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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Free volume model for molecular weights of polymers

A free volume model has been developed for determining molecular weights of linear polymers. It is based on the size of free volume cells in two geometries of poly(arylene ether ketone)s. Free volume cell sizes in test samples were measured using positron lifetime spectroscopy. The molecular weights computed from free volume cell sizes are in good agreement with the values measured by gel permeation chromatography, with a low angle laser light scattering photometer as the detector. The model has been further tested on two atactic polystyrene samples, where it predicted the ratio of their molecular weights with reasonable accuracy.

Singh, J. J.↗
NASA NTRS1993

Warm neutral halos around molecular clouds. V - OH (1665 and 1667 MHz) observations

Ten strip maps of 1665- and 1667-MHz OH emission, traversing the outer boundaries of five molecular clouds, were made. The OH emission is found to be significantly extended relative to CO, from which it inferred that OH is to be found in abundance in the shell of partly atomic, partly molecular gas surrounding the dense molecular clouds. The fractional OH abundance is calculated using existing H I and CO observations, and detailed source models which include a complete chemistry network and a radiative transfer code. It is concluded that the extended OH is formed, not by the exothermic reaction of O with H3(+), but by the endothermic reaction, H(+) + O yields H + O(+).

Wannier, Peter G.↗
NASA NTRS1993

Circumstellar molecular gas of the HH 34 and HH 111 exciting stars

The HH 34 and HH 111 exciting stars, two pre-main-sequence objects which are the sources of highly collimated optical jets, have been observed in the J = 1-0 transition of (C-13)O and in the 2.7 mm continuum using the Owens Valley Radio Observatory Millimeter Interferometer. The high-resolution aperture synthesis maps reveal dense molecular gas concentrations at the positions of both stars. The morphology and kinematics of the bright emission-line cores suggest that the molecular gas is distributed in circumstellar disks, each about 2000 AU in diameter, elongated perpendicular to each system's outflow axis. A fainter component of (C-13)O emission extends along each source's outflow axis. Independent mass determinations based on the dust continuum and molecular line fluxes indicate for HH 34, a disk mass of 0.2 solar mass; and for HH 111, a disk mass of 0.3 solar mass. The inferred circumstellar disks of these two jet sources are significantly more massive than those found associated with T Tauri stars and are therefore among the most massive disks known in association with low-mass pre-main-sequence stars.

Stapelfeldt, Karl R.↗
NASA NTRS1993

Molecular contamination and the calibration of AXAF

By the end of this decade, the two missions comprising the Advanced X-ray Astrophysics Facility (AXAF) will become the X-ray component of NASA's Great Observatories. In order to meet some of the ambitious scientific objectives, the AXAF team plans to calibrate the telescopes and instruments to an accuracy of a few percent. Particulate and molecular contamination potentially limit this precision, because they would likely change between ground calibration and orbital operation. To avoid this requires careful control over procedures affecting the coated optical surfaces, to ensure that neither particulate nor molecular contamination compromise the calibration. In particular, the fractional areal coverage by particulates or condensed droplets must be less than 0.005 projected onto the aperture plane; the thickness of any molecular film must be less than a few tens of angstrom.

Elsner, R. F.↗
NASA NTRS1992

Effects of temperature-dependent molecular absorption coefficients on the thermal infrared remote sensing of the earth surface

The effect of temperature-dependent molecular absorption coefficients on thermal infrared spectral signatures measured from satellite sensors is investigated by comparing results from the atmospheric transmission and radiance codes LOWTRAN and MODTRAN and the accurate multiple scattering radiative transfer model ATRAD for different atmospheric profiles. The sensors considered include the operational NOAA AVHRR and two research instruments planned for NASA's Earth Observing System (EOS): MODIS-N (Moderate Resolution Imaging Spectrometer-Nadir-Mode) and ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer). The difference in band transmittance is as large as 6 percent for some thermal bands within atmospheric windows and more than 30 percent near the edges of these atmospheric windows. The effect of temperature-dependent molecular absorption coefficients on satellite measurements of sea-surface temperature can exceed 0.6 K. Quantitative comparison and factor analysis indicate that more accurate measurements of molecular absorption coefficients and better radiative transfer simulation methods are needed to achieve SST accuracy of 0.3 K, as required for global numerical models of climate, and to develop land-surface temperature algorithms at the 1-K accuracy level.

