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At least 307 records · Page 17

University of Florida nuclear pumped laser program

The mechanism of excitation of laser gases by fast ions (triton, proton, or fission fragments) and especially any role UF6 might play in radiative deexcitation of these gases were investigated. Population densities of excited important for laser action were obtained. Nuclear pumped CW-laser systems, especially He-Ne and CO2, were studied using steady state reactors. It was demonstrated that He-Ne lases in a CW-mode with nuclear pumping at both the red and the infrared transition. The infrared transition was observed to be superradiant.

Richard T. Schneider↗

Study of photon emission by electron capture during solar nuclei acceleration, 1: Temperature-dependent cross section for charge changing processes

The study of charge changing cross sections of fast ions colliding with matter provides the fundamental basis for the analysis of the charge states produced in such interactions. Given the high degree of complexity of the phenomena, there is no theoretical treatment able to give a comprehensive description. In fact, the involved processes are very dependent on the basic parameters of the projectile, such as velocity charge state, and atomic number, and on the target parameters, the physical state (molecular, atomic or ionized matter) and density. The target velocity, may have also incidence on the process, through the temperature of the traversed medium. In addition, multiple electron transfer in single collisions intrincates more the phenomena. Though, in simplified cases, such as protons moving through atomic hydrogen, considerable agreement has been obtained between theory and experiments However, in general the available theoretical approaches have only limited validity in restricted regions of the basic parameters. Since most measurements of charge changing cross sections are performed in atomic matter at ambient temperature, models are commonly based on the assumption of targets at rest, however at Astrophysical scales, temperature displays a wide range in atomic and ionized matter. Therefore, due to the lack of experimental data , an attempt is made here to quantify temperature dependent cross sections on basis to somewhat arbitrary, but physically reasonable assumptions.

Perez-Peraza, J.↗

The cyclotron energization through auroral wave experiments (CENTAUR 2B)

The CENTAUR 2B mission, a dual payload program, is in many aspects the same as the previous missions from Cape Perry and Norway in 1985. It was planned that these payloads would be launched from Andoya, Norway, Nov. 1989 from the Universal II launcher. The payloads are identical, but would have been launched at different azimuths as far north and as far west as possible. Particle experiments include the angular resolving energy analyzer (AREA), the fast ion mass spectrometer (FIMS), the spectrographic particle images (SPI), and finally, the differential ion flux probe (DIFP). SwRI was responsible for the scientific payload, which includes the power supplies, the power supply interfacing, the manipulating of the data from the instruments to format it for the telemetry system, all mechanical structure and restraint mechanisms, and the payload subskin. The status of the various components of this program is given.

Winningham, J. D.↗

3D full wave fast wave modeling with realistic antenna geometry and SOL plasma

This paper reports the significant advancement of our ability to model and to understand how RF waves interact with the SOL plasma, by simulating the full torus 3D SOL plasma together with the antenna and core plasma. We introduce and use a recently developed and open source code, Petra-M, which was constructed on the scalable MFEM C++ finite element library, and performed 3D full wave simulations in the HHFW regime for both NSTX-U and LAPD plasmas. A first full wave simulation for a full 3D torus including a realistic antenna geometry and SOL plasma region for NSTX-U is presented. A scan of the antenna phasing shows a strong interaction between FWs and the SOL plasma for lower antenna phasing, which is consistent with previous NSTX HHFW observations. The effect of the 3D wave field on the fast ion population from NBI beams in NSTX-U is also discussed by using the 3D field obtained from the Petra-M simulations in the full-orbit following particle SPIRAL code. On LAPD, 3D full wave simulations of a new HHFW 4-strap antenna recently installed by TAE Technologies on LAPD are performed showing a qualitative agreement with experimental data.

