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At least 307 records · Page 17

Site-specific Design Case Study for Wet Waste Hydrothermal Liquefaction and Biocrude Upgrading to Hydrocarbon Fuels

Hydrothermal liquefaction (HTL) is a thermal process that converts wet biomass to renewable hydrocarbon fuel blendstocks (i.e., renewable naphtha, renewable diesel, and sustainable aviation fuel (SAF)). It can utilize a wide range of pure and blended wet feedstocks, including sewage sludge from water resource recovery facilities (WRRF), food and agriculture wastes, algae, fats, oils and greases (FOG) and blends of dry and wet wastes/feedstocks. Historically, techno-economic analysis (TEA) and annual state of technology (SOT) assessments with standard economic assumptions used by the Bioenergy Technologies Office (BETO) were conducted for the wet waste HTL pathway leveraging experimental data collected from Pacific Northwest National Laboratory’s (PNNL) continuous flow reactor systems. The objective of the SOT assessment has been to guide and track progress of BETO’s HTL research and development (R&D) toward reduced cost and greenhouse gas (GHG) emissions for the pathway. However, gaps exist between BETO’s traditional SOT updates and the needs of key external stakeholders that – if addressed – will accelerate technology adoption. This Business Case Study aims to bridge this gap by providing an updated design, TEA, and LCA based on PNNL’s FY23 R&D with added analyses and information that provide enhanced relevance for stakeholders of the HTL technology. This includes specific siting, regional wet waste resource inventory and transportation cost analyses, fuel market information, sustainable fuel policy impacts, economic metrics of net present value (NPV) and internal rate of return (IRR), greenhouse gas (GHG) emissions analysis, and statistical analysis of cost and technical uncertainties of the HTL plant design. The study focuses on the “Detroit combined statistical area (CSA)” region for siting of a wet waste HTL plant adjacent to the Great Lakes Water Authority (GLWA) facility with guidance from industry participants. Regional resource and siting analyses were conducted to identify feedstock availability, scale, and cost, as well as a beneficial site location. TEA with detailed rigorous capital cost estimation for the specific site application was conducted to evaluate the key economic metrics of most value to industrial partners. These include total capital investment, operating costs, minimum fuel selling price (MFSP) of the biocrude and fuel blendstock, and NPV and internal rate of return IRR with sustainable fuel credits. Life cycle analysis was conducted to evaluate the supply chain greenhouse gas (GHG) emissions for the wet waste HTL process as compared with petroleum derived diesel. This study is also informed by years of R&D and process de-risking learnings and was conducted with a basic engineering HTL plant design and costing that akin to a “first-of-a-kind” plant economics. This differs from our conventional “nth plant ” SOT assessments. Specifically, the HTL process model has been updated with more operationally reliable methods for feed heating and phase separations. Further, we have implemented additional spare equipment for redundancy, a more rigorous installed equipment cost estimation approach, and additional costs associated with feed formatting and delivery, building, piping and site development. An Excel-based cost sheet based on the basic engineering design is also released alongside the report that allows users to conduct customized TEA with their own feed composition and financial assumptions.

09 BIOMASS FUELS↗

2023 Business Case Study: Hydrothermal Liquefaction of Algal Bloom Biomass

A business case study was developed for the fiscal year (FY) 2023 to explore the technical and economic feasibility of converting lake-harvested algal bloom biomass (ABB) into biofuel via hydrothermal liquefaction (HTL). The case study includes reporting on the experimental demonstration of converting the algal feedstock to HTL biocrude. Using the experimental data, a preliminary techno-economic assessment (TEA) of a commercial-scale facility was completed to determine the economic feasibility of the process.

09 BIOMASS FUELS↗

2024 Case Study: Hydrothermal Liquefaction of Biomass Sources at a Wastewater Treatment Facility

A case study was developed for the fiscal year 2024 to examine the potential of wastewater-grown microalgae as a feedstock for hydrothermal liquefaction (HTL) to produce fuels and other products. In this year’s case study, scenarios are investigated in which the algae cultivation process is placed at different points within the water resource recovery facility (WRRF). Additionally, the supply of biomass for HTL is boosted by blending with wastewater solids collected at different locations within the WRRF.

