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At least 307 records · Page 17

Two-stage gas measurement system

A quick-response, real-time gaseous measurement system allows for the continuous sampling of a low pressure gaseous environment. A sample of test gas from the low pressure gaseous environment is continuously extracted and pumped to a structural tee joint which is open to the atmosphere at one end to maintain the test gas at a constant pressure. The structural tee joint communicates at the other end with a heater for maintaining the test gas at a constant temperature. From the heater, the test gas is sent to a sensor which develops a voltage that is proportional to the partial pressure of the gaseous component to be measured in the test gas, a constant flow rate of test gas being provided through the heater and sensor. Since test gas pressure, temperature, and flow rate are being held constant, changes in sensor voltage are attributable only to changes in the concentration of the measured gas component.

Sprinkle, Danny R.↗

Solar cycle dependence of the location of the Venus bow shock

Initial measurements of the Venus bow shock obtained by Pioneer Venus in 1979 near solar maximum indicated that the bow shock was on average 2.44 RV from the center of the planet in the terminator plane. This is 0.35 RV further from Venus than observed by Venera 9/10 in 1976. In the past this discrepancy has been attributed to some effect of the solar cycle. Recent measurements by Pioneer Venus support this interpretation. In 1980 the distance to the bow shock reached a maximum of 2.45 RV and since then has been almost steadily declining toward the distance measured by Venera near solar minimum. The variation in bow shock position is well correlated with the sunspot number and the F 10.7 cm flux over this period. This behavior is attributed to the variation in the neutral atmosphere of Venus with the solar cycle and its subsequent effect on the mass-loading of the solar wind.

Alexander, C. J.↗

New reference materials for trace-levels of actinide elements in plutonium

In this report two plutonium oxides were prepared as unique reference materials for measurement of actinide elements present as trace constituents. Each reference material unit is approximately 200 mg of PuO 2 powder in a quartz glass bottle. Characterized attributes of the oxides included mass fractions of plutonium, americium, neptunium, and uranium. Isotope-amount ratios were also determined for plutonium and uranium, but neptunium and americium were observed to be monoisotopic 237 Np and 241 Am. Measurements for characterization and verification of the attributes show that plutonium and trace actinides are homogeneous with the exception of limited heterogeneity for uranium, primarily observed for the 238 U isotope. Model purification ages calculated from measured americium and uranium attribute values are consistent with material histories and indicate that these impurities are predominantly due to the decay of plutonium isotopes.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

IUE spectroscopy, visible-band photometry, and polarimetry of HD 47732 (V641 Monocerotis)

Several high- and low-dispersion IUE spectra are described for the hot, massive close binary HD 47732. The stellar silicon lines do not show theoretically expected strength, the weakness being attributed to incipicent emission. A weak stellar wind is measurable with an expansion velocity of about 500 km/s. There is difficulty in fitting a model atmosphere to all of the IUE continuum and visible band and IR measures. These difficulties are resolved by appealing to a 22,500 K model atmosphere and a distinctive interstellar extinction law. Numerous V band measures show the polarization to be variable, but not strongly in a phased-locked way. This suggests sporadic outbursts of gas feeding the shell. Several seasonal V band light curves are discussed, and the seasonal variations among them are attributed to variable developments of a systemic shell which scatters the photospheric light and dilutes to a variable degree the light variation due to ellipticity of figure of the component stars.

