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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

Remote Sensing of Tropical Ecosystems: Atmospheric Correction and Cloud Masking Matter

Tropical rainforests are significant contributors to the global cycles of energy, water and carbon. As a result, monitoring of the vegetation status over regions such as Amazonia has been a long standing interest of Earth scientists trying to determine the effect of climate change and anthropogenic disturbance on the tropical ecosystems and its feedback on the Earth's climate. Satellite-based remote sensing is the only practical approach for observing the vegetation dynamics of regions like the Amazon over useful spatial and temporal scales, but recent years have seen much controversy over satellite-derived vegetation states in Amazônia, with studies predicting opposite feedbacks depending on data processing technique and interpretation. Recent results suggest that some of this uncertainty could stem from a lack of quality in atmospheric correction and cloud screening. In this paper, we assess these uncertainties by comparing the current standard surface reflectance products (MYD09, MYD09GA) and derived composites (MYD09A1, MCD43A4 and MYD13A2 - Vegetation Index) from the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard the Aqua satellite to results obtained from the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm. MAIAC uses a new cloud screening technique, and novel aerosol retrieval and atmospheric correction procedures which are based on time-series and spatial analyses. Our results show considerable improvements of MAIAC processed surface reflectance compared to MYD09/MYD13 with noise levels reduced by a factor of up to 10. Uncertainties in the current MODIS surface reflectance product were mainly due to residual cloud and aerosol contamination which affected the Normalized Difference Vegetation Index (NDVI): During the wet season, with cloud cover ranging between 90 percent and 99 percent, conventionally processed NDVI was significantly depressed due to undetected clouds. A smaller reduction in NDVI due to increased aerosol levels was observed during the dry season, with an inverse dependence of NDVI on aerosol optical thickness (AOT). NDVI observations processed with MAIAC showed highly reproducible and stable inter-annual patterns with little or no dependence on cloud cover, and no significant dependence on AOT (p less than 0.05). In addition to a better detection of cloudy pixels, MAIAC obtained about 20-80 percent more cloud free pixels, depending on season, a considerable amount for land analysis given the very high cloud cover (75-99 percent) observed at any given time in the area. We conclude that a new generation of atmospheric correction algorithms, such as MAIAC, can help to dramatically improve vegetation estimates over tropical rain forest, ultimately leading to reduced uncertainties in satellite-derived vegetation products globally.

tropical ecosystems↗
NASA NTRS2011

Producing Science-Ready Radar Datasets for the Retrieval of Forest Structure Parameters from Backscatter: Correcting for Terrain Topography and Changes in Vegetation Reflectivity

Radar backscatter data contain both geometric and radiometric distortions due to underlying topography and the radar viewing geometry. Our objective is to develop a radiometric correction algorithm specific to the UAVSAR system configuration that would improve retrieval of forest structure parameters. UAVSAR is an airborne Lband radar capable of repeat?pass interferometry producing images with a spatial resolution of 5m. It is characterized by an electronically steerable antenna to compensate for aircraft attitude. Thus, the computation of viewing angles (i.e. look, incidence and projection) must include aircraft attitude angles (i.e. yaw, pitch and roll) in addition to the antenna steering angle. In this presentation, we address two components of radiometric correction: area projection and vegetation reflectivity. The first correction is applied by normalization of the radar backscatter by the local ground area illuminated by the radar beam. The second is a correction due to changes in vegetation reflectivity with viewing geometry.

polarimetry↗
NASA NTRS2019

Improving the AVHRR Long Term Data Record BRDF Correction

The Long Term Data Record (LTDR) project has the goal of developing a quality and consistent surface reflectance product from coarse resolution optical sensors. This paper focuses on the Advanced Very High Resolution Radiometer (AVHRR) part of the record, using the Moderate Resolution Imaging Spectrometer (MODIS) instrument as a reference. When a surface reflectance time series is acquired from satellites with variable observation geometry, the directional variation generates an apparent noise which can be corrected by modeling the bidirectional reflectance distribution function (BRDF). The VJB (Vermote, Justice and Bréon, 2009) method estimates a target’s BRDF shape using 5 years of observation and corrects for directional effects maintaining the high temporal resolution of the measurement using the instantaneous Normalized Difference Vegetation Index (NDVI). The method was originally established on MODIS data but its viability and optimization for AVHRR data have not been fully explored. In this study we analyze different approaches to find the most robust way of applying the VJB correction to AVHRR data, considering that high noise in the red band (B1) caused by atmospheric effect makes the VJB method unstable. Firstly, our results show that for coarse spatial resolution, where the vegetation dynamics of the target don’t change significantly, deriving BRDF parameters from 15+ years of observations reduces the average noise by up to 7% in the Near Infrared (NIR) band and 6% in the NDVI, in comparison to using 3-year windows. Secondly, we find that the VJB method can be modified for AVHRR data to improve the robustness of the correction parameters and decrease the noise by an extra 8% and 9% in the red and NIR bands with respect to using the classical VJB inversion. We do this by using the Stable method, which obtains the volumetric BRDF parameter (V) based on its NDVI dependency, and then obtains the geometric BRDF parameter (R) through the inversion of just one parameter.

