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Atmospheric cycles of nitrogen oxides and ammonia

The atmospheric cycles of nitrogenous trace compounds for the Northern and Southern Hemispheres are discussed. Source strengths and destruction rates for the nitrogen oxides: NO, NO2 and HNO3 -(NOX) and ammonia (NH3) are given as a function of latitude over continents and oceans. The global amounts of NOX-N and NH3-N produced annually in the period 1950 to 1975 (34 + 5 x one trillion g NOx-N/yr and 29 + or - 6 x one trillion g NH3-N/yr) are much less than previously assumed. Globally, natural and anthropogenic emissions are of similar magnitude. The NOx emission from anthropogenic sources is 1.5 times that from natural processes in the Northern Hemisphere, whereas in the Southern Hemisphere, it is a factor of 3 or 4 less. More than 80% of atmospheric ammonia seems to be derived from excrements of domestic animals, mostly by bulk deposition: 24 + or - 9 x one trillion g NO3 -N/yr and 21 + or - 9 x one trillion g NH4+-N/yr. Another fraction may be removed by absorption on vegetation and soils.

Bottger, A.↗

Rotation of the coronal magnetic field

The coronal magnetic field rotates differently than the photosphere. The field configuration of the corona can be calculated from the observed photosphpere field using a potential field model. Correlation of the field patterns at different latitudes with a lag near one solar rotation shows much less differential rotation than observed in the photospheric field; however, the peak is very broad and determines the rotation rate rather poorly. Consideration of longer lags reveals a more complex rotational structure and indicates different rotation rates in the Northern and Southern Hemispheres. Spectral analysis of the equatorial dipole component of the coronal field reveals an organization into just a few discrete rotation frequencies which are apparently present simultaneously. Spectral analysis of the field at different latitudes shows that the frequencies are present simultaneously. Spectra analysis of the field at different latitudes shows that the frequencies are present simultaneously, but in different hemispheres, and that the Southern Hemisphere fields rotate more slowly than those in the north in solar cycle 21.

Hoeksema, J. T.↗

Observations of "Hystereris" in Backscattered Ultraviolet Ozone Data

The backscattered ultraviolet (BUV) technique has been used for almost 3 decades to monitor global total ozone and the distribution of ozone in the stratosphere. Satellite BUV measurements in the 250-340 mn wavelength region are technically challenging because the Earth's radiance varies by approximately 4 orders of magnitude during a single scan. Further, the observed signal increases by over three orders of magnitude in about 2 minutes as the satellite emerges into daylight. The gain of the instrument's photomultiplier tube (PMT) detector is low when the spacecraft first emerges into the sunlit portion of the orbit relative to the gain observed after the PMT has experienced moderately high current levels. This "hysteresis" effect was first observed on the Nimbus-7 SBUV and TOMS instruments. The effect is difficult to characterize prelaunch because of the high signal levels and rapid variations required. We have recently observed and quantified the hysteresis effect for the NOAA-9 SBUV/2 instrument, which collected ozone data from February 1985 to February 1998. The instrument gain is observed to be up to 3% low at high solar zenith angles [Chi = 85-90 degrees] in the emergent hemisphere (i.e. Southern Hemisphere at launch). The gain error decreases as the SZA decreases and average PMT current increases, and is generally negligible for Chi < 65 degrees. The magnitude of the hysteresis effect varies with season, and exhibits long-term changes as the NOAA-9 sun-synchronous orbit drifts. In the latter portion of the record, when the spacecraft emerged from the dark in the Northern Hemisphere, hysteresis effects were then observed in the North. NOAA-9 total ozone errors due to the hysteresis effect are typically on the order of 2%, but can reach 5% in extreme cases. We have developed a quantitative correction for the hysteresis effect that incorporates both seasonal and long-term variations in magnitude. Results of similar analyses for the NOAA-11 and NOAA-14 SBUV/2 instruments will also be discussed. The characterization of the hysteresis effect in high solar zenith angle SBUV/2 ozone data represents a significant step towards reconciling polar ozone measurements from different satellite instruments.