Koch, R. H.↗

A Deeper Look at the Fundamentals of Heterodyne Detection Requirements

We generally accept the experimentally observed criteria for heterodyne detections that the two waves that are mixed must (i) be collinear, (ii) have matched wave fronts and (iii) cannot be orthogonally polarized. We have not found in the literature adequate physical explanations for these requirements. The purpose of this paper is to find deeper physical understanding of the coherent heterodyne detection processes that could lead to better coherent laser radar system designs1. We find that there are a number of unresolved paradoxes in classical and quantum optics regarding the definitions and understanding of the "interference" and "coherence" properties of light, which are attributed as essentially due to inherent properties of the EM waves. A deeper exploration indicates that it is the various quantum mechanical properties of the detecting material dipoles that make light detectable (visible, or measurable) to us. Accordingly, all the properties that we generally attribute to only light, are in reality manifestations of collective properties of dipole-light interactions. "Interference" and "coherence" can be better understood in terms of this mutual interaction, followed by energy absorption by the dipoles from EM wave fields, manifesting in some measurable transformation of the detecting dipoles. Light beams do not interfere by themselves. The superposition effects due to light beams become manifest through the response characteristics of the detecting dipoles. In this paper, we will show some preliminary expe rimental results that clearly demonstrate that the heterodyning wave fronts have quantitative degradation in signal generation as the angle between them deviates from perfect collinearity. Subsequently, we will propose a hypothesis for this behavior. We will present experimental data establishing that the so called incoherent light can be detected through heterodyne mixing as long as the pulse length contained in the "incoherent" light is longer than the response time of the detector. We will also present a correspondingly better interpretation of two distinguishable coherence properties, temporal coherence and spectral coherence. Our investigation provides a deeper insight into how to rela x various system requirements for heterodyne detection and accordingly develop systems that are simpler, more reliable and lower in cost. Also, we believe that engineering of detector architecture by appropriately modifying dipole behavior using emerging nanotechnology to optimize heterodyne efficiency will be advantageous.

Roychoudhuri, Chandrasekhar↗

Wide-angle astrometry with the Mark III stellar interferometer

Astrometric measurements made with the Mark III stellar interferometer on five nights in August-September 1988 yielded average formal 1-sigma errors for 12 FK5 stars of 6 mas in declination and 10 mas in right ascension. This improvement in precision over previously reported measurements with this instrument made in 1986 is attributable to several factors: a second 12 m baseline; oriented E-S, was added to the instrument to improve the determination of right ascension; two-color analysis was included in the data-reduction process, along with a new central-fringe identification algorithm using three spectral channels, in order to reduce atmospheric errors; thermal control was greatly improved; and changes were made to observational procedures and hardware to monitor variations in the delay offset due to residual thermal drifts. Approximately half of the new positions are within 50 mas of their FK5 positions. However, an extended series of measurements are needed to ascertain the accuracy that can be achieved by interferometry.

Shao, M.↗

Acoustic Treatment Design Scaling Methods: Analytical and Experimental Data Correlation - Volume 5

The primary purpose of the study presented in this volume is to present the results and data analysis of in-duct transmission loss measurements. Transmission loss testing was performed on full-scale, 1/2-scale, and 115-scale treatment panel samples. The objective of the study was to compare predicted and measured transmission loss for full-scale and subscale panels in an attempt to evaluate the variations in suppression between full- and subscale panels which were ostensibly of equivalent design. Generally, the results indicated an unsatisfactory agreement between measurement and prediction, even for full-scale. This was attributable to difficulties encountered in obtaining sufficiently accurate test results, even with extraordinary care in calibrating the instrumentation and performing the test. Test difficulties precluded the ability to make measurements at frequencies high enough to be representative of subscale liners. It is concluded that transmission loss measurements without ducts and data acquisition facilities specifically designed to operate with the precision and complexity required for high subscale frequency ranges are inadequate for evaluation of subscale treatment effects.

Chien, W. E.↗

MESSENGER Measurements of Mercury's Magnetic Field during the First Flyby

On 14 January 2008 the MESSENGER spacecraft will encounter Mercury for the first time. Depending upon the solar wind conditions, this initial flyby will return Magnetometer measurements of Mercury's magnetic field over a time interval lasting between - 30 md 60 min. Closest approach for MESSENGER is targeted for an altitude of 200 km as compared with the 707 krn and 327 km attained by Mariner 10 on 29 March 1974 and 16 March 1975, respectively. Furthermore, the differences in the MESSENGER and Mariner 10 encounter trajectories, with respect both to magnetospheric and body-fixed coordinates are highly complementary and expected to lead to significant improvements in our knowledge of Mercury's magnetic field. We present an overview of the MESSENGER magnetic field observations, an initial subtraction of the magnetic fields attributable to magnetospheric current systems from the total measured magnetic field, and an improved model of Mercury's intrinsic magnetic field. We also discuss the expected advances afforded by the two additional MESSENGER flybys, which occur in October 2008 and September 2009, as well as the orbital phase that will begin in March 201 1.