09 BIOMASS FUELS↗

Whole Algae Hydrothermal Liquefaction and Upgrading: A review of progress and challenges and insight into the future

This report summarizes the research at Pacific Northwest National Laboratory (PNNL) to evaluate the economic viability and environmental impact of using microalgae to produce fuels and other products via hydrothermal liquefaction (HTL). Over the past several years, PNNL has examined key aspects of feedstock cost and availability, formatting and conversion techniques, and the utilization of all HTL products. Investigations of feedstock cost led to opportunities to work with cost-advantaged algal feedstocks that can be provided at minimal cost for HTL processing. Cost-advantaged algae include wastewater-grown algae and harvested algal blooms. Although farm-cultivated algae offer the best possible biomass composition and scalability for HTL processing, the cost of the feedstock is too high to yield an economically competitive biofuel. Processing cost-advantaged feedstocks creates other unique challenges in adapting HTL to upgrade biomass with higher than typical ash content and less preferred composition (low lipid). Despite the challenges, HTL of cost-advantaged algae results in economically competitive pricing scenarios and significant advantages in reducing net emissions below 70% of the petroleum baseline. The utilization of a variety of potential non-fuel products from algal HTL, such as the use of HTL solids as a cement additive, provides a significant reduction in net emissions by offsetting emissions from other carbon-intense products. This report presents an analysis of the research conducted at PNNL to develop an economically and environmentally beneficial process for algae HTL.

09 BIOMASS FUELS↗

Algae Hydrothermal Liquefaction: End-of-Project Report

This document is a close-out report for two Pacific Northwest National Laboratory (PNNL) projects funded by the Alternative Fuels and Feedstocks Office (formerly the Bioenergy Technologies Office) of the Department of Energy (DOE). The two projects are: • Thermochemical Interface (DOE ref. no. 1.3.4.101, PNNL ref. no. 64490) • HTL Model Development (DOE ref. no. 1.3.5.202, PNNL ref. no. 71612) At the end of fiscal year 2025, both projects ended. Additional activities related to the topics of algae, hydrothermal liquefaction (HTL), and the techno-economic assessment of HTL of algal feedstocks will be studied in other projects. Key technical findings of the projects were published in early 2025 and highlights will be summarized in this document. A summary of recent technical findings from 2025 are also included herein. This close-out report summarizes key outcomes from both projects highlighting the value and technical impact achieved.

09 BIOMASS FUELS↗

Supporting data for Site-specific Design Case Study for Wet Waste Hydrothermal Liquefaction and Biocrude Upgrading to Hydrocarbon Fuels

Hydrothermal liquefaction (HTL) is a thermal process that converts wet biomass to renewable hydrocarbon fuel blendstocks (i.e., renewable naphtha, renewable diesel, and sustainable aviation fuel (SAF)). It can utilize a wide range of pure and blended wet feedstocks, including sewage sludge from water resource recovery facilities (WRRF), food and agriculture wastes, algae, fats, oils and greases (FOG) and blends of dry and wet wastes/feedstocks. Historically, techno-economic analysis (TEA) and annual state of technology (SOT) assessments with standard economic assumptions used by the Bioenergy Technologies Office (BETO) were conducted for the wet waste HTL pathway leveraging experimental data collected from Pacific Northwest National Laboratory’s (PNNL) continuous flow reactor systems. The objective of the SOT assessment has been to guide and track progress of BETO’s HTL research and development (R&D) toward reduced cost and greenhouse gas (GHG) emissions for the pathway. However, gaps exist between BETO’s traditional SOT updates and the needs of key external stakeholders that – if addressed – will accelerate technology adoption. This Business Case Study aims to bridge this gap by providing an updated design, TEA, and LCA based on PNNL’s FY23 R&D with added analyses and information that provide enhanced relevance for stakeholders of the HTL technology. This includes specific siting, regional wet waste resource inventory and transportation cost analyses, fuel market information, sustainable fuel policy impacts, economic metrics of net present value (NPV) and internal rate of return (IRR), greenhouse gas (GHG) emissions analysis, and statistical analysis of cost and technical uncertainties of the HTL plant design. The study focuses on the “Detroit combined statistical area (CSA)” region for siting of a wet waste HTL plant adjacent to the Great Lakes Water Authority (GLWA) facility with guidance from industry participants. Regional resource and siting analyses were conducted to identify feedstock availability, scale, and cost, as well as a beneficial site location. TEA with detailed rigorous capital cost estimation for the specific site application was conducted to evaluate the key economic metrics of most value to industrial partners. These include total capital investment, operating costs, minimum fuel selling price (MFSP) of the biocrude and fuel blendstock, and NPV and internal rate of return IRR with sustainable fuel credits. Life cycle analysis was conducted to evaluate the supply chain greenhouse gas (GHG) emissions for the wet waste HTL process as compared with petroleum derived diesel. This study is also informed by years of R&D and process de-risking learnings and was conducted with a basic engineering HTL plant design and costing that akin to a “first-of-a-kind” plant economics. This differs from our conventional “nth plant ” SOT assessments. Specifically, the HTL process model has been updated with more operationally reliable methods for feed heating and phase separations. Further, we have implemented additional spare equipment for redundancy, a more rigorous installed equipment cost estimation approach, and additional costs associated with feed formatting and delivery, building, piping and site development. An Excel-based cost sheet based on the basic engineering design is also released alongside the report that allows users to conduct customized TEA with their own feed composition and financial assumptions.