DeLand, Matthew T.↗

Upper-Stratospheric Ozone Trends 1979-1998

Extensive analyses of ozone observations between 1978 and 1998 measured by Dobson Umkehr, Stratospheric Aerosol and Gas Experiment (SAGE) I and II, and Solar Backscattered Ultraviolet (SBUV) and (SBUV)/2 indicate continued significant ozone decline throughout the extratropical upper stratosphere from 30-45 km altitude. The maximum annual linear decline of -0.8 +/- 0.2 %/yr(2sigma) occurs at 40 km and is well described in terms of a linear decline modulated by the 11-year solar variation. The minimum decline of -0.110.1% yr-1(2o) occurs at 25 km in midlatitudes, with remarkable symmetry between the Northern and Southern Hemispheres at 40 km altitude. Midlatitude upper-stratospheric zonal trends exhibit significant seasonal variation (+/- 30% in the Northern Hemisphere, +/- 40% in the Southern Hemisphere) with the most negative trends of -1.2%/yr occurring in the winter. Significant seasonal trends of -0.7 to -0.9%/yr occur at 40 km in the tropics between April and September. Subjecting the statistical models used to calculate the ozone trends to intercomparison tests on a variety of common data sets yields results that indicate the standard deviation between trends estimated by 10 different statistical models is less than 0.1%/yr in the annual-mean trend for SAGE data and less than 0.2%/yr in the most demanding conditions (seasons with irregular, sparse data) [World Meteorological Organization (WMO), 1998]. These consistent trend results between statistical models together with extensive consistency between the independent measurement-system trend observations by Dobson Umkehr, SAGE I and II, and SBUV and SBUV/2 provide a high degree of confidence in the accuracy of the declining ozone amounts reported here. Additional details of ozone trend results from 1978 to 1996 (2 years shorter than reported here) along with lower-stratospheric and tropospheric ozone trends, extensive intercomparisons to assess relative instrument drifts, and retrieval algorithm details are given by WMO [1998].

Newchurch, M. J.↗

Data Assimilation Experiments using Quality Controlled AIRS Version 5 Temperature Soundings

The AIRS Science Team Version 5 retrieval algorithm has been finalized and is now operational at the Goddard DAAC in the processing (and reprocessing) of all AlRS data. Version 5 contains accurate case-by-case error estimates for most derived products, which are also used for quality control. We have conducted forecast impact experiments assimilating AlRS quality controlled temperature profiles using the NASA GEOS-5 data assimilation system, consisting of the NCEP GSI analysis coupled with the NASA FVGCM. Assimilation of quality controlled temperature profiles resulted in significantly improved forecast skill in both the Northern Hemisphere and Southern Hemisphere Extra-Tropics, compared to that obtained from analyses obtained when all data used operationally by NCEP except for AlRS data is assimilated. Experiments using different Quality Control thresholds for assimilation of AlRS temperature retrievals showed that a medium quality control threshold performed better than a tighter threshold, which provided better overall sounding accuracy; or a looser threshold, which provided better spatial coverage of accepted soundings. We are conducting more experiments to further optimize this balance of spatial coverage and sounding accuracy from the data assimilation perspective. In all cases, temperature soundings were assimilated well below cloud level in partially cloudy cases. The positive impact of assimilating AlRS derived atmospheric temperatures all but vanished when only AIRS stratospheric temperatures were assimilated. Forecast skill resulting from assimilation of AlRS radiances uncontaminated by clouds, instead of AlRS temperature soundings, was only slightly better than that resulting from assimilation of only stratospheric AlRS temperatures. This reduction in forecast skill is most likely the result of significant loss of tropospheric information when only AIRS radiances unaffected by clouds are used in the data assimilation process.

