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At least 307 records · Page 17

Geometrical defect detection for additive manufacturing with machine learning models

This study proposed a scheme based on Machine Learning (ML) models to detect geometric defects of additively manufactured objects. The ML models are trained with synthetic 3D point clouds with defects and then applied to detect defects in actual production. Using synthetic 3D point clouds rather than experimental data could save a huge amount of training time and costs associated with many prints for each design. Besides distance differences of individual points between source and target point clouds, this scheme uses a new concept called “patch” to capture macro-level information about nearby points for ML training and implementation. Numerical comparisons of prediction results on experimental data with different shapes showed that the proposed scheme outperformed the existing Z-difference method in the literature. Five ML methods (Bagging of Trees, Gradient Boosting, Random Forest, K-nearest Neighbors and Linear Supported Vector Machine) were compared under various conditions, such as different point cloud densities and defect sizes. Bagging and Random Forest were found the two best models regarding predictability; and the right patch size was found to be at 20. The proposed ML-based scheme is applicable to in-situ defect detection during additive manufacturing with the aid of a proper 3D data acquisition system.

Additive manufacturing↗

Implications for elastic energy storage in the Himalaya from the Gorkha 2015 earthquake and other incomplete ruptures of the Main Himalayan Thrust

Rupture in the 2015 M7.8 Gorkha earthquake nucleated at the downdip edge of the Main Himalayan Thrust (MHT) near the transition from interseismic locking to aseismic creep beneath the Tibetan plateau, and propagated incompletely towards the Main Frontal Thrusts (MFT). Despite the imposition of a substantial static strain in the mid-décollement, afterslip on the MHT within a year of the earthquake had decayed to negligible levels. Earthquakes that incompletely rupture the MHT (7 < Mw < 7.9) have been relatively common in the past two centuries, and as a consequence heterogeneous patches of stored elastic strain must exist throughout the Himalaya similar to that emplaced by the Gorkha earthquake. We show that these patches of stored strain are not dissipated by creep or by subsequent updip earthquakes, with the possible exceptions of a sequence of moderate earthquakes to the west of the great 1950 Assam earthquake, and to the east of the Kangra 1905 earthquake. It is thus considered likely that mid-décollement strain newly imposed by the Gorkha earthquake, and other recent incomplete ruptures will be incorporated in the rupture of a future much larger earthquake. Incomplete ruptures (i.e. those that nucleate downdip but fail to rupture the frontal thrusts) appear to occur preferentially in parts of the central Himalaya characterized by relatively narrow transition regions of interseismic decoupling (<30 km downdip). Assuming uniform strain at failure these narrow zones are unable to store large amounts of strain energy compared to wide zones of interseismic decoupling. Since the transition from fully locked to a fully creeping rheology depends partly on temperature, to first order the width of the interseismic decoupling transition zone depends on the local dip of the MHT. Where the decoupling zone is narrow (25 km) moderate earthquakes (6 < Mw < 7) are observed to occur at intervals of a few hundred years. Where the transition zone is wide (e.g. Kashmir and Assam, 150 km) great earthquakes nucleate at long time intervals (millennia). Because the cumulative moment release of moderate earthquakes in regions of narrow seismic decoupling is insufficient to keep up with plate convergence, we conclude that megaquakes that eventually sweep through these regions are augmented by the heterogenous fossil strain of former incomplete ruptures. Because great earthquakes in the central Himalaya are inferred to nucleate from moderate earthquakes near the base of the MHT, the preparation zones of these moderate earthquakes may provide opportunities for forecasting the approach of future great earthquakes.

