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At least 307 records · Page 17

The WISE Satellite Development: Managing the Risks and the Opportunities

NASA's Wide-field Infrared Survey Explorer (WISE) MIDEX mission is surveying the entire sky in four infrared bands from 3.4 to 22 micrometers. The WISE instrument consists of a 40 cm telescope, a solid hydrogen cryostat, a scan mirror mechanism, and four 1K x1K infrared detectors. The WISE spacecraft bus provides communication, data handling, and avionics including instrument pointing. A Delta 7920 successfully launched WISE into a Sun-synchronous polar orbit on December 14, 2009. WISE was competitively selected by NASA as a Medium cost Explorer mission (MIDEX) in 2002. MIDEX missions are led by the Principal Investigator who delegates day-to-day management to the Project Manager. Given the tight cost cap and relatively short development schedule, NASA chose to extend the development period one year with an option to cancel the mission if certain criteria were not met. To meet this and other challenges, the WISE management team had to learn to work seamlessly across institutional lines and to recognize risks and opportunities in order to develop the flight hardware within the project resources. In spite of significant technical issues, the WISE satellite was delivered on budget and on schedule. This paper describes our management approach and risk posture, technical issues, and critical decisions made.

Risk Management↗

Mode properties of low-frequency waves: Kinetic theory versus Hall-MHD

In fluid theory, the ordering of low-frequency modes in a homogeneous plasma is based on the phase velocity, since modes do not intersect each other in dispersion diagrams as a function of wavenumber or other parameters. In linear kinetic theory, modes cross each other. Thus a consistent and useful classification should be based on the physical properties of the modes instead. This paper attempts such a classification by documeting the dispersion and general mode properties of the low-frequency waves (omega much less than (OMEGA(sub ci) OMEGA(sub ce) (exp 1/2)), where OMEGA(sub ci), OMEGA(sub ce) are the cyclotron frequencies of the ions and electrons, respectively) in kinetic theory, and by comparing them to the results of two-fluid theory. Kinetic theory gives a seperate Alfven/ion-cyclotron (A/IC) wave with phase speed Omega/k approximately = v(sub A) cos theta for omega much less than OMEGA(sub ci), where v(sub A) is the Alfven velocity and theta the angle of propagation between wave vector k and background magnetic field B(sub o). For a given wavenumber, the magnetosonic mode is a double-valued solution with a singular point in theta, beta parameter space, where beta is the ratio of thermal pressure to magnetic pressure. It is shown that a branch cut starting at the singular point theta approximately 30 deg, beta approximately 3 and leading to larger beta gives a practical and consitent seperation of this double-valued magnetosonic solution. Selection of this branch cut results in a moderately damped fast/magnetos onic and a heavily damped slow/sound wave. A comprehensive review of the polarization, compressibility and other mode properties is given and shown to be consistent with the selected branch cut. At small wavenumbers, the kinetic mode properties typically start to deviate significantly from their fluid counterparts at beta approximately 0.5. At larger beta, there is no longer a consistent correspondence between the fluid and kinetic modes. Kinetic theory also dictates the use of different mode properties to distinguish between them in observational data. For example, the phase between the density and magnetic field perturbation may become useless at high beta, whereas the direction of the magnetic field perturbations with respect to k and B(sub o) remains a useful characteristic. Two quantities based on this characteristic are suggested and are shown to be useful also to distinguish between the mirror mode and A/IC waves in a plasma with temperature anisotropy.

Krauss-Varban, D.↗

Entangled spin-polarized excitons from singlet fission in a rigid dimer

Abstract Singlet fission, a process that splits a singlet exciton into a biexciton, has promise in quantum information. We report time-resolved electron paramagnetic resonance measurements on a conformationally well-defined acene dimer molecule, TIPS-BP1', designed to exhibit strongly state-selective relaxation to specific magnetic spin sublevels. The resulting optically pumped spin polarization is a nearly pure initial state from the ensemble. The long-lived spin coherences modulate the signal intrinsically, allowing a measurement scheme that substantially removes noise and uncertainty in the magnetic resonance spectra. A nonadiabatic transition theory with a minimal number of spectroscopic parameters allows the quantitative assignment and interpretation of the spectra. In this work, we show that the rigid dimer TIPS-BP1' supports persistent spin coherences at temperatures far higher than those used in conventional superconducting quantum hardware.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Polarimeter for Low Energy X-ray Astrophysical Sources (PLEXAS)

