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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Electrolytes Containing Triethyl Phosphate Solubilized Lithium Nitrate for Improved Silicon Anode Performance

An electrolyte consisting of lithium nitrate (LiNO3) and lithium difluoro(oxalato)borate (LiDFOB) in ethylene carbonate (EC), ethylmethyl carbonate (EMC), and triethyl phosphate (TEP) is used to improve the long-term cycling stability of silicon anodes. TEP was selected for its ability to dissolve LiNO 3 in carbonates to a concentration of ~0.2 M. The large amount of LiNO 3 combined with the LiDFOB salt leads to a capacity retention of 87.1% after one hundred cycles due to the formation of a relatively stable solid electrolyte interphase (SEI). Ex-situ surface analysis reveals that the SEI consists of oxalates, lithium alkyl carbonates, borates, and nitrate reduction products. By selecting two components which are preferentially reduced (LiNO 3 and LiDFOB), the SEI is able to inhibit continuous solvent decomposition and allows for improved electrochemical cycling for pure silicon anodes.

25 ENERGY STORAGE↗
DOE OSTI2022

Progress Towards Extended Cycle Life Si-based Anodes: Investigation of Fluorinated Local High Concentration Electrolytes

Silicon (Si) anodes are promising candidates for Li-ion batteries due to their high specific capacity and low operating potential. Implementation has been challenged by the significant Si volume changes during (de)lithiation and associated growth/regrowth of the solid electrolyte interphase (SEI). In this report, fluorinated local high concentration electrolytes (FLHCEs) were designed such that each component of the electrolyte (solvent, salt, diluent) is fluorinated to modify the chemistry and stabilize the SEI of high (30%) silicon content anodes. FLHCEs were formulated to probe the electrolyte salt concentration and ratio of the fluorinated carbonate solvents to a hydrofluoroether diluent. Higher salt concentrations led to higher viscosities, conductivities, and contact angles on polyethylene separators. Electrochemical cycling of Si-graphite/NMC622 pouch cells using the FLHCEs delivered up to 67% capacity retention after 100 cycles at a C/3 rate. Post-cycling X-ray photoelectron spectroscopy (XPS) analyses of the Si-graphite anodes indicated the FLHCEs formed a LiF rich solid electrolyte interphase (SEI). The findings show that the fluorinated local high concentration electrolytes contribute to stabilizing the Si-graphite electrode over extended cycling.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Coulombic Efficiency and Capacity Retention are Not Universal Descriptors of Cell Aging

Capacity and coulombic efficiency are often used to assess the performance of Li-ion batteries, under the assumption that these quantities can provide direct insights about the rate of electron consumption due to growth of the solid electrolyte interphase (SEI). Here, we show that electrode properties can actually change the amount of information about aging that can be directly retrieved from capacity measurements. During cycling of full-cells, only portions of the voltage profiles of the positive and negative electrodes are accessible, leaving a reservoir of cyclable Li + stored at both electrodes. The size and availability of this reservoir depends on the shape of the voltage profiles and accessing this extra Li + can offset some of the capacity that is consumed by the SEI. Consequently, capacity and efficiency measurements can, at times, severely underestimate the rate of side reactions experienced by the cell. We show, for example, that a same rate of SEI growth would cause faster capacity fade in LiFePO 4 than in NMC cells, and that the perceived effects of aging depend on testing variables such as depth of discharge. Simply measuring capacity may be insufficient to gauge the true extent of aging endured by Li-ion batteries.

25 ENERGY STORAGE↗
DOE OSTI2025

Decoupling Failure Pathways in Li-O 2 Cells Operated Under Lean Electrolyte Conditions

The operation of lithium-oxygen (Li-O 2 ) batteries under lean electrolyte conditions offers higher energy density but leads to rapid degradation and short cycle life. Although cathode passivation and electrolyte decomposition occur in all regimes, we show that under lean electrolyte conditions, failure is primarily driven by progressive electrolyte consumption at the lithium/solid electrolyte interphase (SEI), rather than by irreversible cathode passivation. Poor wetting of the lithium surface results in heterogeneous SEI growth and high local current densities, which accelerate electrolyte loss and cell failure. Strategies aimed at improving interfacial stability, including optimized wetting and SEI forming additives, significantly extend cycle life without compromising energy density. Our results establish anode-electrolyte interactions as the dominant degradation mechanism under lean electrolyte conditions, and emphasize the need to engineer a stable Li/SEI interface for long-lasting Li-O 2 batteries.