58 GEOSCIENCES↗

Oil spill detection by imaging radars: Challenges and pitfalls

In this paper, criteria for discriminating between radar signatures of oil films and biogenic slicks visible on synthetic aperture radar (SAR) images of the sea surface as dark patches are critically reviewed. We question the often claimed high success rate of oil spill detection algorithms using single-polarization SARs because the SAR images used to train these algorithms are based usually on subjective interpretation and are not validated by on-site inspections or multi-sensor measurements carried out from oil pollution surveillance planes. Furthermore, we doubt that polarimetric parameters derived from fully-polarimetric SAR data, like entropy, anisotropy, and mean scattering angle, are beneficial for discriminating between mineral oil films and biogenic slicks. We challenge the often-made claim that another scattering mechanism than Bragg scattering applies for radar backscattering from mineral oil films than from biogenic slicks. This view is supported by data acquired by the Unmanned Aerial Vehicle Synthetic Aperture Radar (UAVSAR) of NASA/JPL, which operates at L-band and has an extremely low noise floor. We suspect that opposing results obtained from previous analyses of spaceborne polarimetric SAR data are caused by the high noise floors of the spaceborne SARs. However, most of the analyzed spaceborne polarimetric data were not acquired at L-band, but at C-and X-band. On the other hand, differences in the statistical behavior of the radar backscattering could be real due to the fact that, other than biogenic surface films, mineral oil films, can form multi-layers, whose thickness can vary within an oil patch. Radar backscattering from emulsion layers can also fluctuate due to variations of the oil/water mixture ratio. These effects could cause an increase of the standard deviation (STD) of the co-polarized phase difference (CPD) for scattering at mineral oil films and emulsions. In the special case of thick oil layers or oil/water emulsion layers, where the radar is sensitive to the dielectric constant of the oil, discrimination becomes possible due the fact that Bragg scattering depends on the dielectric constant of the scattering medium.

47 OTHER INSTRUMENTATION↗

Contributions of vegetation heterogeneity within tower footprint to CO 2 flux estimations through graph neural network modeling

Net ecosystem exchange of CO 2 (Fc) measured directly by eddy covariance towers is based on various assumptions, including large, flat and homogenous land cover type. In reality, often a tower site is not large enough for flux measurements, and landscapes consist of patches of different land cover types within the flux footprint. In addition, some portions of fluxes are contributed by different cover types when a footprint exceeds the size of the target ecosystem. The contributions of non-dominant patches to Fc are often ignored. Here, in this study, we propose a novel integrated modeling framework that combines random forest (RF) and XGBoost with a residual correction module based on a deep graph convolutional network (DeeperGCN) to simulate Fc for seven flux measurement sites in southwest Michigan. High-resolution remote sensing vegetation indices, soil properties, meteorological variables, and footprint-weighted spatial features were used as model inputs at three spatial resolutions (10 m, 20 m, 30 m), and their importance in predicting Fc with DeeperGCN was assessed. We found that residual correction using DeeperGCN significantly improved prediction accuracy, with the R 2 increasing from 0.9098 to 0.9479 for RF and from 0.9235 to 0.9433 for XGBoost. At site level, the maximum improvement in R 2 reached 0.1617. Paired t-tests confirmed that these improvements were statistically significant (p < 0.05). Among all predictors, leaf area index and incoming shortwave radiation emerged as the dominant drivers of spatial residual variation, followed by precipitation, relative humidity, and selected vegetation indices. The 20 m resolution yielded the best balance between model performance and computational efficiency. In conclusion, our modeling framework effectively captures both spatial heterogeneity and nonlinear interactions, offering a robust solution for spatially explicit flux modeling in structurally diverse ecosystems beyond the study sites.

footprint model↗

Persistent modification of Na{sub v}1.9 following chronic exposure to insecticides and pyridostigmine bromide

