Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “PCM”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17

Long Duration Exposure Facility (LDEF) low temperature Heat Pipe Experiment Package (HEPP) flight results

The Low Temperature Heat Pipe Flight Experiment (HEPP) is a fairly complicated thermal control experiment that was designed to evaluate the performance of two different low temperature ethane heat pipes and a low-temperature (182 K) phase change material. A total of 390 days of continuous operation with an axially grooved aluminum fixed conductance heat pipe and an axially grooved stainless steel heat pipe diode was demonstrated before the data acquisition system's batteries lost power. Each heat pipe had approximately 1 watt applied throughout this period. The HEPP was not able to cool below 188.6 K during the mission. As a result, the preprogrammed transport test sequence which initiates when the PCM temperature drops below 180 K was never exercised, and transport tests with both pipes and the diode reverse mode test could not be run in flight. Also, because the melt temperature of the n-heptane PCM is 182 K, its freeze/thaw behavior could not be tested. Post-flight thermal vacuum tests and thermal analyses have indicated that there was an apparent error in the original thermal analyses that led to this unfortunate result. Post-flight tests have demonstrated that the performance of both heat pipes and the PCM has not changed since being fabricated more than 14 years ago. A summary of HEPP's flight data and post-flight test results are presented.

Mcintosh, Roy↗

Thermal Vacuum Test of Ice as a Phase Change Material Integrated with a Radiator

Water may be used as radiation shielding for Solar Particle Events (SPE) to protect crewmembers in the Lunar Electric Rover (LER). Because the water is already present for radiation protection, it could also provide a mass efficient solution to the vehicle's thermal control system. This water can be frozen by heat rejection from a radiator and used as a Phase Change Material (PCM) for thermal storage. Use of this water as a PCM can eliminate the need for a pumped fluid loop thermal control system as well as reduce the required size of the radiator. This paper describes the testing and analysis performed for the Rover Engineering Development Unit (REDU), a scaled-down version of a water PCM heat sink for the LER. The REDU was tested in a thermal-vacuum chamber at environmental temperatures similar to those of a horizontal radiator panel on the lunar surface. Testing included complete freeze and melt cycles along with scaled transient heat load profiles simulating a 24-hour day for the rover.

Lee, Steve↗

Phase Change Material Trade Study: A Comparison Between Wax and Water for Manned Spacecraft

Phase change material heat sinks have been recognized as an important tool in optimizing thermal control systems for space exploration vehicles and habitats that must deal with widely varying thermal loads and environments. In order to better focus technology investment in this arena, NASA has supported a trade study with the objective of identifying where the best potential pay-off can be found among identified aqueous and paraffin wax phase change materials and phase change material heat sink design approaches. The study used a representative exploration mission with well understood parameters to support the trade. Additional sensitivity studies were performed to ensure the applicability of study results across varying systems and destinations. Results from the study indicate that replacing a wax PCM heat sink with a water ice PCM heat sink has the potential to decrease the equivalent system mass of the mission s vehicle through a combination of a smaller heat sink and a slight 5% increase in radiator size or the addition of a lightweight heat pump. An evaluation of existing and emerging PCM heat sink technologies indicates that further mass savings should be achievable through continued development of those technologies. The largest mass savings may be realized by eliminating the melting and freezing pressure of wax and water, respectively.

Quinn, Gregory↗

Collaborative Software Development Approach Used to Deliver the New Shuttle Telemetry Ground Station

