Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Transition state”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

NICER Observations of the Black Hole Candidate MAXI J0637-430 during the 2019-2020 Outburst

We present detailed timing and spectral studies of the black hole candidate MAXI J0637–430 during its 2019–2020 outburst using observations with the Neutron Star Interior Composition Explorer (NICER)and the Neil Gehrels Swift Observatory. We find that the source evolves through the soft-intermediate, high-soft, hard-intermediate, and low-hard states during the outburst. No evidence of quasi-periodic oscillations is found in the power-density spectra of the source. Weak variability with fraction alarms amplitude<5 per cent is found in the softer spectral states. In the hard-intermediate and hard states, high variability with the fractional rms amplitude of>20 per cent is observed. The 0.7–10 keV spectra with NICER are studied with a combined disc-black-body and nth comp model along with the interstellar absorption. The temperature of the disc is estimated to be 0.6 keV in the rising phase and decreased slowly to 0.1 keV in the declining phase. The disc component was not detectable or absent during the low-hard state. From the state-transition luminosity and the inner edge of the accretion flow, we estimate the mass of the black hole to be in the range of 5–12 M, assuming the source distance of d<10 kpc.

Arghajit Jana↗
NASA NTRSDate not supplied

Constraints on Triple Oxygen Isotope Kinetics

Triple oxygen isotope methods (e.g., using δ 18 O, and Δ′ 17 O) have been used to classify meteorites, to constrain atmospheric chemistry, and to estimate primary productivity, among other uses. Such utility relies on the mass dependency of most chemical reactions: δ 17 O is proportional to δ 18 O by roughly a factor of 0.5. However, in detail, mass-dependency factors vary. While constraints on mass dependency are well established for equilibrium isotope effects, similar constraints for kinetic isotope effects are lacking. Using an ab initio Monte Carlo approach (see envelopes in Figure 1), we find the range of kinetic isotope effects (i.e., resulting from unidirectional chemical reactions) contains and exceeds the range of accessible equilibrium isotope effects for the 16 O 17 O 18 O system (Hayles and Killingsworth, 2022). Accessible kinetic isotope effects can yield Δ′ 17 O variations as large 0.8 ‰ from a single kinetic fractionation step. Reactions that yield the largest deviations from equilibrium are those with the largest molecular mass difference between decomposition fragments, typically the two products such as a gas and solid generated from the thermal decomposition of an initial solid. Comparison of DFT transition state model results against previously published experiments on the thermal decomposition of calcite (CaCO 3 ) (Miller et al., 2002) and dehydroxylation of brucite (Mg(OH) 2 ) (Clayton and Mayeda, 2009) show they are matched with mass-dependent kinetic isotope effects. This approach can be applied to any system with more than two isotopes.

Oxygen isotopes↗
NASA NTRS2023

Reconfigurations in Brain Networks Upon Awakening From Slow Wave Sleep: Interventions and Implications in Neural Communication

Sleep inertia is the brief period of impaired alertness and performance experienced immediately after waking. Little is known about the neural mechanisms underlying this phenomenon. A better understanding of the neural processes during sleep inertia may offer insight into the awakening process. We observed brain activity every 15 min for 1 hr following abrupt awakening from slow wave sleep during the biological night. Using 32-channel electroencephalography, a network science approach, and a within-subject design, we evaluated power, clustering coefficient, and path length across frequency bands under both a control and a polychromatic short-wavelength-enriched light intervention condition. We found that under control conditions, the awakening brain is typified by an immediate reduction in global theta, alpha, and beta power. Simultaneously, we observed a decrease in the clustering coefficient and an increase in path length within the delta band. Exposure to light immediately after awakening ameliorated changes in clustering. Our results suggest that long-range network communication within the brain is crucial to the awakening process and that the brain may prioritize these long-range connections during this transitional state. Our study highlights a novel neurophysiological signature of the awakening brain and provides a potential mechanism by which light improves performance after waking.