Many veterans of the 1991 Gulf War (GW) returned from that conflict with a widespread chronic pain affecting deep tissues. Recently, we have shown that a 60 day exposure to the insecticides permethrin, chlorpyrifos, and pyridostigmine bromide (NTPB) had little influence on nociceptor action potential forming Na{sub v}1.8, but increased K{sub v}7 mediated inhibitory currents 8 weeks after treatment. Using the same exposure regimen, we used whole cell patch methods to examine whether the influences of NTPB could be observed on Na{sub v}1.9 expressed in muscle and vascular nociceptors. During a 60 day exposure to NTPB, rats exhibited lowered muscle pain thresholds and increased rest periods, but these measures subsequently returned to normal levels. Eight and 12 weeks after treatments ceased, DRG neurons were excised from the sensory ganglia. Whole cell patch studies revealed little change in voltage dependent activation and deactivation of Na{sub v}1.9, but significant increases in the amplitude of Na{sub v}1.9 were observed 8 weeks after exposure. Cellular studies, at the 8 week delay, revealed that NTPB also significantly prolonged action potential duration and afterhyperpolarization (22 °C). Acute application of permethrin (10 μM) also increased the amplitude of Na{sub v}1.9 in skin, muscle and vascular nociceptors. In conclusion, chronic exposure to Gulf War agents produced long term changes in the amplitude of Na{sub v}1.9 expressed in muscle and vascular nociceptors. The reported increases in K{sub v}7 amplitude may have been an adaptive response to increased Na{sub v}1.9, and effectively suppressed behavioral pain measures in the post treatment period. Factors that alter the balance between Na{sub v}1.9 and K{sub v}7 could release spontaneous discharge and produce chronic deep tissue pain. - Highlights: • Rats were treated 60 days with permethrin, chlorpyrifos and pyridostigmine bromide. • 8 weeks after treatments, Nav1.9 activation and deactivation were unchanged. • The amplitude and conductance of Nav1.9 were increased 8 weeks following exposure. • Nociceptors exhibit increased action potential duration and afterhyperpolarization. • Acute permethrin altered activation physiology and increased the amplitude of Nav1.9.

60 APPLIED LIFE SCIENCES↗

Deoxynivalenol induced mouse skin cell proliferation and inflammation via MAPK pathway

Several toxicological manifestations of deoxynivalenol (DON), a mycotoxin, are well documented; however, dermal toxicity is not yet explored. The effect of topical application of DON to mice was studied using markers of skin proliferation, inflammation and tumor promotion. Single topical application of DON (84–672 nmol/mouse) significantly enhanced dermal hyperplasia and skin edema. DON (336 and 672 nmol) caused significant enhancement in [{sup 3}H]-thymidine uptake in DNA along with increased myeloperoxidase and ornithine decarboxylase activities, suggesting tissue inflammation and cell proliferation. Furthermore, DON (168 nmol) caused enhanced expression of RAS, and phosphorylation of PI3K/Akt, ERK, JNK and p38 MAPKs. DON exposure also showed activation of transcription factors, c-fos, c-jun and NF-κB along with phosphorylation of IkBα. Enhanced phosphorylation of NF-κB by DON caused over expression of target proteins, COX-2, cyclin D1 and iNOS in skin. Though a single topical application of DMBA followed by twice weekly application of DON (84 and 168 nmol) showed no tumorigenesis after 24 weeks, however, histopathological studies suggested hyperplasia of the epidermis and hypertrophy of hair follicles. Interestingly, intestine was also found to be affected as enlarged Peyer's patches were observed, suggesting inflammatory effects which were supported by elevation of inflammatory cytokines after 24 weeks of topical application of DON. These results suggest that DON induced cell proliferation in mouse skin is through the activation of MAPK signaling pathway involving transcription factors NFκB and AP-1, further leading to transcriptional activation of downstream target proteins c-fos, c-jun, cyclin D1, iNOS and COX-2 which might be responsible for its inflammatory potential. - Highlights: • Topical application of DON enhanced epidermal inflammation and cell proliferation. • DON follows PI3K/Akt/MAPK signaling cascade, with activation of AP-1 and NF-κB. • DON caused over expression of target proteins, COX-2, cyclin D1 and iNOS in skin. • No tumor promotion was observed up to 24 weeks of topical application of DON. • Enhanced Peyer's patches and inflammatory cytokines suggested inflammation in skin.