Li, Shuyun↗

Chemical Free Two-Step Hydrothermal Pretreatment to Improve Sugar Yields from Energy Cane

Energy cane is an attractive lignocellulosic feedstock for processing into biofuels and bioproducts. A low-severity two-step hydrothermal pretreatment was investigated on energy cane for the production of monomeric sugar. Pretreatment temperature and time, in addition to the effect of disk milling, were observed for the glucose and xylose yields during hydrolysis. At residence times above 5 min in case of pretreatment at 200 °C, all of the hemicellulose was observed to be solubilized. The pretreatment condition of 200 °C for 10 min with disk milling was observed to provide the highest glucose concentration of 5.4%, and 200 °C for 5 min with disk milling provided the highest xylose concentration of 2.15%. The effect of disk milling in improving the sugar concentrations during hydrolysis was significant, especially at lower pretreatment temperatures and times. Low xylose yields at higher temperatures were attributed to the formation of degradation products at increased severity.

09 BIOMASS FUELS↗

Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate

The relevance of multidimensional and porous crystalline materials to nuclear waste remediation and storage applications has motivated exploratory research focused on materials discovery of compounds, such as actinide mixed-oxoanion phases, which exhibit rich structural chemistry. The novel phase K1.8Na1.2[(UO2)BSi4O12] has been synthesized using hydrothermal methods, representing the first example of a uranyl borosilicate. The three-dimensional structure crystallizes in the orthorhombic space group Cmce with lattice parameters a = 15.5471(19) Å, b = 14.3403(17) Å, c = 11.7315(15) Å, and V = 2615.5(6) Å3, and is composed of UO6 octahedra linked by [BSi4O12]5− chains to form a [(UO2)BSi4O12]3− framework. The synthesis method, structure, results of Raman, IR, and X-ray absorption spectroscopy, and thermal stability are discussed.

Pace, Kristen A. (ORCID:0000000185748939)↗

Simultaneous Electrospinning and Electrospraying for the Preparation of a Precursor Membrane Containing Hydrothermally Generated Biochar Particles to Produce the Value-Added Product of Carbon Nanofibrous Felt

Biochar is a byproduct generated from the hydrothermal liquefaction of biomass, such as corn stover, in an anaerobic environment. This work aims to convert biochar into a value-added product of carbon nanofibrous felt. First, the biochar-containing precursor membrane was prepared from simultaneous electrospinning and electrospraying. After thermal stabilization in air and carbonization in argon, the obtained precursor membrane was converted into a mechanically flexible and robust carbon nanofibrous felt. Electrochemical results revealed that the biochar-derived carbon nanofibrous felt might be a good candidate as a supercapacitor electrode with a good rate capability and high kinetic performance.

25 ENERGY STORAGE↗

Organic inclusions within hydrothermal minerals from S.W. Africa and elsewhere.

It was observed that quartz crystals from veins within a diabase dike of precambrian age from S.W. Africa contain organic particles which closely resemble, in detailed morphology, coacervates, proteinoid microspheres or fossil and recent microorganisms. The microphotospectrographs in visible and near-ultraviolet light of these minute particles revealed a strong absorption peak at the vicinity of 4000 A, which is indicative of lipids. Hydrothermal mineral from veins from a number of other localities proved to contain the biomorphic organic particles. The theoretical significance of these organic particles is discussed with reference to problems of origin of life.

Mueller, G.↗

Mapping of hydrothermal alternation zones and regional rock types using computer enhanced ERTS MSS images

A combination of digital computer processing and color compositing of ERTS MSS images has been used to map hydrothermal alternation zones and regional rock types in south-central Nevada. The technique is based on enhancement of subtle visible and near infrared reflectivity differences between mineralogically dissimilar rocks, especially unaltered and altered rocks. MSS spectral bands are ratioed, pixel by pixel, in the computer and subsequently stretched. These ratio values are used to produce a new black and white image which shows the subtle spectral reflectivity differences. Additional enhancement is achieved by preparing color composites of two or more stretched ratio images. The choice of MSS bands for rationing depends on the spectral reflectance properties of the rocks to be discriminated. Although this technique is in the initial stage of development and is untested in other areas, it already appears to have considerable potential for targeting mineral prospects and for regional geologic mapping.

