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NASA NTRS2000

SHADOZ Comparisons with TOMS

One year of balloon-sonde profiles taken from the Southern Hemisphere ADditional OZonesondes (SHADOZ) archive have been compared with data from the Earth Probe Total Ozone Mapping Spectrometer (TOMS) by integrating the balloon profiles to obtain total column ozone. The TOMS backscattered ultraviolet measurement loses sensitivity to ozone in the lowest five to ten kilometers of the atmosphere, limiting the accuracy of the TOMS measurement of tropospheric ozone. This is shown by the increased deviation between TOMS total ozone and the sonde total in the tropical Pacific, where tropospheric ozone is known to be lower than the tropical climatological average. The TOMS underestimate is further confirmed by the correlation of deviations between TOMS and the sondes with changes in lower tropospheric ozone. After allowing for the TOMS offset, the sondes appear to underestimate ozone by three to five percent. This is confirmed by a limited number of comparisons with Dobson data.

McPeters, Richard D.↗

NASA NTRS2000

The Heavy Element Abundance in Groups of Galaxies

Over the past few years we have analyzed a sample of clusters observed by the Advanced Spacecraft for Cosmology Astrophysics (ASCA) X-ray satellite. We performed spatially resolved X-ray spectroscopy of a sample of 18 relaxed clusters of galaxies with gas temperatures below 4 keV. The spectral analysis was done using ASCA/SIS (Solid state Imaging Spectrometer) data combined with imaging data from ROSAT/PSPC (German acronym for X-ray satellite/Position Sensitive Proportional Counter) and Einstein/IPC (Imaging Proportional Counter) observations. We derived temperature profiles using single-temperature fits for all of the clusters in the sample, and also corrected for the presence of cold gas in the center of so-called 'cooling flow' clusters. For all of the clusters in the sample we derived Si and Fe abundance profiles. For a few of the clusters we also were able to derive Ne and S abundance profiles. We compared the elemental abundances derived at similar overdensities in all of the clusters in the sample. We also compared element mass-to-light ratios for the entire sample. We concluded that the preferential accretion of low entropy, low abundance gas into the potentials of groups and cold clusters can explain most of the observed trends in metallicity. In addition, we discussed the importance of preheating of the intracluster medium by Type II supernovae on the cluster scaling relations.

David, Laurence↗

NASA NTRS2005

Simulations of a Liquid Hydrogen Inducer at Low-Flow Off-Design Flow Conditions

The ability to accurately model details of inlet back flow for inducers operating a t low-flow, off-design conditions is evaluated. A sub-scale version of a three-bladed liquid hydrogen inducer tested in water with detailed velocity and pressure measurements is used as a numerical test bed. Under low-flow, off-design conditions the length of the separation zone as well as the swirl velocity magnitude was under predicted with a standard k-E model. When the turbulent viscosity coefficient was reduced good comparison was obtained a t all the flow conditions examined with both the magnitude and shape of the profile matching well with the experimental data taken half a diameter upstream of the leading edge. The velocity profiles and incidence angles a t the leading edge itself were less sensitive to the back flow length predictions indicating that single-phase performance predictions may be well predicted even if the details of flow separation modeled are incorrect. However, for cavitating flow situations the prediction of the correct swirl in the back flow and the pressure depression in the core becomes critical since it leads to vapor formation. The simulations have been performed using the CRUNCH CFD(Registered Trademark) code that has a generalized multi-element unstructured framework and a n advanced multi-phase formulation for cryogenic fluids. The framework has been validated rigorously for predictions of temperature and pressure depression in cryogenic fluid cavities and has also been shown to predict the cavitation breakdown point for inducers a t design conditions.

