Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “low-temperature”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

On the brittle-ductile behavior of iron meteorites - New experimental constraints

Impact trials were performed at the NASA vertical gun range to study low-temperature brittle-ductile transitions in meteoritic, steel and iron targets. The trials were performed to enhance the data base underlying the concept of formation of planetesimals in collisional coagulation. Impact velocities of 1.6-5.5 km/sec were used, as were temperatures from 100-300 K. Spallation was observed in the tests with meteorite samples, even at room temperature, and brittleness was enhanced at temperature below 200 C. Net mass losses were induced at the higher impact velocities. It is suggested that iron meteorite agglomerations could form in the inner solar region during nebular condensation, but would not form in farther-out regions such as the asteroid belt. The protoplanets could have an iron core, with metallicity decreasing with radius from the core, which may have happened with the earth.

Matsui, T.↗
NASA NTRS1984

Absorption features in the 5-8 micron spectra of protostars

High signal-to-noise ratio spectra in the range of 5-8 microns of four sources embedded in molecular clouds are examined using low-temperature laboratory measurements of the 5-8-micron spectra of simple molecules and their mixtures. The absorption, apparent in all four sources, is characterized by highly distinct features ranging from two relatively narrow bands at 6.0 and 6.8 microns in W33A to a broad, shallow, and partially structured feature extending from 5.2 to 7.8 microns in Mon R2-IRS2, BN, and NGC2264. The first feature (W33A) is explained by the OH bending mode in H2O and the CH deformation modes in saturated hydrocarbons; while the second feature (Mon R2-IRS2-type) is explained by the presence of a mixture of saturated and unsaturated hydrocarbons possibly containing strongly electronegative groups.

Tielens, A. G. G. M.↗
NASA NTRS1983

Calculation of high-pressure phase transitions in solid N2 and the pressure dependence of intramolecular mode frequencies

A calculation that minimizes the energy of solid N2 with respect to a rhombohedral distortion of the Pm 3n structure shows that a low-temperature phase transition occurs into the R 3c calcite structure at P = 19.2 kbar with a volume change of 0.125 cu cm/mole. This transition agrees with recent Raman scattering measurements. Another transition from R 3c into R3(bar)m is predicted at P = 67.5 kbar, with a volume change of 0.1 cu cm/mole. The pressure dependence of the intramolecular mode frequencies for the R 3c structure are in reasonably good agreement with the two main branches observed experimentally.

Chandrasekharan, V.↗
NASA NTRS1985

Strontium and neodymium isotopes in hot springs on the East Pacific Rise and Guaymas Basin

Solutions collected from 21 deg N, East Pacific Rise (Epr) and Guaymas Basin, Gulf of California, are analyzed for Nd isotopic composition and Sm and Nd concentrations. The results indicate extensive but not complete isotopic exchange with Sr in the depleted oceanic crust and that Sr concentrations in these solutions are buffered. In contrast, the Nd data exhibit a wide range in isotopic composition and concentration between vents. Many samples show substantial contributions from MORB, but all have isotopic compositions below MORB, in spite of enrichments in Nd up to 100 times seawater. It is shown that the fluids must exchange Nd with a sedimentary reservoir having an isotopic composition less than Pacific seawater. Low-temperature reactions with metalliferous sediments on the flanks of the EPR may provide such a source. Using a simple box method, estimates of the hydrothermal fluxes of Nd are compared to fluxes which are necessary to maintain a radiogenic isotopic composition of about -3 in the Pacific against the influx of Antarctic waters. It is concluded that erosion from island arcs is the main source of radiogenic Nd in the Pacific.

