Rapid Open-Air Fabrication of Manufacturable Perovskite Solar Modules
Implementing open-air plasma processing for large-area perovskite modules
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Implementing open-air plasma processing for large-area perovskite modules
We propose to address the challenge of the vast parameter space associated with perovskite manufacturing optimization, by developing a machine learning (ML)-assisted optimization framework for a scalable perovskite PV manufacturing tool. This framework will be interpretable, sequential, and rapidly adaptable to upgraded systems (e.g., via transfer learning). The tool is an open-air rapid spray plasma process (RSPP) of perovskite films, which has already been established at Stanford and is a unique platform to test and deploy the proposed ML-guided framework because the RSPP technique is able to conduct optimization experiments with a high throughput, and easily adjust a wide range of process variables.
As part of the Cyclotron Road program, the Nitricity Inc. research team sought to investigate the electrification of nitrogen fixation and the corresponding development of fixed nitrogen products. Nitricity’s cofounders had developed a plasma process and related technologies to cost-effectively use air, water, and electricity to convert nitrogen gas into nitrogen fertilizer (and other nitrogen products). This project explored ways to make this process more efficient and robust. Synthetic nitrogen fixation is critical for growing crops and feeding most of the world’s populace. However, the incumbent method to fix nitrogen, the Haber–Bosch process, requires unsustainable fossil fuels and ultra-centralized facilities with a supply-chain network that fails to reach many developing countries. Nitricity envisions that their process when scaled, may provide sustainable fixed nitrogen in many forms to fit the needs of the end user.
Though weak surface interactions and adsorption can play an important role in plasma processing and materials science, they are not necessarily simple to model. A boron adatom adsorbed on a graphene sheet serves as a case study for how carefully one must select the correct technique from a toolbox of computational chemistry methods. Using a variety of molecular dynamics potentials and density functional theory functionals, we evaluate the adsorption energy, investigate barriers to adsorption and migration, calculate corresponding reaction rates, and show that a surprisingly high level of theory may be necessary to verify that the system is described correctly.
Abstract Relativistic magnetic reconnection is a nonideal plasma process that is a source of nonthermal particle acceleration in many high-energy astrophysical systems. Particle-in-cell (PIC) methods are commonly used for simulating reconnection from first principles. While much progress has been made in understanding the physics of reconnection, especially in 2D, the adoption of advanced algorithms and numerical techniques for efficiently modeling such systems has been limited. With the GPU-accelerated PIC code WarpX, we explore the accuracy and potential performance benefits of two advanced Maxwell solver algorithms: a nonstandard finite-difference scheme (CKC) and an ultrahigh-order pseudo-spectral method (PSATD). We find that, for the relativistic reconnection problem, CKC and PSATD qualitatively and quantitatively match the standard Yee-grid finite-difference method. CKC and PSATD both admit a time step that is 40% longer than that of Yee, resulting in a ∼40% faster time to solution for CKC, but no performance benefit for PSATD when using a current deposition scheme that satisfies Gauss’s law. Relaxing this constraint maintains accuracy and yields a 30% speedup. Unlike Yee and CKC, PSATD is numerically stable at any time step, allowing for a larger time step than with the finite-difference methods. We found that increasing the time step 2.4–3 times over the standard Yee step still yields accurate results, but it only translates to modest performance improvements over CKC, due to the current deposition scheme used with PSATD. Further optimization of this scheme will likely improve the effective performance of PSATD.
Solar radio burst generation - propagation modes in solar plasma, radiation processes, and plasma waves
Proposals for environment modification experiments in space to determine dynamics of field, particle, and plasma processes in magnetosphere
Discharge chamber plasma processes in electron bombardment ion thrustors, considering factors affecting thrustor performance
Discharge chamber plasma processes in electron bombardment ion thrustors, considering factors affecting thrustor performance
Activity in galaxies and quasars is interpreted in terms of plasma processes occurring in the magnetosphere of a magnetoid model. The magnetoid is comprised of a core and an annulus rotating about a common axis with different angular velocities. It is conjectured that the transition from a closed force field configuration to an open one will be effected by an MHD eruptive instability, and that such eruptions lead to high velocity clouds of cool gas, identified with clouds producing absorption lines in quasars. The ejection of radio clouds from galaxies and quasars is attributed to galactic flares. Current sheets contain mildly relativistic electrons moving in directions partially transverse to the magnetic field. Synchrotron radiation from these electrons is held responsible for the nonthermal radiation from quasars and certain galaxies. It is proposed that minor instabilities of the current sheets are responsible for fluctuations in the nonthermal luminosity and for small scale radio bursts sometimes observed.