Hosangadi, A.↗

NASA NTRS2006

Opposed Jet Burner Approach for Characterizing Flameholding Potentials of Hydrocarbon Scramjet Fuels

Opposed Jet Burner (OJB) tools have been used extensively by the authors to measure Flame Strength (FS) extinction limits of laminar H2/N2 air and (recently) hydrocarbon (HC) air Counterflow Diffusion Flames (CFDFs) at one atm. This paper details normalization of FSs of N2- diluted H2 and HC systems to account for effects of fuel composition, temperature, pressure, jet diameter, inflow Reynolds number, and inflow velocity profile (plug, contoured nozzle; and parabolic, straight tube). Normalized results exemplify a sensitive accurate means of validating, globally, reduced chemical kinetic models at approx. 1 atm and the relatively low temperatures approximating the loss of non-premixed idealized flameholding, e.g., in scramjet combustors. Laminar FS is defined locally as maximum air input velocity, U(sub air), that sustains combustion of a counter-jet of g-fuel at extinction. It uniquely characterizes a fuel. And global axial strain rate at extinction (U(sub air) normalized by nozzle or tube diameter, D(sub n or (sub t)) can be compared directly with computed extinction limits, determined using either a 1-D Navier Stokes stream-function solution, using detailed transport and finite rate chemistry, or (better yet) a detailed 2-D Navier Stokes numerical simulation. The experimental results define an idealized flameholding reactivity scale that shows wide ranging (50 x) normalized FS s for various vaporized-liquid and gaseous HCs, including, in ascending order: JP-10, methane, JP-7, n-heptane, n-butane, propane, ethane, and ethylene. Results from H2 air produce a unique and exceptionally strong flame that agree within approx. 1% of a recent 2-D numerically simulated FS for a 3 mm tube-OJB. Thus we suggest that experimental FS s and/or FS ratios, for various neat and blended HCs w/ and w/o additives, offer accurate global tests of chemical kinetic models at the Ts and Ps of extinction. In conclusion, we argue the FS approach is more direct and fundamental, for assessing, e.g., idealized scramjet flameholding potentials, than measurements of laminar burning velocity or blowout in a Perfectly Stirred Reactor, because the latter characterize premixed combustion in the absence of aerodynamic strain. And FS directly measures a chemical kinetic characteristic of non-premixed combustion at typical flameholding temperatures. It mimics conditions where gfuels are typically injected into a subsonic flameholding recirculation zone that captures air, where the effects of aerodynamic strain and associated multi-component diffusion become important.

Pellett, Gerald L.↗

NASA NTRS2011

Submillimeter Remote Sensing of Planetary and Cometary Atmospheres and LRO/LCROSS Observations of the Moon

Submillimeter remote sensing of planetary and cometary atmospheres have been proposed for Venus and Mars while MIRO on Rosetta will observe the coma of Comet 67P/Churyumov - Cierasimenko in December 2015, UARS and AURA MLS have observed millimeter and submillimeter molecule emissions in the Earth's stratosphere for many decades, Observations of submillimeter wave molecular emissions provide a wealth of information not obtainable by alternative techniques. Submillimeter line emissions exhibit linear temperature dependence, insensitivity to aerosol scattering, extinction, and have separated transitions with well determined line-shapes. These observations have high sensitivities to trace chemical species and can; 1) Fully resolve the line profiles of molecules with high resolution, 2) Provide deterministic retrievals of species abundance, temperature, and pressure, and 3) Measure Doppler shifts of detected molecules for wind velocities.

Chin, Gordon↗

NASA NTRSDate not supplied

TPSAS-NF1676L-20351-DND

Characterization of atmospheric variability is crucial to the design of the Entry, Descent, and Landing (EDL) activities at Mars. The distribution of dust in the Martian atmosphere has a significant impact on the atmospheric structure and variability. Information obtained through reconstruction of EDL data from past missions can be used in studying the performance of a model used in preflight atmospheric characterization for future missions. We use the Mars Weather Research and Forecasting (MarsWRF) General Circulation Model to simulate the atmospheric temperature during the landing time periods of Mars Exploration Rovers MER-A and MER-B in 2004. The multi-scale capability of MarsWRF is useful for conducting high- resolution nested simulation centered at the landing site. This version of MarsWRF includes a high spectral accuracy k-distribution radiative transfer model. We use the IR dust opacity profile data from the Thermal Emission spectrometer (TES) limb scan data as well as the TES Nadir data to prescribe the dust opacity distribution. Data from MY 26, which corresponds to the year of MER landing, and data from a climatology based on the median of 4 years (MY24 to MY27) of TES data are used. Model temperature profiles are compared with the reconstructions from EDL data and TES observations. Sensitivity of the model simulation to variations in the input opacity data are shown.

Murali Natarajan↗

NASA NTRS1995

What is the source of observed annual variations in plasmaspheric density?