Córdoba, Daniel [Argonne National Laboratory (ANL)↗
DOE OSTI2024

Fully Fluorinated Local High Concentration Electrolytes Enabling High Energy Density Si Anodes

To develop fluorinated localized high concentration electrolytes as a novel approach for constructing a functional SEI on Si based anodes. The technological approach combines the SEI modification strategies of fluorinated carbonate solvents and local high concentration electrolytes. The resulting synergy of anion and fluorinated solvent decomposition will form a mechanically robust, fluorinated SEI that enables extended cycling with high capacity retention. The electrolytes will enable demonstration of silicon-graphite anodes with high Si content, paired with NMC811 cathodes. Characterization will focus on galvanostatic cycling to evaluate electrochemical performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Role of electrolyte in silicon electrolyte interface stabilization

Transition metal ion dissolution was long thought to be the reason for poor cycling performance in Lithium ion batteries cycled to a high voltage, but since the anode SEI is electrochemically insulating, the mechanism for transition metal mediated SEI decomposition in unclear. Our results show that acidic species such as F 2 PO 2 H generation on the cathode side and their subsequent crossover reactions with the SEI components damaging it could more likely be a major factor to capacity fade.

25 ENERGY STORAGE↗
NASA NTRS1991

Next generation: In-space transportation system(s)

The development of the next generation In-Space Transportation System presents a unique challenge to the design of a propulsion system for the Space Exploration Initiative (SEI). Never before have the requirements for long-life, multiple mission use, space basing, high reliability, man-rating, and minimum maintenance come together with performance in one system that must protect the lives of space travelers, support the mission logistics needs, and do so at an acceptable cost. The challenge that is presented is to quantify the bounds of these requirements. The issue is one of degree. The length of acceptable life in space, the time it takes for reuse to pay off, and the degree to which space basing is practical (full, partial, or expended) are the issues that determine the reusable bounds of a design and include dependability, contingency capabilities, resilency, and minimum dependence on a maintenance node in preparation for and during a mission. Missions to planet earth, other non-NASA missions, and planetary missions will provide important but less demanding requirements for the transportation systems of the future. The mission proposed for the SEI require a family of transportation vehicles to meet the requirements for establishing a permanent human presence on the Moon and eventually on Mars. Specialized vehicles are needed to accomplish the different phases of each mission. These large scale missions require assembly in space and will provide the greatest usage of the planned integrated transportation system. The current approach to defining the In-Space Transportation System for the SEI Moon missions with later Mars mission applications is presented. Several system development options, propulsion concepts, current/proposed activities are reviewed, and key propulsion design criteria, issues, and technology challenges for the next generation In-Space Transportation System(s) are outlined.

Huffaker, Fredrick↗
NASA NTRS1990

Technology needs of the Exploration Initiative

An overview of the U.S. Space Exploration Initiative (SEI) is presented. The two primary objectives of the initiative are a return to the moon to create a permanent lunar base and a human mission to Mars. Even though mission architectural concepts are not yet defined, previous studies indicate that the SEI will require developments in numerous areas, including advanced engines for space transportation, in-space assembly and construction to support permanent basing of exploration systems in space, and advanced surface operations capabilities including satisfactory levels of power and surface roving vehicles, and technologies to safely support human space operations of long duration. The process of mission definition has begun and it is shown that it is possible to identify a family of fundamental functional building blocks from which all SEI mission architectures will be constructed.

Aldrich, Arnold↗
NASA NTRS1991

Status and plans for exploration technology

The present status of the Space Exploration Initiative (SEI) is discussed. SEI mission planning is reviewed, including various architectural options, their waypoints, and their strategic features. SEI technology needs and issues are examined in order of priority and technology development plans are described.