LTDR↗
NASA NTRS2023

Assessment of the Performance of the Atmospheric Correction Algorithm MAJA for Sentinel-2 Surface Reflectance Estimates

The correction of atmospheric effects on optical remote sensing products is an essential component of Analysis Ready Data (ARD) production lines. The MAJA processor aims at providing accurate time series of surface reflectances over land for satellite missions, such as Sentinel-2, Venμs, and Landsat 8. The Centre d’Études Spatiales de la Biosphère (CESBIO) and the Centre National d’Études Spatiales (CNES) share a common effort to maintain, validate, and improve the MAJA processor, using state-of-the-art ground measurement sites, and participating in processor inter-comparisons, such as the Atmospheric Correction Intercomparison Exercise (ACIX). While contributing to the second ACIX-II Land validation exercise, it was found that the candidate MAJA dataset could not adequately be compared to the main reference dataset. MAJA reflectances were corrected for adjacency and topography effects while the reference dataset was not, excluding MAJA from a part of the performance metrics of the exercise. The first part of the following study aims at providing complementary performance assessment to ACIX-II by reprocessing MAJA surface reflectances without adjacency nor topographic correction, allowing for an un-biased full resolution comparison with the reference Sentinel-2 dataset. The second part of the study consists of validating MAJA against surface reflectance measurements time series of up to five years acquired at three automated stations. Both approaches provide extensive insights on the quality of MAJA Sentinel-2 Level 2 products.

ROSAS↗
DOE OSTI2019

On the connection between hydrodynamics and quantum chaos in holographic theories with stringy corrections

Pole-skipping is a recently discovered signature of many-body quantum chaos in collective energy dynamics. It establishes a precise connection between resummed, all-order hydrodynamics and the underlying microscopic chaos. In this paper, we demonstrate the existence of pole-skipping in holographic conformal field theories with higher-derivative gravity duals. In particular, we first consider Einstein-Hilbert gravity deformed by curvature-squared ( R 2 ) corrections and then type IIB supergravity theory with the α ' 3 R 4 term, where α ' is set by the length of the fundamental string. The former case allows us to discuss the effects of leading-order 1 /N c corrections (with N c being the number of colours of the dual gauge group) and phenomenological coupling constant dependence. In Einstein-Gauss-Bonnet theory, pole-skipping turns out to be valid non-perturbatively in the Gauss-Bonnet coupling. The α ' 3 R 4 deformation enables us to study perturbative inverse ’t Hooft coupling corrections ( α ' 3 ~ 1 /λ 3/2 ) in SU( N c ), \( \mathcal{N}=4 \) supersymmetric Yang-Mills theory with infinite N c . While the maximal Lyapunov exponent characterising quantum chaos remains uncorrected, the butterfly velocity is shown to depend both on N c and the coupling. Several implications of the relation between hydrodynamics and chaos are discussed, including an intriguing similarity between the dependence of the butterfly velocity and the ratio of shear viscosity to entropy density on stringy corrections.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Isospin-breaking corrections to light-meson leptonic decays from lattice simulations at physical quark masses

The decreasing uncertainties in theoretical predictions and experimental measurements of several hadronic observables related to weak processes, which in many cases are now smaller than O(1%), require theoretical calculations to include subleading corrections that were neglected so far. Precise determinations of leptonic and semi-leptonic decay rates, including QED and strong isospin-breaking effects, can play a central role in solving the current tensions in the first-row unitarity of the CKM matrix. In this work we present the first RBC/UKQCD lattice calculation of the isospin-breaking corrections to the ratio of leptonic decay rates of kaons and pions into muons and neutrinos. The calculation is performed at fixed lattice spacing (a –1 ≃ 1.730 GeV) on a 48 3 × 96 volume with N f = 2 + 1 dynamical quarks close to the physical point and domain wall fermions in the Möbius formulation are employed. Long-distance QED interactions are included according to the QED L prescription and the crucial role of finite-volume electromagnetic corrections in the determination of leptonic decay rates, which produce a large systematic uncertainty, is extensively discussed. Finally, we study the different sources of uncertainty on |V us |/|V ud | and observe that, if finite-volume systematics can be reduced, the error from isospin-breaking corrections is potentially sub-dominant in the final precision of the ratio of the CKM matrix elements.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2019