EEG↗
NASA NTRS2025

Robust Trajectory Optimization for NRHO Rendezvous Using SPICE Kernel Relative Motion

In this paper, robust optimization is performed on trajectory correction maneuvers during the lunar lander return phase of an Artemis mission, treating the trajectory from one hour after low lunar orbit departure to arrival in the vicinity of the lunar Gateway as a relative motion problem. To enable rapid stochastic optimization techniques requiring many candidate trajectories, SPICE kernel relative motion as implemented by the Quadratic Interpolated State Transition (QIST) system is used as the underlying dynamics propagation. The optimization is performed with a genetic optimizer using linear covariance (LinCov) software in a simplified operational context, taking into account the availability of navigation sensors with varying measurement models, ranges, and accuracies. No numerical integration is used, since the relative motion around Gateway is fully characterized with the a priori computation of the QIST coefficients. Maneuver placements are computed to optimize the minimum 3σ delta-v of the trajectory, the position dispersion at a target point, and a convex combination of these two metrics. An order of magnitude runtime improvement is provided over legacy methods with less than 10% error introduced. All QIST results are shown to be in-family with legacy methods. The tradespace for optimal delta-v design is found to range from 77.0 to 93.9 m/s, while the range of optimal dispersion is between 1.4 and 11.7 km.

Relative Motion↗
NASA NTRS1975

Lifetimes for OH and OD electronic states with resonance transitions in the region between 1700 and 1950 A

The upper states of the OH and OD bands in the region between 1700 and 1950 A have been studied with a phase-shift radiative lifetime apparatus. Lifetimes varying from 1.8 to 2.9 ns have been found. Lifetimes for OH and OD are essentially the same, indicating that the upper states are likely to be depopulated via purely radiative processes under the present experimental conditions. Lifetimes have also been obtained for the C(2)Sigma(+) - A(2)Sigma(+) transition in OH and OD. These results are consistent with the preliminary analysis of Pryce (private communication) that the bands between 1700 and 1950 A in OH are partly due to the C(2)Sigma(+) - X(2)Pi sub i transition.

Smith, W. H.↗
NASA NTRS1991

Development of diapiric structures in the upper mantle due to phase transitions

Solid-state phase transition in time-dependent mantle convection can induce diapiric flows in the upper mantle. When a deep mantle plume rises toward phase boundaries in the upper mantle, the changes in the local thermal buoyancy, local heat capacity, and latent heat associated with the phase change at a depth of 670 kilometers tend to pinch off the plume head from the feeding stem and form a diapir. This mechanism may explain episodic hot spot volcanism. The nature of the multiple phase boundaries at the boundary between the upper and lower mantle may control the fate of deep mantle plumes, allowing hot plumes to go through and retarding the tepid ones.

Liu, M.↗
NASA NTRS1985

Observation of far-infrared transitions between excited states of OH

Spectra of the Kleinmann-Low nebula in Orion detected the 84.42 and 84.60 micron transitions between the 2Pi(3/2) J = 7/2 and 2Pi(3/2) J = 5/2 levels of OH with respective fluxes of 1 x 10 to the -17th and 1.4 x 10 to the -17th W/sq cm. When compared to the 119 micron flux levels of OH discussed by Watson (1982) and the 163 micron flux levels of OH by Viscuso et al. (1985), these results suggest appreciable self-absorption of OH line radiation within the nebula. The CO emission due to the J = 31 to 30 rotational transition at 84.411 microns makes a substantial contribution to the observed 84.22 micron flux, and is probably at least partially absorbed at the 84.42 micron OH transition frequency.

