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At least 307 records · Page 17

Integrated Monitoring Volume: A Summary of Monitoring Studies Conducted in Niagaran Carbonate Pinnacle Reefs During Enhanced Oil Recovery with CO2

This introductory report to the Integrated Monitoring Volume provides an executive summary style overview of each of the monitoring methods deployed during the MRCSP Phase III Program. Each method is discussed in detail in a separate report that together with this Executive Summary comprise the Integrated Monitoring Volume.

BHG,DAS,Monitoring,PNC,VSP,borehole gravity,distri↗

A Preliminary Feasibility Study on Multi-Cavity Cryomodule Integration for the Electron Ion Collider Energy Recover Linac Cooler

The Electron-Ion Collider (EIC) is a state-of-the-art accelerator designed for collisions between highly polarized electrons and ions. To achieve optimal luminosity, the ion beam is cooled using an electron beam sourced from an energy recovery linac (ERL). In the current ERL baseline design, one BNL type RF cavity is used per cryomodule, leading to spatial and cost challenges. This study examines the feasibility of using more compact PERLE (Powerful Energy Recovery Linac for Experiments) type cavities, which can house multiple cavities within a single cryomodule, by evaluating their Beam Breakup (BBU) instability performance. Higher Order Modes (HOM) parameters were obtained through frequency scaling, assuming constant quality factor Q_L, R/Q, and linearly scaling HOM frequencies. To predict the BBU threshold current and ensure accuracy, two different BBU tracking simulations are used for cross-verification. Although the reduced footprint of PERLE-type cavities is advantageous, maintaining sufficient damping of HOMs remains crucial. Finally, we compare the HOM damping efficiency of both cavity types and suggest a pathway forward.

Deitrick, K.↗

Overview of the New Beam Physics Research at the IOTA/FAST Facility

The Fermilab Accelerator Science and Technology (FAST) facility is dedicated to the exploration of novel concepts in accelerator and beam physics, and the development of a robust workforce, in order to enable and enhance next-generation particle accelerators. FAST comprises a high-brightness superconducting electron linac, and a storage ring, the Integrable Optics Test Accelerator (IOTA). Experiments in the most recent operational run include studies of nonlinear integrable lattices; tracking of single electrons; precise characterization of undulator radiation; studies with low-momentum-compaction lattices; and ultra-wide range beam diagnostics based on Photomultiplier tubes. In the linac, experiments on noise in intense electron bunches were conducted. The IOTA proton injector, currently being commissioned, will enable a diverse program on space-charge-dominated beams. Research areas include non-invasive beam profile monitoring for proton beams; beam dynamics with electron lenses; halo suppression, feedback systems, and electron cooling. In this presentation, we provide an overview of the recent results and highlight future plans together with opportunities for collaboration.

43 PARTICLE ACCELERATORS↗

Idaho National Laboratory Integrated Multisite SSHAC Level 3: Probabilistic Volcanic Hazards Assessment