The Polarimeter for Low Energy X-ray Astrophysical Sources (PLEXAS) is an astrophysics mission concept for measuring the polarization of X-ray sources at low energies below the C-K band (less than 277 eV). PLEXAS uses the concept of variations in the reflectivity of a multilayered X-ray telescope as a function of the orientation of an X-rays polarization vector with respect to the reflecting surface of the optic. By selecting an appropriate multilayer, and rotating the X-ray telescope while pointing to a source, there will be a modulation in the source intensity, as measured at the focus of the telescope, which is proportional to the degree of polarization in the source.

Murray, Stephen S.↗

Engineered selective biotoxin‐binding hydrogels for toxin sequestration

The development of synthetic selective membranes that separate materials of similar sizes, charges, and/or polarities remains a difficult challenge, and looking towards biology provides inspiration for new designs. In this work, a series of cholera toxin binding peptides (CTBPs) are identified, spanning a range of binding inhibitions, and integrated into chemically cross-linked cholera toxin binding gels (CTBGs) via thiol-Michael polycondensation reactions. All gels demonstrate rheological profiles consistent with elastic solids. The CTBGs are probed via small-angle neutron scattering and exhibit a correlation length, ξ, smaller than most proteins (1.3–2.5 nm). Thus, an effective entropic mesh is formed to block non-targeted proteins. However, the CTBGs have a dynamic mesh size, Ξ, that is larger than cholera toxin (CT) to allow the transport of target proteins. The CTBGs with the highest binding inhibitions both show high selectivity and permeation of CT, rejecting all other tested proteins. In total, two new highly selective CTBGs are synthesized and validated for use in cholera toxin remediation. Together, this platform demonstrates the wide applicability of selectively-diffusive materials for difficult separations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Alkali-induced catalytic tuning at metal and metal oxide interfaces

Alkali metals have been recognized as effective promoters in heterogeneous catalysis, capable of enhancing catalytic activity and tuning product distributions. Over the past few decades, significant efforts have been made aiming to reveal the mechanisms underlying the promoting effect of alkalis. However, the roles that alkali metals play in the catalytic process remain elusive due to challenges in capturing their catalytic behaviours upon exposure to reactive environments. This review summarizes recent surface science and theoretical studies of alkali (potassium, cesium)-decorated metal and metal oxide model catalysts, revealing the crucial tuning by alkalis of activity and selectivity for CO 2 hydrogenation. The analysis of electronic structures identifies the selective binding mechanism of the positively charged alkali ions on the surface, being able to reduce the surface work function and lead to strong electron polarization on the surfaces. Depending on the alkali–support interaction, the deposition of alkalis can selectively modify the bindings of reaction intermediates involved in CO 2 hydrogenation via the interplay among the ionic, covalent and electrostatic tunings. As a result, CO 2 can be effectively activated and converted into diverse products at the alkali–support interface, ranging from formic acid to methanol and ethanol. The identified selective bond-tuning advances the application of alkalis in promoting catalytic activity and controlling catalytic selectivity at alkali–support interfaces.

03 NATURAL GAS↗

Optimal selection of space transportation fleet to meet multi-mission space program needs

A space program that spans several decades will be comprised of a collection of missions such as low earth orbital space station, a polar platform, geosynchronous space station, lunar base, Mars astronaut mission, and Mars base. The optimal selection of a fleet of several recoverable and expendable launch vehicles, upper stages, and interplanetary spacecraft necessary to logistically establish and support these space missions can be examined by means of a linear integer programming optimization model. Such a selection must be made because the economies of scale which comes from producing large quantities of a few standard vehicle types, rather than many, will be needed to provide learning curve effects to reduce the overall cost of space transportation if these future missions are to be affordable. Optimization model inputs come from data and from vehicle designs. Each launch vehicle currently in existence has a launch history, giving rise to statistical estimates of launch reliability. For future, not-yet-developed launch vehicles, theoretical reliabilities corresponding to the maturity of the launch vehicles' technology and the degree of design redundancy must be estimated. Also, each such launch vehicle has a certain historical or estimated development cost, tooling cost, and a variable cost. The cost of a launch used in this paper includes the variable cost plus an amortized portion of the fixed and development costs. The integer linear programming model will have several constraint equations based on assumptions of mission mass requirements, volume requirements, and number of astronauts needed. The model will minimize launch vehicle logistic support cost and will select the most desirable launch vehicle fleet.