Piepgras, D. J.↗
NASA NTRS1985

Laboratory simulation of meteoritic noble gases. I - Sorption of xenon on carbon: Trapping experiments

The sorption of Xe-127 at 5 x 10 to the -7th atm onto carbon black, pyrolyzed polyvinylidene chloride, and pyrolyzed acridine at 100-1000 C for 5 min-240 h is measured experimentally by gamma spectrometry. The results are presented in tables and graphs and characterized in detail. The tightly bound Xe remaining in the samples after 4000 min pumping at temperatures above 100 C is found to comprise two components: a low-temperature component attributed to physisorption within an atomic-scale labyrinth of micropores, and a high-temperature component due to volume diffusion. The implications for the trapping of noble gases near grain surfaces of amorphous carbon in meteorites are considered.

Wacker, J. F.↗
NASA NTRS1985

Solution Growth of Crystals in Zero-Gravity

In a low-g environment, buoyancy driven convection effects in solution crystal growth are greatly reduced and, thus, one can study diffusion mass transport which in 1-g is masked by convective phenomena. Crystals of triglycine sulfate (TGS) will be grown aboard the Spacelab 3 mission, using a specially developed Fluids Experiments System (FES). The objectives of the experiment are: (1) to develop a technique for solution crystal growth in a low-g environment, (2) to characterize the growth environment provided by an orbiting spacecraft and to determine the influence of the environment on the growth behavior, and (3) to determine how gravity in a low-gravity environment influences the properties of a resulting TGS crystal. Single crystals of TGS have been grown using conventional low-temperature solution crystal growth method and the growth process has been extensively characterized. Various physical properties of TGS solution have been measured. Also, a unique technique of growing solution growth crystals by extracting heat at a programmed rate from the crystal through a semi-insulating sting has been developed and tested in 1-g environment.

Lal, R. B.↗
NASA NTRS1984

Crystallization of fluorozirconate glasses

The crystallization of a number of glasses of the fluorozirconate family has been studied (using powder X-ray diffraction and DSC) as a function of time and temperature of heating. The main crystalline phases were beta BaZrF6 and beta BaZr2F10. Stable and metastble transformations to the low-temperature alpha phases were also investigated. The size of crystallites in fully devitrified glasses was calculated (from line broadening of the X-ray diffraction peaks) to be about 60 nm.

Bansal, Narottam P.↗
NASA NTRS1983

Low background IR detector and detector array evaluations

A technology program has been underway at Ames since 1978 to develop and evaluate detectors and integrated detector arrays for low-background astronomical applications. The approach is to evaluate existing (less than 24 micron) array technology under low-background conditions, with the aim of adapting and optimizing existing devices. For longer wavelengths, where the technology is much less mature, development is sponsored and devices are evaluated, in both discrete and array formats, for eventual applications. The status of this program has been reported previously. We rely on industrial and university sources for the detectors. Typically, after a brief functionality check in the supplier's laboratory, we work with the device at Ames to characterize its low-background performance. In the case of promising arrays or detectors, we conduct ground-based telescope testing to face the problems associated with real applications. A list of devices tested at Ames is given. In the array category, accumulation-mode charge-injection-devices (AMCIDs) appear repeatedly; this reflects our recent experience with the 2 x 64 and 16 x 16 arrays. Results from the 1 x 16 CID and InSb CCD have been reported. The status of our tests of the discrete Ge:x detectors from Lawrence Berkeley Laboratory are described below. Tests of a 1 x 2 switched sample photoconductor array are just beginning. A 32-channel CMOS multiplexer has been tested at 10 K. Low-temperature silicon MOSFETs and germanium JFETs have also been tested, primarily at Ball Aerospace. This paper describes results to date on three elements of this program: AMCID array, discrete Ge:Ga detectors, and Ge JFET preamplifiers.