The Idaho National Laboratory (INL) resides on the eastern Snake River Plain (ESRP), part of the Snake River Plain (SRP) with a complex origin and geologic history of volcanism. Much of the Quaternary (last 2.58 million years) volcanism within 400 km of INL is genetically associated with a major thermal anomaly referred to as the Yellowstone hotspot, which is currently located more than 180 km northeast of INL. Near INL, local volcanic sources include silicic domes near its southern border, and numerous dike-fed basaltic vents of the ESRP, some of which are near or within the INL boundaries. Quantitative probabilistic assessments of screened-in volcanic hazardous phenomena for nine different facility complexes at the INL are presented for a Senior Seismic Hazard Analysis Committee (SSHAC) Level 3 (SL3) study. The comprehensive, integrated multisite SSHAC study consists of a single regional Probabilistic Volcanic Hazards Assessment (PVHA) that pertains to all nine INL facility complexes, with site-specific information developed at each respective area of interest (AOI), referred to as the "INL facility AOI" (Figure ES-1). Hazard products are generated for specified INL facility AOIs for use by multiple stakeholders from different agencies in risk-informed decision-making regarding site selection, operations, and design of nuclear facilities at INL, consistent with U.S. Department of Energy (DOE) and U.S. Nuclear Regulatory Commission (NRC) regulatory guidance. The study also serves as the basis for future periodic safety assessments required for existing DOE facilities, such as 10-year evaluations of natural-phenomena hazards. Elements of the INL PVHA including initial characterization, screening, quantitative assessments of eruption and hazard potential, and consideration of facility needs are conducted using the three phases of the SSHAC process: evaluation, integration, and documentation. As per regulatory guidance, the SSHAC framework provided the necessary processes and procedures for the PVHA Technical Integration (TI) team, at three workshops, five formal working meetings and many TI team remote meetings, to conduct initial characterization, screen the volcanic hazards, create PVHA model inputs, exercise those models in the PVHA, consider facility-specific volcanic hazard needs, and perform final hazard calculations. The Participatory Peer Review Panel (PPRP) provided independent oversight and performed process and technical reviews of the PVHA throughout its duration. The study included an extensive New Data Collection and Analyses (NDCA) program developed by the PVHA TI team to reduce uncertainties in hazard-significant elements in the PVHA model. NDCA activities generated 20 reports providing important contributory datasets and results to the project database for characterizing the ESRP. For example, a report compiling the dimensions of ESRP shield volcanoes and lava fields was used to construct volcanic footprints (areas of impact), was compared with data from INL subsurface cores, and was used to validate the results of lava-flow inundation modeling on the contemporary terrain. Another example is the acquisition of aeromagnetic data over INL and its surrounding area, with maps of buried magmatic features (e.g., subsurface volcanoes and swarms of feeder dikes) that informed the PVHA conceptual model of volcanism. The SSHAC evaluation process was used to conduct all elements of the PVHA including initial characterization and screening. Existing data and NDCA activities provided the foundation to develop the tectonomagmatic conceptual model of volcanism for the region of geographical interest in the SRP and Yellowstone hotspot volcanic system, and for considering volcanoes in the western US. Considering Quaternary volcanic sources active during this period, the screening approach identified and evaluated magma compositions, types of eruptive and intrusive phenomena, types of hazardous phenomena, and proximity of sources to INL. The PVHA TI team evaluated 18 types of magmatic sources in terms of 20 potentially hazardous phenomena, resulting in 360 screening decisions. The screening process resulted in 140 screened-in hazardous volcanic phenomena for Quaternary volcanic sources 1) proximal to INL facility complexes in the ESRP (64 basaltic and 54 silicic), 2) regional sources associated with the Yellowstone caldera system and Blackfoot Reservoir volcanic field (7), and 3) more distal sources from thirteen Cascade volcanoes and two volcanoes at Long Valley caldera (CA).

58 GEOSCIENCES↗

Radiation-Enhanced Anion Transport in Hematite

The influence of radiation-induced (1 MeV energy H+ to ~0.1 dpa at 450°C), non-equilibrium point defect populations on mass transport is studied with an integrated campaign of experimental and theoretical methods. Using epitaxial thin films of hematite with embedded 18O tracer layers and nanoscale atom probe tomography measurements, it is shown that anion self-diffusion is enhanced by at least 2 orders of magnitude under irradiation compared to thermal diffusion alone. Complementary scanning transmission electron microscopy of vacuum annealed specimens, reveals associated microstructural changes in the oxide films, including local phase transformation to Fe3O4 and the development of nanoscale voids from vacancy coalescence. Point defect formation and migration energies were computed from density functional theory and applied within the context of chemical rate theory to analyze contributions from both interstitial and vacancy mechanisms to self-diffusion in thermal and irradiation conditions. Comparisons are made between calculated, literature and newly measured self-diffusion values, revealing good agreement on the magnitude of radiation-enhanced anion diffusion. Further, the model suggests a transition from vacancy to interstitialcy mechanisms at low temperatures and high oxygen activity, consistent with the varied activation energies reported from prior studies.

