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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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A proximity-focusing RICH detector for the ePIC Experiment at the EIC
The Electron-Proton/Ion Collider Experiment (ePIC) will be a large, multi-purpose detector to be installed at the Electron-Ion Collider (EIC) being built at Brookhaven National Laboratory. As robust particle identification (PID) capabilities are essential for fully realizing the EIC science program, ePIC contains several PID subsystems spanning different angular ranges. PID capability in the electron-going endcap is provided by a proximity-focusing Ring Imaging Cherenkov detector (pfRICH) designed to deliver at least 3σ separation between pions and kaons for momenta up to 7 GeV/ c . It will also aid with electron-hadron discrimination at low momentum and assist in the determination of the collision time (t 0 ). This contribution will summarize the design of the pfRICH as well as ongoing fabrication and component testing efforts. geant-based performance simulations will also be discussed.
Incorporation of protons and hydroxide species in BaZrO 3 and BaCeO 3
We calculate the energetics of protonation in proton-conducting oxides, as well as defect concentrations and mobility under electrolysis conditions.
Future accelerator projects: new physics at the energy frontier
High-energy colliders provide direct access to the energy frontier, allowing to search for new physics at scales as high as the machine’s center-of-mass energy, perform precision measurements of the Standard Model (SM) parameters, including those related to the flavor sector, and determine the Higgs boson properties and their connection to electroweak symmetry breaking. Each proposed future collider option has its own specific science goals and capabilities, depending on the designed running energy (energies) amongst other parameters. In this paper, an overview of the discovery potential of future circular and linear colliders is presented. Results from searches for beyond the Standard Model (BSM) phenomena at proton–proton, proton–electron, electron–positron, and muon–antimuon colliders are summarized.
In Situ Conversion of Artificial Proton‐Rich Shell to Inorganic Maskant Toward Stable Single‐Crystal Ni‐Rich Cathode
Single-crystal high-nickel oxide with an integral structure can prevent intergranular cracks and the associated detrimental reactions. Yet, its low surface-to-volume ratio makes surficial degradation a more critical factor in electrochemical performance. Herein, artificial proton-rich (ammonium bicarbonate) shell is successfully introduced on the nickel-rich LiNi 0.92 Co 0.06 Mn 0.02 O 2 single crystals for in situ electrochemically conversing into inorganic maskant to enhance stability of cathode. The process is that the surficial enriched proton, once released from the ammonium bicarbonate shell (proton reservoir) during 1st charge, is immediately captured by LiPF 6 , in situ electrochemically conversing to LiF and Li 3 PO 4 sub-nano particle dense maskant (sub-nano F-&P-maskant). The in situ formed compact nano F-&P-maskant significantly resists the cathode against electrolyte attack and improves the surface stability of particles during long-term cycling. Consequently, this surface modification enables 95% capacity retention after 100 cycles at a high voltage of 4.5 V in the half cell and 83% capacity retention after 800 cycles in the full cell. In conclusion, this work demonstrates a strategy for reconstructing the protective layer using the rational design of surficial enriched proton shells for advanced lithium batteries.
Differential cross section measurements of the 6.13 MeV gamma ray from proton-induced reaction of fluorine
Not provided.
Channelrhodopsin C1C2: Photocycle kinetics and interactions near the central gate
Channelrhodopsins (ChR) are light-sensitive cation channels used in optogenetics, a technique that applies light to control cells (e.g., neurons) that have been modified genetically to express those channels. Although mutations are known to affect pore kinetics, little is known about how mutations induce changes at the molecular scale. To address this issue, we first measured channel opening and closing rates of a ChR chimera (C1C2) and selected variants (N297D, N297V, and V125L). Then, we used atomistic simulations to correlate those rates with changes in pore structure, hydration, and chemical interactions among key gating residues of C1C2 in both closed and open states. Overall, the experimental results show that C1C2 and its mutants do not behave like ChR2 or its analogous variants, except V125L, making C1C2 a unique channel. Furthermore, our atomistic simulations confirmed that opening of the channel and initial hydration of the gating regions between helices I, II, III, and VII of the channel occurs with 1) the presence of 13-cis retinal; 2) deprotonation of a glutamic acid gating residue, E129; and 3) subsequent weakening of the central gate hydrogen bond between the same glutamic acid E129 and asparagine N297 in the central region of the pore. Also, an aspartate (D292) is the unambiguous primary proton acceptor for the retinal Schiff base in the hydrated channel.
