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At least 307 records · Page 17

Determination of carbon by the oxidation reduction reaction with chromium

Free carbon was determined in silicon and boron carbides in ash, oxides, and other materials by oxidation to carbon dioxide with a mixture of K2Cr2O7 + H2SO4. The determination was made from the amount of CR(6) consumed, by adding excess Mohr's salt and titrating with a standard solution of KMnO4. The amount of Cr(6) self reduced was determined in a blank test. Optimum oxidation and conditions were achieved when the volumes of 5% k2Cr2Oz and H2SO4 were equal. The mixture was boiled for 1-2 hours using a reflex condenser. The volume should not be reduced, in order to avoid an increase in the sulfuric acid concentration. The relative error was 4-7% for 0.005-0.04 g C and less than or equal to 3.5% for 0.1 g C.

Mashkovich, L.↗

Use of accelerated helium-3 ions for determining oxygen and carbon impurities in some pure materials

Methods are developed for the determination of O impurity in Be and Si carbide and concurrent determination of C and O impurities in Si and W by irradiation with accelerated He-3 ions and subsequent activity measurements of C-11 and F-18 formed from C and O with the aid of a gamma-gamma coincidence spectrometer. Techniques for determining O in Ge and Ga arsenide with radiochemical separation of F-18 are also described.

Aleksandrova, G. I.↗

Determining crustal strain rates with a spaceborne geodynamics ranging system. 2: Station coordinate analysis

The use of a spaceborne geodynamics ranging system for determining crustal strain rates is analyzed. The use of site coordinates rather than intersite baseline distances for the strain rate determinations is emphasized. After discussing the analytical techniques which are to be employed, numerical results are presented which suggest that the use of site coordinates would result in a 20-70% improvement in the precision of the deduced values of straining. Precision of a few parts in 10 to the 9th power would be achievable with simple geometrics and a decade or two of measurements; precisions of a few parts in 10 to the 8th power would be achievable in a few years. A consideration of possible correlations among the derived target site coordinates leads to the conclusion that, with the proper choice of coordinate systems, the correlations can be made small and non-detrimental to the strain rate determinations.

Cohen, S. C.↗

Single-axis attitude determination accuracy

This paper extends the analysis of attitude determination accuracy introduced at the 1975 American Astronautical Society/American Institute of Aeronautics and Astronautics (AAS/AIAA) Astrodynamics Conference. It contains more generalized expressions, new geometrical relations, and additional applications. A complete set of attitude accuracy equations for both arc-length (portion of a great circle) and rotation-angle (dihedral angle) measurements are presented. These expressions can then be applied to determine the geometrical conditions under which a specified accuracy can be achieved by using either the attitude or a selected reference-vector direction as the independent variable. Representative applications to attitude determination accuracy studies and launch window analyses are discussed. The clear physical interpretation and straightforward graphical procedures greatly simplify mission analysis, maneuver planning, hardware configuration studies, and interpretation of results.

Chen, L. C.↗

A new basis for the determination of fracture toughness

A study is presented which shows that the growth of the plastic zone and the constraint in a compact tension specimen depends significantly on specimen width. The analysis permits the estimation of the contribution of the growth of plastic zone to the deviation from linearity. The contribution of the crack growth to the deviation from linearity is evaluated from the analysis of a typical R-curve data. A combination of these two analyses enables one to define a very simple procedure for the determination of fracture toughness. The fracture toughness is defined as the stress intensity value at which the crack extension starts. The good agreement between analytical results and experimental KQ and KIC values determined over a wide range of thicknesses, widths, and materials justifies the proposed procedures. The KIC determined according to this procedure is independent of specimen width and such a procedure enhances the range of applicability of the K concept to a wider combination of configurations and materials.

Banerjee, S.↗

A method of determining spectral analytical dye densities

A straightforward method for the user of color imagery to determine the spectral analytical density of dyes present in the processed imagery is presented. The method involves exposing a large number of different color patches on the film which span the gamut of the film's imaging capabilities. From integral spectral density measurements at 16 to 19 different wavelengths, the unit spectral dye curves for each of the three dyes present were determined in two different types of color films. A discussion of the use of these spectral dye densities to determine the transformation between integral density measurements and analytical density is presented.

Scarpace, F. L.↗

Orbit determination accuracies using satellite-to-satellite tracking

The results are reported of the ATS-6/GEOS-3 and the ATS-6 Nimbus-6 satellite-to-satellite orbit determination experiments. NASA intends to use the tracking data relay satellite system for operational orbit determination of NASA satellites. Hence, in the near future, satellite-to-satellite tracking data will be routinely processed to obtain orbits. The satellite-to-satellite tracking system used in the ATS-6/Nimbus-6 and ATS-6/GEOS-3 experiments performed with a resolution of 1 to 2 m in range and less than 1 mm/s in range rate for a 10-s averaging. A Bayesian least squares estimation technique utilizing independent ranging to the synchronous relay satellite was determined to be the most effective procedure for estimating orbits from satellite-to-satellite tracking data. The use of this technique yields estimates of user satellite orbits which are comparable in accuracy to what is usually obtained from ground based systems.