Activity in galaxies and quasars is interpreted in terms of plasma processes occurring in the magnetosphere of a certain magnetoid model. This magnetoid comprises a core and an annulus rotating about a common axis with different angular velocities. The magnetic field linking the core to the annulus may begin in an initial current-free state but will be distorted along a sequence of force-free configurations. After a finite differential rotation, the force-free configuration has higher energy than a corresponding open-field configuration. It is conjectured that the transition from the closed configuration to an open configuration will be effected by an MHD eruptive instability, and that such eruptions lead to high-velocity clouds of cool gas identified with clouds producing absorption lines in quasars. It is proposed that minor instabilities of the current sheets are responsible for fluctuations in the nonthermal luminosity and for small-scale radio bursts sometimes observed in galaxies and quasars.
The capability of the Space Shuttle for the conduct of magnetospheric experiments is critically analyzed. Some physical problems are discussed on which a particle and field payload program could be based. They include the study of magnetospheric plasma processes, wave-particle interactions and auroral phenomena, both by artificial modification experiments and by systematic wide-scale observations of naturally occurring magnetospheric perturbation events.
The mathematical model developed by Brown and Shook is used to explain the absence of asteroids in the Kirkwood gaps as well as the existence of some resonant asteroids with orbital periods commensurable to that of Jupiter. In addition, this model can possibly explain the biased number distributions at the commensurable positions of both resonant gaps and clusters. However, this resonant model is probably not applicable to the Saturnian ring system due to the possible cosmogonic plasma process during its formation.
The solar probe offers a platform with particular advantages for studying solar nonthermal plasma processes via the observations of hard X-radiation from energetic electrons in the chromosphere and corona, these include (1) high sensitivity, (2) a second line of sign (in addition to the earth's) that can aid in three dimensional reconstruction of the source distribution, and, (3) the possibility of correlation with direct measurements of the nonthermal particles from the probe itself.
Energetic particle events relating to quasi-stationary particle populations, solar flare events, and solar composition are discussed in the context of similar observations likely to be made during solar probe encounter. Particlar emphasis is given to interrelationships with coronal magnetic structure and plasma processes. General instrumental requirements are listed, and it is concluded that energetic particle detectors meeting these requirements will successfully complement other essential experiments on the Solar Probe.
Two 12 cm magneto-electrostatic containment (MESC) ion thrusters were performance mapped with argon and xenon. The first, hexagonal, thruster produced optimized performance of 48.5to 79 percent argon mass utilization efficiencies at discharge energies of 240 to 425 eV/ion, respectively, Xenon mass utilization efficiencies of 78 to 95 percent were observed at discharge energies of 220 to 290 eV/ion with the same optimized hexagonal thruster. Changes to the cathode baffle reduced the discharge anode potential during xenon operation from approximately 40 volts to about 30 volts. Preliminary tests conducted with the second, hemispherical, MESC thruster showed a nonuniform anode magnetic field adversely affected thruster performance. This performance degradation was partially overcome by changes in the boundary anode placement. Conclusions drawn the hemispherical thruster tests gave insights into the plasma processes in the MESC discharge that will aid in the design of future thrusters.
By examining the exact analytic solution of a kinetic model of collisional interaction of ionospheric ions with atmospheric neutrals in the Bhatnagar-Gross-Krook approximation, we show that the onset of intense auroral electric fields in the topside ionosphere can produce the following kinetic effects: (1) heat the bulk ionospheric ions to approximately 2 eV, thus driving them up to higher altitudes where they can be subjected to collisionless plasma processes; (2) produce a non-Maxwellian superthermal tail in the distribution function; and (3) cause the ion distribution function to be anisotropic with respect to the magnetic field with the perpendicular average thermal energy exceeding the parallel thermal energy.
Examination of the exact analytic solution of a kinetic model of collisional interaction of ionospheric fions with atmospheric neutrals in the Bhatnagar-Gross-Krook approximation, shows that the onset of intense auroral electric fields in the topside ionosphere can produce the following kinetic effects: (1) heat the bulk ionospheric ions to approximately 2 eV, thus driving them up to higher altitudes where they can be subjected to collisionless plasma processes; (2) produce a nonMaxwellian superthermal tail in the distribution function; and (3) cause the ion distribution function to be anisotropic with respect to the magnetic field with the perpendicular average thermal energy exceeding the parallel thermal energy.