Does Confinement Mediate Cerium Exchange and Its Impact on Ionomer Properties?
Thin-film ionomers, pivotal in the function of fuel-cell catalyst layers (CLs), are undercharacterized compared to their bulk membrane counterparts, especially with respect to cation effects. Cerium cations, used as an additive in fuel-cell membranes, tend to migrate from the membrane into the CL ionomer during operation. Further, this study investigates whether cerium doping of perfluorinated sulfonic acid ionomer changes under confinement (to a nanometer thin film) and affects the hydration behavior. Confinement has a negligible effect on the ionomer’s cerium partitioning, yet it reduces the ionomer water uptake. Thus, cerium replaces protons similarly in a membrane or CL ionomer; however, its presence affects the thermodynamics of hydration differently.
Pile-up mitigation using attention
Abstract Particle production from secondary proton-proton collisions, commonly referred to as pile-up, impair the sensitivity of both new physics searches and precision measurements at large hadron collider (LHC) experiments. We propose a novel algorithm, Puma , for modeling pile-up with the help of deep neural networks based on sparse transformers. These attention mechanisms were developed for natural language processing but have become popular in other applications. In a realistic detector simulation, our method outperforms classical benchmark algorithms for pile-up mitigation in key observables. It provides a perspective for mitigating the effects of pile-up in the high luminosity era of the LHC, where up to 200 proton-proton collisions are expected to occur simultaneously.
The Impact of Reconstruction in Pandora on Sensitivity to the Low-Energy Excess Signal at MicroBooNE
With the MicroBooNE collaboration’s first low-energy excess (LEE) searches complete and twice the amount of data to analyse in future iterations, it is imperative that we begin considering the potential analysis upgrades that can be achieved, such as those in the event reconstruction level. This note identifies the areas in Pandora reconstruction framework that could be improved upon, and evaluates their impact through cheated selections using MicroBooNE’s exclusive pionless LEE search as a benchmark. Vertexing and proton reconstruction improvements are demonstrated to have significant potential benefits in terms of sensitivity to the LEE signal and thus should be prioritised. Sensitivity projections for the full 10.1e20 POT are 3.2σ and 2.3σ for vertex and proton cheated selections respectively, and 3.3σ for the combined effect of both, compared to 2.1σ in the absence of the cheated selections.
Preliminary Introduction of the IOTA Bake System
The Integrable Optics Test Accelerator (IOTA) ring is vital to the advancement of accelerator sciences, and a large part of its attractiveness to accelerator physicists is its modularity and the versatility that this function provides. Up until this point, the FAST accelerator has provided electron beam for the studies in IOTA. With the soon to be commissioned IOTA Proton Injector in lieu, the requirement for better vacuum to support future proton studies in the ring have arrived. Our solution is the IOTA Bake System which has the goal of facilitating this requirement.
Radiation Hardening – Test Capabilities (LANSCE) [Slides]
The Los Alamos Neutron Science Center (LANSCE) has exceptional facilities for research and testing of radiation effects in electronics. We have the best terrestrial neutron source for sea-level and airplane-altitude environments. We have a thermal neutron test capability at the Lujan Center and a proton beam test capability at the “Blue Room”. LANL has the programmatic mission to develop this radiation-effects program, namely space and satellite environments, high-performance computing (silent data corruption), and weapons delivery systems. We have a strong connection to industry which continues to grow.