Vonbun, F. O.↗

Total ozone determination by spectroradiometry in the middle ultraviolet

A method has been developed to determine total ozone from multispectral measurements of the direct solar irradiance. The total ozone is determined by a least squares fit to the spectrum between 290 nm and 380 nm. The aerosol extinction is accounted for by expanding it in a power series in wavelength; use of the linear term proved adequate. A mobile laboratory incorporating a sky scanner has been developed and used to obtain data to verify the method. Sun tracking, wavelength setting of the double monochromator, and data acquisition are under control of a minicomputer. Results obtained at Wallops Island, Virginia, and Palestine, Texas, agree well with simultaneous Dobson and Canterbury spectrometer and balloon ECC ozonesonde values. The wavelength calibration of the monochromator and the values for the normalized ozone absorption are the most important factors in an accurate determination of total ozone.

Garrison, L. M.↗

New determinations of far-side lunar radii from Apollo photography

Determinations of far side lunar radii based on the reduction of photogrammetric measurements derived from Apollo 16 photographs obtained during the trans-earth phase of the spacecraft trajectory are presented. Reduction is accomplished by determining the Apollo 16 metric camera orientation relative to control points on the lunar surface whose coordinates are known exactly, than charting the surface on the basis of data coverage. The positions of 66 surface features in the area between longitudes 90 and 130 deg E and 10 and 60 deg N relative to the center of mass of the moon, with a relative accuracy of 500 km, are presented. A topographical map which can resolve basin-sized features has been derived from radius determinations. It is found that the craters Fabry, Riemann and Szilard comprise a topographically depressed region about 500 km in diameter with a floor 2.4 to 3.4 km below the 1730.0 km reference sphere and 4.8 to 5.8 km below the northern rim of the unfilled basin.

Mohan, S. N.↗

Forward-bias capacitance and current measurements for determining lifetimes and band narrowing in p-n junction solar cells

A new method is described and illustrated for determining the minority-carrier diffusion length and lifetime in the base region of p-n junction solar cells. The method requires only capacitance measurements at the device terminals and its accuracy is estimated to be + or - 5%. It is applied to a set of silicon p-n junction devices and the values of the diffusion lengths agree with those obtained using the current response to X-ray excitation but disagree with those obtained by the OCVD method. The reasons for the relative inaccuracy of OCVD applied to silicon devices are discussed. The capacitance method includes corrections for a two-dimensional fringing effects which occur in small area devices. For a device having highly-doped base region and surface (emitter) layer, the method can be extended to enable the determination of material properties of the degenerately doped surface layer. These material properties include the phenomenological emitter lifetime and a measure of the energy band-gap narrowing in the emitter. An alternate method for determining the energy band-gap narrowing from temperature dependence of emitter current is discussed and demonstrated.

Neugroschel, A.↗

A Geos 3 Orbit determination experiment

The purpose of this experiment was to investigate the value of altimetry data in high-precision satellite orbit determination. To accomplish this, software was developed to process laser, C-band, doppler and altimeter data singly or jointly. Initially, orbit determination studies were undertaken using synthetic data to validate the software. As data became available, preliminary experiments were carried out. When all the data became available, an intensive study was made covering a 4-day span in 1976. The results showed that even with sparse altimeter data it was possible to accurately determine the semimajor axis and eccentricity with altimeter data only. When altimeter data was supplemented with (as few as) two C-band passes, high-precision ephemerides were obtained. Using two laser passes to supplement the altimetry data did not achieve that same high precision. This is probably because the geographic location (mid-Atlantic) of the highly accurate laser data were such that they did not ideally complement the available (south Atlantic and Indian Ocean) altimeter data.

Pisacane, V. L.↗

The strategy and technique in determining the orbits of the Pioneer Venus multiprobe bus and probes

The Venus Multiprobe Mission presented the greatest degree of complexity for an Orbit Determination task inasmuch as the spacecraft was composed of a bus, a large probe, and three small probes, all of which impacted the planet at various times and locations. In addition, there were eight major maneuvers for the purpose of spacecraft-probe separation and trajectory retargeting. The multiprobe antenna polarization, antenna offset from the spin axis, and spacecraft rotation introduce signatures into the radiometric Doppler data. These signatures, especially in regard to effects seen in Doppler residuals, further increase the complexity of the orbit determination problem. This paper describes the strategy and technique in using this Doppler data to determine the orbits of the multiprobe bus, the large probe, and the three small probes.