Susskind, Joel↗

Behavior of Solar Cycles 23 and 24 Revealed by Microwave Observations

Using magnetic and microwave butterfly diagrams, we compare the behavior of solar polar regions to show that (1) the polar magnetic field and the microwave brightness temperature during solar minimum substantially diminished during the cycle 23/24 minimum compared to the 22/23 minimum. (2) The polar microwave brightness temperature (Tb) seems to be a good proxy for the underlying magnetic field strength (B). The analysis indicates a relationship, B = 0.0067Tb - 70, where B is in G and Tb in K. (3) Both the brightness temperature and the magnetic field strength show north-south asymmetry most of the time except for a short period during the maximum phase. (4) The rush-to-the-pole phenomenon observed in the prominence eruption (PE) activity seems to be complete in the northern hemisphere as of 2012 March. (5) The decline of the microwave brightness temperature in the north polar region to the quiet-Sun levels and the sustained PE activity poleward of 60degN suggest that solar maximum conditions have arrived at the northern hemisphere. The southern hemisphere continues to exhibit conditions corresponding to the rise phase of solar cycle 24. Key words: Sun: chromosphere Sun: coronal mass ejections (CMEs) Sun: filaments, prominences Sun: photosphere Sun: radio radiation Sun: surface magnetism

Gopalswamy, N.↗

The Mars Atmosphere Water Ice Aerosol Climatology by MRO/CRISM: 5 Mars Years of Observations

We use near-infrared spectra returned from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter (MRO) to provide retrievals of the column-integrated optical depth of water ice aerosols for more than 5 Martian years between Mars Year (MY) 28 at Ls = 112° (27 September 2006) and MY 33 at Ls = 213° (30 August 2016). We have developed a radiative transfer model for this purpose that retrieves aerosol opacity from the water ice aerosol feature near 3.3 μm using CRISM hyperspectral observations for the first time. The resulting retrievals well depict the main features in the water ice aerosol climatology with repeatable patterns every Martian year. The aphelion cloud belt (ACB) is observed between 10°S and 30°N, with peak optical depth around Ls = 90°. Apart from the global dust storm during MY 28, modest interannual variability in the water ice aerosol optical depth is observed in the ACB. The north polar hood is observed at latitudes poleward of 45°N throughout northern spring and summer seasons and reappears in northern winter. The south polar hood is observed in early to mid-southern autumn, reaching latitudes around 60°S, and re-emerging during southern winter between 45°S and 60°S. A lack of water ice aerosols is repeatedly seen in the southern hemisphere throughout southern spring and summer. High optical depth in the ACB is observed over the volcanoes of Olympus Mons, Elysium, and the Tharsis bulge, as well as over Hellas Basin.

Mars↗

Ultrasoft X-rays from the southern galactic hemisphere

Results are reported for sounding-rocket measurements of the X-ray background at ultrasoft energies (90 to 280 eV) in selected regions of the southern galactic hemisphere. The spectrum of the background is found to be extremely soft, being characterized by a kinetic temperature of less than 100 eV in thermal models. A lower limit of about 0.2 per cu pc is set on the space density of stellar sources in a discrete-source model for the background. The results show that the observed background radiation in the southern galactic hemisphere is about 50% less intense than that sampled at corresponding northern latitudes, the intensity at energies less than 150 eV varies along the scan path and is strongest south of -60 deg, there is no evidence for the existence of any ultrasoft pointlike sources, and the background is probably diffuse in origin. A temperature of about 600,000 K and an electron density of the order of 0.007 per cu cm are derived from a simple model where the radiation originates in a hot interstellar plasma interspersed with cold gas along the line of sight.

Levine, A.↗

The influence of thermal inertia on temperatures and frost stability on Triton

It is presently argued, in view of (1) a thermal inertia model for the surface of Triton which (like previous ones) predicts a monotonic recession of permanent N2 deposits toward the poles and very little seasonal N2 frost in the southern hemisphere, and (2) new spectroscopic evidence for nonvolatile CO2 on Triton's bright southern hemisphere, that much of that bright southern material is not N2. Such bright southern hemisphere volatiles may allow the formation of seasonal frosts, thereby helping to explain the observed spectroscopic changes of Triton during the last decade.