Aldrich, Arnold D.↗
NASA NTRS1991

Is bigger always better? An economic study of U.S. ETO vehicle architectures

This analysis, performed as part of NASA's Space Transportation Infrastructure Study, compares the cost efficiency of two candidate launch vehicle families, used in conjunction with existing expendable launch vehicles and the Shuttle, to accomplish the nation's future space missions through 2030. Missions analyzed include those identified in NASA's Civil Needs Data Base (CNDB) and Space Exploration Initiative (SEI) Option E program, as well as estimates of commercial and U.S. Department of Defense flights. A family of Shuttle-derived In-line vehicles is compared against a family designed around a vehicle optimized for large (250t) payloads. The analysis is performed within the context of an entire space transportation architecture. The goal is to determine which architecture best captures the required missions most cost-effectively. Results indicate that, for the particular mission model analyzed, neither option is clearly superior across the entire payload range. The Shuttle-derived family displays a better evolutionary path for supporting the total mission model (CNDB plus SEI missions). It also reduces earth-to-orbit (ETO) peak funding by 20 percent. The architecture incorporating the Heavy Lift ETO family minimizes SEI program cost and on-orbit operations but is subject to greater schedule risk because of the need for concurrent ETO core and engine development.

Eimers, Dan R.↗
NASA NTRS1991

An assessment of prospects for international cooperation on the Space Exploration Initiative

This paper discusses the unique characteristics of the Space Exploration Initiative (SEI) which will have to be taken into account if the Initiative is to become an international one; the technical capabilities offered by prospective international partners; the political and economic prospects for proceeding with the Initiative both in the United States and elsewhere; and the advantages and disadvantages of various possible approaches to international cooperation on SEI. SEI preparatory activities are likely to extend over a several-year period. Such an extended preparatory period should provide the time needed for coordinating studies, for identifing interests and potential contributions, and for resolving the numerous planning, budgeting, organizational and political issues which will have to be dealt with if such a complex undertaking is to be successfully internationalized.

Cline, Lynn F. H.↗
NASA NTRS1991

The Space Exploration Initiative - An information system perspective

The authors look at the Space Exploration Initiative (SEI) from an information system perspective an discuss information system definition effort being conducted in support of NASAs Lunar Mars Exploration Program Office (LMEPO) Johnson Space Center (JSC). The development of an integrated, effective SEI information system (SIS) is recognized as crucial to the success of the SEI missions. Some of the new and unique challenges for the SIS as evidenced in the Lunar and the Mars missions are outlined along with some preliminary conceptual approaches, both architectural and technological, being investigated to address them.

Hartenstein, Ray↗
NASA NTRS1992

Needs for supervised space robots in space exploration

The areas of application for space robots in the Space Exploration Initiative (SEI) are examined by reviewing the roles of SEI supervised robots particularly with planet-surface systems (PSSs). Treatment is given to both teleoperated conventional robot systems and autonomous intelligent systems for comparison in terms of safety, reliability, and productivity. Two development stages are proposed including one with a robotic actor, human observer, and a human supervisor and a second in which a closed-loop control and monitoring system is established. The use of remote control is shown to require robustness, self-calibration and -diagnosis, adjustable autonomy, and multitask capability. The requirements of intelligent control are also listed so that the PSSs of the SEI can be used to enable surface exploration, local-resource utilization potential, and reductions of human tasks.

Erickson, Jon D.↗
NASA NTRS1992

Space Exploration Initiative - Overview, current status, near term plans

An overview is presented of the Space Exploration Initiative (SEI) describing current activities, accomplishemnts, and directions. The program is considered in terms of activities relevant to the three phases which are: manned robotic/precursor missions, manned lunar missions, and manned Mars missions. SEI is shown to be in the First Lunar Outpost (FLO) mission phase which is based on an early manned lunar return, and development is described of earth-to-orbit (ETO) vehicles, a translunar injection stage, and a lunar surface habitat. Two ETO vehicles are considered, and the translunar injection stage is illustrated. The FLO mission is also considered as an initiation of the design activity for the Mars mission so that the requirements and preliminary designs could be defined. The FLO program demonstrates the feasibility of a manned return to the moon as an initiation of subsequent SEI activities.