Goebel, J. H.↗
NASA NTRS1952

Flame Speeds of Methane-Air, Propane-Air, and Ethylene-Air Mixtures at Low Initial Temperatures

Flame speeds were determined for methane-air, propane-air, and ethylene-air mixtures at -73 C and for methane-air mixtures at -132 C. The data extend the curves of maximum flame speed against initial mixture temperature previously established for the range from room temperature to 344 C. Empirical equations for maximum flame speed u(cm/ sec) as a function of initial mixture temperature T(sub O) were determined to be as follows: for methane, for T(sub O) from 141 to 615 K, u = 8 + 0.000160 T(sub O)(exp 2.11); for propane, for T(sub O) from 200 to 616 K, u = 10 + 0.000342 T(sub O)(exp 2.00); for ethylene, for T(sub O) from 200 to 617 K, u = 10 + 0.00259 T(sub O)(exp 1.74). Relative flame speeds at low initial temperatures were predicted within approximately 20 percent by either the thermal theory as presented by Semenov or by the diffusion theory of Tanford and Pease. The same order was found previously for high initial temperatures. The low-temperature data were also found to extend the linear correlations between maximum flame speed and calculated equilibrium active-radical concentrations, which were established by the previously reported high-temperature data.

Dugger, Gordon L↗
NASA NTRS1951

Ignition-delay Characteristics in Modified Open-cup Apparatus of Several Fuels with Nitric Acid Oxidants Within Temperature Range 70 to 105 Degrees F

Fluid properties and low-temperature ignition delays were obtained for approximately 90 fuel-oxidant combinations. A red fuming nitric acid containing approximately 3 percent water and 19 percent nitrogen tetroxide froze at approximately -87 degrees F and ignited several low-viscosity fuel blends of aromatic amines in triethylamine at -76 degrees F and lower. With this acid, the following average ignition delays were obtained with a blend of 30 percent o-toluidine in triethylamine: ...

FUEL SYSTEMS - ENGINES, ROCKET↗
NASA NTRS1952

Spreading of Exhaust Jet from 16 Inch Ream Jet at Mach Number 2.0 / Fred Wilcox, Donald Pennington

An investigation of the jet-spreading characteristics of a 16 inch ram-jet engine was conducted in the 8 by 6 foot supersonic tunnel at a Mach number of 2.0; both a converging nozzle having a contraction ratio of 0.71 and a cylindrical extension to the combustion chamber were used. The jet boundaries determined by means of pitot pressure surveys were compared with boundaries calculated from one-dimensional continuity and momentum relations. For the cylindrical nozzle, the jet reaches its maximum diameter, 4 percent greater than calculated, about 0.6 nozzle-exit diameter downstream of the nozzle exit. The maximum diameter for the converging nozzle was 7 percent greater than calculated from one dimensional relations and occurred from 1 to 1.5 nozzle-exit diameters downstream of the exit. Non dimensional maximum jet diameters agreed closely with results of an investigation by Rousso and Baughman; these data were obtained with low-temperature jets exhausting into a stream at a Mach number of 1.91 from nozzles having exit diameters of 0.75 inch.

INTERFERENCE, JET-MISSILES↗
NASA NTRS1957

Nonmetallic Material Compatibility with Liquid Fluorine

Static tests were made on the compatibility of liquid fluorine with several nonmetallic materials at -3200 F and at pressures of 0 and 1500 pounds per square inch gage. The results are compared with those from previous work with gaseous fluorine at the same pressures, but at atmospheric temperature. In general, although environmental effects were not always consistent, reactivity was least with the low-temperature, low-pressure liquid fluorine. Reactivity was greatest with the warm, high-pressure gaseous fluorine. None of the liquids and greases tested was found to be entirely suitable for use in fluorine systems. Polytrifluorochloroethylene and N-43, the formula for which is (C4F9)3N, did not react with liquid fluorine at atmospheric pressure or 1500 pounds per square inch gage under static conditions, but they did react when injected into liquid fluorine at 1500 pounds per square inch gage; they also reacted with gaseous fluorine at 1500 pounds per square inch gage. While water did not react with liquid fluorine at 1500 pounds per square inch gage, it is known to react violently with fluorine under other conditions. The pipe-thread lubricant Q-Seal did not react with liquid fluorine, but did react with gaseous fluorine at 1500 pounds per square inch gage. Of the solids, ruby (Al2O3) and Teflon did not react under the test conditions. The results show that the compatibility of fluorine with nonmetals depends on the state of the fluorine and the system design.

