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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Buffer-layer effect on the ferromagnetism of manganite heterojunctions

Identifying and understanding interfacial magnetic structures of transition-metal oxides are of great importance not only for fundamental physics but also for potential device applications. Among them, manganite and ruthenate heterostructures have attracted considerable interest due to their intriguing interfacial properties induced by complex magnetic interactions. Here, we report the observation of dramatic buffer-layer dependence of ferromagnetism in ultrathin (L⁢a 2/3 ⁢C⁢a 1/3 )⁢Mn⁢O 3 (LCMO)-based heterostructures. Though all trilayers are nonmetallic, the SrRu⁢O 3 -buffered LCMO trilayer exhibits enhanced ferromagnetism with the Curie temperature (𝑇 C ∼ 198K) much higher than for CaRu⁢O 3 (𝑇 C ∼ 99K)- and SrTi⁢O 3 (𝑇 C ∼ 42K)-buffered counterparts, as well as the monolithic LCMO films with similar thickness. Combining atomically resolved scanning transmission electron microscopy imaging with electron energy loss spectroscopy mapping, we reveal that asymmetric interfaces exist in the SrRu⁢O 3 buffered trilayer, with one exhibiting 1 unit-cell Sr diffusion into LCMO, which is responsible for the 𝑇 C enhancement. In contrast, charge transfer, which has been proposed previously as a possible mechanism, is excluded in this study. In conclusion, our results may pave a promising road toward effective atomic control of interfacial magnetism.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1988

Measurements of the anisotropy of the cosmic background radiation and diffuse galactic emission at millimeter and submillimeter wavelengths

The results of a balloon-borne observing program to measure the large angular scale brightness distribution of the 2.7 K cosmic background radiation (CBR) at millimeter and submillimeter wavelengths are reported. A new determination of the dipole anisotropy of the CBR is found with 3.40 + or - 0.42 mK toward alpha = 12.1 + or - 0.24 hr, delta = - 23 + or - 5 deg in a 1.2 to 8/cm band and 4.7 + or - 1.4 mK toward alpha = 9.9 + 1.7 or - 1.1 hr, delta = - 38 + or - 21 deg between 5 and 18/cm, where the amplitudes are listed as thermodynamic temperatures. New estimates of the absolute temperature in these two bands of 2.86 + or - 0.26 K and 3.01 + or - 0.31 are obtained under the assumption that the CBR has a Planck spectrum. The diffuse Galactic emission is fitted by a secant distribution in Galactic latitude, and the resulting Galactic pole antenna temperatures are given. Maps of sky brightness, measurements of zodiacal emission, and measurements of fluctuations of the atmospheric emission which dominates the noise budget are also presented.

Halpern, Mark↗
NASA NTRS1989

Viscous evolution of accretion discs in the quiescence of dwarf novae

Viscous evolution of accretion disks in the quiescence of dwarf novae is investigated semi-analytically. There are two key factors: the inward flow of the initial mass in the disk and the diffusion of the material added into the disk. The results are compared with the brightness temperature distributions obtained by the eclipse mapping of Z Cha and OY Car. The functional form of the viscosity parameter a, its values, the types of outbursts, and the application to soft X-ray transients are discussed.

Mineshige, Shin↗
NASA NTRS1990

Central star formation in S0 galaxies

As a class, S0 galaxies are characterized by a lack of resolved bright stars in the disk. However, several lines of evidence support the hypothesis that a high rate of star formation is occurring at the centers of some S0 galaxies. Many of the warmest, most powerful far infrared sources in nearby bright galaxies occur in S0 galaxies. (Dressel 1988, Ap. J., 329, L69). The ratios of radio continuum flux to far infrared flux for these S0 galaxies are comparable to the ratios found for spiral galaxy disks and for star-burst galaxies. Very Large Array (VLA) maps of some of these S0 galaxies show that the radio continuum emission originates in the central few kiloparsecs. It is diffuse or clumpy, unlike the radio sources in active S0 galaxies, which are either extremely compact or have jet-lobe structures. Imaging of some of these galaxies at 10.8 microns shows that the infrared emission is also centrally concentrated. Many of the infrared-powerful S0 galaxies are Markarian galaxies. In only one case in this sample is the powerful ultraviolet emission known to be generated by a Seyfert nucleus. Optical spectra of the central few kiloparsecs of these S0 galaxies generally show deep Balmer absorption lines characteristic of A stars, and H beta emission suggestive of gas heated by O stars. A key question to our understanding of these galaxies is whether they really are S0 galaxies, or at least would have been recognized as S0 galaxies before the episode of central star formation began. Some of Nilson's classifications (used here) have been confirmed by Sandage or de Vaucouleurs and collaborators from better plates; some of the galaxies may be misclassified Sa galaxies (the most frequent hosts of central star formation); some are apparently difficult to classify because of mixed characteristics, faint non-S0 features, or peculiarities. More optical imaging is needed to characterize the host galaxies and to study the evolution of their star-forming regions.