60 APPLIED LIFE SCIENCES↗

Chronic alcohol consumption regulates the expression of poly immunoglobulin receptor (pIgR) and secretory IgA in the gut

The effect of ethanol (EtOH) on the gut immune system was analyzed using an experimental model previously described, where EtOH was provided ad libitum in the drinking water in a 20% w/v concentration for up to 12 weeks. Dendritic cells, T cells and macrophages were analyzed in Peyer's patches and the small intestines using flow cytometry. Cytokine and immunoglobulin levels were analyzed in sera, feces, and homogenates from small and large intestines and lungs. Decreases in the proportion of T cells and alterations in dendritic cells and macrophages were observed after EtOH treatment. Levels of immunoglobulin A (IgA) increased in tissue homogenates but decreased in small intestine fecal contents. Meanwhile poly-immunoglobulin receptor (pIgR) levels decreased in tissue homogenates and fecal contents. Levels of cytokines associated with the regulation of pIgR expression decreased for IL-10 and TGF-β, and increased for IFN-γ and IL-17 in the small intestine. The data indicate that chronic EtOH consumption disrupts the homeostasis of the mucosal immune system by altering the phenotype and functionality of multiple immune cell types, leading to a diminished secretion of SIgA, due to pIgR expression decreased. - Highlights: • Chronic alcohol (EtOH) alters monocytes and dendritic cells ratios in the gut. • EtOH decreases the number of T cells synthesizing IFN-γ in Peyer's patches. • EtOH decreases IgA and pIgR levels in small (SI) and large (LI) intestine feces. • EtOH decreases pIgR levels in SI homogenates. • EtOH favors the appearance of an inflammatory cytokine profile in SI homogenates.

60 APPLIED LIFE SCIENCES↗

Characterization of the transport signals that mediate the nucleocytoplasmic traffic of low risk HPV11 E7

We previously discovered that nuclear import of low risk HPV11 E7 is mediated by its zinc-binding domain via a pathway that is independent of karyopherins/importins (Piccioli et al., 2010. Virology 407, 100–109). In this study we mapped and characterized a leucine-rich nuclear export signal (NES), {sub 76}IRQLQDLLL{sub 84}, within the zinc-binding domain that mediates the nuclear export of HPV11 E7 in a CRM1-dependent manner. We also identified a mostly hydrophobic patch {sub 65}VRLVV{sub 69} within the zinc-binding domain that mediates nuclear import of HPV11 E7 via hydrophobic interactions with the FG-repeats domain of Nup62. Substitutions of hydrophobic residues to alanine within the {sub 65}VRLVV{sub 69} sequence disrupt the nuclear localization of 11E7, whereas the R66A mutation has no effect. Overall the data support a model of nuclear entry of HPV11 E7 protein via hydrophobic interactions with FG nucleoporins at the nuclear pore complex. - Highlights: • HPV11 E7 has a leucine-rich nuclear export signal that mediates its nuclear export via CRM1. • HPV11 E7 interacts via its unique cNLS with the FG domain of Nup62. • Identification of a hydrophobic patch essential for nuclear localization of HPV11 E7.

60 APPLIED LIFE SCIENCES↗

Nuclear import of high risk HPV16 E7 oncoprotein is mediated by its zinc-binding domain via hydrophobic interactions with Nup62

We previously discovered that nuclear import of high risk HPV16 E7 is mediated by a cNLS located within the zinc-binding domain via a pathway that is independent of karyopherins/importins (Angeline et al., 2003; Knapp et al., 2009). In this study we continued our characterization of the cNLS and nuclear import pathway of HPV16 E7. We find that an intact zinc-binding domain is essential for the cNLS function in mediating nuclear import of HPV16 E7. Mutagenesis of cysteine residues to alanine in each of the two CysXXCys motifs involved in zinc-binding changes the nuclear localization of the EGFP-16E7 and 2xEGFP-16E7 mutants. We further discover that a patch of hydrophobic residues, {sub 65}LRLCV{sub 69}, within the zinc-binding domain of HPV16 E7 mediates its nuclear import via hydrophobic interactions with the FG domain of the central channel nucleoporin Nup62. - Highlights: • An intact zinc-binding domain is essential for the nuclear localization of HPV16 E7. • Identification of a hydrophobic patch that is critical for the nuclear import of HPV16 E7. • HPV16 E7 interacts via its zinc-binding domain with the FG domain of Nup62.