Wan, Zhengming↗
NASA NTRS1993

Development of a molecular beam technique to study early solar system silicon reactions

Silicon monoxide is one of the major gas phase silicon bearing components observed in astronomical environments. Silicon oxide serves as the major rock forming material for terrestrial and meteoritic bodies. It is known that several gas phase reactions produce mass independent isotopic fractionations which possess the same delta(O-17)/delta(O-18) ratio observed in Allende inclusions. The general symmetry dependence of the chemically produced mass independent isotopic fractionation process suggests that there are several plausible reactions which could occur in the early solar system which may lead to production of the observed meteoritic oxygen isotopic anomalies. An important component in exploring the role of such processes is the need to experimentally determine the isotopic fractionations for specific reactions of relevance to the early solar system. It has already been demonstrated that atomic oxygen reaction with CO, a major nebular oxygen bearing species, produces a large (approximately 90 percent), mass independent isotopic fractionation. The next hurdle regarding assessing the involvement of symmetry dependent isotopic fractionation processes in the pre-solar nebula is to determine isotopic fractionation factors associated with gas phase reactions of metallic oxides. In particular, a reaction such as O + SiO yields SiO2 is a plausible nebular reaction which could produce a delta(O-17) is approximately delta(O-18) fractionation based upon molecular symmetry considerations. While the isotopic fractionations during silicate evaporation and condensation have been determined, there are no isotopic studies of controlled, gas phase nucleation processes. In order to carefully control the reaction kinetics, a molecular beam apparatus has been constructed. This system produces a supersonic, collimated beam of SiO molecules which is reacted with a second beam of oxygen atoms. An important feature of molecular beams is that they operate at sufficiently low pressures and high temperatures in the jet that avalanche nucleation and clustering processes may be avoided.

Dong, Q. W.↗
NASA NTRS1992

Atomic and molecular data for space astronomy - Needs, analysis, and availability; 21st IAU General Assembly, Buenos Aires, Argentina, July 23-Aug. 1, 1991, Selected Papers

The present volume on atomic and molecular spectroscopic data for space astrophysics discusses scientific problems and laboratory data needs associated with the Hubble Space Telescope, atomic data needed for far ultraviolet astronomy with HUT and FUSE and for analysis of EUV and X-ray spectra, and data for observations of interstellar medium with the Hubble Space Telescope. Attention is also given to atomic and molecular data for analysis of IR spectra from ISO and SIRTF, atomic data from the opacity project, sources of atomic spectroscopic data for astrophysics, and summary of current molecular data bases.

Smith, Peter L.↗
NASA NTRS1995

Molecular dynamics simulation of a piston driven shock wave in a hard sphere gas

Molecular dynamics simulation is used to study the piston driven shock wave at Mach 1.5, 3, and 10. A shock tube, whose shape is a circular cylinder, is filled with hard sphere molecules having a Maxwellian thermal velocity distribution and zero mean velocity. The piston moves and a shock wave is generated. All collisions are specular, including those between the molecules and the computational boundaries, so that the shock development is entirely causal, with no imposed statistics. The structure of the generated shock is examined in detail, and the wave speed; profiles of density, velocity, and temperature; and shock thickness are determined. The results are compared with published results of other methods, especially the direct simulation Monte-Carlo method. Property profiles are similar to those generated by direct simulation Monte-Carlo method. The shock wave thicknesses are smaller than the direct simulation Monte-Carlo results, but larger than those of the other methods. Simulation of a shock wave, which is one-dimensional, is a severe test of the molecular dynamics method, which is always three-dimensional. A major challenge of the thesis is to examine the capability of the molecular dynamics methods by choosing a difficult task.