IOTA Bake System
The IOTA ring is vital to the advancement of accelerator sciences, and a large part of its attractiveness to accelerator physicists is its modularity and the versatility that this function provides. Up until this point, the FAST accelerator has provided electron beam for the studies in IOTA. With the soon to be commissioned IOTA Proton Injector in lieu, the requirement for better vacuum to support future proton studies in the ring have arrived. Our solution is the IOTA Bake System which has the goal of facilitating this requirement.
Abrupt structural transition in exotic molybdenum isotopes unveils an isospin-symmetric island of inversion
Like electrons in atoms, protons and neutrons in nuclei occupy orbitals in a shell structure with energy gaps at magic numbers. Radioactive-beam experiments revealed the disappearance of magic numbers in some neutron-rich isotopes. In these nuclei, configurations involving particles excited across the shell gap gain correlation energy, becoming the ground state. Neutron-rich regions of the nuclear chart that exhibit this property are known as “Islands of Inversion”. Here we present the lifetime measurement of the first 2 + states in 84 Mo (N = Z) and 86 Mo (N = Z + 2) revealing an unexpected sharp structural change between them defining the edge of the region of deformation around 80 Zr. Similarly to the neutron-rich N = 40 Island of Inversion near 64 Cr where cross-shell excitations dominate, we identify this region as an Island of Inversion with symmetrical proton and neutron excitations that we term “Isospin-Symmetric Island of Inversion”. Three-nucleon forces are suggested to drive Mo isotope structural changes.
Structural chemistry of penta- and hexanitrato thorium($\tiny{IV}$) complexes isolated using N–H donors
In this study, a series of fifteen tetravalent thorium phases were prepared. The compounds were isolated from acidic aqueous nitrate solutions using protonated nitrogen heterocycles of varying hydrogen-bond donation strength. Structural analysis via single crystal X-ray diffraction showed that the structures are built from pentanitrato, [Th(NO 3 ) 5 (H 2 O) 2 ] 1- , and hexanitrato, [Th(NO 3 ) 6 ] 2- , molecular units, with the latter being far more prevalent in the solid state. The vibrational properties of the compounds were examined using Raman and IR spectroscopy; the spectra are dominated by stretches characteristic of nitrate and the organic ions. The relative energetics of nitrate complexation was examined using electronic structure theory. These results confirmed that there are clear thermodynamic sinks for the penta- and hexanitrato structural units that were observed experimentally. Additionally, electrostatic surface potentials (ESPs) were calculated in an effort to better understand the counterion stabilization of the complexes. The ESP surfaces showed that the position of the water and nitrate molecules and the coordination geometry of the metal complex had a clear effect on the polarizability of the two structural motifs. Despite limited speciation of the Th–nitrate structural units, the compounds exhibit rich supramolecular chemistry resulting from hydrogen bonding of the Th complexes with the organic N–H donors and π–π stacking interactions from the protonated N-heterocycles.
Controlling product selectivity in hybrid gas/liquid reactors using gas conditions, voltage, and temperature
For the conversion of CO 2 into fuels and chemical feedstocks, hybrid gas/liquid-fed electrochemical flow reactors provide advantages in selectivity and production rates over traditional liquid phase reactors. However, fundamental questions remain about how to optimize conditions to produce desired products. Here, using an alkaline electrolyte to suppress hydrogen formation and a gas diffusion electrode catalyst composed of copper nanoparticles on carbon nanospikes, we investigate how hydrocarbon product selectivity in the CO 2 reduction reaction in hybrid reactors depends on three experimentally controllable parameters: (1) supply of dry or humidified CO 2 gas, (2) applied potential, and (3) electrolyte temperature. Changing from dry to humidified CO 2 dramatically alters product selectivity from C 2 products ethanol and acetic acid to ethylene and C 1 products formic acid and methane. Water vapor evidently influences product selectivity of reactions that occur on the gas-facing side of the catalyst by adding a source of protons that alters reaction pathways and intermediates.