Spencer, John R.↗

The Response of Ozone and Nitrogen Dioxide to the Eruption of Mt. Pinatubo

Observations have shown that the global mass of nitrogen dioxide decreased in both hemispheres in the year following the eruption of Mt. Pinatubo. In contrast, the observed ozone response was largely asymmetrical with respect to the equator, with a decrease in the northern hemisphere and little change and even a small increase in the southern hemisphere. Simulations including enhanced heterogeneous chemistry due to the presence of the volcanic aerosol reproduce a decrease of ozone in the northern hemisphere, but also produce a comparable ozone decrease in the southern hemisphere, contrary to observations. Our simulations show that the heating due to the volcanic aerosol enhanced both the tropical upwelling and the extratropical downwelling. The enhanced extratropical downwelling, combined with the time of the eruption relative to the phase of the Brewer-Dobson circulation, increased the ozone in the southern hemisphere and counteracted the ozone depletion due to heterogeneous chemistry on volcanic aerosol.

Aquila, Valentina↗

Signatures of troposphere-stratosphere momentum coupling Implications for global atmospheric angular momentum and earth rotation budgets

During January-August 1978, the global atmospheric angular momentum (M) exhibits distinct patterns of short term momentum interchange across latitudes. In the Northern Hemisphere winter-spring season, 30-50 day modulations of M are present in which momentum enhancements at mid-latitudes (20-30 deg) are closely matched by momentum depressions at high latitudes (50-60 deg). During the same interval there are no corresponding variations in M evident in the Southern Hemisphere. Conversely, during Southern Hemisphere fall-winter, similar anti-correlations in monthly scale momentum excursions are evident between mid and high latitudes. In the Northern Hemisphere, the winter-spring momentum signatures are detected throughout the atmosphere, from the lower troposphere to the stratosphere. During the Southern Hemisphere fall-winter, the modulation patterns are not evident at the higher altitudes. Structural details of the momentum signatures indicate that the coupling is sometimes effective on very short time scales, e.g., 1-2 days, or less. The evidence of distinct anti-correlation between large regions has interesting implications for studies of global atmospheric circulation, and also for studies of the excitation of variations in earth rotation in response to short term modulations of M.

Taylor, H. A.↗

Investigation of the Differences in Onset Times for Magnetically Conjugate Magnetometers

We have identified nearly 1,000 onsets using two pairs of hemispheric conjugate ground magnetometers where the onset is defined based on a sharp decline in the H component of the magnetic field at a ground magnetometer station. Specifically, we used the pair of stations at West Antarctica Ice Sheet Divide and Sanikiluaq, Canada; Syowa, Antarctica; and Tjörnes, Iceland. While the onset time in the southern hemisphere is identified by eye, the value of the differences in the onset time between the northern and southern hemispheres is determined using cross covariance. We observe differences in the onset time between the two hemispheres as large as several minutes, but 53% of the events show no difference in the onset time. Using statistics, we show that the largest differences in onset time are associated with the summer and winter seasons and when the IMF By value is limited between 0.5 and 2.5 nT, which is the IMF By range when the local time difference between the northern and southern hemisphere foot points is the smallest. The results indicate that ionospheric conductivity associated with solar illumination plays a role in the differences in onset time between the northern and southern hemisphere when only non-zero differences in onset time are considered. We validate these results with two other less robust methods. The median value of the differences in onset time indicates that the onsets occur ∼23 s earlier in the winter hemisphere than that in the summer hemisphere. It has been reported that the time difference between the start of the substorm in the magnetotail and the observed auroral break up (substorm auroral onset) in the ionosphere is 30 s to 2 min in the current disruption model and the near earth neutral line model, respectively. Our results may be of interest to those two models.