Woo, Myeung-Jouh↗
NASA NTRS1994

Ultraviolet illuminated molecular cloud boundaries: Extended (C II) 158 micrometer emission toward L1630

The construction of a large scale map of the 158 micrometer C+ line toward the L1630/Orion B molecular cloud, covering an approximately 35' by 45' area which includes the NGC 2024 H II region, zeta-Ori, the reflection nebula NGC 2023, and the Horsehead nebula, is reported. Emission in the C II line is very widespread. The line was detected at levels in excess of a few 0.0001 erg/sq cm/s/sr over almost the entire mapped region. Extended emission associated with the NGC 2024 H II region and its envelope accounts for more than half of the C II flux. Over this approximately 1.5 by 2.5 pc region, the amount of gas phase carbon in the form of C+ is comparable to the amount of carbon in CO. This result, together with the C II distribution implies that C II emission arises on the surface of clumps throughout the cloud rather than in a single layer at the H II region boundary. Away from the H II region, most of the C II emission comes from the western edge of the L1630 cloud and probably results from excitation by external OB stars. The overall extent of the C II emission is comparable to that of millimeter molecular lines but the distributions are different in detail. The difference in C II and molecular line distributions, in particular, the larger extent of the C II emission west of NGC 2024 implies large variations in the ratio of the C II and J = 1 towards 0 intensities. Models of photon dominated regions can explain the relation between C II and CO intensities only if the cloud edges and cloud interior are considered separately. A method for using C II and radio continuum emission to characterize the relationship between OB stars and photon dominated regions is proposed.

Jaffe, D. T.↗
NASA NTRS1995

Molecular beam scattering from C-13 enriched Kapton and correlation with the EOIM-3 carousel experiment

Mass spectra of products emerging from identical samples of a C-13-enriched polyimide polymer (chemically equivalent to Kapton) under atomic oxygen bombardment in space and in the laboratory were collected. Reaction products unambiguously detected in space were CO-13, NO, (12)CO2, and (13)CO2. These reaction products and two others, H2O and CO-12, were detected in the laboratory, along with inelastically scattered atomic and molecular oxygen. Qualitative agreement was seen in the mass spectra taken in space and in the laboratory; the agreement may be improved by reducing the fraction of O2 in the laboratory molecular beam. Both laboratory and space data indicated that CO and CO2 products come preferentially from reaction with the imide component of the polymer chain, raising the possibility that the either component may degrade in part by the 'evaporation' of higher molecular weight fragments. Laboratory time-of-flight distributions showed: (1) incomplete energy accommodation of impinging O and O2 species that do not react with the surface; and (2) both hyperthermal and thermal CO and CO2 products, suggesting two distinct reaction mechanisms with the surface.

Minton, Timothy K.↗
NASA NTRS1995

The Wide Field/Planetary Camera 2 (WFPC-2) molecular adsorber

A device has been developed at the Jet Propulsion Laboratory, California Institute of Technology, for the adsorption of contaminants inside a space instrument during flight. The molecular adsorber was developed for use on the Wide Field Planetary Camera 2, and it has been shown to perform at its design specifications in the WFPC-2. The basic principle of the molecular adsorber is a zeolite-coated ceramic honeycomb. The arrangement is efficient for adsorption and also provides the needed rigidity to retain the special zeolite coating during the launch vibrational environment. The adsorber, on other forms, is expected to be useful for all flight instruments sensitive to internal sources of contamination. Typically, some internal contamination is unavoidable. A common design solution is to increase the venting to the exterior. However, for truly sensitive instruments, the external contamination environment is more severe. The molecular adsorber acts as a one-way vent to solve this problem. Continued development is planned for this device.

Barengoltz, Jack↗
NASA NTRS1993

Spectroscopic detection of molecular hydrogen frozen in interstellar ices

A weak infrared absorption feature near 4141 wavenumbers (2.415 micrometers) in the spectrum of WL5, an infrared source in the rho Ophiuchus cloud complex, has been detected. It is attributed to molecular hydrogen created by irradiation and frozen in situ into water-rich ices. A second, broader absorption at 4125 wavenumbers centimeters (2.424 micrometers) is probably due to methanol in the ices. The column densities of frozen molecular hydrogen and methanol are inferred to be about 2.5 x 10(exp 18) and 3.0 x 10(exp 19), respectively. There is about three times more frozen molecular hydrogen than frozen carbon monoxide along this line of sight.