Plasmaspheric densities have been observed previously to be higher in December than in June, with the ratio varying between 1.5 and 3.0 and with larger variations at lower L shells. In order to search for the cause of the observed annual variations, we have modeled plasmaspheric density, using a time-dependent hydrodynamic model. On an L = 2 field line with geomagnetic longitude equal to 300 deg, the modeled plasmaspheric densities were a factor of 1.5 times higher in December than in June. The modeled December to June density ratio was found to increase slightly with L shell, in contrast to observations; this discrepancy may be due to the fact that outer plasmaspheric flux tubes are never completely full. In addition, for an L = 2 field line with geomagnetic longitude equal to 120 deg, the modeled plasmaspheric density was higher in June than in December by a factor of about 1.2. Various numerical tests were also performed in order to examine the sensitivity of plasmaspheric density to various parameters. In particular, a large vertical neutral wind was applied in order to raise the O(+) profile which had the effect of raising plasmaspheric density by a factor of 6. This in conjunction with a theoretical analysis suggests that plasmaspheric density levels are very sensitive to O(+) levels in the upper ionosphere. We conclude that annual variations in plasmaspheric density are due to similar variations in ionospheric O(+).

Guiter, S. M.↗

NASA NTRS2012

Prevention of Over-Pressurization During Combustion in a Sealed Chamber

The combustion of flammable material in a sealed chamber invariably leads to an initial pressure rise in the volume. The pressure rise is due to the increase in the total number of gaseous moles (condensed fuel plus chamber oxygen combining to form gaseous carbon dioxide and water vapor) and, most importantly, the temperature rise of the gas in the chamber. Though the rise in temperature and pressure would reduce with time after flame extinguishment due to the absorption of heat by the walls and contents of the sealed spacecraft, the initial pressure rise from a fire, if large enough, could lead to a vehicle over-pressure and the release of gas through the pressure relief valve. This paper presents a simple lumped-parameter model of the pressure rise in a sealed chamber resulting from the heat release during combustion. The transient model considers the increase in gaseous moles due to combustion, and heat transfer to the chamber walls by convection and radiation and to the fuel-sample holder by conduction, as a function of the burning rate of the material. The results of the model are compared to the pressure rise in an experimental chamber during flame spread tests as well as to the pressure falloff after flame extinguishment. The experiments involve flame spread over thin solid fuel samples. Estimates of the heat release rate profiles for input to the model come from the assumed stoichiometric burning of the fuel along with the observed flame spread behavior. The sensitivity of the model to predict maximum chamber pressure is determined with respect to the uncertainties in input parameters. Model predictions are also presented for the pressure profile anticipated in the Fire Safety-1 experiment, a material flammability and fire safety experiment proposed for the European Space Agency (ESA) Automated Transfer Vehicle (ATV). Computations are done for a range of scenarios including various initial pressures and sample sizes. Based on these results, various mitigation approaches are suggested to prevent vehicle over-pressurization and help guide the definition of the space experiment.

Gokoglu, Suleyman A.↗

NASA NTRS1980

Analyses of moisture in polymers and composites

A suitable method for the direct measurement of moisture concentrations after humidity/thermal exposure on state of the art epoxy and polyimide resins and their graphite and glass fiber reinforcements was investigated. Methods for the determination of moisture concentration profiles, moisture diffusion modeling and moisture induced chemical changes were examined. Carefully fabricated, precharacterized epoxy and polyimide neat resins and their AS graphite and S glass reinforced composites were exposed to humid conditions using heavy water (D20), at ambient and elevated temperatures. These specimens were fixtured to theoretically limit the D20 permeation to a unidirectional penetration axis. The analytical techniques evaluated were: (1) laser pyrolysis gas chromatography mass spectrometry; (2) solids probe mass spectrometry; (3) laser pyrolysis conventional infrared spectroscopy; and (4) infrared imaging thermovision. The most reproducible and sensitive technique was solids probe mass spectrometry. The fabricated exposed specimens were analyzed for D20 profiling after humidity/thermal conditioning at three exposure time durations.