James M. Weygand↗

Comparison of seasonal variations of upper stratospheric ozone concentrations revealed by Umkehr and Nimbus 4 BUV observations

This paper reports the results of a comparison between upper stratospheric ozone concentration profiles in the region between 22 and 1.4 mbar, as determined from surface-based Umkehr observations and satellite Nimbus 4 BUV observations. The Umkehr data, consisting of monthly averages of observations extending over several years or longer, were obtained at three stations located in the Northern Hemisphere and two in the Southern Hemisphere. The BUV data were obtained during the period from May 1970 to March 1971. Aside from some bias in the magnitudes of the Umkehr and BUV data, marked annual cycles of ozone concentration in the upper stratosphere are clearly revealed. Above 4 mbar the profiles show a summer minimum and a winter maximum, while below 4 mbar the annual variation is reversed from this pattern. In the Northern Hemisphere the winter maximum is accompanied by a secondary minimum of 1- to 2-month duration near 3 mbar. This short-term minimum is much less obvious in the Southern Hemisphere data. Some of the problem of attempting to monitor long-term changes in the upper stratosphere are discussed briefly.

Deluisi, J. J.↗

The Quasi-Biennial Oscillation in atmospheric ozone

Examination of the relationship between tropical stratosphere zonal wind and ozone indicate a variable response in latitude with Northern Hemisphere tropics and polar regions and Southern Hemisphere mid-latitudes showing the strongest response with relatively weaker response at Northern Hemisphere mid-latitudes and the Southern Hemisphere tropics. In tropical regions, the west winds and ozone maxima are in phase while at higher latitudes, a more nearly out-of-phase relationship prevails. At subtropical and middle latitudes, the QBO in ozone does not appear to change phases with altitude. These features are suggestive of an interaction between the tropical zonal winds and poleward transport of horizontal eddies in conjunction with the annual poleward transport of ozone.

Oltmans, S. J.↗

Climate Response of Direct Radiative Forcing of Anthropogenic Black Carbon

The equilibrium climate effect of direct radiative forcing of anthropogenic black carbon (BC) is examined by 100-year simulations in the Goddard Institute for Space Studies General Circulation Model II-prime coupled to a mixed-layer ocean model. Anthropogenic BC is predicted to raise globally and annually averaged equilibrium surface air temperature by 0.20 K if BC is assumed to be externally mixed. The predicted increase is significantly greater in the Northern Hemisphere (0.29 K) than in the Southern Hemisphere (0.11 K). If BC is assumed to be internally mixed with the present day level of sulfate aerosol, the predicted annual mean surface temperature increase rises to 0.37 K globally, 0.54 K for the Northern Hemisphere, and 0.20 K for the Southern Hemisphere. The climate sensitivity of BC direct radiative forcing is calculated to be 0.6 K W (sup -1) square meters, which is about 70% of that of CO2, independent of the assumption of BC mixing state. The largest surface temperature response occurs over the northern high latitudes during winter and early spring. In the tropics and midlatitudes, the largest temperature increase is predicted to occur in the upper troposphere. Direct radiative forcing of anthropogenic BC is also predicted to lead to a change of precipitation patterns in the tropics; precipitation is predicted to increase between 0 and 20 N and decrease between 0 and 20 S, shifting the intertropical convergence zone northward. If BC is assumed to be internally mixed with sulfate instead of externally mixed, the change in precipitation pattern is enhanced. The change in precipitation pattern is not predicted to alter the global burden of BC significantly because the change occurs predominantly in regions removed from BC sources.

Chung, Serena H.↗

Surface temperatures in the polar regions from Nimbus 7 temperature humidity infrared radiometer

Monthly surface temperatures in the Arctic and Antarctic regions have been derived from the 11.5 micrometer thermal infrared channel of the Nimbus 7 temperature humidity infrared radiometer (THIR) for a whole year in 1979 and for a winter and a summer month from 1980 through 1985. The data set shows interannual variability and provides spatial details that allow identification of temperature patterns over sea ice and ice sheet surfaces. For example, the coldest spot in the southern hemisphere is observed to be consistently in the Antarctic plateau in the southern hemisphere, while that in the northern hemisphere is usually located in Greenland, or one of three other general areas: Siberia, the central Arctic, or the Canadian Archipelago. Also, in the southern hemisphere, the amplitude of the seasonal fluctuation of ice sheet temperatures is about 3 times that of sea ice, while in the northern hemisphere, the corresponding fluctuations for the two surfaces are about the same. The main sources of error in the retrieval are cloud and other atmospheric effects. These were minimized by first choosing the highest radiance value from the set of measurements during the day taken within a 30 km by 30 km grid of each daily map. Then the difference of daily maps was taken and where the difference is greater than a certain threshold (which in this case is 12 C), the data element is deleted. Overall, the monthly maps derived from the resulting daily maps are spatially and temporally consistent, are coherent with the topograph y of the Antarctic continent and the location of the sea ice edge, and are in qualitative agreement with climatological data. Quantitatively, THIR data are in good agreement with Antarctic ice sheet surface air temperature station data with a correlation coefficient of 0.997 and a standard deviation of 2.0 C. The absolute values are not as good over the sea ice edges, but a comparison with Russian 2-m drift station temperatures shows very high correlation (with correlation coefficient at 0.998) and a standard deviation of 1.1 C. Overall, the rms error is estimated to be from 1 to 2 C, depending on the surface, while the average bias when compared with in situ data is less than 2 C.