iron oxides, isotopic tracers, atom probe tomograp↗

Integrated U.S. nationwide corridor charging infrastructure planning for mass electrification of inter-city trips

This study introduces an integrated modeling framework to evaluate long-term national corridor charging infrastructure requirements in the United States to support the growing inter-city charging demand with the rapid growth in the battery electric vehicle (BEV) market. The core model is an optimization model that considers spatial and temporal dimensions and models heterogeneous behaviors between travelers. The model also introduces the travelers’ inconvenience cost function by linking travelers’ acceptance of the charging infrastructure with exogenous technology and social factors. The inconvenience cost function simulates mode choice between BEVs and alternative modes by heterogenous travelers. We applied the framework to assess the inter-regional charging infrastructure requirements for the entire U.S. mainland interstate highway network. We evaluated impacts on the infrastructure design and its public acceptance with changes in policy, technology, and demographic characteristics, and we also quantified the importance of modeling full-scale inter-regional charging infrastructure requirements compared to the conventional regional level analyses.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Doping Effects on Multivalence States, Electronic Structure, and Optical Band Gap in LaCrO 3 under Varied Atmospheres: An Integrated Experimental and Density Functional Theory Study

Doping effects on the valence state, electronic structure, and optical band and the effects on electrical conductivity were studied on the doped lanthanum chromite (LaCrO 3 ) system. The specific compositions studied were La 1–x Ca x CrO 3 (LCCx), La 1–x Sr x CrO 3 (LSCx), and La 0.8 Sr 0.2 Cr 1–x Mn x O 3 (LSCMx) (0.1 ≤ x ≤ 0.4). The powders were synthesized using a modified Pechini sol–gel method, and the ceramic samples were densified using a reactive sintering method resulting in densities >96% theoretical. X-ray photoelectron spectroscopy (XPS) was completed to characterize the defect states and cationic valence compensation as a result of divalent (Ca 2+ or Sr 2+ ) and trivalent (Mn 3+ ) substitutions. XPS was completed for samples tested in oxidizing and reducing atmospheres (up to 1500 °C), which provided insights into the oxidation state transitions induced by the Ca 2+ and Sr 2+ dopants. The work notably demonstrated, for the first time, the oxidation/reduction transitions of Cr 4+ to Cr 3+ in Sr 2+ /Mn 3+ co-doped samples under reducing atmospheres. Reflectance UV–vis spectrophotometry optical band gap measurements were also completed for the same materials; a decrease in the optical band gap (2.81–3.12 eV) was shown with increased substitution, suggesting electronic structure modifications in the LaCrO 3 perovskite. Density functional theory calculations validated experimental trends, predicting a diminishing band gap with a rising dopant concentration. The transition in Cr oxidation states was attributed to the presence of divalent/trivalent cations. These findings contribute some insights into methods to tune the LaCrO 3 electrical properties for various low- and high-temperature applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reliable, High Power Density Inverters for Heavy Equipment Applications

With this final report, the combined team of the University of Arkansas (UA), University of Illinois, Urbana-Champaign (UIUC), Wolfspeed, Caterpillar, and Ampaire have successfully met all of their project objectives. Noteworthy for the heavy equipment portion of the project with Caterpillar is that the team made its project milestones two years into the project by designing a power dense motor drive for a permanent magnet synchronous machine. Upon finding out that Caterpillar had pivoted to switched-reluctance machines (SRMs), the team subsequently redesigned and implemented the SRM drive with a coolant temperature of 105°C! The other major task that the UA, UIUC, and Wolfspeed teams took on was the design of a PMSM drive for a hybrid aircraft that was flown on Feb. 20, 2023 by Ampaire after extensive testing and evaluation. While there were also technical objectives in thermal management, integrated gate drivers, reliability studies, and high temperature capacitors with integrated bussing, each of these have been fully reported on in quarterly reports. In brief, advances in thermal management and high temperature capacitors were utilized in order to achieve a 105°C motor drive. The integrated gate driver work resulted in a higher density drive with no loss of efficiency. Most of the last year, during a no-cost extension, was spent waiting for the Ampaire motor drive to be tested (outside of our project). Many months passed with the device just sitting in California while the company dealt with battery-related issues. This delayed the integration and testing activities until Fall 2022. Once those began, then the process took about 4-5 months to complete culminating in the test flight in Feb. 2023. By providing technical advances and integration into final platforms, the barrier to economic impact has been lowered. This project benefits the public by overcoming key technical barriers to electrified and hybrid electric heavy equipment and aircraft. This, in turn, leads to lower greenhouse gas emissions and a cleaner environment. This final report summarizes the integrated gate driver work and the Ampaire hybrid electric aircraft integration and test flight efforts. All other information has been previously reported in quarterly reports. A summary of the motor drives created during this project is provided along with a listing of publications.