Slavin, James A.↗

X-ray-line coincidence photopumping in a potassium-chlorine mixed plasma

Exploiting the multiple long pulse capability and suite of x-ray diagnostics of the Orion laser, we have set out to explore line coincidence photopuming—the enhancement in population of an atomic level brought on by resonant absorption of x rays from a different emitting ion. Unlike previous work, the two ions are in the same plasma and so the experiment is an x-ray analog of the well-known Bowen resonance fluorescence mechanism that operates in astrophysical situations in the optical region. Herein, our measurements have shown enhanced fluorescence in a chlorine plasma, attributable to line coincident photopumping from co-mixed potassium ions. To detect this relatively low signal-to-noise phenomenon, the data from multiple shots are combined, and the statistical method of bootstrapping is used to assign a confidence value to the measured enhancement, resulting in an estimate of the enhancement of 39 ± 18 16 % compared to the null case, where no pumping occurs. The experimental results have been compared to coupled radiation-transport and radiation hydrodynamics simulations using the CRETIN code together with the NYM radiation hydrodynamics model and agreement has been found, with the simulations also predicting modest enhancement.

74 ATOMIC AND MOLECULAR PHYSICS↗

Physics of debris clouds from hypervelocity impacts

The protection scheme developed for long duration space platforms relies primarily upon placing thin metal plates or 'bumpers' around flight critical components. The effectiveness of this system is highly dependent upon its ability to break up and redistribute the momentum of any particle which might otherwise strike the outer surface of the spacecraft. Therefore it is of critical importance to design the bumpers such that maximum dispersion of momentum is achieved. This report is devoted to an in-depth study into the design and development of a laboratory instrument which would permit the in-situ monitoring of the momentum distribution as the impact event occurs. A series of four designs were developed, constructed and tested culminating with the working instrument which is currently in use. Each design was individually tested using the Space Environmental Effects Facility (SEEF) at the Marshall Space Flight Center in Huntsville, Alabama. Along with the development of the device, an experimental procedure was developed to assist in the investigation of various bumper materials and designs at the SEEF. Preliminary results were used to compute data which otherwise were not experimentally obtainable. These results were shown to be in relative agreement with previously obtained values derived through other methods. The results of this investigation indicated that momentum distribution could in fact be measured in-situ as the impact event occurred thus giving a more accurate determination of the effects of experimental parameters on the momentum spread. Data produced by the instrument indicated a Gaussian-type momentum distribution. A second apparatus was developed and it was placed before the shield in the line of travel utilized a plate to collect impact debris scattered backwards. This plate had a passage hole in the center to allow the particle to travel through it and impact the proposed shield material. Applying the law of conservation of angular momentum a backward momentum vector was determined from the angular velocity of the plate. The forward scattered and backward scattered momentum values were then analyzed to judge the distribution of debris. Loss of momentum was attributed to the inaccuracies of the means of measurement. Assumptions of symmetrical debris for the forward and backward scattered directions also contributed to this loss.

Zee, Ralph↗

Rocket plume flowfield characterization using laser Rayleigh scattering

A Doppler-resolved laser Rayleigh scattering diagnostic was applied to a 111 N thrust, regenerative and fuel-film cooled, gaseous hydrogen/gaseous oxygen rocket engine. The axial and radial mean gas velocities were measured from the net Doppler shifts observed for two different scattering angles. Translational temperatures and number densities were estimated from the Doppler widths and scattered intensities, respectively, by assuming that water was the dominant scattering species in the exhaust. The experimental results are compared with theoretical predictions from a full Navier-Stokes code (RD/RPLUS) and the JANNAF Two-Dimensional Kinetics (TDK) and Standardized Plume Flowfield (SPF-II) codes. Discrepancies between the measured and predicted axial velocities, temperatures, and number densities are evident. Radial velocity measurements, however, show excellent agreement with predictions. The discrepancies are attributed primarily to inefficient mixing and combustion caused by the injection of excessive oxidizer along one side of the thrust chamber. Thrust and mass flow rate estimates obtained from the Rayleigh measurements show excellent agreement with the globally measured values.

Zupanc, Frank J.↗

Rocket plume flowfield characterization using laser Rayleigh scattering

A Doppler-resolved laser Rayleigh scattering diagnostic was applied to a 111 N thrust, regenerative and fuel-film cooled, gaseous hydrogen/gaseous oxygen rocket engine. The axial and radial mean gas velocities were measured from the net Doppler shifts observed for two different scattering angles. Translational temperatures and number densities were estimated from the Doppler widths and scattered intensities, respectively, by assuming that water was the dominant scattering species in the exhaust. The experimental results are compared with theoretical predictions from a full Navier-Stokes code (RD/RPLUS) and the JANNAF Two-Dimensional Kinetics (TDK) and Standardized Plume Flowfield (SPF-II) codes. Discrepancies between the measured and predicted axial velocities, temperatures, and number densities are evident. Radial velocity measurements, however, show excellent agreement with predictions. The discrepancies are attributed primarily to inefficient mixing and combustion caused by the injection of excessive oxidizer along one side of the thrust chamber. Thrust and mass flow rate estimates obtained from the Rayleigh measurements show excellent agreement with the globally measured values.