Sandford, Scott A.↗
NASA NTRS1994

Molecular abundances and low-mass star formation. 1: Si- and S-bearing species toward IRAS 16293-2422

Results from millimeter and submillimeter spectral line surveys of the protobinary source Infrared Astronomical Satellite (IRAS) 16293-2422 are presented. Here we outline the abundances of silicon- and sulfur-containing species. A combination of rotation diagram and full statistical equilibrium/radiative transfer calculations is used to constrain the physical conditions toward IRAS 16293 and to construct its beam-averaged chemical composition over a 10 to 20 sec (1600 to 3200 AU) scale. The chemical complexity as judged by species such as SiO, OCS, and H2S, is intermediate between that of dark molecular clouds such as L134N and hot molecular cloud cores such as Orion KL. From the richness of the spectra compared to other young stellar objects of similar luminosity, it is clear that molecular abundances do not scale simply with mass; rather, the chemistry is a strong function of evolutionary state, i.e., age.

Blake, Geoffrey A.↗
NASA NTRS1994

Atomic and molecular gas in interstellar cirrus clouds

The dust, atomic gas, and molecular gas content of a sample of 26 of isolated, degree-sized infrared clouds are compared. Half of the clouds have an infrared excess indicating the presence of H2, and 14 contain compact CO-emitting regions. Complete, high angular resolution H I and CO maps of one cloud, G236+39, resolve the transition between atomic and molecular H, as well as the location of CO formation. Assuming the infrared emission traces the total column density, H2 is inferred to be much more widely distributed than the CO. The CO rotational levels are subthermally excited, and the (2 - 1)/(1 - 0) line ratios suggest a density n(H2) approximately 200/cm(exp 3) where CO was detected. A model of H2 formation on grain surfaces balanced by self-shielded photodissociation fits the variation of infrared brightness with H I column density. Assuming a temperature of 80 K, typical of diffuse H2 (Savage et al. 1977), the H2 chemistry requires an average density n(H + 2H2) approximately 50/cm(exp 3). For G236+39, if the distance is 100 pc, the H I and H2 masses are estimated to be 90 and 70 solar mass, respectively. High-resolution H I and infrared maps of a smaller cloud, G249.0+73.7, reveal no evidence for molecular gas, which is likely due to the low total column density through this cloud. These results suggest the H2 and H I content are comparable for some interstellar cirrus clouds with column densities N(H I) greater than 4 x 10(exp 20)/cm(exp 2), even where CO was not detected.

Reach, William T.↗
NASA NTRS1994

Ultraviolet-illuminated molecular cloud boundaries: Extended (C II) 158 micron emission toward L1630

We have made a large-scale map of the 158 micrometers C(+) line toward the L1630/Orion B molecular cloud. The map covers a approximately 35 min x 45 min area which includes the NGC 2024 H II region, zeta Ori, the reflection nebula NGC 2023, and the Horsehead nebula. Emission in the (C II) line is very widespread. The line was detected at levels in excess of a few 10(exp -4) ergs/sq cm/s/sr over almost the entire mapped region. Extended emission associated with the NGC 2024 H II region and its envelope accounts for more than half of the (C II) flux. Over this approximately 1.5 x 2.5 pc region, the amount of gas-phase carbon in the form of C(+) is comparable to the amount of carbon in CO. This result, together with the (C II) distribution, implies that (C II) emission arises on the surfaces of clumps throughout the cloud rather than in a single layer at the H II region boundary. Away from the H II region, most of the (C II) emission comes from the western edge of the L1630 cloud and probably results from excitation by external OB stars. The overall extent of the (C II) emission is comparable to that of millimeter molecular lines, but the distributions are different in detail. The difference in (C II) and molecular line distributions, in particular, the larger extent of the (C II) emission west of NGC 2024 implies large variations in the radio of the (C II) and CO J = 1 goes to 0 intensities. Models of photon-dominated regions can explain the relation between (C II) and CO intensities only if one considers the cloud edges and cloud interior separately. We propose a method for using (C II) and radio continuum emission to characterize the relationship between OB stars and photon-dominated regions.

