Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “nanotubes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Structural Carbon Nanotube Development

Mechanical properties of carbon nanotubes (CNTs) at the nanoscale suggest their potential to enable significantly lighter structures of interest in aerospace applications. As different formats of the material became available over the last 20 years, understanding of how CNTs contribute to improvements in mechanical properties of structural composites has evolved.Although the material is now available in large quantities that permit the development of composite fabrication processes, the retention of properties that make these materials attractive on the nano scale remains a challenge in large assemblies of CNTs. The work to be presented will summarize lessons learned in our efforts to produce carbon nanotube composites with tensile properties that begin to rival those of carbon fiber reinforced polymer composites. Challenges that need to be overcome for practical adoption of this emerging material system will be considered.

Carbon nanotube↗
NASA NTRS1999

Carbon Nanotubes: Miracle of Materials Science?

Article to be sent to Advanced Materials and Processes, journal of ASM International, as attached. This is a news-type technical journal for a large organization of scientists, engineers, salesmen, and managers. The article is quite general, meant to be an introduction to the properties of nanotubes. This is a materials science organization, therefore the article is geared toward using nanotubes for materials uses. Pictures have not been included in this version.

Files, Bradley S.↗
NASA NTRS1999

Transport Through Higher Subbands of a Carbon Nanotube

The sub-band spacing can be comparable to the bias and kT in large diameter carbon nanotubes. As a result, the role of higher sub-bands cannot be neglected in transport. We discuss two interesting effects involving single particle transport such nanotubes: (i) The transmission probability of electrons at the crossing bands (around E=0) and higher sub-bands are quantitatively different. As a result, we show that the small bias resistance may be larger when the Fermi energy is away from the band center as opposed to being close to the band center. (ii) The primary contribution to current flowing in the presence of an applied bias is due to the crossing sub-bands. This is a result of the electron in the higher sub-bands undergoing Bragg reflection. As a consequence, in an idealized case where scattering is neglected, the differential conductance cannot be much larger than 4e(2)/h.

Anantram, M.P.↗
NASA NTRS2000

Molecular Dynamics Simulations of the Thermal Conductivity of Single-Wall Carbon Nanotubes

Carbon nanotubes (CNT) have very attractive electronic, mechanical. and thermal properties. Recently, measurements of thermal conductivity in single wall CNT mats showed estimated thermal conductivity magnitudes ranging from 17.5 to 58 W/cm-K at room temperature. which are better than bulk graphite. The cylinderical symmetry of CNT leads to large thermal conductivity along the tube axis, additionally, unlike graphite. CNTs can be made into ropes that can be used as heat conducting pipes for nanoscale applications. The thermal conductivity of several single wall carbon nanotubes has been calculated over temperature range from l00 K to 600 K using non-equilibrium molecular dynamics using Tersoff-Brenner potential for C-C interactions. Thermal conductivity of single wall CNTs shows a peaking behavior as a function of temperature. Dependence of the peak position on the chirality and radius of the tube will be discussed and explained in this presentation.

Osman, M.↗
NASA NTRS2000

Carbon Nanotubes: Properties and Functionalization

A viewgraph presentation (including an explanation for each slide) gives an overview of nanoscale hybrid materials, chemistry in confined environments, and single molecule/single atom detection. The allotropes of carbon are described and illustrated, and the production of nanotubes is outlined. Single-wall nanotube interaction and irradiation are discussed. The formation of peapods in PLV material is shown.

David E. Luzzi↗
NASA NTRS2001

Nanotube-based Sensors and Systems for Outer Planetary Exploration

Direct sensing and processing at the nanometer scale offer NASA the opportunity to expand its capabilities in deep space exploration, particularly for the search for signatures of life, the analysis of planetary oceans and atmospheres, and communications systems. Carbon nanotubes, with their unique mechanical, electrical, and radiation-tolerant properties, are a promising tool for this exploration. We are developing devices based on carbon nanotubes, including sensors, actuators, and oscillators. Additional information is contained in the original extended abstract.