Zupanc, Frank J.↗

Solar position confounds the relationship between ecosystem function and vegetation indices derived from solar and photosynthetically active radiation fluxes

Vegetation indices derived from solar and photosynthetically active radiation (PAR) sensors (i.e. radiation derived) have been under-utilized in inferring ecosystem function, despite measurement capability at hundreds of sites. This under-utilization may be attributed to reported mismatches among the seasonality of radiation- and satellite-derived vegetation indices and canopy photosynthesis; herein referred to as measurement biases. In this work, biases in radiation derived reflectance and vegetation indices were assessed using a decadal record of satellite and ground based spectroradiometer data, ecosystem phenology and CO 2 fluxes, and radiation derived vegetation indices (i.e. the Normalized Difference Vegetation Index [NDVI], the two band Enhanced Vegetation Index [EVI2]) from a high latitude tundra site (i.e. Imnaviat). At Imnaviat, we found poor correspondence between the three types of reflectance and vegetation indices, especially during the latter part of the growing season. Radiation derived vegetation indices resulted in incorrect estimates of phenological timing of up to a month and poor relationships with canopy photosynthesis (i.e. Gross Ecosystem Exchange (GEE)). These mismatches were attributed to solar position (i.e. solar zenith and azimuth angle) and a method, based on the diel visible and near-infrared albedo variation, was developed to improve the performance of the vegetation indices. The ability of radiation derived vegetation indices to infer GEE and phenological dates drastically improved once radiation derived vegetation indices were corrected for solar position associated biases at Imnaviat. Moreover, radiation derived vegetation indices became better aligned with MODerate resolution Imaging Spectroradiometer (MODIS) satellite estimates after solar position associated biases were corrected at Imnaviat and at 25 Fluxnet sites (~90 site years) across North America. Corrections developed here provide a way forward in understanding daily ecosystem function or filling large gaps in eddy covariance data at a significant number of Fluxnet sites.

54 ENVIRONMENTAL SCIENCES↗

Melting of magnesium oxide up to two terapascals using double-shock compression

Constraining the melting behavior of magnesium oxide, a major constituent of gaseous and rocky planets, is key to benchmarking their evolutionary models. Using a double-shock technique, we extended the MgO melt curve measurements to 2 TPa; this is twice the pressure achieved by previous melting experiments on any material. A temperature plateau is observed between 1218 and 1950 GPa in the second shock states, which is attributed to latent heat of melting. At 1950 GPa, the measured melting temperature is 17,600 K, 17% lower than recent theoretical predictions. Furthermore, the melting curve is steeper than that of MgSiO 3 , indicating that MgO is likely solid in the interior of Saturn-sized gas giants and extra-solar super-Earth planets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Investigating Deposition Sequence During Synthesis of Pd/Al2O3 Catalysts Modified with Organic Monolayers

Modification of supported metal catalysts with self-assembled monolayers (SAMs) has been shown to improve selectivity and turnover frequencies (TOFs) for many catalytic reactions. However, these benefits are often accompanied by a decrease in overall mass activity due to partial blocking of active sites by the monolayers. Therefore, a potential method for increasing site accessibility is to deposit the active metal (e.g., Pd) after deposition of a SAM modifier on the support material. In this work, Pd/Al2O3 catalysts were synthesized using both a conventional, "metal-first" sequence in which the phosphonic acid (PA) SAM was deposited on Pd/Al2O3 and a "SAM-first" technique in which the ligands were deposited onto the support prior to deposition of the metal. Although metal-first catalysts showed a significant increase in TOF during benzyl alcohol HDO, they exhibited only a modest increase in overall mass activity due to a decrease in the number of active sites. Meanwhile, SAM-first catalysts showed similar improvements in TOF and toluene selectivity but exhibited significantly improved HDO rates compared to metal-first catalysts. The rate increase was attributed to reduced site blocking as evidenced by CO chemisorption measurements. Additionally, analysis of catalysts having high Pd loadings using transmission electron microscopy (TEM) showed that SAM-first catalysts generally resulted in lower average particle sizes than traditionally modified and unmodified catalysts, suggesting that precoating the support surface with PAs changes the way that Pd is deposited during incipient wetness, leading here to improved activity.