Comiso, Josefino C.↗

Interhemispheric asymmetry of the high-latitude ionospheric convection pattern

The assimilative mapping of ionospheric electrodynamics technique has been used to derive the large-scale high-latitude ionospheric convection patterns simultaneously in both northern and southern hemispheres during the period of January 27 to 29, 1992. When the interplanetary magnetic field (IMF) B(sub z) component is negative, the convection patterns in the southern hemisphere are basically the mirror images of those in the northern hemisphere. The total cross-polar cap potential drops in the two hemispheres are similar. When B(sub z) is positive and absolute value of B(sub y) greater than B(sub z), the convection configurations are mainly determined by B(sub y) and they may appear as normal 'two-cell' patterns in both hemispheres much as one would expect under southward IMF conditions. However, there is a significant difference in the cross-polar-cap potential drop between the two hemispheres, with the potential drop in the southern (summer) hemisphere over 50% larger than that in the northern (winter) hemisphere. As the ratio of absolute value of B(sub y)/B(sub z) decreases (less than one), the convection configuration in the two hemispheres may be significantly different, with reverse convection in the southern hemisphere and weak but disturbed convection in the northern hemisphere. By comparing the convection patterns with the corresponding spectrograms of precipitating particles, we interpret the convection patterns in terms of the concept of merging cells, lobe cells, and viscous cells. Estimates of the ' merging cell' potential drops, that is, the potential ascribed to the opening of the dayside field lines, are usually comparable between the two hemispheres, as they should be. The 'lobe cell' provides a potential between 8.5 and 26 kV and can differ greatly between hemispheres, as predicted. Lobe cells can be significant even for southward IMF, if absolute value of B(sub y) greater than the absolute value of B(sub z). To estimate the potential drop of the 'viscous cells,' we assume that the low-latitude boundary layer is on closed field lines. We find that this potential drop varies from case to case, with a typical value of 10 kV. If the source of these cells is truly a viscous interaction at the flank of the magnetopause, the process is likely spatially and temporally varying rather than steady state.

Lu, G.↗

A Model of the Effect of Ozone Depletion on Lower-Stratospheric Structure

We have run two twenty-year integrations of a global circulation model using 1978-1980 and 1998-2000 monthly mean ozone climatologies. The ozone climatology is used solely in the radiation scheme of the model. Several key differences between the model runs will be presented. The temperature and potential vorticity (PV) structure of the lower stratosphere, particularly in the Southern Hemisphere, is significantly changed using the 1998-2000 ozone climatology. In the Southern Hemisphere summer, the lapse rate and PV-defined polar tropopauses are both at altitudes on the order of several hundred meters greater than the 1978-1980 climatological run. The 380 K potential temperature surf= is likewise at a greater altitude. The mass of the extratropical lowermost stratosphere (between the tropopause and 380 K surface) remains unchanged. The altitude differences are not observed in the Northern Hemisphere. The different ozone fields do not produce a significant change in the annual extratropical stratosphere-troposphere exchange of mass although slight variations in the spatial distribution of the exchange exist. We are also investigating a delay in the breakup of the Southern Hemisphere polar vortex due to the differing ozone climatologies.

Olsen, Mark A.↗