United Space Alliance (USA) developed and used a new software development method to meet technical, schedule, and budget challenges faced during the development and delivery of the new Shuttle Telemetry Ground Station at Kennedy Space Center. This method, called Collaborative Software Development, enabled KSC to effectively leverage industrial software and build additional capabilities to meet shuttle system and operational requirements. Application of this method resulted in reduced time to market, reduced development cost, improved product quality, and improved programmer competence while developing technologies of benefit to a small company in California (AP Labs Inc.). Many modifications were made to the baseline software product (VMEwindow), which improved its quality and functionality. In addition, six new software capabilities were developed, which are the subject of this article and add useful functionality to the VMEwindow environment. These new software programs are written in C or VXWorks and are used in conjunction with other ground station software packages, such as VMEwindow, Matlab, Dataviews, and PVWave. The Space Shuttle Telemetry Ground Station receives frequency-modulation (FM) and pulse-code-modulated (PCM) signals from the shuttle and support equipment. The hardware architecture (see figure) includes Sun workstations connected to multiple PCM- and FM-processing VersaModule Eurocard (VME) chassis. A reflective memory network transports raw data from PCM Processors (PCMPs) to the programmable digital-to-analog (D/A) converters, strip chart recorders, and analysis and controller workstations.

Kirby, Randy L.↗

Phase Change Material for Temperature Control of Loop Heat Pipe Compensation Chamber

The compensation chamber (CC) of a loop heat pipe (LHP) requires a stable temperature. In the current technology, the CC is commonly cold biased by exposing it to deep space, and active heater control is used to maintain its temperature stable. Heater power required for a typical LHP with a 300 W heat transport capacity is as much as 25 W. If multiple LHPs are used, heater power requirement could be a bigger issue. Also heater controller or temperature sensor failure could lead to a LHP or mission failure. This paper presents an innovative concept of using phase change material (PCM) for temperature control of LHP CC. Some of the electronics and/or detector assembly waste heat is stored in the PCM and transferred to the LHP CC by constant conductance heat pipes (CCHPs). Phase change of the PCM occurs at a constant temperature and maintains the LHP CC temperature stable. It eliminates heater power and active heater control for the CC. It also increases the reliability of LHP.

Choi, Michael K.↗

Phase Change Material Thermal Power Generator

An innovative modification has been made to a previously patented design for the Phase Change Material (PCM) Thermal Generator, which works in water where ocean temperature alternatively melts wax in canisters, or allows the wax to re-solidify, causing high-pressure oil to flow through a hydraulic generator, thus creating electricity to charge a battery that powers the vehicle. In this modification, a similar thermal PCM device has been created that is heated and cooled by the air and solar radiation instead of using ocean temperature differences to change the PCM from solid to liquid. This innovation allows the device to use thermal energy to generate electricity on land, instead of just in the ocean.

Jones, Jack A.↗

Phase Change Material for Temperature Control of Imager or Sounder on GOES Type Satellites in GEO

This paper uses phase change material (PCM) in the scan cavity of an imager or sounder on satellites in geostationary orbit (GEO) to maintain the telescope temperature stable. When sunlight enters the scan aperture, solar heating causes the PCM to melt. When sunlight stops entering the scan aperture, the PCM releases the thermal energy stored to keep the components in the telescope warm. It has no moving parts or bimetallic springs. It reduces heater power required to make up the heat lost by radiation to space through the aperture. It is an attractive thermal control option to a radiator with a louver and a sunshade.

phase change material↗

A Liquid-Liquid Thermoelectric Heat Exchanger as a Heat Pump for Testing Phase Change Material Heat Exchangers

The primary objective of the Phase Change HX payload on the International Space Station (ISS) is to test and demonstrate the viability and performance of Phase Change Material Heat Exchangers (PCM HX). The system was required to pump a working fluid through a PCM HX to promote the phase change material to freeze and thaw as expected on Orion's Multipurpose Crew Vehicle. Due to limitations on ISS's Internal Thermal Control System, a heat pump was needed on the Phase Change HX payload to help with reducing the working fluid's temperature to below 0degC (32degF). This paper will review the design and development of a TEC based liquid-liquid heat exchanger as a way to vary to fluid temperature for the freeze and thaw phase of the PCM HX. Specifically, the paper will review the design of custom coldplates and sizing for the required heat removal of the HX.