Price, Harold G , Jr↗
NASA NTRS1960

Equipment for Thermal-Balance Studies in the Langley Instrument Research Division

The Langley Research Center is in the process of obtaining emissivity measuring apparatus. This apparatus will be used to measure the solar absorptance and low-temperature emittance of space-vehicle materials. Two types of instrumentation will be used. One type will be the total hemispherical emissivity apparatus being constructed at this Center. The other will be double-beam photoelectric ratio-recording spectrophotometer apparatus which is being purchased.

Spiers, Robert B., Jr.↗
NASA NTRS1946

Characteristics of a Hot Jet Discharged from a Jet-Propulsion Engine

An investigation of a heated jet was conducted in conjunction with tests of an axial-flow jet-propulsion engine in the Cleveland altitude wind tunnel. Pressure and temperature surveys were made across the jet 10 and 15 feet behind the jet-nozzle outlet of the engine. Surveys were obtained at pressure altitudes of 10,000, 20,000, 30,000, and 40,000 feet with test-section velocities from 30 to 110 feet per second and test-section temperatures from 60 F to -50 F. From measurements taken throughout the operable range of engine speeds, tail-pipe outlet temperatures from 500 F to 1250 F and jet velocities from 400 to 2200 feet per second were obtained. The jet-survey data presented extend the work previously done with low-velocity and low-temperature jets to the region of high velocities and high temperatures. The results obtained agree with previously determined experimental data and with predicted theoretical expressions for the dimensionless transverse velocity and temperature profiles across a jet. The spread of both the temperature and the velocity profiles was very nearly linear. Dimensionless plots of temperature and velocity along the axis of a heated jet agree with experimental results of tests with a cold jet.

Fleming, William A.↗
NASA NTRS1960

A Solid Film Lubricant Composition for Use at High Sliding Velocities in Liquid Nitrogen

Solid-lubricant-containing compositions can be of value as films and solid bodies for bearing and seal surfaces in low-temperature liquefied gases. An experimental composition including polytetrafluoroethylene (PTFE), an epoxy resin, and lithium-alumina-silicate was studied in friction, wear, and endurance experiments in liquid nitrogen (−320 F). This composition was formulated to approximate the thermal expansion of metals used in cryogenic systems. Hemisphere (3/6-in. radius) rider specimens were used and in most experiments the load was 1000 g. Films (0.005-in. thick) on disk specimens gave good endurance life, low rider wear, and desirable friction (f = 0.02 to 0.07). They functioned at a higher sliding velocity (no failure at 16, 000 ft/min) with copper rider specimens than with stainless steel riders (failure at 9000 ft/min). Solid rider material of the experimental composition had good friction and wear properties at sliding velocities above 4000 ft/min. It is important to use the experimental composition with mating materials having good thermal conductivity.

Wisander, D. W.↗
NASA NTRS2026

Molecular Inventory and Comparative Organic Profiling of A Homogenized Aggregate Sample From Asteroid (101955) Bennu