Wong, S. K.↗

Interplanetary orbit determination

A general description of the Viking interplanetary orbit determination activity extending from launch to Mars encounter is given. The emphasis is on the technical fundamentals of the problem, basic strategies and data types used, quantitative results, and specific conclusions derived from the inflight experience. Special attention is given to the use of the spacecraft-based optical measurements and their first application as a principal navigational data type for an interplanetary mission. The optical-based orbit determination, in fact, was the primary contributor to the exceptional interplanetary navigation accuracy experienced by both Viking missions. The Viking application of optical orbit determination relied in large part on the technology developed and demonstrated by the Mariner 9 Optical Navigation Demonstration.

Rourke, K. H.↗

Satellite orbit determination

The determination of the Mars-centered ephemerides of the Viking Orbiters and positions of the Landers from two way Doppler and range data is described. An overview of mission satellite orbit determination functions and methods is given. Topics covered include: postmaneuver orbit convergence, local orbit knowledge accuracies, the effects of interplanetary media, use of constrained solutions, and solving through trim burns. Procedure and results relevant to the determination of the planet gravity field are included. Results relative to sensing Mars' gravity field during the extended mission are presented along with a discussion of the Phobos Flyby Experiment conducted during February 1977.

Hildebrand, C. E.↗

Determination of the Solar Energy Microclimate of the United States Using Satellite Data

The determination of total solar energy reaching the ground over the United States using measurements from meteorological satellites as the basic data set is examined. The methods of satellite data processing are described. Uncertainty analysis and comparison of results with well calibrated surface pyranometers are used to estimate the probable error in the satellite-based determination of ground insolation. It is 10 to 15 percent for daily information, and about 5 percent for monthly values. However, the natural space and time variability of insolation is much greater than the uncertainty in the method. The most important aspect of the satellite-based technique is the ability to determine the solar energy reaching the ground over small areas where no other measurements are available. Thus, it complements the widely spaced solar radiation measurement network of ground stations.

Vonderharr, T. H.↗

Coordinated aircraft and ship surveys for determining impact of river inputs on great lakes waters. Remote sensing results

The remote sensing results of aircraft and ship surveys for determining the impact of river effluents on Great Lakes waters are presented. Aircraft multi-spectral scanner data were acquired throughout the spring and early summer of 1976 at five locations: the West Basin of Lake Erie, Genesee River - Lake Ontario, Menomonee River - Lake Michigan, Grand River - Lake Michigan, and Nemadji River - Lake Superior. Multispectral scanner data and ship surface sample data are correlated resulting in 40 contour plots showing large-scale distributions of parameters such as total suspended solids, turbidity, Secchi depth, nutrients, salts, and dissolved oxygen. The imagery and data analysis are used to determine the transport and dispersion of materials from the river discharges, especially during spring runoff events, and to evaluate the relative effects of river input, resuspension, and shore erosion. Twenty-five LANDSAT satellite images of the study sites are also included in the analysis. Examples of the use of remote sensing data in quantitatively estimating total particulate loading in determining water types, in assessing transport across international boundaries, and in supporting numerical current modeling are included. The importance of coordination of aircraft and ship lake surveys is discussed, including the use of telefacsimile for the transmission of imagery.

Raquet, C. A.↗

A preliminary assessment of the accuracy of selected meteorological parameters determined from Nimbus 6 satellite profile data

Published rms errors in rawinsonde data and discrepancies between satellite and rawinsonde profile data for temperature, dewpoint temperature, mixing ratio, and wind speed. Satellite rms errors were found to be 2 to 3 times as large as those for rawinsonde data. Gradients of the preceding parameters were computed for both rawinsonde and satellite data and compared with means and near extreme values computed from the AVE 2 and AVE 4 experiments. In all cases, it was found that satellite data can be used to determine with relatively good accuracy the near extreme gradients but not those whose value does not exceed the average. Synoptic charts were prepared to show that patterns of temperature could be determined with relatively good accuracy, while those of dew point were not as good as those for temperature. Winds represented by cloud motion vectors (satellite winds) were compared with rawinsonde winds, and it was found that large gaps exist in satellite values for a given pressure level and that errors in the satellite determined concluded that satellite profile data are very useful in synoptic analysis, particularly in data sparse regions as well as regions where near extreme gradients exist in the measured parameters.

Scoggins, J. R.↗

A spectral method for determining the percentage of green herbage material in clipped samples

A laboratory radiometric method for the rapid determination of green and brown vegetation percentages in clipped grass samples has been developed and tested. The method uses red and photographic infrared radiance or reflectance differences between green and brown vegetation. Mixtures of green and brown material were found to have radiances or reflectances proportional to the percentage of green material present. This method may permit the use of rapid green/brown radiometric determinations to replace the tedious hand sorting now generally used. It may also have application in remote sensing of vegetation ground-truth work where the determination of dry green biomass in clipped samples is necessary.

Tucker, C. J.↗