Dressel, L. L.↗
NASA NTRS2024

Heat-Exchange Driven Aircraft for Low Altitude and Surface Exploration of Venus: Phase 1 Study Final Report

Exploration of Venus below its clouds has long been impaired by the planet’s massive CO2 atmosphere, corrosive trace gases, and high opacity. Except for a few narrow spectral windows, the 20 km thick global cloud cover blocks light over the entirety of the ultraviolet through thermal infrared spectrum, impeding orbital studies of the surface and lower portion of the atmosphere. In addition to the cloud opacity, Rayleigh scattering through 80 bars of CO 2 in the lower 40 km of the atmosphere results in a Rayleigh scattering depth between 25 and1 in the visible through near infrared portion of the spectrum. That optically thick scattering, combined with the uniform angular distribution of the illumination provided by the highly diffusing clouds overhead greatly reduces even very large surface albedo contrasts (Crisp, pers. Comm.). To date, the surface has only been mapped via synthetic aperture radar by the Magellan mission at scales of 120 to 300 m/pixel. In addition to contributing to the difficulty of performing studies of the surface from orbit, the extreme temperatures and pressures at the surface also create a challenging environment to utilize a lander for exploration. The longest-lived lander on Venus’ surface survived for 2 hours. Hence, limited access to observe the surface and lower atmosphere of Venus arguably puts the surface and lower atmosphere of Venus as one of the least explored regions of the inner Solar System.

NIAC Phase I↗
DOE OSTI2020

Quantitative nanoscale tracking of oxygen vacancy diffusion inside single ceria grains by in situ transmission electron microscopy

Oxygen vacancy formation and migration in ceria is critical to its electrochemical and catalytic properties in systems for chemical and energy transformation, but its quantification is rather challenging especially at atomic-scale because of disordered distribution. Here we report a rational approach to track oxygen vacancy diffusion in single grains of pure and Sm-doped ceria at -20 °C to 160 °C using in situ (scanning) transmission electron microscopy ((S)TEM). To create a gradient in oxygen vacancy concentration, a small region (~30 nm in diameter) inside a ceria grain is reduced to the C-type CeO 1.68 phase by the ionization or radiolysis effect of a high-energy electron beam. The evolution in oxygen vacancy concentration is then mapped through lattice expansion measurement using scanning nano-beam diffraction or 4D STEM at a spatial resolution better than 2 nm; this allows direct determination of local oxygen vacancy diffusion coefficients in a very small domain inside pure and Sm-doped ceria at different temperatures. Further, the activation energies for oxygen transport are determined to be 0.59, 0.66, 1.12, and 1.27 eV for pure CeO 2 , Ce 0.94 Sm 0.06 O 1.97 , Ce 0.89 Sm 0.11 O 1.945 , and Ce 0.8 Sm 0.2 O 1.9 , respectively, implying that activation energy increases due to impurity scattering. The results are qualitatively supported by density functional theory (DFT) calculations. In addition, our in situ TEM investigation reveals that dislocations impede oxygen vacancy diffusion by absorbing oxygen vacancies from the surrounding areas and pinning them locally. With more oxygen vacancies absorbed, dislocations show extended strain fields with local tensile zone sandwiched between the compressed ones. Therefore, dislocation density should be reduced in order to minimize the resistance to oxygen vacancy diffusion at low temperatures.