60 APPLIED LIFE SCIENCES↗

Experimental study of the stability and dynamics of a two-dimensional ideal vortex under external strain

The dynamics of two-dimensional (2-D) ideal fluid vortices is studied experimentally in the presence of an irrotational strain flow. Laboratory experiments are conducted using strongly magnetized pure electron plasmas, a technique which is made possible by the isomorphism between the drift–Poisson equations describing plasma dynamics transverse to the field and the 2-D Euler equations describing an ideal fluid. The electron plasma system provides an excellent opportunity to study the dynamics of a 2-D Euler fluid due to weak dissipation and weak 3-D effects, simple diagnosis and precise control. The plasma confinement apparatus used here was designed specifically to study vortex dynamics under the influence of external flow by applying boundary conditions in two dimensions. Additionally, vortex-in-cell simulations are carried out to complement the experimental results and to extend the parameter range of the studies. It is shown that the global dynamics of a quasi-flat vorticity profile is in good quantitative agreement with the theory of a piecewise-constant elliptical patch of vorticity, including the equilibria, dynamical orbits and stability properties. Deviations from the elliptical patch theory are observed for non-flat vorticity profiles; they include inviscid damping of the orbits and modified stability limits. The dependence of these phenomena on the flatness of the initial profile is discussed. The relationship of these results to other theoretical, numerical and experimental studies is also discussed.

Mechanics↗

Spatiotemporal dynamics of wetted soils across a polar desert landscape

Liquid water is scarce across the landscape of the McMurdo Dry Valleys (MDV), Antarctica, a 3800 km 2 ice-free region, and is chiefly associated with soils that are adjacent to streams and lakes (i.e. wetted margins) during the annual thaw season. However, isolated wetted soils have been observed at locations distal from water bodies. The source of water for the isolated patches of wet soil is potentially generated by a combination of infiltration from melting snowpacks, melting of pore ice at the ice table, and melting of buried segregation ice formed during winter freezing. In this paper, high resolution remote sensing data gathered several times per summer in the MDV region were used to determine the spatial and temporal distribution of wet soils. The spatial consistency with which the wet soils occurred was assessed for the 2009–10 to 2011–12 summers. The remote sensing analyses reveal that cumulative area and number of wet soil patches varies among summers. The 2010–11 summer provided the most wetted soil area (10.21 km 2 ) and 2009–10 covered the least (5.38 km 2 ). Finally, these data suggest that wet soils are a significant component of the MDV cold desert land system and may become more prevalent as regional climate changes.

54 ENVIRONMENTAL SCIENCES↗

Accelerated Cu2O Reduction by Single Pt Atoms at the Metal-Oxide Interface§

The reducibility of metal oxides, when serving as the catalyst support or the active sites themselves, plays an important role in heterogeneous catalytic reactions. Here we present an integrated experimental and theoretical study that reveals how the addition of small amounts of atomically dispersed Pt at the metal/oxide interface dramatically enhances the reducibility of a Cu2O thin film by H2. X-ray photoelectron spectroscopy (XPS) and temperature-programmed desorption (TPD) results reveal that upon oxidation, a PtCu single-atom alloy (SAA) surface is covered by a thin Cu2O film and is therefore unable to dissociate H2. Despite this, in situ studies using ambient pressure (AP) XPS reveal that the presence of a small amount of Pt under the oxide layer can, at the single-atom limit, promote the reduction of Cu2O by H2 at room temperature. We build two density functional theory based surface models to better understand these experimental findings: A Cu2O/Cu(111)-like surface oxide layer, known as the ‘29’ oxide, in which Pt is alloyed into the Cu(111) surface as well as a PtCu SAA. Our calculations suggest that the increased activity is due to the presence of atomically dispersed Pt under the surface oxide layer, which weakens the Cu-O bonds in its immediate vicinity, thus making the interface between subsurface Pt and the surface oxide a nucleation site for the formation of metallic Cu. This initial step in the reduction process results in the presence of surface Pt atoms surrounded by metallic Cu patches, and the Pt atoms become active in H2 dissociation, which consequently accelerates the reduction of the oxide layer. This work demonstrates how isolated Pt atoms at the metal/oxide interface of a Cu-based catalyst accelerate the reduction of the oxide and, therefore, helps maintain the active, reduced state of the catalyst under reaction conditions, as is required for the synthesis of methanol from CO2 hydrogenation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Three-Dimensional Patterning of Nanoparticles by Molecular Stamping