42 ENGINEERING↗

Sustainable Materials Selection in Manufactured Products: A Framework for Design-Integrated Life Cycle Thinking with Case Studies

Materials selection can provide a major opportunity to improve the environmental performance of manufactured products. Substitution of conventional materials with eco-friendly options can lower a product's environmental impact while still meeting key application requirements. A prerequisite for sustainability-informed decision-making is that relevant data and information are available for all materials being considered. Here we outline examples of the types and sources of data needed; and we explore key considerations for sustainable materials selection through a series of practical, cross-sectoral case studies.

36 MATERIALS SCIENCE↗

Fermions at finite density in the path integral approach

Abstract We study relativistic fermionic systems in 3 + 1 spacetime dimensions at finite chemical potential and zero temperature, from a path-integral point of view. We show how to properly account for theiεterm that projects on the finite density ground state, and compute the path integral analytically for free fermions in homogeneous external backgrounds, using complex analysis techniques. As an application, we show that the U(1) symmetry is always linearly realized for free fermions at finite charge density, differently from scalars. We study various aspects of finite density QED in a homogeneous magnetic background. We compute the free energy density, non-perturbatively in the electromagnetic coupling and the external magnetic field, obtaining the finite density generalization of classic results of Euler-Heisenberg and Schwinger. We also obtain analytically the magnetic susceptibility of a relativistic Fermi gas at finite density, reproducing the de Haas-van Alphen effect. Finally, we consider a (generalized) Gross-Neveu model forNinteracting fermions at finite density. We compute its non-perturbative effective potential in the large-Nlimit, and discuss the fate of the U(1) vector and$$ {\mathbb{Z}}_2^A $$ ℤ 2 A axial symmetries.

Physics↗

Summary of Consolidated Interim Storage Advantages and Disadvantages from an Integrated Systems Perspective from Prior Reports and Studies

The question of whether centralized storage of civilian spent nuclear fuel (SNF) should be part of the federal waste management system as an intermediate step before permanent disposal has been debated for more than four decades. Centralized storage facilities were included as a potential component of the U.S. spent fuel management system in the Nuclear Waste Policy Act of 1982 (NWPA), but these facilities were not identified as being essential. When the NWPA was passed, it was expected that a permanent repository would be available around the turn of the century to meet the commitments that were made to start accepting waste by that time. For a number of reasons, a permanent repository was not available at that stage. This report summarizes the advantages and disadvantages of including an ISF as part of an integrated waste management system that have been identified in numerous analyses of the impacts of a consolidated interim storage facility (ISF), previously discussed as monitored retrievable storage, the form of ISF authorized in the NWPA) by the U.S. Department of Energy (DOE) and independent groups. Storing SNF before disposal is a functional requirement for an integrated waste management system. As described below, the studies reviewed in this report have identified a range of benefits that could be obtained by adding a consolidated ISF to the waste management system, including (1) earlier acceptance of fuel by the federal government, (2) reduction in the number of unintended long-term storage sites, (3) added system flexibility and opportunity for better integration, and (4) near-term development and demonstration of institutional and technical infrastructures for large-scale management of SNF. At the same time, these studies have identified potential drawbacks to deployment of an ISF, including (1) potential adverse impacts on development of a repository, (2) additional transportation of SNF, and (3) a large upfront economic investment to establish the consolidated storage capability. In general, the studies that have considered the positive and negative impacts of consolidated storage most comprehensively have concluded that in light of these considerations, the benefits of including an ISF as part of an integrated waste management system can outweigh any real or perceived disadvantages.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Multi-scale computer-aided design and photo-controlled macromolecular synthesis boosting uranium harvesting from seawater