36 MATERIALS SCIENCE↗
NASA NTRS2024

The Global Mapping of Electron Precipitation and Ionospheric Conductance From Whistler-Mode Chorus Waves

Auroral precipitation is the second major energy source after solar irradiation that ionizes the Earth’s upper atmosphere. Diffuse electron aurora caused by wave-particle interaction in the inner magnetosphere (L < 8) takes over 60% of total auroral energy flux, strongly contributing to the ionospheric conductance and thus to the ionosphere-thermosphere dynamics. This paper quantifies the impact of chorus waves on the diffuse aurora and the ionospheric conductance during quiet, medium, and strong geomagnetic activities, parameterized by AE <100, 100 < AE < 300, and AE > 300, respectively. Using chorus wave statistics and inner-magnetosphere plasma conditions from Timed History Events and Macroscale Interactions during Substorms (THEMIS) observations, we directly derive the energy spectrum of diffuse electron precipitation under quasi-linear theory. We then calculate the height-integrated conductance from the wave-driven aurora spectrum using the electron impact ionization model of Fang et al. (Geophys. Res. Lett., 2010, 37) and the MSIS atmosphere model. By utilizing Fang’s ionization model, the US Naval Research Laboratory Mass Spectrometer and Incoherent Scattar Radar (NRLMSISE-00) model from 2000s for the neutral atmosphere components, and the University of California, Los Angeles (UCLA) Full Diffusion Code, we improve upon the standard generalization of Maxwellian diffuse electron precipitation patterns and their resulting ionosphere conductance. Our study of global auroral precipitation and ionospheric conductance from chorus wave statistics is the first statistical model of its kind. We show that the total electron flux and conductance pattern from our results agree with those of Ovation Prime model over the pre-midnight to post-dawn sector as geomagnetic activity increases. Our study examines the relative contributions of upper band chorus (UBC) and lower band chorus wave (LBC) driven conductance in the ionosphere. We found LBC waves drove diffuse electron precipitation significantly more than UBC waves, however it is possible that THEMIS data may have underestimated the upper chorus band wave observations for magnetic latitudes below 65 degrees. ° .

diffuse auroral precipitation↗
DOE OSTI2021

Density functional theory calculations of the thermodynamic and kinetic properties of point defects in β -U

Density functional theory (DFT) calculations of the thermodynamic and kinetic properties of point defects in the β phase of uranium are reported. Defect energies and entropies were calculated using 2 x 2 x 2 supercells and the Generalized Gradient Approximation (GGA) of Perdew-Burke-Ernzerhof (PBE) for the exchange-correlation potential. Due to computational cost, calculations of the vibrational properties governing entropies were performed by only displacing atoms within (roughly) the 3rd or 4th nearest neighbor shell of the defect, which implicitly assumes that atoms beyond this distance are unaffected by the defect. Migration barriers were estimated by nudged elastic band (NEB) calculations. The low symmetry of the β-U phase (the unit cell is tetragonal and contains 30 atoms) results in many point defect configurations and even more migration pathways. A connectivity map, starting from the most stable point defects, was developed in order to identify the rate-limiting step controlling the net diffusion rate in each crystallographic direction. The uranium self-diffusivity tensor was calculated by combining the defect formation energies, entropies, migration barriers and attempt frequencies. The fastest diffusion rate was determined to be a vacancy mechanism in the z crystallographic direction. The predicted uranium self-diffusivity for this mechanism agrees well with available experimental data. Finally, the diffusion mechanisms and rates identified in this study will inform fuel performance models of swelling and gas evolution.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Tuning Electrogenerated Chemiluminescence Intensity Enhancement Using Hexagonal Lattice Arrays of Gold Nanodisks

Electrogenerated chemiluminescence (ECL) microscopy shows promise as a technique for mapping chemical reactions on single nanoparticles. The technique’s spatial resolution is limited by the quantum yield of the emission and the diffusive nature of the ECL process. To improve signal intensity, ECL dyes have been coupled with plasmonic nanoparticles, which act as nanoantennas. Here, we characterize the optical properties of hexagonal arrays of gold nanodisks and how they impact the enhancement of ECL from the coreaction of tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate and tripropylamine. Here, we find that varying the lattice spacing results in a 23-fold enhancement of ECL intensity because of increased dye-array near-field coupling as modeled using finite element method simulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1971