Bertelli, Nicola↗

Operando Measurements of Electrolyte Li-ion Concentration during fast charging with FTIR/ATR

The ability to charge a Li-ion battery at high charging rates is critical for electric vehicle adoption; however, further study of ion transport is required to develop electrolytes suitable for fast charge. Fourier transform infrared spectroscopy (FTIR) used with attenuated total reflection (ATR) enables operando measurements of liquid electrolytes. This research focused on solvation shifting of solvent infrared absorption bands in the presence of lithium ions. Lithium-shifted infrared absorption bands and non-shifted bands of ethyl methyl carbonate (EMC) and ethylene carbonate (EC) were compared to infer ion concentration changes during cycling. Lithium concentrations were calibrated using EC/EMC/LiPF 6 electrolytes with known lithium concentrations. A Li-ion half-cell with a graphite anode and EC/EMC/LiPF 6 electrolyte was observed with FTIR/ATR. The results showed that the magnitude of lithium concentration changes increased with increasing C-rate. During a galvanostatic intermittent titration technique (GITT) test, changes in lithium concentration could be observed. During intercalation, a lithium depletion occurred when a negative current was applied, and a lithium surplus occurred during deintercalation when a positive current was applied. The capability of observing lithium concentration has significant implications for the utility of operando studies and the potential to link lithium movement to battery performance.

25 ENERGY STORAGE↗

Fast and Simple Ag/Cu Ion Exchange on Cu Foil for Anode-Free Lithium-Metal Batteries

Lithium-metal batteries with zero excess lithium on the anode side paired with a fully lithiated cathode are regarded as a form of the highest energy-density configuration. Unfortunately, the continuous lithium loss over cycling from a limited amount of lithium reservoir significantly degrades the overall cell performance in the anode-free system. To mitigate the deterioration, modifying the current collector for enhanced lithium cycling is an indispensable route. Here, we apply a Ag/Cu ion exchange to precipitate micro-sized Ag particles on the Cu current collector to enhance the lithium reversibility via (de)alloying process. Further, we show a smoother morphology of lithium upon alloying, which leads to a lowered nucleation potential as well as increased average Coulombic efficiency in Li||Cu cells regardless of electrolyte formulation. The preferred lithium adsorption on Ag and AgLi over Cu is demonstrated with density functional theory calculations, which supports that Li is forming a gamma-phase alloy in the last stage rather than being deposited beneath the alloy. Lastly, this simple Cu foil modification enhances lithium reversibility and reduces its nucleation barrier, thus mitigating the capacity fade of a Cu||LiFePO 4 with reduced polarization.

25 ENERGY STORAGE↗

Closed-loop optimization of fast trapped-ion shuttling with sub-quanta excitation

Shuttling ions at high speed and with low motional excitation is essential for realizing fast and high-fidelity algorithms in many trapped-ion-based quantum computing architectures. Achieving such performance is challenging due to the sensitivity of an ion to electric fields and the unknown and imperfect environmental and control variables that create them. Here we implement a closed-loop optimization of the voltage waveforms that control the trajectory and axial frequency of an ion during transport in order to minimize the final motional excitation. The resulting waveforms realize fast round-trip transport of a trapped ion across multiple electrodes at speeds of 0.5 electrodes per microsecond (35 m∙s -1 for a one-way transport of 210 μm in 6 s) with a maximum of 0.36 ± 0.08 mean quanta gain. This sub-quanta gain is independent of the phase of the secular motion at the distal location, obviating the need for an electric field impulse or time delay to eliminate the coherent motion.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Impact of the LiPF6 Concentration on the Interfacial Charge Transfer and Fast-charging Capabilities of Lithium-Ion Batteries

Fast-charging lithium-ion batteries (LIB) demand optimized electrolyte formulations to balance ionic conductivity, viscosity, and interfacial charge transfer kinetics. This study examines how LiPF 6 concentration shapes solvation structure, desolvation energy, charge transfer activation energy, and solid electrolyte interphase (SEI) properties, which are critical for fast-charging performance. Using Raman spectroscopy, electrochemical cycling, X-ray photoelectron spectroscopy, and atomistic modeling, we analyze how varying LiPF 6 concentrations impact interfacial and bulk transport properties. Our findings show that increasing LiPF 6 concentration alters lithium solvation structures, reduces desolvation energy, and accelerates charge transfer at the electrode interface. Higher concentrations lower the activation energy for charge transfer and suppress excessive SEI growth, improving interfacial kinetics. However, concentrations above a certain threshold increase viscosity and reduce ionic conductivity, limiting transport efficiency. These results offer insights into electrolyte solvation and interfacial charge transfer mechanisms, providing guidelines for designing next-generation fast-charging LIB electrolytes with enhanced efficiency, stability, and longevity.

