular flakes from the same growth cycle and reveal larger spin valley polarization near the edges of the flakes. This spatial dependence is observed across multiple WSe 2 flakes in the Kerr rotation measurements but not in the spatially resolved reflectivity or microphotoluminescence data. Time-resolved pump-probe overlap measurements further reveal that the Kerr signal’s spatial dependence is not due to spin diffusion on the nanosecond timescale.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A Spatiotemporal-Aware Weighting Scheme for Improving Climate Model Ensemble Predictions

Multimodel ensembling has been widely used to improve climate model predictions, and the improvement strongly depends on the ensembling scheme. In this work, we propose a Bayesian neural network (BNN) ensembling method, which combines climate models within a Bayesian model averaging framework, to improve the predictive capability of model ensembles. Our proposed BNN approach calculates spatiotemporally varying model weights and biases by leveraging individual models' simulation skill, calibrates the ensemble prediction against observations by considering observation data uncertainty, and quantifies epistemic uncertainty when extrapolating to new conditions. More importantly, the BNN method provides interpretability about which climate model contributes more to the ensemble prediction at which locations and times. Thus, beyond its predictive capability, the method also brings insights and understanding of the models to guide further model and data development. In this study, we design experiments using an ensemble of CMIP6 climate model simulations to illustrate the BNN ensembling method's capability with respect to prediction accuracy, interpretability, and uncertainty quantification (UQ). We demonstrate that BNN can correctly assign larger weights to the regions and seasons where the individual model fits the observation better. Moreover, its offered interpretability is consistent with our understanding of localized climate model performance. Additionally, BNN shows an increasing uncertainty when the prediction is farther away from the period with constrained data, which appropriately reflects our trustworthiness of the models in the changing climate.

54 ENVIRONMENTAL SCIENCES↗

Graphite Characterization: Baseline Variability Analysis Report

The Idaho National INL’s Baseline Material Property program provides many measurements of different material properties on a variety of nuclear graphite grades being investigated for irradiation-induced changes in material properties. The baseline material properties provide an unirradiated reference for comparison with measurements of those properties after irradiation. This study describes how uncertainty, or variance, in estimates of important material properties, like compressive strength, may depend on sample size, sample distribution and parameter estimation methods. Compressive strength data from two large collections of specimens from a billet of PCEA graphite (sample size = 230) and a billet of IG-110 graphite (sample size = 48) are used to illustrate these dependencies. The grades of graphite used represent approximate end members in terms of relative variability in strength measurements. Monte Carlo simulation and bootstrapping methods were used to examine variance in Weibull-parameter estimates as a function of sample size. Results were consistent with what previous statistical analyses have shown about the relationship between sample size and width of the confidence interval for maximum likelihood (ML) estimated parameters when samples are repeatedly drawn from a Weibull distribution. As a function of sample size, the precision of the modulus estimate increases faster than that of the characteristic strength. The modulus maximum likelihood estimates (MLEs) are biased for low sample sizes. The American Society for Testing and Materials document ASTM D7846-16 provides equations that describe the dependence of the variance of parameter MLEs on sample size. Using the same methodology, we show that the polynomials provided for variance dependence on sample size are inaccurate for sample sizes greater than ~120. We provide approximations to that relationship that illustrate relative constancy for sample size > ~10, in the logspace relationship of the modulus variance and the log transformed characteristic strength variance. Bootstrapping provided a means of comparing Weibull parameters obtained using ASME’s guidance for specimen collection to those obtained using different weighting in a case where strength is related to position in a billet and to grain orientation and a single distribution is used to characterize the billet. ASME specifies that samples be collected with equal representation in all locations and grain orientations. Parameter values obtained using ASME’s method were different from those obtained using random sampling of the complete data sets, and this was particularly true for the PCEA data. In addition, while the ASME approach yielded more conservative parameters for the PCEA data, the opposite was true for the IG-110 data. The difference observed for the PCEA data set likely reflects the larger number of against-grain specimens collected, which had generally higher strength than the with-grain specimens. This emphasizes the importance of the dependence of strength on location or grain orientation and suggests that it may be prudent to weight specimen collection toward the weaker subgroups if a conservative estimate as desired, as the equal weighting method recommended by ASME would will not always provide the most conservative Weibull parameters. Because spatial correlations commonly exist in certain grades of graphite, future work may involve developing a methodology for parameter inference that relaxes the assumption of independent specimens. ASTM and ASME codes recommend different parameter estimation methods and models of the Weibull distribution in different situations. Descriptions of the effects on parameter estimates for the example billets used in this study provide an example of how the method may affect the parameter estimate, and how—in this case—that compares to differences due to other factors, such as sample size and dependence on grain orientation or sample location.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Gamma Spectrometry Examination of the AGR-3/4 Irradiation