By integrating multi-scale computational simulation with photo-regulated macromolecular synthesis, this study presents a new paradigm for smart design while customizing polymeric adsorbents for uranium harvesting from seawater. A dissipative particle dynamics (DPD) approach, combined with a molecular dynamics (MD) study, is performed to simulate the conformational dynamics and adsorption process of a model uranium grabber, i.e., PAO m -b-PPEGMA n , suggesting that the maximum adsorption capacity with atomic economy can be achieved with a preferred block ratio of 0.18. The designed polymers are synthesized using the PET-RAFT polymerization in a microfluidic platform, exhibiting a record high adsorption capacity of uranium (11.4 ± 1.2 mg/g) in real seawater within 28 days. This study offers an integrated perspective to quantitatively assess adsorption phenomena of polymers, bridging metal-ligand interactions at the molecular level with their spatial conformations at the mesoscopic level. The established protocol is generally adaptable for target-oriented development of more advanced polymers for broadened applications.

97 MATHEMATICS AND COMPUTING↗

FINAL TECHNICAL AND ECONOMIC FEASIBILITY STUDY ON THE APPLICATION OF A HEAT INTEGRATED POST-COMBUSTION CO2 CAPTURE SYSTEM WITH HITACHI ADVANCED SOLVENT INTO EXISTING COAL-FIRED POWER PLANT