Son, Seoung-Bum [Argonne National Laboratory (ANL)↗

Anodic Interfacial Evolution in Extremely Fast Charged Lithium-Ion Batteries

Interfacial reaction mechanisms at the anode/separator interface play a central role in the performance and safety of lithium-ion batteries during fast charging. We report a mechanistic study on the evolution and interactions of the aging mechanisms at the anode/separator interface in lithium cobalt oxide/graphite pouch cells charged with variable charging rates (1–6C) over 10 cycles. In situ electrochemical measurements, including voltage relaxation, Coulombic efficiency, and direct current internal resistance, indicated an incremental lithium loss until the C rates were ≤5C. A substantial capacity fade is observed in the first few cycles of fast charging, but the magnitude of capacity fade progressively diminishes with the number of cycles, indicating a suppression in the lithium deposition mechanism. Post-mortem film thickness, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) analyses were performed to elucidate the evolution of electrolyte decomposition, the solid–electrolyte interface (SEI), lithium plating, and film fracture mechanisms with C rate. XPS measurements confirmed an increasing lithium concentration in an SEI film with an increase in the C rate. SEM images showed a growth of dendritic lithium on the anode surface from 1C to 3C. Precrack formation leading to an interfacial film fracture was observed at higher C rates. Furthermore, a differential analysis of the discharge capacity indicated a possible two-phase delithiation from the anode and reduced cathodic lithiation due to lithium loss at high C rates.

36 MATERIALS SCIENCE↗

Enabling 6C Fast Charging of Li–Ion Batteries with Graphite/Hard Carbon Hybrid Anodes

Li-ion batteries that can simultaneously achieve high-energy density and fast charging are essential for electric vehicles. Graphite anodes enable a high-energy density, but suffer from an inhomogeneous reaction current and irreversible Li plating during fast charging. In contrast, hard carbon exhibits superior rate performance but lower energy density owing to its lower initial coulombic efficiency and higher average voltage. In this work, these tradeoffs are overcome by fabricating hybrid anodes with uniform mixtures of graphite and hard carbon, using industrially-relevant multi-layer pouch cells (>1 Ah) and electrode loadings (3 mAh cm –2 ). By controlling the graphite/hard carbon ratio, this study shows that battery performance can be systematically tuned to achieve both high-energy density and efficient fast charging. Pouch cells with optimized hybrid anodes retain 87% and 82% of their initial specific energy after 500 cycles of 4C and 6C fast-charge cycling, respectively. This is significantly higher than the 61% and 48% specific energy retention with graphite anodes under the same conditions. The enhanced performance is attributed to improved homogeneity of the reaction current throughout the hybrid anode, which is supported by continuum-scale modeling. Furthermore, this process is directly compatible with existing roll-to-roll battery manufacturing, representing a scalable pathway to fast charging.

25 ENERGY STORAGE↗

Magnetohydrodynamic Control of Interfacial Degradation in Lithium-Ion Batteries for Fast Charging Applications

Interfacial anodic degradation in graphitic materials under fast charging conditions causes severe performance loss and safety hazard in lithium ion batteries. We present a novel method for minimizing the growth of these aging mechanism by application of an external magnetic field. Under magnetic field, paramagnetic lithium ions experience a magnetohydrodynamic force, which rotates the perpendicularly diffusing species and homogenizes the ionic transport. This phenomenon minimizes the overpotential hotspots at the anode/separator interface, consequently reducing SEI growth, lithium plating, and interfacial fracture. In situ electrochemical measurements indicate an improvement in capacity for lithium cobalt oxide/graphite pouch cell (20 mAh) charged from 1–5 C under an applied field of 1.8 kG, with a maximum capacity gain of 22% at 5C. Post-mortem FE-SEM and EDS mapping shows that samples charged with magnetic field have a reduced lithium deposition at 3C and a complete suppression of interfacial fracture at 5C. At 5C, a 24% reduction in the lithium content is observed by performing XPS on the anodic interfacial film. Finally, fast charging performance under variable magnetic field strengths indicate a saturation behavior in capacity at high fields (>2 kG), thereby limiting the field and consequent energy requirements to obtain maximum capacity gain under extreme conditions.