Rowan, L. C.↗

Discrimination of hydrothermally altered rocks along the Battle Mountain-Eureka, Nevada mineral belt using LANDSAT images

The author has identified the following significant results. Limonitic alteration halos associated with two copper prophyry deposits were successfully mapped at Battle Mountain. Alteration halos from both a hypogene system at Copper Canyon and a supergene system at Copper Basin are recognizable in the composite. Both copper porphyry deposits are located in sedimentary rock units that commonly have ferruginous coatings; yet, in most cases, the hydrothermally derived limonite was distinguishable in the CRC from sedimentary limonite. Large format playback images with pixel sizes from 200 to 400 micron m provided details of spatial resolution and color separation unachievable on enlargements from 70 mm film chips. Details of the alteration halos could be resolved only in the large format images. Two aspects of the alteration halos of the porphyry copper deposits were not mapped on the CRC. The optimum CRC image for the area studied consists of MSS 4/5 as blue, MSS 4/6 as yellow, and MSS 6/7 as magenta using diazo films. The disseminated gold deposits at Gold Acres are not depicted in the CRC image.

Krohn, M. D.↗

Sulphur isotopic compositions of deep-sea hydrothermal vent animals

The S-34/S-32 ratios of tissues from vestimentiferan worms, brachyuran crabs, and giant clams living around deep hydrothermal vents are reported. Clean tissues were dried, ground, suspended in 0.1 M LiCl, shaken twice at 37 C to remove seawater sulfates, dried at 60 C, combusted in O2 in a Parr bomb. Sulfur was recovered as BaSO4, and the isotopic abundances in SO2 generated by thermal decomposition of 5-30-mg samples were determined using an isotope-ratio mass spectrometer. The results are expressed as delta S-34 and compared with values measured in seawater sulfates and in normal marine fauna. The values ranged from -4.7 to 4.7 per thousand, comparable to vent sulfide minerals (1.3-4.1 per thousand) and distinct from seawater sulfates (20.1 per thousand) and normal marine fauna (about 13-20 per thousand). These results indicate that vent sulfur rather than seawater sulfur is utilized by these animals, a process probably mediated by chemoautotrophic bacteria which can use inorganic sulfur compounds as energy sources.

Fry, B.↗

Mapping hydrothermal alteration using aircraft VNIR scanners at the Rosemont porphyry copper deposit

Two Visible-Near Infrared (VNIR) scanners, the NS-001 and the M2S, were flown over the Rosemont porphyry copper deposit as part of the NASA/JPL/GEOSAT test site program. This program was established to determine the feasibility and limitations of mapping hydrothermal alteration with multispectral scanners. Data from the NS-001 at 0.83 and 2.2 microns were used to identify Fe(3+) and OH enriched outcrops. These areas were then correlated with three alteration assemblages. The first correlation, hematite-epidote, was the most obvious and appeared as a strong ferric iron signature associated with hematite stained Cretaceous arkoses and andesites. The second correlation, qtz-sericite, showed a combined ferric-hydroxyl signature for a phyllicly altered quartz monzonite. The third correlation, skarn, was identified only after a review of calc-silicate mineral VNIR spectra. Altered limestones that outcrop west of the deposit have a similar ferric iron-hydroxyl signature as the quartz-sericite altered quartz monzonite. This skarn signature has been interpreted to indicate the presence of andradite, hydro-grossularite and idocrase. Data from the second scanner, M2S, was used to search for variation in ferric iron mineral type. Resulting imagery data indicated that hematite was the dominant ferric iron mineral present in the Rosemont area.

Sadowski, R. M.↗

Hydrothermal alteration of CM carbonaceous chondrites: Implications of the identification of tochilinite as one type of meteoritic PCP

Poorly characterized phases (PCP's) constitute up to 30 volume percent of some CM carbonaceous chondrites, and are therefore an important key to an understanding of the physico-chemical conditions attending matrix evolution. An iron rich form of the terrestrial phase tochilinite was recently identified as a common type of PCP. Tochilinite has the general formula 6Fe(0.9)S.5(Mg,Fe)(OH)2 and consists of alternating machinawite (FeS) and brucite ((Mg,Fe)(OH)2) sheets, with iron vacancies in the sulfide sheets. In iron rich tochilinite, ferrous hydroxide, called amakinite, replaces brucite. If CM carbonaceous kchondrites have underdone hydrothermal alteration, iron rich tochilinite, at least, probably grew from aqueous solutions characterized by low FO2, high FS2, pH 10 to 12, and at a temperature at or below 170 C.

Zolensky, M. E.↗

Identification of hydrothermal mineralization in Baja California, Mexico from orbit using the Shuttle multispectral infrared radiometer

Data from the Space Shuttle Multispectral IR Radiometer (SMIRR), which is a 10-channel remote sensor designed to record narrow band spectral data in the 0.5-2.4 micron wavelength range, were used to identify and study a previously unreported area of hydrothermal alteration on the Baja California peninsula. Absorption at 2.17 microns, which is diagnostic of the minerals pyrophyllite, dickite, and alunite, was observed in many spectra and the presence of pyrophyllite and dickite was confirmed by X-ray diffraction analysis of field samples. Anomalously high Mo, B, Sn, Zr, and Ag were found in three samples.

Rowan, L. C.↗