Directing the formation of nanoscale architectures from nanoparticles is one of the key challenges in designing nanomaterials with prescribed functions. Atomic systems, given their ability to form molecules and crystals via directional chemical bonds, provide an inspiration for establishing approaches where nanoparticles with designed anisotropic binding modalities can be assembled into nanoscale architectures. However, fabricating such nanoparticles has been challenging due to their small dimensions and limited ways for site-specific control of their surface. To this end, we present a Molecular Stamping (MOST) approach to pattern DNA-coated nanoparticles with molecules at the predefined positions on a nanoparticle surface. This patterning is realized by use of a rigid and coordinative DNA frame as a molecular stamping apparatus (MOST App). The MOST App transfers multiple types of molecular “inks”, DNA sequences, onto nanoparticle surface and fixes these molecular inks into place to form a designed pattern. After a nanoparticle release from MOST App, it possesses single-molecule patches that can provide anisotropic bonds with distinctive affinities. We further use these stamped nanoparticles to assemble prescribed clusters, whose structure is determined by the locations of patches. Using electron microscopy and tomographic methods, we investigate the efficiency of cluster formation and the resulting spatial arrangements of nanoparticles. The presented approach provides a single-molecule and spatiallydetermined control over nanoparticle functionalization for creating nanoparticles with designed placement of different molecules and for realizing a rational fabrication of nanomaterial architectures.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Twisted MoSe 2 bilayers with variable local stacking and interlayer coupling revealed by low-frequency Raman spectroscopy

Unique twisted bilayers of MoSe 2 with multiple stacking orientations and interlayer couplings in the narrow range of twist angles, 60 ± 3°, are revealed by low-frequency Raman spectroscopy and theoretical analysis. The slight deviation from 60 allows the concomitant presence of patches featuring all three high-symmetry stacking configurations (2H or AA', AB', A'B) in one unique bilayer system. In this case, the periodic arrangement of the patches and their size strongly depend on the twist angle. Ab initio modeling predicts significant changes in frequencies and intensities of low-frequency modes versus stacking and twist angle. Experimentally, the variable stacking and coupling across the interface is revealed by the appearance of two breathing modes corresponding to the mixture of the high-symmetry stacking configurations and unaligned regions of monolayers. Only one breathing mode is observed outside the narrow range of twist angles. This indicates a stacking transition to unaligned monolayers with mismatched atom registry without the in-plane restoring force required to generate a shear mode. As a result, the variable interlayer coupling and spacing in transition metal dichalcogenide bilayers revealed in this study may provide a new platform for optoelectronic applications of these materials.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Revealing Amphiphilic Nanodornains of Anti-Biofouling Polymer Coatings