Viscuso, P. J.↗
NASA NTRS1985

Observations of far-infrared transitions between excited states of OH

In observations of the Kleinmann-Low Nebula were detected of Orion 84.42 and 84.60 micron transitions between the P-2 sub 3/2 and Pi-2 sub 3/2 (J = 5/2) levels of OH with respective fluxes of 1.0 + or - 0.3 to the minus 17th power and 1.4 + or - 0.4 x 10 to the minus 17th power W cm/sq. When compared to 119 micron flux levels of OH and 153 micron flux levels of these radicals by Viscuso, these results suggest appreciable self-absorption of OH line radiation within the Nebula. It is probable that the CO emission due to the J = 31 yields 30 rotational transition at 84.411 micron makes a substantial contribution to the observed 84.42 micron flux, and that it also is at least partially absorbed at the 84.42 micron OH transition frequency. The 88.55 and 88.78 micron (J = 9/2 to 7/2) transitions of CH also were sought, but yielded only to upper limits of 3 x 10 to the minus 18th power W /sq cm each. A search of W3-IRS5 yields upper limits to the 84.42 micron OH and 87.19 micron CO (J = 30 to 29) transitions of 2 x 10 minus 18th power W cm/2.

Viscuso, P. J.↗
NASA NTRS1994

Time-dependent evolution of cosmic-ray-modified shock structure: Transition to steady state

Steady state solutions to the two-fluid equations of cosmic-ray-modified shock structure were investigated first by Drury and Volk (1981). Their analysis revealed, among other properties, that there exist regions of upstream parameter space where the equations possess three different downstream solutions for a given upstream state. In this paper we investigate whether or not all these solutions can occur as time-asymptotic states in a physically realistic evolution. To do this, we investigate the time-dependent evolution of the two-fluid cosmic-ray equations in going from a specified initial condition to a steady state. Our results indicate that the time-asymptotic solution is strictly single-valued, and it undergoes a transition from weakly to strongly cosmic-ray-modified at a critical value of the upstream cosmic ray energy density. The expansion of supernova remnant shocks is considered as an example, and it is shown that the strong to weak transition is in fact more likely. The third intermediate solution is shown to influence the time-dependent evolution of the shock, but it is not found to be a stable time-asymptotic state. Timescales for convergence to these states and their implications for the efficiency of shock acceleration are considered. We also investigate the effects of a recently introduced model for the injection of seed particles into the shock accelerated cosmic-ray population. The injection is found to result in a more strongly cosmic-ray-dominated shock, which supports our conclusion that for most classes of intermediate and strong cosmic-ray-modified shocks, the downstream cosmic-ray pressure component is at least as large as the thermal gas pressure, independent of the upstream state. As a result, cosmic rays almost always play a significant role in determining the shock structure and dissipation and they cannot be regarded as test particles.

Donohue, D. J.↗
NASA NTRS1992

Near-optimal energy transitions for energy-state trajectories of hypersonic aircraft

A problem of the instantaneous energy transition that occurs in energy-state approximation is considered. The transitions are modeled as a sequence of two load-factor bounded paths (either climb-dive or dive-climb). The boundary-layer equations associated with the energy-state dynamic model are analyzed to determine the precise location of the transition.

Ardema, M. D.↗
NASA NTRS2008

Using Pipelined XNOR Logic to Reduce SEU Risks in State Machines

Single-event upsets (SEUs) pose great threats to avionic systems state machine control logic, which are frequently used to control sequence of events and to qualify protocols. The risks of SEUs manifest in two ways: (a) the state machine s state information is changed, causing the state machine to unexpectedly transition to another state; (b) due to the asynchronous nature of SEU, the state machine's state registers become metastable, consequently causing any combinational logic associated with the metastable registers to malfunction temporarily. Effect (a) can be mitigated with methods such as triplemodular redundancy (TMR). However, effect (b) cannot be eliminated and can degrade the effectiveness of any mitigation method of effect (a). Although there is no way to completely eliminate the risk of SEU-induced errors, the risk can be made very small by use of a combination of very fast state-machine logic and error-detection logic. Therefore, one goal of two main elements of the present method is to design the fastest state-machine logic circuitry by basing it on the fastest generic state-machine design, which is that of a one-hot state machine. The other of the two main design elements is to design fast error-detection logic circuitry and to optimize it for implementation in a field-programmable gate array (FPGA) architecture: In the resulting design, the one-hot state machine is fitted with a multiple-input XNOR gate for detection of illegal states. The XNOR gate is implemented with lookup tables and with pipelines for high speed. In this method, the task of designing all the logic must be performed manually because no currently available logic synthesis software tool can produce optimal solutions of design problems of this type. However, some assistance is provided by a script, written for this purpose in the Python language (an object-oriented interpretive computer language) to automatically generate hardware description language (HDL) code from state-transition rules.