Ryan, L. E.↗

NASA NTRS1995

Calculated coupling efficiency between an elliptical-core optical fiber and an optical waveguide over temperature

To determine the feasibility of coupling the output of a single-mode optical fiber into a single-mode rib waveguide in a temperature varying environment, a theoretical calculation of the coupling efficiency between the two was investigated. Due to the complex geometry of the rib guide, there is no analytical solution to the wave equation for the guided modes, thus, approximation and/or numerical techniques must be utilized to determine the field patterns of the guide. In this study, three solution methods were used for both the fiber and guide fields; the effective-index method (EIM), Marcatili's approximation, and a Fourier method. These methods were utilized independently to calculate the electric field profile of each component at two temperatures, 20 C and 300 C, representing a nominal and high temperature. Using the electric field profile calculated from each method, the theoretical coupling efficiency between an elliptical-core optical fiber and a rib waveguide was calculated using the overlap integral and the results were compared. It was determined that a high coupling efficiency can be achieved when the two components are aligned. The coupling efficiency was more sensitive to alignment offsets in the y direction than the x, due to the elliptical modal field profile of both components. Changes in the coupling efficiency over temperature were found to be minimal.

Tuma, Margaret L.↗

NASA NTRS1984

Observed Spatial Properties of the Solar Eigenfunctions and the Implications for the Existence of Resolved Multiplets

Solar oscillations are manifested in the solar atmosphere as spatial and temporal perturbations in the local thermodynamical and mechanical properties. When measuring the solar radius/diameter, these perturbations enter the observation through changes in the radiative source function and opacity at the extreme limb. When compared to the disk center, the observable portion of these perturbations is changed in spatial character by projection effects and oblique optical depth geometry. The time varying solar radius signal at SCLERA (Santa Catalina Laboratory for Experimental Relativity) is produced by an edge definition sensitive to the resultant changes in the spatial shape of the limb intensity profile. An attempt is made to further determine the shape and properties of the limb signals which display global solar oscillations.

Caudell, T. P.↗

NASA NTRS1988

Detailed mechanism of toluene oxidation and comparison with benzene

A detailed mechanism for the oxidation of toluene in both argon and nitrogen dilutents is presented. The mechanism was used to compute experimentally ignition delay times for shock-heated toluene-oxygen-argon mixtures with resonably good success over a wide range of initial temperatures and pressures. Attempts to compute experimentally measured concentration profiles for toluene oxidation in a turbulent reactor were partially successful. An extensive sensitivity analysis was performed to determine the reactions which control the ignition process and the rates of formation and destruction of various species. The most important step was found to be the reaction of toluene with molecular oxygen, followed by the reactions of hydroperoxyl and atomic oxygen with benzyl radicals. These findings contrast with the benzene oxidation, where the benzene-molecular oxygen reaction is quite unimportant and the reaction of phenyl with molecular oxygen dominates. In the toluene mechanism the corresponding reaction of benzyl radicals with oxygen is unimportant. Two reactions which are important in the oxidation of benzene also influence the oxidation of toluene for several conditions. These are the oxidations of phenyl and cyclopentadienyl radicals by molecular oxygen. The mechanism presented successfully computes the decrease of toluene concentration with time in the nitrogen diluted turbulent reactor. This fact, in addition to the good prediction of ignition delay times, shows that this mechanism can be used for modeling the ignition and combustion process in practical, well-mixed combustion systems.

Bittker, David A.↗

NASA NTRS1994

A new variability parameter for gamma-ray burst time profiles

We present a parameter that measures the structure of gamma-ray burst time profiles. This parameter is based on the statistics of runs and is a good measure of time profile variability. It is shown to be independent of burst duration and less sensitive to burst distance than algorithms that depend directly on the intensity of a burst.

Lestrade, John Patrick↗

NASA NTRS1994

A New Variability Parameter for Gamma-Ray Burst Time Profiles

Lestrade, John Patrick↗

NASA NTRS1999

Carbon Monoxide Formation in SN 1987A

The formation of carbon monoxide in the supernova SN 1987A at 200 days is investigated. Rather than the one-zone that have previous been employed, this work utilizes a radially dependent radiative transport model to compute the temperature and ionization structure and the destruction of CO and CO+ by ultraviolet radiation. The CO profile is computed assuming chemical equilibrium. Two models for the density and abundance profiles are examined: model 10H (unmixed) and model 10HMM (mixed) of Pinto & Woosley. Sensitivity to adopted rates and temperature as it might be affected by CO cooling is examined. The models give a total mass of 10-4 M_sun at 200 days for the unmixed model, which is comparable with the estimated observed abundance by Syromilio et al. but nearly 2 orders of magnitude less than the estimated observed and that computed in thermal-chemical models by Liu & Dalgarno. The effect of different model assumptions and results concerning ionization structure and radiative transfer are discussed. We confirm that CO+ is not expected to be produced in significant amounts and that the amount of CO is sensitive to the degree of the mixing of the composition of various elements present in the ejecta.