The results from gamma spectrometry examination of the different components from the combined third and fourth U.S. Advanced Gas Reactor (AGR) TRISO-coated particle fuel irradiation tests (AGR-3/4) have been analyzed. This experiment was designed to provide information about in-pile fission product migration. In each of the 12 capsules, a single stack of four compacts with designed-to-fail (DTF) particles surrounded by inner and outer graphite and/or graphitic matrix rings and a graphite sink ring were irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). Gamma spectrometry has been used to evaluate the gamma-emitting fission product inventory of compacts from the irradiation and evaluate the burnup of these compacts based on the activity of the radioactive cesium isotopes (i.e., Cs-134 and Cs-137) in the compacts. Burnup from gamma spectrometry compares well with predicted burnup from simulations. The inner and outer rings were also examined by gamma spectrometry to evaluate the total fission product inventory of the rings, and gamma emission computed tomography (GECT) was used to investigate the spatial distribution of gamma-emitting fission products within the rings. This report focuses on results obtained via the Precision Gamma Scanner (PGS) for the compacts and inner and outer rings. These non-destructive gamma measurements are currently being compared to recent destructive measurements of spatial fission product distributions in the rings and to predictions made via mathematical modeling. A separate report discusses the entire AGR-3/4 fission product mass balance for all irradiation capsule components including the inner and outer rings, graphite sink rings, capsule spacers, capsule foils, through tubes, and felts. This report is similar to the conference proceedings: Harp, J.M., Demkowicz, P.A., and Stempien, J.D., “Initial gamma spectrometry examination of the AGR-3/4 irradiation,” International Topical Meeting High Temperature Reactor Technology (HTR 2016), Las Vegas, NV, USA, November 2016, Paper HTR2016-18593, but it has been updated to reflect all the data that has been collected on AGR-3/4 using PGS. The Appendices contain extensive data from the collected gamma spectra.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Acoustic Impedance Inversions for Offshore CO 2 Storage: South Georgia Embayment, United States

This study builds and expands on previous CO 2 storage resource assessment studies of the southeastern offshore Atlantic margin by providing a detailed evaluation on how rock porosities and permeabilities are distributed across the Upper Cretaceous strata restricted to the South Georgia Embayment (SGE). Using legacy industry two-dimensional seismic reflection and well data, this assessment is the first application of multiple seismic inversion techniques in this area. This workflow provides a reliable and repeatable model-based inversion which gives an improved image to discriminate lithology and predict porosity. The workflow is applicable to future CO 2 storage resource assessment studies elsewhere. The inversion results indicate that distinct porosity and permeability regimes are present and distributed in the Upper Cretaceous strata within the SGE. The impedance and porosity relationships show well-founded and reliable correlation. These relationships reveal low impedance coincident to the high porosity intervals which are proposed as potential reservoir intervals for CO 2 storage. In addition, the result shows that the Upper Cretaceous strata have two main potential reservoirs in the lower part. These are overlain by a thick impermeable interval, mostly shale, which has high impedance, low porosity, and low permeability and extends within the SGE. This result is in agreement with a previous study that also proposed two significant storage reservoirs for CO 2 in the Upper Cretaceous strata. Since porosity distribution is estimated using multiple methods, it follows the trends of seismic signature and structures of the Upper Cretaceous strata. The extracted values of porosity, ranging from 15 to 36%, and permeability, ranging from 1 to 100 mD, are close to the measured values from the well core data at the Upper Cretaceous strata interval.