Morgenthaler, George W.↗

Determination of sea ice parameters with the Nimbus 7 SMMR

A method of determining sea ice parameters using Nimbus 7 polarized multispectral radiance data obtained with the Nimbus 7 Scanning Multichannel Microwave Radiometer (SMMR) is presented. Observed radiances from selected areas in the Arctic region for the period February 3-7, 1979 were used in computing algorithm coefficients. Polar maps of sea ice concentration, multiyear fraction, and ice temperature are illustrated for this period. The variation of the mean and standard deviation of ice concentration and multiyear ice fraction for a region of perennial ice cover over the first 11 months of SMMR operation is also presented. Comparisons are made between the calculated sea ice parameters and information obtained from previous studies using aircraft, submarine and surface observations. The absolute accuracy of the SMMR parameters remains uncertain.

Cavalieri, D. J.↗

Polarized views of the earth from orbital altitude

By means of a pair of boresighted and synchronized cameras fitted with orthogonally oriented polarizing filters and carried aboard the Space Shuttle, a large number of polarized images of the earth's surface have been obtained from orbital altitude. Selected pairs of images, both in color and in black and white, have been digitized and computer processed to yield analogous images in each of the three Stokes parameters necessary for characterizing the state of linear polarization of the emergent light. Many of the images show surface properties more distinctly in degree and plane of polarization than in simple intensity alone. However, the maximum information content as well as noise suppression and minimization of atmospheric interference, is achieved by proper combinations of the Stokes parameters. It is believed that these are the first, and certainly the most extensive, set of polarized images of the earth ever obtained from space.

Coulson, Kinsell L.↗

Technical Routes to Achieve High Circular Polarized Luminescence in Chiral Perovskites: A Mini‐Review

Chiral hybrid organic-inorganic perovskites (HOIPs) have emerged as promising materials for optoelectronic and spintronic applications, leveraging unique properties such as circularly polarized luminescence (CPL), circularly polarized nonlinear optical (NLO) emission, and chiral-induced spin selectivity (CISS). However, challenges remain in stabilizing these materials under environmental stresses and precisely controlling chirality for scalable use. This review summarizes five main strategies to induce chirality in HOIPs, i.e., direct incorporation of chiral cations, surface modification with chiral ligands, ion doping, template-induced chirality, and chiral metasurfaces. Each approach offers distinct advantages for optimizing CPL efficiency and device stability, paving the way for next-generation applications in CPL detectors, information encryption, spintronic devices, etc.

14 SOLAR ENERGY↗

A Mixed-Method Design Approach for Empirically Based Selection of Unbiased Data Annotators

Implicit bias embedded in the annotated data is by far the greatest impediment in the effectual use of supervised machine learning models in tasks involving race, ethics, and geopolitical polarization. For societal good and demonstrable positive impact on wider society, it is paramount to carefully select data annotators and rigorously validate the annotation process. Current approaches to selecting annotators are not sufficiently grounded in scientific principles and are limited at the policy-guidance level, thereby rendering them unusable for machine learning practitioners. This work proposes a new approach based on the mixed-methods design that is functional, adaptable, and simpler to implement in selecting unbiased annotators for any machine learning problem. By demonstrating it on a real-world geopolitical problem, we also identified and ranked key inane profile characteristics towards an empirically-based selection of unbiased data annotators.