Le, Martin↗
NASA NTRS1999

Quasi-Periodic Oscillations in Black Hole Candidates as an Indicator of Transition Between Low and High States

By comparing positions on a spectral color-color diagram from 10 black hole candidates (BHCS) observed with Ginga (1354-64, 1826-24, 1630-47, LMC X-1, LMC X-3, GS 2000+25, GS 2023+33, GS 1124-68, Cyg X-1, and GX 339-4) with the observed broadband noise (BBN) (0.001-64 Hz) and quasi-periodic oscillation (QPO) variability, we find that the "very high state" is spectrally intermediate to the soft/high state and hard/low state. We find a transition point in spectral hardness where the dependence of the BHC QPO centroid frequency (of GS 1124-68 and GX 339-4) on spectral hardness switches from a correlation to an anticorrelation; where the BBN variability switches from high state to low state; and where the spectral hardness of the QPO relative to that of the BBN variability is a maximum. This coincidence of changing behavior in both the QPO and the broadband variability leads us to hypothesize that the QPO is due to interaction between the physical components which dominate the behaviors of BHCs when they occupy the hard/low and soft/high states. We conclude that these QPOs should be observed from BHCs during transition between these two states. Comparison with QPO and BBN behavior observed during the 1996 transition of Cyg X-1 supports this hypothesis. We also report 1-3 Hz QPOs observed in GS 2000+25 and Cyg X-1 in the hard/low state, and we compare these to the QPOs observed in GS 1124-68 and GX 339-4.

Rutledge, Robert E.↗
NASA NTRS1999

Energetic and spatial parameters for gating of the bacterial large conductance mechanosensitive channel, MscL

MscL is multimeric protein that forms a large conductance mechanosensitive channel in the inner membrane of Escherichia coli. Since MscL is gated by tension transmitted through the lipid bilayer, we have been able to measure its gating parameters as a function of absolute tension. Using purified MscL reconstituted in liposomes, we recorded single channel currents and varied the pressure gradient (P) to vary the tension (T). The tension was calculated from P and the radius of curvature was obtained using video microscopy of the patch. The probability of being open (Po) has a steep sigmoidal dependence on T, with a midpoint (T1/2) of 11.8 dyn/cm. The maximal slope sensitivity of Po/Pc was 0.63 dyn/cm per e-fold. Assuming a Boltzmann distribution, the energy difference between the closed and fully open states in the unstressed membrane was DeltaE = 18.6 kBT. If the mechanosensitivity arises from tension acting on a change of in-plane area (DeltaA), the free energy, TDeltaA, would correspond to DeltaA = 6.5 nm2. MscL is not a binary channel, but has four conducting states and a closed state. Most transition rates are independent of tension, but the rate-limiting step to opening is the transition between the closed state and the lowest conductance substate. This transition thus involves the greatest DeltaA. When summed over all transitions, the in-plane area change from closed to fully open was 6 nm2, agreeing with the value obtained in the two-state analysis. Assuming a cylindrical channel, the dimensions of the (fully open) pore were comparable to DeltaA. Thus, the tension dependence of channel gating is primarily one of increasing the external channel area to accommodate the pore of the smallest conducting state. The higher conducting states appear to involve conformational changes internal to the channel that don't involve changes in area.

Non-NASA Center↗
NASA NTRS1993

Interband optical transitions between confined and unconfined states in quantum wells

The interband optical absorption in single quantum wells (SQWs) due to transitions between confined states and unconfined continuum states (C-U transitions) were measured, calculated, and compared to absorption due to transitions involving pairs of confined states (C-C transiitons). An In(0.25)Ga(0.75)As/GaAs SQW with a 61-A well width was used in the experiment. A simple model describes how the slow-turnon absorption line shapes characterisic of SQWs evolve into sharp steplike features as more wells are added.

Ksendzov, A.↗