54 ENVIRONMENTAL SCIENCES↗

Advancing Industry 4.0: Multimodal Sensor Fusion for AI-Based Fault Detection in 3D Printing

Additive manufacturing, particularly fused deposition modeling, is transforming modern production by enabling rapid prototyping and complex part fabrication. However, its layer-by-layer process remains vulnerable to faults such as nozzle clogging, filament runout, and layer misalignment, which compromise print quality and reliability. Traditional inspection methods are costly, time-intensive, and often limited to post-process analysis, making them unsuitable for real-time intervention. In this current study, the authors developed a novel, low-cost, and portable faultdetection system that leverages multimodal sensor fusion and artificial intelligence for real-time monitoring in FDM-based 3D printing. The system integrates acoustic, vibration, and thermal sensing into a non-intrusive architecture, capturing complementary data streams that reflect both mechanical and process-related anomalies. Acoustic and thermal sensors operate in a fully contactless manner, while the vibration sensor requires minimal attachment such that it will not interfere with printer hardware, thereby preserving portability and ease of deployment. The multimodal signals are processed into spectrograms and time-frequency features, which are classified using convolutional neural networks for intelligent fault detection. The proposed system advances Industry 4.0 objectives by offering an affordable, scalable, and practical monitoring solution that improves faultdetection accuracy, reduces waste, and supports sustainable, adaptive manufacturing.

42 ENGINEERING↗

Tropical continental downdraft characteristics: mesoscale systems versus unorganized convection

Downdrafts and cold pool characteristics for strong mesoscale convective systems (MCSs) and isolated, unorganized deep precipitating convection are analyzed using multi-instrument data from the DOE Atmospheric Radiation Measurement (ARM) GoAmazon2014/5 campaign. Increases in column water vapor (CWV) are observed leading convection, with higher CWV preceding MCSs than for isolated cells. For both MCSs and isolated cells, increases in wind speed, decreases in surface moisture and temperature, and increases in relative humidity occur coincidentally with system passages. Composites of vertical velocity data and radar reflectivity from a radar wind profiler show that the downdrafts associated with the sharpest decreases in surface equivalent potential temperature ( θ e ) have a probability of occurrence that increases with decreasing height below the freezing level. Both MCSs and unorganized convection show similar mean downdraft magnitudes and probabilities with height. Mixing computations suggest that, on average, air originating at heights greater than 3 km must undergo substantial mixing, particularly in the case of isolated cells, to match the observed cold pool θ e , implying a low typical origin level. Precipitation conditionally averaged on decreases in surface equivalent potential temperature (Δ θ e ) exhibits a strong relationship because the most negative Δ θ e values are associated with a high probability of precipitation. The more physically motivated conditional average of Δ θ e on precipitation shows that decreases in θ e level off with increasing precipitation rate, bounded by the maximum difference between surface θ e and its minimum in the profile aloft. In conclusion, robustness of these statistics observed across scales and regions suggests their potential use as model diagnostic tools for the improvement of downdraft parameterizations in climate models.

54 ENVIRONMENTAL SCIENCES↗

Coherent order parameter dynamics in SmTe 3

We present a combined ultrafast optical pump-probe and ultrafast x-ray diffraction measurement of the CDW dynamics in SmTe$_3$ at 300 K. The ultrafast x-ray diffraction measurements, taken at the Linac Coherent Light Source reveal a $\sim 1.55$ THz mode that becomes overdamped with increasing fluence. We identify this oscillation with the lattice component of the amplitude mode. Furthermore, these data allow for a more clear identification of the frequencies present in the optical pump-probe data. In both, reflectivity and diffraction, we observe a crossover of the response from linear (for small displacements) to quadratic in the amplitude of the order parameter displacement. Finally, a time-dependent Ginzburg-Landau model captures the essential features of the experimental observations.