electromagnetism↗

On the Structural Origin of Fast Li-Ion Cycling in Tetragonal Bronze-Type Nb 8 W 9 O 47

Bronze and bronze-derived, mixed metal oxides are materials of growing interest for lithium-ion battery anodes due to their high-rate capabilities and the potential for high energy densities via multielectron redox. We report on the synthesis and electrochemical properties of the tetragonal tungsten bronzetype phase Nb 8 W 9 O 47 and our investigation into the structural evolution of this phase upon lithium (de)intercalation, with particular attention to how it relates to the fast-cycling capabilities. Electrochemical cycling shows Nb 8 W 9 O 47 can achieve greater than one Li + per transition metal at rates of C/2 or slower and maintains a capacity equivalent to 0.65 Li + per transition metal at a rate of 20C. Sequential Rietveld analysis of operando X-ray diffraction data reveals anisotropic changes to the unit cell parameters during discharge, accompanied by an off-centering of the transition metals within their octahedral environments. While higher capacities can be accessed below 1.2 V, cells discharged to 1.0 V exhibit a significant expansion of the unit cell volume and reduced Coulombic efficiencies. This report suggests that rigid crystal structures incapable of undergoing polyhedral rotational deformations can instead exploit displacive distortions of the transition metal redox center to enable fast Li-ion cycling with minimal atomic rearrangements.

25 ENERGY STORAGE↗

Effects of solvent formulations in electrolytes on fast charging of Li-ion cells

Improving the fast charging performance of lithium ion batteries (LIBs) has the promise to increase the widespread adoption of electric vehicles (EVs). Electrolyte development plays an important role in enabling fast charging. In this study, fast charging performance of LIBs is studied with different electrolytes of 1.2 M LiPF 6 in Ethylene Carbonate (EC)/Ethyl Methyl Carbonate (EMC)/co-solvents at 30/50/20 wt%. The co-solvents are methyl acetate (MA), ethyl acetate (EA), ethyl formate (EF), dimethyl carbonate (DMC) and EMC. Long term cycling performance under fast charging shows different capacity retention behaviors for different co-solvents. The structural changes in the electrode material are studied by X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD). The molarity changes in electrolyte is investigated by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The electrode/electrolyte interfaces before and after fast charging are analyzed by X-ray photoemission spectroscopy (XPS). The characterization results are in good agreement with the long-term cycling performance. DMC shows the highest fast-charging capability among the five studied co-solvents due to its increased conductivity, improved electrode/electrolyte interface and stable electrode structural integrity.

25 ENERGY STORAGE↗

Initial testing of Alfvén eigenmode feedback control with machine-learning observers on DIII-D

A first of its kind fully data-driven system has been developed and implemented into the DIII-D plasma control system to detect and control Alfvén eigenmodes (AE) in real-time. Susceptibility to fast ion-induced AE is a challenge in fully non-inductive tokamak operation, which significantly reduces fast-particle confinement and results in degraded fusion gain. Controlling AEs in real-time to improve fast-ion confinement is, hence, important for future advanced tokamak fusion reactors. The models were implemented and tested in experiments which showed that neural networks (NN) are highly effective in detecting 5 types of AE (BAE, EAE, LFM, RSAE, TAE) using high resolution ECE. To estimate the neutron deficit, a NN has been trained that outputs the classical neutron rate using similar inputs to NUBEAM. Also a preliminary ML-based proportional control has been designed and gone through initial testing in experiment to use feedback-control on the neutral beam power to achieve desired amplitude of AE modes and neutron deficits. The effect of AEs on fast-ion confinement is measured by analysing the gap in classical neutron rate from the proposed NN-based NUBEAM and the measured neutron rate.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Observations of energetic ion enhancements and fast neutrals upstream and downstream of Uranus' bow shock by the Voyager 2 spacecraft