Evaluating the distribution and diversity of solvent-soluble organic molecules in extraterrestrial materials provide information about the physicochemical environments where prebiotic chemistry occurred and is essential for assessing the inventory of prebiotic compounds available to the early Earth. In this work, we conducted a comprehensive molecular characterization of solvent-soluble organic compounds in a homogenized aggregate sample (ID: OREX-800107-128) of unsorted regolith from asteroid (101955) Bennu returned by NASA’s OSIRIS-REx mission. Using two-dimensional gas chromatography coupled with high-resolution time-of-flight mass spectrometry (GC×GC-HRMS), we identified 87 organic compounds across several molecular classes, including alkanes, polycyclic aromatic hydrocarbons, and nitrogen-, oxygen-, and sulfur-bearing species. Comparison with the organic inventory of CI (Orgueil), C2-ungrouped (Tagish Lake and Tarda), and CM2 (Murchison) carbonaceous chondrites revealed that Bennu sample OREX-800107-128 is most similar to Tagish Lake and Tarda yet compositionally distinct from all of these meteorites. This Bennu sample exhibits a relatively high abundance of low-molecular-weight aromatics (e.g., toluene), pyridine derivatives, and sulfur species such as dimethyl sulfite, consistent with episodic low-temperature aqueous alteration. The presence of these organic compounds suggests that this material experienced chemically diverse processes in the parent body conducive to complex organic synthesis, including aldol condensation reactions responsible for N- and O-bearing compounds. We also compared the molecular distributions of this Bennu sample and previously analyzed samples from (162173) Ryugu to assess potential common origins between these two carbonaceous asteroids. Bennu shows more chemically diverse and nitrogen-rich organic materials than Ryugu. While both asteroids share broadly similar primitive compositions, the observed chemical differences indicate distinct evolutionary histories within a likely common formation environment though whether Bennu and Ryugu derive from a single compositionally heterogeneous parent body or from multiple closely related progenitors remains unresolved. Further detailed comparative analyses of material from Bennu, Ryugu, and specific carbonaceous meteorites (e.g., Tagish Lake and Tarda) will provide new insights into how the N-rich molecular profile observed in Bennu samples was formed and evolved in the outer Solar System.

sample return↗
NASA NTRS2026

A Review of Superconducting Electric Machines with On-Board Cryocoolers

This paper reviews the evolution and emerging direction of superconducting electric machines that employ onboard cryocoolers integrated directly into the rotor, eliminating the need for cryogenic fluid coupling and, in some cases, rotary seals. Traditional low-temperature superconducting (LTS) machines relied on external cryogenic systems and liquid helium transfer couplers, which introduced excessive complexity, poor reliability, and significant parasitic energy losses. The advent of high-temperature superconductors (HTS) has enabled compact, closed-cycle cryocoolers that support self-contained, fluid-free refrigeration architectures suitable for rotating applications. This paper examines the key technological challenges associated with on-board cryocooler integration and reviews three representative efforts by KAIST, NASA, and Hinetics, each illustrating distinct strategies and milestones toward practical implementation. KAIST demonstrated early proof-of-concept for rotating machines with on-board cryocoolers, NASA developed a shaft-integrated Stirling-type pulse tube cryocooler for a 1.4 MW hybrid-electric motor, and Hinetics achieved full-scale validation of a self-contained HTS rotor incorporating a commercial Stirling cryocooler and spoke-suspension torque tube. Collectively, these achievements confirm the technical feasibility of on-board cryogenic refrigeration and highlight steady progress toward compact and efficient superconducting rotating systems across various applications. Embedding cryocoolers directly within the rotor enables practical, efficient, and commercially viable superconducting propulsion technologies.

Cryogenics↗
NASA NTRS2026

List of Commercial and Advanced Developmental Niobium-Based Alloys of the Space Age

This report compiles a list of commercial and developmental niobium-based alloys developed during the Space Age (late 1950s through mid-1970s) for extreme-temperature applications, including rocket engine thrust chambers, hypersonic re-entry thermal protection systems, and space fission reactor loops. Niobium (Nb) was widely pursued because it provided the lowest density (~8.6 g/cc) among the primary refractory metals, a high melting temperature (~2470°C), exceptional low-temperature ductility, good formability, and compatibility with liquid alkali metals. An evaluation of physical metallurgy mechanisms, focusing on solid-solution strengthening via heavy refractory solutes (W, Mo, Ta), dual-purpose reactive solutes (Hf, Zr, Ti), and dispersion strengthening using carbides, nitrides, and oxides is presented. Additionally, the report compares Western and Soviet Union metallurgical approaches, explaining how supply chain factors and manufacturing infrastructure influenced element selection, interstitial chemistry, and alloy identification/naming conventions. Cataloging these historical alloy chemical compositions serves as a foundational reference for modern alloy additive manufacturing, thermodynamic CALPHAD modeling, and machine-learning discovery pipelines for next-generation extreme-environment niobium-based alloys.

Physical Metallurgy↗