This report contains the results of a techno-economic assessment (TEA) conducted of a heat integrated post-combustion CO2 capture process with Hitachi advanced solvent for retrofit into an existing coal-fired power plant (but treated as greenfield plant on cost analysis). The process has been developed by the University of Kentucky Center for Applied Energy (UK CAER). EPRI was chiefly responsible for this analysis, with significant input from WorleyParsons, Hitachi Power Systems America (Hitachi) and UK CAER. The project also involves the design, fabrication, installation, testing, and analyses of a slipstream facility located at L&GE-KU’s E.W. Brown Generating Station to demonstrate the UK CAER carbon capture system that could utilize heat integration with the main power plant. The design, start-up, and baseline of the pilot system was performed with a generic 30 wt% MEA solvent to obtain data for direct comparison with the DOE/NETL Reference Case followed by testing Hitachi’s proprietary solvent H3-1. In this techno-economic analysis, two cases utilizing the UK CAER process are compared, using different approach temperatures and solvent, against the DOE/NETL Reference Case (Case 10). The results are shown comparing the energy demand for post-combustion CO2 capture and the net higher heating value (HHV) efficiency of the power plant integrated with the post-combustion capture (PCC) plant. A levelized cost of electricity (LCOE) assessment was performed showing the costs of the options presented in the study. The key factors contributing to the reduction of LCOE were identified as CO2 partial pressure increase at the flue gas inlet, thermal integration of the process, and performance of the Hitachi H3-1 solvent. Recent UK CAER process pilot-scale testing data and process simualtion data showed that the packing heights of absorber and stripper columns were significantly oversized in the prelimanary TEA (Task 2 of this project) and thus updated in this final TEA for the H3-1 case only. In addition, the solvent make-up cost for H3-1 was updated based on lattest test results. Finally, a heat integration with the main power plant was applied in this final TEA to increase overall energy effciency for both the MEA and H3-1 cases. Additonal reductions in capital and operational costs are expected but not taken into account here. Shorter columns result in reduced pressure drops, smaller blower head and pump hydraulic head requirements. An increase in overall energy efficiency resuls in a decreased size of the power plant, the CCS and a reduced parasitic steam requirement to the CCS. The net efficiency of the UK CAER integrated PC power plant with CO2 capture changes from 26.2% for the Reference Case 10 plant in 2010 revised DOE/NETL baseline report to 27.6% for the MEA options considered, and 29.1% for the options utilizing the Hitachi advanced solvent. The UK CAER Process + Hitachi case also produces an extra 30.9 MW of generation compared to the UK CAER Process + MEA case and total 60.9 MW more than DOE Case 10. LCOE ($/MWh) values are $172.08/MWh for the MEA option and $157.65/MWh for the Hitachi H3-1 solvent cases considered in comparison to $189.59/MWh in January 2012 dollar for the Reference Case 10. The UK CAER CCS process with MEA case lowers energy consumption for CO2 capture to 1340 Btu/lb-CO2 captured as compared to 1540 Btu/lb-CO2 in the Reference Case 10. The UK CAER CCS process with H3-1 case further lowers energy consumption for CO2 capture to 973 Btu/lb-CO2 captured, for an advantage of 36.8% less energy consumption than Case 10. The study also shows 38.1% less heat rejection associated with the carbon capture system from 3398 MBtu/hr (Case 10) to 2104 MBtu/hr for the UK CAER + MEA system. Heat rejection is reduced to 2464 MBtu/hr in the UK CAER + H3-1 case, for a 27.5 % decrease compared to Case 10. Modeling outputs show that in the UK CAER process, the cooling water that is 2-5°C cooler than conventional cooling tower water can be achieved for ambient conditions common to the midwest and other regions. The results from the techno-economic assessment show that the proposed technology can be investigated further as a viable alternative to conventional CO2 capture technology. The evaluation also shows the effect of the critical parameters on the LCOE, with the main variables being the approach temperature and CO2 partial pressure increase at the flue gas inlet. A summary of the key advantages of the UK CAER Process + H3-1 case for LCOE and other economic factors compared to the DOE Case 10 is as follows: • A lower variable operating cost by $1.56/MWh ($1.08MWh less than the UK CAER Process + MEA Case), a 11.7% reduction compared to the DOE Case 10 • A lower COE by $25.32MWh ($13.94/MWh lower than the UK CAER Process + MEA Case), a 16.9% reduction compared to the DOE Case 10 • A lower LCOE by $31.94/MWh ($17.51/MWh lower than the UK CAER Process + MEA Case), a 16.9% reduction compared to the DOE Case 10 • A lower cost of CO2 captured by $18.65/tonne CO2 ($9.44/tonne CO2 lower than the UK CAER Process + MEA Case), a 30.4% reduction compared to the DOE Case 10 • A lower cost of CO2 avoided by $34.95/tonne CO2 ($18.53 tonne CO2 lower than the UK CAER Process + MEA Case), a 38.7% reduction compared to the DOE Case 10

Bhown, Abhoyjit S.↗

Optimal Energy Storage System and Smart Switch Placement in Dynamic Microgrids With Applications to Marine Energy Integration

Here this paper studies a dynamic microgrid (DMG) planning problem that places energy storage systems (ESSs) and smart switches (SSWs) optimally in the system. We apply the proposed methodology to applications concerning marine renewable energy (MRE). MRE is an emerging clean energy resource with enormous capacity but volatile and intermittent energy output profiles. Innovative grid-integration technologies designed to enhance the reliability of an MRE-integrated system are needed. However, there are still limited studies in this regard. Existing works have shown the promising prospect of using a dynamic microgrid (DMG) operational concept to accommodate renewable resources in distribution systems, but they usually assume fixed ESS and SSW installations. To further improve the operational flexibility of DMGs, we propose a DMG planning methodology that optimally places ESSs and SSWs so that a DMG with MRE is warranted with proper resource adequacy and topological flexibility in both the contingency and normal operations. We use realistic case studies based on a real-world distribution network and the U.S. Department of Energy's MRE dataset to verify the value and validity of the proposed work.

25 ENERGY STORAGE↗