Adams, Alan M.↗
NASA NTRS1992

Nuclear thermal propulsion transportation systems for lunar/Mars exploration

Nuclear thermal propulsion technology development is underway at NASA and DoE for Space Exploration Initiative (SEI) missions to Mars, with initial near-earth flights to validate flight readiness. Several reactor concepts are being considered for these missions, and important selection criteria will be evaluated before final selection of a system. These criteria include: safety and reliability, technical risk, cost, and performance, in that order. Of the concepts evaluated to date, the Nuclear Engine for Rocket Vehicle Applications (NERVA) derivative (NDR) is the only concept that has demonstrated full power, life, and performance in actual reactor tests. Other concepts will require significant design work and must demonstrate proof-of-concept. Technical risk, and hence, development cost should therefore be lowest for the concept, and the NDR concept is currently being considered for the initial SEI missions. As lighter weight, higher performance systems are developed and validated, including appropriate safety and astronaut-rating requirements, they will be considered to support future SEI application. A space transportation system using a modular nuclear thermal rocket (NTR) system for lunar and Mars missions is expected to result in significant life cycle cost savings. Finally, several key issues remain for NTR's, including public acceptance and operational issues. Nonetheless, NTR's are believed to be the 'next generation' of space propulsion systems - the key to space exploration.

Clark, John S.↗
NASA NTRS1991

Telecommunications, navigation and information management concept overview for the Space Exploration Initiative program

An overview is provided of the Space Exploration Initiative (SEI) concepts for telecommunications, information systems, and navigation (TISN), and engineering and architecture issues are discussed. The SEI program data system is reviewed to identify mission TISN interfaces, and reference TISN concepts are described for nominal, degraded, and mission-critical data services. The infrastructures reviewed include telecommunications for robotics support, autonomous navigation without earth-based support, and information networks for tracking and data acquisition. Four options for TISN support architectures are examined which relate to unique SEI exploration strategies. Detailed support estimates are given for: (1) a manned stay on Mars; (2) permanent lunar and Martian settlements; short-duration missions; and (4) systematic exploration of the moon and Mars.

Bell, Jerome A.↗
NASA NTRS1993

Risk management for the Space Exploration Initiative

Probabilistic Risk Assessment (PRA) is a quantitative engineering process that provides the analytic structure and decision-making framework for total programmatic risk management. Ideally, it is initiated in the conceptual design phase and used throughout the program life cycle. Although PRA was developed for assessment of safety, reliability, and availability risk, it has far greater application. Throughout the design phase, PRA can guide trade-off studies among system performance, safety, reliability, cost, and schedule. These studies are based on the assessment of the risk of meeting each parameter goal, with full consideration of the uncertainties. Quantitative trade-off studies are essential, but without full identification, propagation, and display of uncertainties, poor decisions may result. PRA also can focus attention on risk drivers in situations where risk is too high. For example, if safety risk is unacceptable, the PRA prioritizes the risk contributors to guide the use of resources for risk mitigation. PRA is used in the Space Exploration Initiative (SEI) Program. To meet the stringent requirements of the SEI mission, within strict budgetary constraints, the PRA structure supports informed and traceable decision-making. This paper briefly describes the SEI PRA process.

Buchbinder, Ben↗
NASA NTRS1992

Projected NASA power requirements for space science and exploration missions

NASA's Office of Space Science and Applications has recently completed its long-range strategic plan which describes a number of exciting space science missions into the early 21st century. In parallel, NASA's new Office of Exploration has begun defining in more detail the architectures of the Space Exploration Initiative (SEI) for returning to the Moon and going to Mars. Both the space science missions and the SEI missions are dependent upon power sources and energy storage with strong requirements for reliability, long life, ease of assembly, autonomy, and light weight. This paper reviews the currently planned space science and SEI missions and focuses upon the power requirements with a view toward guiding technology developers and power designers.

Gary L Bennett↗