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At least 307 records · Page 17

Carbon monoxide pollution experiment. I - A solution to the carbon monoxide sink anomaly.

The observed lack of a high rate of growth in global CO concentration implies that there is some sink mechanism for destroying the CO as rapidly as it is being produced. A program is described which is intended to develop both the experiment concept and the remote sensor required to measure atmospheric CO with sufficient accuracy to locate the sink, whether it be at the earth's surface or in the upper atmosphere. The program calls for the development of a remote sensor which can look for surface sinks by mapping the vertical CO burden in the atmosphere on a daily basis, and which can look for an upper atmospheric sink by means of measurements of total CO in a horizontal path through the limb of the earth's atmosphere, using the sun as the source.

Grenda, R. N.↗

High resolution spectroscopic measurements of carbon dioxide and carbon monoxide

A modified 1.83 meter Jarrell-Ash spectrometer is reported. The instrument was double passed and achieved a resolution of 0.05 cm at 15 micrometers. An integrating voltmeter was used to optimize the available integration time. Data were obtained in the 15 micrometer and 4.3 micrometer band of CO2 and the 4.6 micrometer and 2.3 micrometer bands of CO. The data are summarized and examples of typical spectra are given. All the data are stored on IBM cards.

Chaney, L. W.↗

Stability analysis of a reinforced carbon carbon shell

This paper presents the development of a stability analysis for the nose cap of the NASA Space Shuttle Orbiter. Stability is evaluated by the differential stiffness analysis of the NASTRAN finite-element computer code, addressing those nonstandard characteristics in the nose cap such as nonuniform curvature, asymmetrical and nonuniform loads, support fixity, and various combinations of membrane and bending stresses. A full-sized nose cap, thinner than production, was statically tested and stability analyzed. The failing load level correlated to within 30%. The region and mode of buckling that occurred during test was accurately predicted by analysis. The criterion for predicting instability is based on the behavior of the nonlinear deflections. The deflections are nonlinear elastic in that the stresses are well within the elastic range of the material, but the geometry-load relationship produces nonlinear deflections. The load-deflection relationship is well defined by differential stiffness analysis up to the zero-slope portion of the curve, the point of neutral stability or where the shell 'snaps through' just prior to general instability.

Agan, W. E.↗

Coupling between the nickel-carbon and carbon-oxygen stretch motion in NiCO

Linear-combination-of-Gaussian-type-orbital (LCGTO) X-alpha calculations are performed on NiCO for various linear Ni-CO and NiC-O bond distances. The basis sets used are moderately large, approximately double zeta, and thus are fairly accurate within the X-alpha approximation. The electronic structure and equilibrium bond distances are consistent with recent CI calculations, indicating a much stronger Ni-CO bond than occurs in Ni(CO)4. The calculations agree to within 100/cm with the experimentally observed NiC-O stretch frequency. The Ni-CO stretch is predicted to occur at 656/cm, although at an intensity that is 640 times less. Compared with experimental results for CO adsorbed on single crystal Ni(100), the computed vibrational frequencies and intensities are less appropriate than the relevant experimental values for Ni(CO)4. This is interpreted to mean that an accurate description of the electronic structure of the nickel atom participating directly in the surface bond requires proper accounting of the bonds to its other nearest neighbors.

Dunlap, B. I.↗