Eigenstate thermalization hypothesis and approximate quantum error correction

The eigenstate thermalization hypothesis (ETH) is a powerful conjecture for understanding how statistical mechanics emerges in a large class of many-body quantum systems. It has also been interpreted in a CFT context, and, in particular, holographic CFTs are expected to satisfy ETH. Recently, it was observed that the ETH condition corresponds to a necessary and sufficient condition for an approximate quantum error correcting code (AQECC), implying the presence of AQECCs in systems satisfying ETH. In this paper, we explore the properties of ETH as an error correcting code and show that there exists an explicit universal recovery channel for the code. Based on the analysis, we discuss a generalization that all chaotic theories contain error correcting codes. We then specialize to AdS/CFT to demonstrate the possibility of total bulk reconstruction in black holes with a well-defined macroscopic geometry. When combined with the existing AdS/CFT error correction story, this shows that black holes are enormously robust against erasure errors.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

A method for correcting the substructure of multiprong jets using the Lund jet plane

Many analyses at the CERN LHC exploit the substructure of jets to identify heavy resonances produced with high momenta that decay into multiple quarks and/or gluons. This paper presents a new technique for correcting the substructure of simulated large-radius jets from multiprong decays. The technique is based on reclustering the jet constituents into several subjets such that each subjet represents a single prong, and separately correcting the radiation pattern in the Lund jet plane of each subjet using a correction derived from data. The data presented here correspond to an integrated luminosity of 138 fb −1 collected by the CMS experiment between 2016–2018 at a center-of-mass energy of 13 TeV. The correction procedure improves the agreement between data and simulation for several different substructure observables of multiprong jets. This technique establishes, for the first time, a robust calibration for the substructure of jets with four or more prongs, enabling future measurements and searches for new phenomena containing these signatures.

Hadron-Hadron Scattering↗
DOE OSTI2018

Power corrections for N-jettiness subtractions at $ \mathcal{O}\left({\alpha}_s\right) $

We continue the study of power corrections for N -jettiness subtractions by analytically computing the complete next-to-leading power corrections at O(α s ) for colorsinglet production. This includes all nonlogarithmic terms and all partonic channels for Drell-Yan and gluon-fusion Higgs production. These terms are important to further improve the numerical performance of the subtractions, and to better understand the structure of power corrections beyond their leading logarithms, in particular their universality. We emphasize the importance of computing the power corrections differential in both the invariant mass, Q, and rapidity, Y, of the color-singlet system, which is necessary to account for the rapidity dependence in the subtractions. This also clarifies apparent disagreements in the literature. Performing a detailed numerical study, we find excellent agreement of our analytic results with a previous numerical extraction.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

Finite Size Corrections to the Parisi Overlap Function in the GREM

We investigate the effects of finite size corrections on the overlap probabilities in the Generalized Random Energy Model in two situations where replica symmetry is broken in the thermodynamic limit. Our calculations do not use replicas, but shed some light on what the replica method should give for finite size corrections. In the gradual freezing situation, which is known to exhibit full replica symmetry breaking, we show that the finite size corrections lead to a modification of the simple relations between the sample averages of the overlaps Y{sub k} between k configurations predicted by replica theory. This can be interpreted as fluctuations in the replica block size with a negative variance. The mechanism is similar to the one we found recently in the random energy model in Derrida and Mottishaw (J Stat Mech 2015(1): P01021, 2015). We also consider a simultaneous freezing situation, which is known to exhibit one step replica symmetry breaking. We show that finite size corrections lead to full replica symmetry breaking and give a more complete derivation of the results presented in Derrida and Mottishaw (Europhys Lett 115(4): 40005, 2016) for the directed polymer on a tree.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Assessment of attenuation correction for myocardial PET imaging using combined PET/MRI

