An alternative separation procedure for 90 Sr age dating using DGA Resin
The likelihood of an attack by a terrorist organization using a radiological dispersal device (RDD) is much higher than that of an attack with an improvised nuclear device or true nuclear weapon, as much less technical expertise is required to build an RDD. Consequently, there has been an effort to develop methods for age-dating radiological sealed sources in recent years. One such procedure, described by Steeb et al., is used for determining the age of 90 Sr sources. That procedure utilized a rather expensive extraction chromatography resin and was based on an uncommon apparatus with limited sample capacity for the separation step. The procedure also left the Zr fraction contaminated with the radioactive 90 Y daughter nuclide. This work investigates using an alternative separation scheme that utilizes a less costly resin in a widely available column configuration and results in the isolation of 90 Sr's stable granddaughter, 90 Zr, without 90 Y contamination. This allows the zirconium quantification to be done with a mass spectrometer outside the radiological environment and increases the number of instruments capable of making the measurement, which could allow measurements to be made more quickly.