Jaffe, D. T.↗
NASA NTRS1994

Anatomy of a Photodissociation Region: High angular resolution images of molecular emission in the Orion Bar

We present observations of the molecular component of the Orion Bar, a prototypical Photodissociation Region (PDR) illuminated by the Trapezium cluster. The high angular resolution (6 sec-10 sec) that we have achieved by combining single-dish and interferometric observations has allowed us to examine in detail the spatial and kinematic morphology of this region and to estimate the physical characteristics of the molecular gas it contains. Our observations indicate that this PDR can be essentially described as a homogeneously distributed slab of moderately dense material (approximately 5 x 10(exp 4)/cu cm), in which are embedded a small number of dense (greater than 10(exp 6)/cu cm) clumps. The latter play little or no role in determining the thickness and kinetic temperature structure of this PDR. This observational picture is largely supported by PDR model calculations for this region, which we describe in detail in this work. We also find our model predictions of the intensities of a variety of atomic and molecular lines to be in good general agreement with a number of previous observations.

Tauber, Jan A.↗
NASA NTRS1995

Gas-phase chemistry in dense interstellar clouds including grain surface molecular depletion and desorption

We present time-dependent models of the chemical evolution of molecular clouds which include depletion of atoms and molecules onto grain surfaces and desorption, as well as gas-phase interactions. We have included three mechanisms to remove species from the grain mantles: thermal evaporation, cosmic-ray-induced heating, and photodesorption. A wide range of parameter space has been explored to examine the abundance of species present both on the grain mantles and in the gas phase as a function of both position in the cloud (visual extinction) and of evolutionary state (time). The dominant mechanism that removes molecules from the grain mantles is cosmic-ray desorption. At times greater than the depletion timescale, the abundances of some simple species agree with abundances observed in the cold dark cloud TMC-1. Even though cosmic-ray desorption preserves the gas-phase chemistry at late times, molecules do show significant depletions from the gas phase. Examination of the dependence of depletion as a function of density shows that when the density increases from 10(exp 3)/cc to 10(exp 5)/cc several species including HCO(+), HCN, and CN show gas-phase abundance reductions of over an order of magnitude. The CO: H2O ratio in the grain mantles for our standard model is on the order of 10:1, in reasonable agreement with observations of nonpolar CO ice features in rho Ophiuchus and Serpens. We have also examined the interdependence of CO depletion with the space density of molecular hydrogen and binding energy to the grain surface. We find that the observed depletion of CO in Taurus in inconsistent with CO bonding in an H2O rich mantle, in agreement with observations. We suggest that if interstellar grains consist of an outer layer of CO ice, then the binding energies for many species to the grain mantle may be lower than commonly used, and a significant portion of molecular material may be maintained in the gas phase.

Bergin, E. A.↗
NASA NTRS1994

The giant molecular cloud Monoceros R2. 1: Shell structure

We have obtained a 45 sec resolution, Nyquist-sampled map in CO J = 1-0 covering approximately a 3 deg x 3 deg region of the giant molecular cloud Monoceros R2. The map consists of 167,000 spectra observed with the 15 element focal-plane array system on the FCRAO 14 m telescope. The data reveal that the large-scale structure of Mon R2 is dominated by a is approximately 30 pc diameter largely hemispherical shell containing approximately 4 x 10(exp 4) solar mass of molecular material and expanding at approximately 3-4 km s(exp -1) with symmetric axis roughly along the line of sight. The dynamical timescale of the shell is estimated to be approximately 4 x 10(exp 6) yr, which is consistent with the age of main-sequence stars powering the clusters of reflection nebulea in this region. There is no evidence for a redshifted shell on the far side of the interior 'bubble,' which is largely devoid of molecular material. Distortions of the shell are obvious, suggesting inhomogeneity of the cloud and possible presence of a magnetic field prior to its formation. Dense clumps in Mon R2, including the main core and the GGD 12-15 core, appear to be condensations located on the large shell. The reflection nebulea with their illuminating stars as well as embedded IRAS sources suggest that triggered star formation has taken place over a large part of the Mon R2 shell.

Xie, Taoling↗