Noca, F.↗
NASA NTRS2001

Growth Orientation of Carbon Nanotubes by Thermal CVD

Carbon nanotubes with a few shells are synthesized using thermal chemical vapor depositions. The sizes of these carbon nanotubes (CNT) are quite uniform and the length is up to several tens of micrometers. With the particular substrate location for which the substrate surface is normal along or against the gravity vector, different growth orientations of CNT are observed by scanning electron microscopy, though the Raman spectra for samples at different locations are similar to each other. The results suggest the gravitation effects in growth of the long and small diameter CNT.

Zhu, S.↗
NASA NTRS2001

Gravity Effects in Carbon Nanotube Growth by Thermal Chemical Vapor Deposition

Carbon nanotubes are synthesized using thermal chemical vapor deposition. The sizes of these carbon nanotubes (CNT) are quite uniform and the length of the tube is up to several tens of micrometers. With the substrate surface normal either along or against the gravity vector, different growth orientations of CNT are observed by scanning electron microscopy although the Raman spectra are similar for samples synthesized at different locations. These results suggest the gravitation effects in the growth of long and small diameter CNT.

Zhu, S.↗
NASA NTRS2000

Anisotropic Nanomechanics of Boron Nitride Nanotubes: Nanostructured "Skin" Effect

The stiffness and plasticity of boron nitride nanotubes are investigated using generalized tight-binding molecular dynamics and ab-initio total energy methods. Due to boron-nitride BN bond buckling effects, compressed zigzag BN nanotubes are found to undergo novel anisotropic strain release followed by anisotropic plastic buckling. The strain is preferentially released towards N atoms in the rotated BN bonds. The tubes buckle anisotropically towards only one end when uniaxially compressed from both. A "skin-effect" model of smart nanocomposite materials is proposed which will localize the structural damage towards the 'skin' or surface side of the material.

Srivastava, Deepak↗
NASA NTRS2001

High Coverages of Hydrogen on a (10,0) Carbon Nanotube

The binding energy of H to a (10,0) carbon nanotube is calculated at 24, 50, and 100% coverage. Several different bonding configurations are considered for the 50% coverage case. Using the ONIOM (our own n-layered integrated molecular orbital and molecular mechanics) approach, the average C-H bond energy for the most stable 50% coverage and for the 100% coverage are 57.3 and 38.6 kcal/mol, respectively. Considering the size of the bond energy of H2, these values suggest that it will be difficult to achieve 100% atomic H coverage on a (10,0) nanotube.

Bauschlicher, Charles W., Jr.↗
NASA NTRS2001

Analysis of long-channel nanotube field-effect-transistors (NT FETs)

This viewgraph presentation provides an analysis of long-channel nanotube (NT) field effect transistors (FET) from NASA's Ames Research Center. The structure of such a transistor including the electrode contact, 1D junction, and the planar junction is outlined. Also mentioned are various characteristics of a nanotube tip-equipped scanning tunnel microscope (STM).

Toshishige, Yamada↗
NASA NTRS2001

Nanotube Tunneling as a Consequence of Probable Discrete Trajectories

It has been recently reported that the electrical charge in a semiconductive carbon nanotube is not evenly distributed, but is divided into charge "islands." A clear understanding of tunneling phenomena can be useful to elucidate the mechanism for electrical conduction in nanotubes. This paper represents the first attempt to shed light on the aforementioned phenomenon through viewing tunneling as a natural consequence of "discrete trajectories." The relevance of this analysis is that it may provide further insight into the higher rate of tunneling processes, which makes tunneling devices attractive. In a situation involving particles impinging on a classically impenetrable barrier, the result of quantum mechanics that the probability of detecting transmitted particles falls off exponentially is derived without wave theory. This paper should provide a basis for calculating the charge profile over the length of the tube so that nanoscale devices' conductive properties may be fully exploited.

Robinson, Daryl C.↗
NASA NTRS2001

Theoretical Investigation of Thermo-Mechanical Behavior of Carbon Nanotube-Based Composites Using the Integral Transform Method

This project uses the integral transform technique to model the problem of nanotube behavior as an axially symmetric system of shells. Assuming that the nanotube behavior can be described by the equations of elasticity, we seek a stress function x which satisfies the biharmonic equation: del(exp 4) chi = [partial deriv(r(exp 2)) + partial deriv(r) + partial deriv(z(exp 2))] chi = 0. The method of integral transformations is used to transform the differential equation. The symmetry with respect to the z-axis indicates that we only need to consider the sine transform of the stress function: X(bar)(r,zeta) = integral(from 0 to infinity) chi(r,z)sin(zeta,z) dz.