Trigo, Mariano↗

Gamma Spectrometry Examination of the AGR-3/4 Irradiation

The results from gamma spectrometry examination of the different components from the combined third and fourth U.S. Advanced Gas Reactor (AGR) TRISO-coated particle fuel irradiation tests (AGR-3/4) have been analyzed. This experiment was designed to provide information about in-pile fission product migration. In each of the 12 capsules, a single stack of four compacts with designed-to-fail (DTF) particles surrounded by inner and outer graphite and/or graphitic matrix rings and a graphite sink ring were irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). Gamma spectrometry has been used to evaluate the gamma-emitting fission product inventory of compacts from the irradiation and evaluate the burnup of these compacts based on the activity of the radioactive cesium isotopes (i.e., Cs-134 and Cs-137) in the compacts. Burnup from gamma spectrometry compares well with predicted burnup from simulations. The inner and outer rings were also examined by gamma spectrometry to evaluate the total fission product inventory of the rings, and gamma emission computed tomography (GECT) was used to investigate the spatial distribution of gamma-emitting fission products within the rings. This report focuses on results obtained via the Precision Gamma Scanner (PGS) for the compacts and inner and outer rings. These non-destructive gamma measurements are currently being compared to recent destructive measurements of spatial fission product distributions in the rings and to predictions made via mathematical modeling. A separate report discusses the entire AGR-3/4 fission product mass balance for all irradiation capsule components including the inner and outer rings, graphite sink rings, capsule spacers, capsule foils, through tubes, and felts. This report is similar to the conference proceedings: Harp, J.M., Demkowicz, P.A., and Stempien, J.D., “Initial gamma spectrometry examination of the AGR-3/4 irradiation,” International Topical Meeting High Temperature Reactor Technology (HTR 2016), Las Vegas, NV, USA, November 2016, Paper HTR2016-18593, but it has been updated to reflect all the data that has been collected on AGR-3/4 using PGS. The Appendices contain extensive data from the collected gamma spectra.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Specific Recognition of Arginine Methylated Histone Tails by JMJD5 and JMJD7

We have reported that JMJD5 and JMJD7 (JMJD5/7) are responsible for the clipping of arginine methylated histone tails to generate "tailless nucleosomes", which could release the pausing RNA polymerase II (Pol II) into productive transcription elongation. JMJD5/7 function as endopeptidases that cleave histone tails specifically adjacent to methylated arginine residues and continue to degrade N-terminal residues of histones via their aminopeptidase activity. Here, we report structural and biochemical studies on JMJD5/7 to understand the basis of substrate recognition and catalysis mechanism by this JmjC subfamily. Recognition between these enzymes and histone substrates is specific, which is reflected by the binding data between enzymes and substrates. High structural similarity between JMJD5 and JMJD7 is reflected by the shared common substrates and high binding affinity. However, JMJD5 does not bind to arginine methylated histone tails with additional lysine acetylation while JMJD7 does not bind to arginine methylated histone tails with additional lysine methylation. Furthermore, the complex structures of JMJD5 and arginine derivatives revealed a Tudor domain-like binding pocket to accommodate the methylated sidechain of arginine, but not lysine. There also exists a glutamine close to the catalytic center, which may suggest a unique imidic acid mediated catalytic mechanism for proteolysis by JMJD5/7.

59 BASIC BIOLOGICAL SCIENCES↗

ENDF/B-VIII.0 Augmented Covariance Data The first iteration [Slides]

Nuclear data are necessary for reliable modeling and simulation of the next generation of nuclear reactors. However, the variation in the ratio of the computed to experimental values (C/E) for certain types of nuclear systems is much less than predicted by evaluated nuclear data file (ENDF)/B covariances. Figure 1 provides an example of a set of metal-plutonium-fueled, fast-spectrum (PU-MET-FAST) integral experiments from the International Criticality Safety Benchmark Evaluation Project (ICSBEP) in the Oak Ridge National Laboratory (ORNL) VALID database. The variation in the C/E values, shown with one standard deviation error bars, is 100% covered by both the SCALE and ENDB/VIII.0 covariance data. This is due to the comparisons to integral data that are essential during the evaluation process. However, the ENDF evaluations represent uncertainties and correlations in differential data only; they do not reflect the impact of the comparison to integral data in the covariance evaluations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