catalytic reactions↗

Optical and Atomic Force Microscopy Characterization of PbI2 Quantum Dots

Lead iodide (PbI2) clusters were synthesized from the chemical reaction of NaI (or KI) with Pb(NO3)2 in H2O, D2O, CH3OH, and C3H7OH media. The observation of the absorption features above 350 nm with the help of integrating sphere accessory strongly suggests the quantum dot formation of PbI2 in solution. Spectral comparison between the synthesized PbI2 clusters in solution and PbI2 nanophase by impregnation of PbI2 in four different pore-sized porous silica indicates that the PbI2 cluster size in solution is less than 2.5 nm in lateral dimension. Atomic force microscopy (AFM) measurements show that the PbL clusters deposited onto three different molecularly flat surfaces are single-layered. The measured height is 1.0 - 0.1 nm. The swollen layer thickness can be attributed to the intralayer contraction from the strong lateral interaction among PbI2 molecules, which is supported by ab initio calculation. Raman scattering measurement of LO and TO modes of PbI2 in bulk and in the confined state were also conducted in 50-150 cu cm region. The observed three bands at 74, %, 106 1/cm are assigned to TO2, LO2, and LO, mode, respectively. The relatively small red-shift in LO modes may be caused by the surface phonon polaritons of PbI2 nanophase in the porous silica.

Mu, R.↗

Electropolishing parameters study for surface smoothening of low-$\beta$650 MHz five-cell niobium superconducting radio frequency cavity

Electropolishing (EP) is applied to niobium (Nb) superconducting radio frequency (SRF) cavities, which are used in particle accelerators for their surface treatment. The EP process for 1.3 GHz cavities has been extensively studied earlier. In this work, a parametric study on EP of low-β (0.61) 650 MHz Nb SRF cavities (LB650), which will be used in pre-production cryomodule for proton improvement plan-II (PIP-II) linear accelerator, was conducted to determine adequate EP conditions for attaining a smooth surface of the cavities. EP performed with the standard parameters and an initial cathode (cathode-I) having a cathode surface area of ~5% of the cavity surface area yielded a rough equator surface of the cavity. The grain step height on the equator weld position was measured to be ~ 32 μm. The rough surface was attributed to preferential grain etching confirmed by a polarization curve showing a linear relationship between the EP current and voltage and the absence of the current plateau region. The cathode was modified to make its surface area twice that of cathode-I. The modified cathode (cathode-M) provided a current plateau region in the corresponding I-V curves measured at different cavity temperatures. The onset voltage for the plateau was found to be higher at higher cavity temperatures. Here this study revealed that even with cathode-M, the standard 18 V was low for EP of such large-sized cavities when the cavity temperature was 18 °C. EP performed at a higher voltage of 22–24.5 V with cathode-M yielded a smooth surface with a grain step height of only 0.6 μm. The applied EP conditions also improved removal uniformity along the cavity length. In contrast to the cavity treated with cathode-I, the cavities treated with cathode-M achieved a significantly higher accelerating gradient (E acc ) in vertical tests conducted in a cryostat at 2 K. The modified EP was found efficient to produce the cavities that achieved E acc of 22.4 MV/m, required by PIP II project in the baseline RF tests, to qualify for further surface processing used to enhance their quality factors.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Dual-Pump CARS Measurements in the University of Virginia's Dual-Mode Scramjet: Configuration "A"

In this paper we describe efforts to obtain canonical data sets to assist computational modelers in their development of models for the prediction of mixing and combustion in scramjet combustors operating in the ramjet-scramjet transition regime. The CARS technique is employed to acquire temporally and spatially resolved measurements of temperature and species mole-fraction at four planes, one upstream of an H2 fuel injector and three downstream. The technique is described and results are presented for cases with and without chemical reaction. The vibrational energy mode in the heated airstream of the combustor was observed to be frozen at near facility heater conditions and significant nonuniformities in temperature were observed, attributed to nonuniformities of temperature exiting the heater. The measurements downstream of fuel injection show development of mixing and combustion, and are already proving useful to the modelers.

Cutler, Andrew D.↗