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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Propynal, an Interstellar Molecule with an Exceptionally Strong C≡C Infrared Band - Laboratory Infrared Data and Applications

Isomers with the formulaC3H2Ohave intrigued and puzzled astronomers and astrochemists for many years, with propynal and cyclopropenone, but not propadienone, known to be interstellar. However, there is a severe lack of laboratory spectra of the solid phases of these compounds with which to investigate their interstellar chemistry. Here we present the first infrared spectra of amorphous and crystalline forms of propynal, HCC C(O)H, at multiple temperatures. Band positions are tabulated and band strengths are derived in terms of absorption coefficients and integrated intensities. Optical constants are calculated for amorphous propynal, refractive indices aremeasured, and densities are estimated. Three laboratory astrochemistry applications are described, including a new spectral identification in an earlier paper. It is shown that propynal’s C C infrared absorbance is about 30 000 per cent stronger than the corresponding feature in acetylene. This band’s intensity and spectral position make it an attractive candidate for astronomical searches involving interstellar ices.

astrochemistry – ISM: molecules↗
NASA NTRS2022

Exceptional Warmth in the Northern Hemisphere during January through March of 2020: The Roles of Unforced and Forced Modes of Atmospheric Variability

Much of northern Eurasia experienced record high temperatures during the first three months of 2020, and the eastern United States experienced a significant heat wave during March. In this study, we show that the above episodes of extraordinary warmth reflect to a large extent the unusual persistence and large amplitude of three well-known modes of atmospheric variability: the Arctic Oscillation (AO), the North Atlantic Oscillation (NAO), and the Pacific–North American (PNA) pattern. We employ a “replay” approach in which simulations with the NASA GEOS AGCM are constrained to remain close to MERRA-2 over specified regions of the globe in order to identify the underlying forcings and regions that acted to maintain these modes well beyond their typical submonthly time scales. We show that an extreme positive AO played a major role in the surface warming over Eurasia, with forcing from the tropical Pacific and Indian Ocean regions acting to maintain its positive phase. Forcing from the tropical Indian Ocean and Atlantic regions produced positive NAO-like responses, contributing to the warming over eastern North America and Europe. The strong heat wave that developed over eastern North America during March was primarily associated with an extreme negative PNA that developed as an instability of the North Pacific jet, with tropical forcing providing support for a prolonged negative phase. A diagnosis of the zonally symmetric circulation shows that the above extratropical surface warming occurred underneath a deep layer of tropospheric warming, driven by stationary eddy-induced changes in the mean meridional circulation.

Northern Hemisphere↗