Quantitative evaluation of water quality in the coastal zone by remote sensing

Remote sensing as a tool in a waste management program is discussed. By monitoring both the pollution sources and the environmental quality, the interaction between the components of the exturaine system was observed. The need for in situ sampling is reduced with the development of improved calibrated, multichannel sensors. Remote sensing is used for: (1) pollution source determination, (2) mapping the influence zone of the waste source on water quality parameters, and (3) estimating the magnitude of the water quality parameters. Diffusion coefficients and circulation patterns can also be determined by remote sensing, along with subtle changes in vegetative patterns and density.

James, W. P.↗
NASA NTRS1972

Trinity Bay Study: Dye tracing experiments

An analysis of the heat balance and temperature distribution within Trinity Bay near Galveston, Texas is presented. The effects of tidal currents, wind driven circulations, and large volume inflows are examined. Emphasis is placed on the effects of turbulent diffusion and local shears in currents. The technique of dye tracing to determine the parameters characterizing dispersion is described. Aerial photographs and maps are provided to show the flow conditions existing at different times and seasons.

Ward, G. H., Jr.↗
NASA NTRS1979

Eliminating Clutter in Synthetic-Aperture Radar

Diffusion technique reduces clutter noise in coherent SAR (synthetic-aperature radar) image signal without degrading its resolution. Technique makes radar-mapped terrain features more obvious.It also has potential application in holographic microscopy.

Jain, A.↗
NASA NTRS1987

Fast-dynamo action in unsteady flows and maps in three dimensions

Unsteady fast-dynamo action is obtained in a family of stretch-fold-shear maps applied to a spatially periodic magnetic field in three dimensions. Exponential growth of a mean field in the limit of vanishing diffusivity is demonstrated by a numerical method which alternates instantaneous deformations with molecular diffusion over a finite time interval. Analysis indicates that the dynamo is a coherent feature of the large scales, essentially independent of the cascade of structure to small scales.

Bayly, B. J.↗
NASA NTRS1993

A comparison of the cosmic microwave and cosmic X-ray backgrounds - Constraints on local sources of the fluctuations observed by COBE

It has been suggested by Hogan (1992) that the microwave background anisotropy detected by the COBE DMR experiment (Smoot et al., 1992) might be produced by inverse Compton scattering from hot diffuse clouds of electrons in nearby superclusters. If the COBE fluctuations are due to this mechanism, then the absence of anticorrelations between maps of the cosmic microwave and cosmic X-ray backgrounds constrains the temperature (16 keV) and density (less than 2 x 10 exp -6/cu cm) of the ionized supercluster gas. Since the COBE limits on spectral distortion indicate that the temperature of the intergalactic medium is less than 10 keV, we conclude that the fluctuations observed by COBE are probably not produced by this mechanism.

Boughn, S. P.↗
NASA NTRS1995

The interstellar disk-halo connection in the spiral galaxy NGC 3079

We discuss the morphology and excitation of ionized gas in the nearby Sc galaxy NGC 3079. The almost edge-on orientation is ideal for studying the vertical structure of the gaseous disk, and especially the diffuse ionized medium (DIM) found between the bright H II regions. We used the Hawaii Imaging Fabry-Perot Interferometer (HIFI) to map 150,000 H-alpha + (N II) lambda lambda 6548, 6583 emission-line profiles across the entire disk, with resolution 70 km/s at subarcsecond steps, down to a flux level of approximately 10(exp -17) ergs/s/sq cm (EM approximately equal to 4 cm(exp -6) pc). The DIM contributes approximately 30% of the total disk H-alpha emission within a radius of 10 kpc. The DIM has broader emission lines and larger (N II) H-alpha flux ratios than the adjacent H II regions. Within a radius of 5 kpc, we find that the X-shaped filaments reported in previous studies emerge from the inner (R approximately equal to 1.5 kpc) disk, and rise more than 4 kpc above the disk plane. The morphology, kinematics, and excitation of the filaments suggest that they form a biconic interface between the undisturbed disk gas, and gas entrained in the wide-angle outflow. The DIM beyond 5 kpc radius is more vertically extended than the thick ionized disk detected in our Galaxy and in a few nearby edge-on systems. After correcting for dust, the vertical profile of this DIM has an exponential scale height of about 1.1 kpc, similar to that of the H I disk. The (N II) lambda 6538/H-alpha flux ratio of the DIM increases monotonically with vertical height, reaching unity for absolute value of z greater than or approximately equal to 2.5 kpc. The flux required to keep the DIM ionized at R = 8 kpc is similar to that near the solar circle of our Galaxy. Highly dilute radiation from O stars in the galactic plane probably maintains the DIM. The total mass of the DIM is of order 10(exp 8) - 10(exp 9) solar mass, representing less than 1% of the total dynamical mass of NGC 3079. Mechanical energy from intense star formation in the disk probably lifts the DIM above the disk. The several bubbles and filaments within 1 kpc of the disk plane is direct evidence for gas flow between the disk and halo.