Thakur, Gautam Malviya↗

Global Sensitivity Analysis of Simulated Remote Sensing Polarimetric Observations Over Snow

This study presents a detailed theoretical assessment of the information content of passive polarimetric observations over snow scenes, using a global sensitivity analysis (GSA) method. Conventional sensitivity studies focus on varying a single parameter while keeping all other parameters fixed. In contrast, the GSA correctly addresses the covariance of state parameters across their entire parameter space, hence favoring a more correct interpretation of inversion algorithms and the optimal design of their state vectors. The forward simulations exploit a vector radiative transfer model to obtain the Stokes vector emerging at the top of the atmosphere for different solar zenith angles, when the bottom boundary consists of a vertically resolved snowpack of non-spherical grains. The presence of light-absorbing particulates (LAPs), either embedded in the snow or aloft in the atmosphere above in the form of aerosols, is also considered. The results are presented for a set of wavelengths spanning the visible (VIS), near-infrared (NIR), and shortwave infrared (SWIR) region of the spectrum. The GSA correctly captures the expected, high sensitivity of the reflectance to LAPs in the VIS–NIR and to grain size at different depths in the snowpack in the NIR–SWIR. With adequate viewing geometries, mono-angle measurements of total reflectance in the VIS–SWIR (akin to those of the Moderate Resolution Imaging Spectroradiometer, MODIS) resolve grain size in the top layer of the snowpack sufficiently well. The addition of multi-angle polarimetric observations in the VIS–NIR provides information on grain shape and microscale roughness. The simultaneous sensitivity in the VIS–NIR to both aerosols and snow-embedded impurities can be disentangled by extending the spectral range to the SWIR, which contains information on aerosol optical depth while remaining essentially unaffected when the same particulates are mixed with the snow. Multi-angle polarimetric observations can therefore (i) effectively partition LAPs between the atmosphere and the surface, which represents a notorious challenge for snow remote sensing based on measurements of total reflectance only and (ii) lead to better estimates of grain shape and roughness and, in turn, the asymmetry parameter, which is critical for the determination of albedo. The retrieval uncertainties are minimized when the degree of linear polarization is used in place of the polarized reflectance. The Sobol indices, which are the main metric for the GSA, were used to select the state parameters in retrievals performed on data simulated for multiple instrument configurations. Improvements in retrieval quality with the addition of measurements of polarization, multi-angle views, and different spectral channels reflect the information content, identified by the Sobol indices, relative to each configuration. The results encourage the development of new remote sensing algorithms that fully leverage multi-angle and polarimetric capabilities of modern remote sensors. They can also aid flight planning activities, since the optimal exploitation of the information content of multi-angle measurements depends on the viewing geometry. The better characterization of surface and atmospheric parameters in snow-covered regions advances research opportunities for scientists of the cryosphere and ultimately benefits albedo estimates in climate models.

remote sensing↗

Exploring Subsite Selectivity within Plasmodium vivax N -Myristoyltransferase Using Pyrazole-Derived Inhibitors

N-myristoyltransferase (NMT) is a promising antimalarial drug target. Despite biochemical similarities between Plasmodium vivax and human NMTs, our recent research demonstrated that high selectivity is achievable. Herein, we report PvNMT-inhibiting compounds aimed at identifying novel mechanisms of selectivity. Various functional groups are appended to a pyrazole moiety in the inhibitor to target a pocket formed beneath the peptide binding cleft. The inhibitor core group polarity, lipophilicity, and size are also varied to probe the water structure near a channel. Selectivity index values range from 0.8 to 125.3. Cocrystal structures of two selective compounds, determined at 1.97 and 2.43 Å, show that extensions bind the targeted pocket but with different stabilities. A bulky naphthalene moiety introduced into the core binds next to instead of displacing protein-bound waters, causing a shift in the inhibitor position and expanding the binding site. Our structure-activity data provide a conceptual foundation for guiding future inhibitor optimizations.

60 APPLIED LIFE SCIENCES↗

Intense Source of Polarized Hydrogen Atoms

Atoms produced by radio-frequency dissociation of hydrogen molecules sorted according to their hyperfine states in improved polarized hydrogen source. By use of combination of dc magnetic fields, atoms of upper hyperfine ground level selected in numbers greater than those of undesired F = O state. Source built with permanent magnets or electromagnets. Principal utility is source of polarized hydrogen for masers or experimental studies.