Undesired bacterial adhesion and biofilm formation on wetted surfaces leads to significant economic and environmental costs in various industries. Amphiphilic coatings with molecular hydrophilic and hydrophobic patches can mitigate such biofouling effectively in an environmentally friendly manner. The coatings are synthesized by copolymerizing (Hydroxyethyl)methacrylate and perfluorodecylacrylate via initiated chemical vapor deposition (iCVD). In previous studies, the size of the patches was estimated to be similar to 1.4-1.75 nm by fitting protein adsorption data to a theoretical model. However, no direct observations of the molecular heterogeneity exist and therefore the origin of the fouling resistance of amphiphilic coatings remains unclear. Here, the amphiphilic nature is investigated by amplitude modulation atomic force microscopy (AM-AFM). High-resolution images obtained by penetrating and oscillating the AFM tip under the naturally present water layer with sub-nanometer amplitudes reveal, for the first time, the existence of amphiphilic nanodomains (1-2 nm(2)). Compositional heterogeneity at the nanoscale is further corroborated by a statistical analysis on the data obtained with dynamic AM-AFM force spectroscopy. Variations in the long range attractive forces, responsible for water affinity, are also identified. These nanoscopic results on the polymers wettability are also confirmed by contact angle measurements (i.e., static and dynamic). The unprecedented ability to visualize the amphiphilic nanodomains as well as sub-nanometer crystalline structures provides strong evidence for the existence of previously postulated nanostructures, and sheds light on the underlying antifouling mechanism of amphiphilic chemistry.

Amadei, CA↗

Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

In this work, a series of Pd/Fe2O3 catalysts were synthesized, characterized, and evaluated for the hydrodeoxygenation (HDO) of m-cresol. It was found that the addition of Pd remarkably promotes the catalytic activity of Fe while the product distributions resemble that of monometallic Fe catalyst, showing high selectivity towards the production of toluene (C-O cleavage without saturation of aromatic ring and C-C cleavage). Reduced catalysts featured with Pd patches on the top of reduced Fe nanoparticle surface, and the interaction between Pd and Fe was further confirmed using X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray absorption near edge fine structure (XANES). A possible mechanism, including Pd assisted H2 dissociation and Pd facilitated stabilization of metallic Fe surface as well as Pd enhanced product desorption, is proposed to be responsible for the high activity and HDO selectivity in Pd-Fe catalysts. The synergic catalysis derived from Pd-Fe interaction found in this work was proved to be applicable to other precious metal promoted Fe catalysts, providing a promising strategy for future design of highly active and selective HDO catalysts.

09 BIOMASS FUELS↗

Controlling Nanoparticle Orientations in the Self-Assembly of ‘Patchy’ Quantum Dot-Gold Heterostructural Nanocrystals

Self-assembly of nanocrystals is a promising route for creating macroscale materials that derive function from the properties of their nanoscale building blocks. While much progress has been made assembling nanocrystals into different superlattices, controlling the relative orientations of nanocrystals in those lattices remains a challenge. Here, we combine experiments with computer simulations to study the self-assembly of patchy heterostructural nanocrystals (HNCs), consisting of near-spherical quantum dots decorated with regular arrangements of small gold satellites, into close-packed superlattices with pronounced orientational alignment of HNCs. Our simulations indicate that the orientational alignment is caused by van der Waals interactions between gold patches and is sensitive to the interparticle distance in the superlattice. We demonstrate experimentally that the degree and type of orientational alignment can be controlled by changing ligand populations on HNCs. This study provides guidance for the design and fabrication of nanocrystal superlattices with enhanced structural control.

ZHu, Hua↗

Upstream and Downstream Boundary Conditions Control the Physical and Biological Development of River Deltas

Relative sea level rise is depleting coastal land. Success in coastal restoration depends on understanding interactions between physical and biological processes that influence landscape change. We present results from flume experiments examining the coevolution of vegetation and delta channel networks. We show that channel mobility—controlled by upstream and downstream boundary conditions and delta size—controls vegetation colonization. The spatial patterns of plants in turn control the stability and spatial distribution of channels. Experiments with low–channel mobility develop large, dense plant patches that become denser over time and stabilize channels. Experiments with more mobile channels have sparse vegetation patterns that limit vegetation growth within existing patches, maintaining sparse, patchy vegetation. Thus, the ecogeomorphic development of deltas depends on the rate of channel lateral migration and avulsion, suggesting that upstream and downstream boundary conditions control both the physical and biological evolution of coastal landscapes.

54 ENVIRONMENTAL SCIENCES↗