Measurements of energetic ions and electrons upstream and downstream from Uranus obtained during the low energy charged particle experiment on Voyager 2 are discussed. The results indicate that energetic ions were present upstream of Uranus' bow shock and that their charcteristics, in terms of anisotropies and energy spectra, are consistent with an Uranian magnetospheric origin and are inconsistent with predictions of in situ acceleration via the Fermi mechanism. An upper limit to the flux of energetic neutrals escaping the magnetosphere is established, and the volume-averaged neutral hydrogen density inside 5 Uranian radii is constrained.

Krimigis, S. M.↗

Enhanced Electrolyte Transport and Kinetics Mitigate Graphite Exfoliation and Li Plating in Fast–Charging Li–Ion Batteries

Despite significant progress in energy retention, lithium-ion batteries (LIBs) face untenable reductions in cycle life under extreme fast-charging (XFC) conditions, which primarily originate from a variety of kinetic limitations between the graphite anode and the electrolyte. Through quantitative Li + loss accounting and comprehensive materials analyses, it is directly observed that the operation of LIB pouch cells at 4 C||C/3 (charging||discharging) results in Li plating, disadvantageous solid-electrolyte-interphase formation, and solvent co-intercalation leading to interstitial decomposition within graphite layers. It is found that these failure modes originate from the insufficient properties of conventional electrolytes, where employing a designed ester-based electrolyte improved the capacity retention of these cells from 55.9% to 88.2% after 500 cycles when operated at the aforementioned conditions. These metrics are the result of effective mitigation of the aforementioned failure modes due to superior Li + transport and desolvation characteristics demonstrated through both experimental and computational characterization. Finally, this work reveals the vital nature of electrolyte design to XFC performance.

25 ENERGY STORAGE↗

Carbon-Binder Optimization for Lithium-Ion Battery Extreme Fast Charge

Battery performance is strongly correlated with electrode microstructure and weight loading of the electrode components. Among them are the carbon-black and binder additives that enhance effective conductivity and provide mechanical integrity. However, these both reduce effective ionic transport in the electrolyte phase and reduce energy density. Therefore, an optimal additive loading is required to maximize performance, especially for fast charging where ionic transport is essential. Such optimization analysis is however challenging due to the nanoscale imaging limitations that prevent characterizing this additive phase and thus quantifying its impact on performance. Herein, an additive-phase generation algorithm has been developed to remedy this limitation and identify percolation threshold used to define a minimal additive loading. Improved ionic transport coefficients from reducing additive loading has been then quantified through homogenization calculation, macroscale model fitting, and experimental symmetric cell measurement, with good agreement between the methods. Rate capability test demonstrates capacity improvement at fast charge at the beginning of life, from 37% to 55%, respectively for high and low additive loading during 6C CC charging, in agreement with macroscale model, and attributed to a combination of lower cathode impedance, reduced electrode tortuosity and cathode thickness.

carbon-binder additives↗

Designing Electrolytes With Controlled Solvation Structure for Fast‐Charging Lithium‐Ion Batteries

Recharging battery-powered electric vehicles (EVs) in a similar timeframe as those used for refueling gas-powered internal combustion vehicles is highly desirable for rapid penetration of the EV market. It is well known that the electrolyte in a battery plays a critical role in fast-charging capability of the battery because it determines the rate of ion transport together with its derived electrode/electrolyte interphases on both cathode and anode of the battery. In this study, the effects of contents of salt, coordinating solvent, and noncoordinating diluent on salt dissociation degree and electrolyte ionic conductivity are investigated, and a controlled solvation structure electrolyte is developed to improve the lithium ion mobility and conductivity in the electrolyte and to enhance the kinetics and stability of the electrode/electrolyte interphases in the battery. This electrolyte enables fast-charging capability of high energy density lithium-ion batteries (LIBs) at up to 5 C rate (12-min charging), which significantly outperforms the state-of-the-art electrolyte. The controlled solvation structure sheds light on the future electrolyte design for fast-charging LIBs.

25 ENERGY STORAGE↗