Objective: To evaluate the frequency of artifacts in MR-based attenuation correction (AC) maps and their impact on the quantitative accuracy of PET-based flow and metabolism measurements in a cohort of consecutive heart failure patients undergoing combined PET/MR imaging. Methods: Myocardial viability studies were performed in 20 patients following a dual-tracer protocol involving the assessment of myocardial perfusion ({sup 13}N-NH{sub 3}: 813 ± 86 MBq) and metabolism ({sup 18}F-FDG: 335 ± 38 MBq). All acquisitions were performed using a fully-integrated PET/MR system, with standard DIXON-attenuation correction (DIXON-AC) mapping for each PET scan. All AC maps were examined for spatial misalignment with the emission data, total lung volume, susceptibility artifacts, and tissue inversion (TI). Misalignment and susceptibility artifacts were corrected using rigid co-registration and retrospective filling of the susceptibility-induced gaps, respectively. The effects of the AC artifacts were evaluated by relative difference measures and perceived changes in clinical interpretations. Results: Average respiratory misalignment of (7 ± 4) mm of the PET-emission data and the AC maps was observed in 18 (90%) patients. Substantial changes in the lung volumes of the AC maps were observed in the test–retest analysis (ratio: 1.0 ± 0.2, range: 0.8-1.4). Susceptibility artifacts were observed in 10 (50%) patients, while six (30%) patients had TI artifacts. Average differences of 14 ± 10% were observed for PET images reconstructed with the artifactual AC maps. The combined artifact effects caused false-positive findings in three (15%) patients. Conclusion: Standard DIXON-AC maps must be examined carefully for artifacts and misalignment effects prior to AC correction of cardiac PET/MRI studies in order to avoid misinterpretation of biased perfusion and metabolism readings from the PET data.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2018

DSP methods for correcting dispersion and pulse width effects during pulsed wire measurements

Measuring a magnetic field by applying electric current to a wire in a magnetic field for a short duration and recording the resulting travelling wave is referred to as the pulsed wire method. This technique is beneficial when other methods for acquiring magnetic field data are not feasible, e.g. small aperture limit of a Hall probe to measure an insertion device, or it can be used as a complement to other techniques. Data collected during pulsed wire measurements require corrections due to dispersion of the travelling wave and averaging effects of the current pulse duration. As a result, a flexible method for correcting dispersion has been developed using all pass digital filtering techniques and deconvolution is used to correct for pulse width averaging. Implementing the correction method is described along with the results of measuring a reference magnet and a 2.4-meter long undulator.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

Absorption Correction for Reliable Pair Distribution Functions from Low Energy X-ray Sources

This paper explores the development and testing of a simple absorption correction model for processing powder X-ray diffraction data from Debye−Scherrer geometry laboratory X-ray experiments. This may be used as a preprocessing step before using PDFGETX3 to obtain reliable pair distribution functions (PDFs). Various experimental and theoretical methods for estimating μR were explored, and the most appropriate μR values for correction were identified for different capillary diameters and X-ray beam sizes. We identify operational ranges of μR where a reasonable signal-to-noise ratio is possible after correction. A user-friendly software package, DIFFPY.LABPDFPROC, is presented that can help estimate μR and perform absorption corrections with a rapid calculation for efficient processing.

Absorption↗
DOE OSTI2022

Systematic Evaluation of Counterpoise Correction in Density Functional Theory

A widespread belief persists that the Boys–Bernardi function counterpoise (CP) procedure “overcorrects” supramolecular interaction energies for the effects of basis-set superposition error. To the extent that this is true for correlated wave function methods, it is usually an artifact of low-quality basis sets. The question has not been considered systematically in the context of density functional theory, however, where basis-set convergence is generally less problematic. We present a systematic assessment of the CP procedure for a representative set of functionals and basis sets, considering both benchmark data sets of small dimers and larger supramolecular complexes. The latter include layered composite polymers with ~150 atoms and ligand–protein models with ~300 atoms. Provided that CP correction is used, we find that intermolecular interaction energies of nearly complete-basis quality can be obtained using only double-ζ basis sets. Furthermore, this is less expensive as compared to triple-ζ basis sets without CP correction. CP-corrected interaction energies are less sensitive to the presence of diffuse basis functions as compared to uncorrected energies, which is important because diffuse functions are expensive and often numerically problematic for large systems. Our results upend the conventional wisdom that CP “overcorrects” for basis-set incompleteness. In small basis sets, CP correction is mandatory in order to demonstrate that the results do not rest on error cancellation.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2026

Assessing the Limitations of Self-Interaction-Corrected Functionals for Describing the Hydrated Electron

Simulating the hydrated electron using density functional theory is challenging due to the prevalence of self-interaction error in standard functionals. Hybrid functionals like PBEh(40) can reasonably describe the chemistry of an excess electron in water and partially mitigate self-interaction error by incorporating exact Hartree–Fock exchange, but they are computationally expensive making them impractical for large-scale and long-time ab initio molecular dynamics simulations. Explicit self-interaction correction schemes that are applied on an orbital-by-orbital basis offer a potential alternative when the correction is limited to the singly occupied molecular orbital obtained with a generalized gradient approximation functional. Here, we examine whether the Perdew–Zunger self-interaction correction scheme applied to the revPBE functional can provide a computationally efficient and physically sensible alternative to PBEh(40) for the hydrated electron. We find that functionals incorporating a self-interaction correction scheme should be viewed with caution when applied to the hydrated electron and its reactivity. Furthermore, we show that it is critical to consider extensive sampling and diverse chemical environments when validating their performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Correction to “Ruthenium Dye Excitations and Relaxations in Natural Sunlight”