Pawloski, Janice S.↗
NASA NTRS2001

PECVD Growth of Carbon Nanotubes

Plasma enhanced chemical vapor deposition (PECVD), using inductively coupled plasma, has been used to grow carbon nanotubes (CNTs) and graphitic carbon fibers (GCF) on substrates sputtered with aluminum and iron catalyst. The capacitive plasma's power has been shown to cause a transition from nanotubes to nanofibers, depending on the strength of the plasma. The temperature, placement, and other factors have been shown to affect the height and density of the tube and fiber growth.

McAninch, Ian↗
NASA NTRS1997

Quantum Chemistry Study of Cycloaddition Pathways for the Reaction of o-Benzyne with Fullerenes and Carbon Nanotubes

Functionalization of fullerenes via the [2+2] cycloaddition reaction with o-benzyne has been demonstrated in the laboratory. In contrast, [2+4) cycloaddition products are formed when benzyne reacts with planar polycyclic aromatic hydrocarbons. Using density functional theory (DFT) calculations with Becke's hybrid functional and small contracted gaussian basis sets, we are able to reproduce these product preferences. The objective of this work is to explore the functionalization of carbon nanotubes. We have studied o-benzyne cycloaddition products with a [14,0] single-walled nanotube. We find both the [2+2] and [2+4] adducts to be stable, with the latter product being somewhat favored.

Jaffe, Richard↗
NASA NTRS2002

Equivalent-Continuum Modeling With Application to Carbon Nanotubes

A method has been proposed for developing structure-property relationships of nano-structured materials. This method serves as a link between computational chemistry and solid mechanics by substituting discrete molecular structures with equivalent-continuum models. It has been shown that this substitution may be accomplished by equating the vibrational potential energy of a nano-structured material with the strain energy of representative truss and continuum models. As important examples with direct application to the development and characterization of single-walled carbon nanotubes and the design of nanotube-based devices, the modeling technique has been applied to determine the effective-continuum geometry and bending rigidity of a graphene sheet. A representative volume element of the chemical structure of graphene has been substituted with equivalent-truss and equivalent continuum models. As a result, an effective thickness of the continuum model has been determined. This effective thickness has been shown to be significantly larger than the interatomic spacing of graphite. The effective thickness has been shown to be significantly larger than the inter-planar spacing of graphite. The effective bending rigidity of the equivalent-continuum model of a graphene sheet was determined by equating the vibrational potential energy of the molecular model of a graphene sheet subjected to cylindrical bending with the strain energy of an equivalent continuum plate subjected to cylindrical bending.

Odegard, Gregory M.↗
NASA NTRS1997

Carbon Nanotubes: Molecular Electronic Components

The carbon Nanotube junctions have recently emerged as excellent candidates for use as the building blocks in the formation of nanoscale molecular electronic networks. While the simple joint of two dissimilar tubes can be generated by the introduction of a pair of heptagon-pentagon defects in an otherwise perfect hexagonal graphene sheet, more complex joints require other mechanisms. In this work we explore structural characteristics of complex 3-point junctions of carbon nanotubes using a generalized tight-binding molecular-dynamics scheme. The study of pi-electron local densities of states (LDOS) of these junctions reveal many interesting features, most prominent among them being the defect-induced states in the gap.

Srivastava, Deepak↗
NASA NTRS1998

Modeling Intermolecular Interactions in Nanotubes, Fullerenes and Graphite using a New Long-Range Potential

The cohesive energy and compressibility of strands of a single-wall nanotube rope has been computed using a new long-range potential energy function derived from accurate ab initio quantum chemistry calculations of the benzene dimer and calibrated for energetic and mechanical properties of graphite (at pressures up to 12 GPa). We also use this potential to calculate a variety of properties of carbon nanotubes (both single- and multi-wall) and fullerenes. Extensive comparisons are made with previously published potentials.

Jaffe, Richard↗