ENDF/B-VIII.0 Augmented Covariance Data The first iteration [Slides]

Nuclear data are necessary for reliable modeling and simulation of the next generation of nuclear reactors. However, the variation in the ratio of the computed to experimental values (C/E) for certain types of nuclear systems is much less than predicted by evaluated nuclear data file (ENDF)/B covariances. Figure 1 provides an example of a set of metal-plutonium-fueled, fast-spectrum (PU-MET-FAST) integral experiments from the International Criticality Safety Benchmark Evaluation Project (ICSBEP) in the Oak Ridge National Laboratory (ORNL) VALID database. The variation in the C/E values, shown with one standard deviation error bars, is 100% covered by both the SCALE and ENDB/VIII.0 covariance data. This is due to the comparisons to integral data that are essential during the evaluation process. However, the ENDF evaluations represent uncertainties and correlations in differential data only; they do not reflect the impact of the comparison to integral data in the covariance evaluations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

ENDF/B-VIII.0 Augmented Covariance Data: The first iteration

Nuclear data are necessary for reliable modeling and simulation of the next generation of nuclear reactors. However, the variation in the ratio of the computed to experimental values (C/E) for certain types of nuclear systems is much less than predicted by evaluated nuclear data file (ENDF)/B covariances. Figure 1 provides an example of a set of metal-plutonium-fueled, fast-spectrum (PU-MET-FAST) integral experiments from the International Criticality Safety Benchmark Evaluation Project (ICSBEP) in the Oak Ridge National Laboratory (ORNL) VALID database. The variation in the C/E values, shown with one standard deviation error bars, is 100% covered by both the SCALE and ENDB/VIII.0 covariance data. This is due to the comparisons to integral data that are essential during the evaluation process. However, the ENDF evaluations represent uncertainties and correlations in differential data only; they do not reflect the impact of the comparison to integral data in the covariance evaluations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A New Approach to Predict Hydrogeological Parameters Using Shear Waves from the Multichannel Analysis of Surface Waves Method

For near-surface contaminant characterization, the accurate prediction of hydrogeological parameters in anisotropic and heterogeneous environments has been a challenge since the last decades. However, recent advances in near-surface geophysics have facilitated the use of geophysical data for hydrogeological characterization in the last few years. A pseudo 3-D high resolution P-wave shallow seismic reflection survey was performed at the P Reactor Area, Savannah River Site, South Carolina in order to delineate and predict migration pathways of a large contaminant plume including trichloroethylene. This contaminant plume originates from the northwest section of the reactor facility that is located within the Upper Atlantic Coastal Plain. The data were collected with 40 Hz geophones, an accelerated weight-drop as seismic source and 1 m receiver spacing with near- and far-offsets of 0.5 and 119.5 m, respectively. In such areas with near-surface contaminants, a detailed subsurface characterization of the vadose zone hydraulic parameters is very important. Indeed, an inexpensive method of deriving such parameters by the use of seismic reflection surveys is beneficial, and our approach uses the relationship between seismic velocity and hydrogeological parameters together with empirical observations relating porosity to permeability and hydraulic conductivity. Shear wave velocity ( V s ) profiles were estimated from surface wave dispersion analysis of the seismic reflection data and were subsequently used to derive hydraulic parameters such as porosity, permeability, and hydraulic conductivity. Additional geophysical data including core samples, vertical seismic profiling, surface electrical resistivity tomography, natural gamma and electrical resistivity logs allowed for a robust assessment of the validity and geological significance of the estimated V s and hydrogeological models. The results demonstrate the usefulness of this approach for the upper 15 m of shallow unconsolidated sediments even though the survey design parameters were not optimal for surface wave analysis due to the higher than desired frequency geophones.

Engineering↗