Gearhart, Rob A.↗

NASA NTRS2010

Ice Sheet Change Detection by Satellite Image Differencing

Differencing of digital satellite image pairs highlights subtle changes in near-identical scenes of Earth surfaces. Using the mathematical relationships relevant to photoclinometry, we examine the effectiveness of this method for the study of localized ice sheet surface topography changes using numerical experiments. We then test these results by differencing images of several regions in West Antarctica, including some where changes have previously been identified in altimeter profiles. The technique works well with coregistered images having low noise, high radiometric sensitivity, and near-identical solar illumination geometry. Clouds and frosts detract from resolving surface features. The ETM(plus) sensor on Landsat-7, ALI sensor on EO-1, and MODIS sensor on the Aqua and Terra satellite platforms all have potential for detecting localized topographic changes such as shifting dunes, surface inflation and deflation features associated with sub-glacial lake fill-drain events, or grounding line changes. Availability and frequency of MODIS images favor this sensor for wide application, and using it, we demonstrate both qualitative identification of changes in topography and quantitative mapping of slope and elevation changes.

Bindschadler, Robert A.↗

NASA NTRS2023

Evaluation of EPIC Oxygen Bands Stability With Radiative Transfer Simulations Over the South Pole

The Earth Polychromatic Imaging Camera (EPIC) onboard the Deep Space Climate Observatory (DSCOVR) satellite orbiting the Sun at the Lagrange-1 point was launched without onboard calibration systems. Vicarious calibration is conducted for 8 of the 10 UV/VIS/NIR channels using other low earth orbiting satellite instruments, while its two O 2 bands (688 nm and 764nm) rely on indirect moon-view calibrations because the same narrow-band O 2 bands are not readily available from other in-flight instruments. This study compares EPIC measurements from the four O 2 bands aiming at examining sensor stability over a uniquely suited location, i.e., the permanently snow-covered South Pole. The study utilizes radiative transfer model simulations with in-situ atmospheric soundings taken at South Pole during months of December and January from 2015 to 2022. The absolute discrepancy between the model simulations and observations is less than 1.0% for the two reference bands, but 5.75% and 15.63% for the 688nm, and 764 nm absorption bands, respectively. The simulated A-band and B-band ratios are 16.09% and 4.74% higher than that from the observations. Various sensitivities are conducted to estimate possible contributions to the discrepancies from input atmospheric profiles, spectral surface albedos and surface BRDF. While none of the input uncertainties is likely to account for the large discrepancies in the oxygen absorption bands, a small shift in the instrument response function could be the main reason for these biases. On the other hand, the model simulations are able to capture systematic variations with observed angular measurements and explain the multi-year trends found in observed O 2 band ratios due to satellite orbit shifting. When model simulated contributions from the angle variations are deducted from the observed O 2 band ratios, the residual O 2 band ratios are found to be stable since 2015.

EPIC↗

NASA NTRS1979

Thermal analysis of Bridgman-Stockbarger growth

A thermal analysis of a cylindrical HgCdTe sample in a Bridgman-Stockbarger crystal growth configuration was conducted with emphasis on the thermal profile, interface shape and position, and the thermal gradients at the liquid-solid interface. Alloys of HgTe and CdTe with compositions approximating 20 percent CdTe, 80 percent HgTe were used. This composition results in a bandgap suited for the detection of 10.6 micron CO2 radiation. The sensitivity of the sample thermal characteristics to important growth parameters, such as thermal diffusivities, thermal conductivities, furnace temperature profile, ampoule dimensions, and growth velocity was assessed. Numerical techniques and associated computational models necessary to analyze the heat transfer process within the sample and the Bridgman-Stockbarger boundary conditions were developed. This thermal analysis mode was programmed in FORTRAN V, and is currently operational on the MSFC Univac 1100 system.

Knopf, F. W.↗