An error in computing the optical rate coefficients for dye RuP was discovered in Table S4 of the Supporting Information Section S8 Model S? for this article, published in J. Phys. Chem. A, 2021, 125, 4365-4372, 10.1021/acs.jpca.1c02386. The optical rate coefficients include absorption, stimulated emission, and ground-state bleach associated with the ground state and the singlet and triplet excited states as well as for the excited-state absorption between the excited states and implicit higher-energy excited states. The optical rate coefficients for continuous solar irradiance were computed using eq 3 of the main text in which the product of the individual signal components and the solar spectrum are integrated and multiplied by the fundamental optical rate coefficient. We determined the incorrect signal components were used for RuP in the published Supporting Information Table S4. The corrected Table S4 column for RuP is presented with the reported values from the original paper in the corrected Supporting Information. New simulations have been performed using the corrected values, and the results were used to update Figures 5 and 6 and also Figure S9 in the corrected Supporting Information. The published conclusions are unchanged. The populations of RuP excited states, Figure 5, are only marginally smaller, which should be expected with minor changes to the optical rate coefficients. There is not a significant change in the results for the number of radiative and nonradiative interactions per dye per second (the optical transitions and nonradiative transitions increased, respectively, by approximately 2% and 10%, Figure 6A). The occurrence of excited-state absorption (ESA) and excited-state emission (ESE) events, Figure 6C, both decreased from the original simulation results by 20% and 33%. The most notable difference is exhibited in Figure 6B; the fraction of population moving from the lowest-energy singlet state (i.e., intersystem crossing or ultrafast nonradiative relaxation) and nonradiative relaxation from the triplet state have decreased from ~0.45 to ~0.4 and increased from ~0.35 to ~0.4, respectively..

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Evaluating Thermal Corrections for Adsorption Processes at the Metal/Gas Interface

Adsorption and desorption steps are key for active catalysts and rely on a subtle balance between enthalpic and entropic terms. Although the enthalpic term is becoming ever more accurate through density functional development, the entropic term remains underrated and its precise determination a great challenge. In this work, we have performed extensive first principles thermodynamic integration (TI) simulations for the adsorption of small (e.g., CO) to larger (e.g., phenol) molecules at metallic surfaces and compared their adsorption free energies to the values obtained by vertical, static statistical mechanics approximations to thermal corrections invoking three different approximations for the low-frequency modes. We have found an excellent agreement between the vertical corrections and the TI for minima, for both weakly bound systems (e.g. CO 2 and formic acid) and strongly chemisorbed molecules such as phenol or CO. While the treatment of the low-frequency modes has a minor impact on the agreement with TI, all vertical corrections systematically overestimate activation energies by 0.1-0.2 eV compared to TI, demonstrating a noticeable lowering of activation barriers. As an effect of this study, we suggest that the vertical corrections and in particular the standard harmonic approximation can be safely applied to chemisorption minima, while the activation energies are likely to be overestimated. Hence, if a greater accuracy than ~0.2 eV is required for activation free energies, we recommend to use thermodynamic integration, which for small to medium-sized molecules in gas phase is accessible with a reasonable computational effort, but requires a dense sampling in the transition state region.

Réocreux, Romain↗
DOE OSTI2018

Correction Scheme for Comparison of Computed and Experimental Optical Transition Energies in Functionalized Single-Walled Carbon Nanotubes

We present that covalent functionalization of single-walled carbon nanotubes (SWCNTs) introduces red-shifted emission features in the near-infrared spectral range due to exciton localization around the defect site. Such chemical modifications increase their potential use as near-infrared emitters and single-photon sources in telecommunications applications. Density functional theory (DFT) studies using finite-length tube models have been used to calculate their optical transition energies. Predicted energies are typically blue-shifted compared to experiment due to methodology errors including imprecise self-interaction corrections in the density functional and finite-size basis sets. Furthermore, artificial quantum confinement in finite models cannot be corrected by a constant-energy shift since they depend on the degree of exciton localization. Herein, we present a method that corrects the emission energies predicted by time-dependent DFT. Confinement and methodology errors are separately estimated using experimental data for unmodified tubes. Finally, corrected emission energies are in remarkable agreement with experiment, suggesting the value of this straightforward method toward predicting and interpreting the optical features of functionalized SWCNTs.

36 MATERIALS SCIENCE↗