Veilleux, Sylvain↗
NASA NTRS1995

Ground-based observations of the corona in the visible and NIR spectral ranges

Since late 1993 we have been using a mirror coronagraph on Pic du Midi (PICO) to observe the solar emission corona in several spectral lines of (FE-X), (FE-XIII), and (FE-XIV). For good meteorological conditions the diffuse corona and coronal holes in between can be seen out to 1.2 solar mass for sun center. Active regions can be mapped to bond 1.5 solar mass in the green and infrared lines. Recent observations of PICO are presented.

Epple, Alexander↗
NASA NTRS1999

Investigating Galactic Structure with COBE/DIRBE

In this work I applied the current version of the SKY model of the point source sky to the interpretation of the diffuse all-sky emission observed by COBE/DIRBE. The goal was to refine the SKY model using the all-sky DIRBE maps of the Galaxy, in order that a search could be made for an isotropic cosmic back-ground. Arendt et al. constructed their "Faint Source Model" (FSM) to remove Galactic foreground stars from the ZSMA products. The FSM mimics SKY version 1 but Arendt et al.'s concluded that it was inadequate to seek cosmic background emission because of the sizeable residual emission in the ZSMA products after this starlight subtraction. At this point I can only support Arendt et al.'s conclusion, namely that such models are currently inadequate to reveal a cosmic background. Even SKY5 yields the same disappointing result. On the positive side, our knowledge of the fundamental parameters of stars is increasing through the legacy of the Hipparcos mission. These parameters are critical inputs to any model of the stellar sky and it is my hope to revisit the problem once the new values are for visual-absolute magnitudes and stellar, space densities. I also hope to make progress through an independent analysis of Pioneer optical starlight with SKY, under a NASA Heliospheric Mission Guest Investigator proposal.

Cohen, Martin↗
NASA NTRS1989

The 100 and 160 micron maps of the dust reemission from the nucleus and inner-arm regions of NGC 6946

Dust reemission from the Scd galaxy NGC 6946 has been measured at 100 and 160 microns with the 32-channel University of Chicago Far-Infrared Camera. Researchers present fully sampled maps of the nucleus and inner spiral arms at 45 seconds resolution. The far-infrared morphology of the galaxy is a bright peak centered on a diffuse disk, where the peak occurs about 24 seconds NE of the Dressel and Condon optical center. The 100/160 micron color temperature is correlated with the H alpha surface brightness. Assuming the distance from Earth to the galaxy is 10.1 Mpc, researchers determine that Tc is 32 K at the nucleus and at radius 5.4 kpc, where there is a concentration of H II regions. In the intermediate annulus of relatively low H alpha surface brightness, the temperature drops to a local minimum of 25 K at radius 3 kpc. The ratio of reradiated to transmitted stellar luminosity is approx. 3.0 at the nucleus and approx. 0.9 for the disk. The optical depth at 100 micron increases from .0005 at the edges of our map to .0035 at the far infrared radiation (FIR) peak. Combining our observations with a fully sampled map of similar spatial extent in CO(1 greater than 0), researchers determine that the ratio F sub IR/I sub CO at the center of the galaxy is almost twice that for the disk, where the value is more or less constant.

Engargiola, Gregory↗