Maleki, L.↗

Effects of simulated space radiation on selected optical materials

The effect of simulated Nimbus spacecraft orbital (1100 km, circular, and polar) radiation on wide bandpass glass filters, narrow bandpass thin film interference filters, and several fused silicas was determined by transmittance measurements over the 200 to 3400 nanom wavelength region. No changes were observed in the filters, which were shielded with fused silica during irradiation, after exposure to a 1-year equivalent orbital dose of electrons, nor in the fused silicas after the same electron exposure plus a 1-year equivalent dose of protons. Exposure to a 1/2-year equivalent dose of solar ultraviolet radiation caused a significant degradation in the transmittance of two ultraviolet-transmitting interference filters but had no effect on two colored glass filters that transmitted in the visible and near infrared regions. As a result of the ultraviolet exposure the fused silicas exhibited losses of several percent over the 200- to 300 nanom wavelength region.

Nicoletta, C. A.↗

Effect of simulated space radiation on selected optical materials.

The effect of simulated Nimbus spacecraft orbital (1100 km, circular, and polar) radiation on wide-band-pass glass filters, narrow-bandpass thin-film interference filters, and several fused silicas was determined by transmittance measurements over the 200-3400-nm wavelength region. No changes were observed in the filters, which were shielded with fused silica during irradiation, after exposure to a 1-yr equivalent orbital dose of electrons, nor were changes observed in the fused silicas after the same electron exposure plus a 1-yr equivalent dose of protons. Exposure to a 1/2-yr equivalent dose of solar uv radiation, however, caused a significant degradation in the transmittance of two uv-transmitting interference filters but had no effect on two colored glass filters that transmitted in the visible and near-ir regions. As a result of the uv exposure, the fused silicas exhibited losses of several percent over the 200-300-nm wavelength region.

Nicoletta, C. A.↗

Positron Injector for Ce+BAF

A baseline concept for a continuous wave (CW) polarized positron injector was developed for the CEBAF at Jefferson Lab. This concept is based on the generation of CW longitudinally polarized positrons by a high-current, polarized electron beam 1 mA, 130-370 MeV, and 90% longitudinal polarization that passes through a rotating, water-cooled, tungsten target. The simulations for the Ce+BAF injector at the Low Energy Recirculator Facility (LERF) are performed, including positron beam generation, capture, energy selection, and acceleration to 123 MeV. The positron yield (or positron current) and longitudinal polarization are calculated considering the longitudinal and transverse CEBAF acceptances (<1% energy spread, 1.2 mm bunch length and normalized emittance of 100 mm·mrad). The impact of target thickness, electron beam energy, and transverse size on positron yield within the required emittance limit is evaluated. Target thermal and structural FEM analyses (ANSYS Fluent) are performed to determine the maximum electron beam current and minimum transverse beam size on the target.

Benesch, Jay [Thomas Jefferson National Accelerato↗

Spin-Polarized Oxygen Evolution Reaction Enabled by Chiral Molecules Coupled with Ferromagnetic Electrocatalysts

The discovery of chirality-induced spin selectivity (CISS) revolutionized our understanding of the capabilities of chiral molecules, revealing that chiral molecules can function as spin filters, aligning the spin orientation of electrons when they transmit through them. Recently, CISS has been exploited to direct energy conversion, especially the oxygen evolution reaction (OER). However, despite the remarkable progress that has been achieved, the effect of CISS in influencing the intermediate species formation and changing the rate-determining step (RDS) is still vague. To understand those key reaction mechanism steps, electrocatalysts with distinct magnetic characteristics, ferromagnetic CoFe2O4 and paramagnetic Co3O4, were synthesized. The results show that spin-polarized charge carriers retain their spin alignment when coupled with ferromagnetic CoFe2O4, akin to the behavior observed under a magnetic field. The Tafel analysis and kinetic isotope studies (kinetic isotope effect) suggest that in the absence of chiral molecules, the initial electron transfer step, the formation of O* species, governs the rate-determining step (RDS). However, introducing chiral molecules shifts the RDS to a combination of the first and second electron transfers, leading to the formation of OOH*. This conclusion was further supported by in situ infrared spectroscopy, which shows that l-methionine-modified CoFe2O4 (l-CoFe2O4) promotes the formation of OOH*, a key intermediate for O2 generation. This study highlights the critical role of CISS in affecting the OER mechanism and intermediate species formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