Sheth, Rubik B.↗

Thermal Assessment of Paraffin Phase Change Material Mini-Packs on IceCube 3U CubeSat in Flight

Three paraffin phase change material (PCM) mini-packs were flown on the IceCube instrument in the International Space Station (ISS) orbit. They contained a total of 40.69 g of n-Hexadecane. In flight, from Day of Year (DOY) 250-255 in 2017, the IceCube instrument operation scheme was "Day-On Every Other Orbit." The instrument power-on time was approximately 45.6 minutes longer than the design power-on time. Its power-off time was 47 minutes longer than the design power-off time. Flight temperature telemetry data revealed that latent heat change of the paraffin PCM maintained the instrument temperatures at about 18 degrees Centigrade most of the time. It validated the functionality of the paraffin PCM mini-packs.

Paraffin phase change material; CubeSat; latent he↗

Tunable mid-wave infrared spectral filters based on GexSbyTez for multispectral imaging

The mid-wave infrared (MWIR) spectrum contains a wealth of invaluable information including the spectral ‘fingerprint’ of many chemical species and has applications in remote sensing and astronomical imaging. Traditionally, filtering for the MWIR is achieved by means of passive multilayer interference (dichroic) filters, Fabry-Perot-based micro-electro-mechanical system (MEMS) filters, liquid crystal tunable filters, and focal plane array (FPA) filters. For accurate multispectral imaging applications, these approaches suffer from various limitations such as: having moving parts; exhibiting slow response times, and; having limited spectral bandwidth / resolution. Recently, there has been significant interest toward ‘active’ spectral imaging technologies, whereby the ability to provide electrically tunable narrowband filtering—spanning the entire MWIR—is highly desirable. In this work we introduce a new spectral imaging technology, namely actively tunable optical transmission filters using the phase-change material (PCM) GexSbyTez (GST). The GST exhibits a large, reversible change in its refractive index across the MWIR upon a phase transition (from amorphous to crystalline). This refractive index modulation governs the filter’s optical characteristics. Through an optical stimulus or applied voltage—which changes the GST state from amorphous to crystalline—one can actively tune the filter with MHz speed. We incorporate GST into optimized guided mode resonance (GMR) and plasmonic nanohole array (PNA) device architectures, enabling <10nm spectral resolution and tunable operation across 3~5µm. Our proposed PCM-MWIR filter will be able to extract the maximum amount of ‘useful’ information within the atmosphere for remote Earth sensing measurements at operational speeds orders of magnitude faster than current airborne-based sensors. Moreover, it may enable affordable SmallSat-based MWIR instrumentation which is complimentary to other observation systems. The MISSE (Materials International Space Station Experiment-Flight Facility) experiment has been proposed as a testbed for a PCM-based tunable MWIR filter module to allow exposure of the module to the low Earth orbit space environment. This will provide valuable data regarding the robustness of the filter to withstand the radiation and atomic oxygen environment and allow assessment of the technology for use in space applications.

Kim, Hyun Jung↗

Space-qualified Chalcogenide Materials through ISS MISSE Exposure —From Property to Application

In March 2021, twenty-four samples of various phase change materials (PCMs - Ge2Sb2Te5, Ge2Sb2Se4Te1, and Sb2Se3) along with metasurface optical components comprised of these PCMs, were delivered to the International Space Station (ISS) as part of the Materials International Space Station Experiment (MISSE-14) test campaign [1]. Although PCMs have previously been noted for their resilience to various forms of radiation [2], they had not been tested in a realistic space environment until this exposure campaign with joint NASA and MIT collaboration. During the six-month total open exposure time in low earth orbit (LEO), high-resolution cameras scanned and captured photographs of the samples to detect changes as a function of time along with on-orbit measured temperature, UV radiation, total atomic oxygen fluence, and total ionizing radiation doses. The samples were returned to NASA Langley Research Center in March 2022 for post-flight characterization. This duplicated the preflight characterization (i.e., material composition and crystallinity that limits switching speed, index contrast, loss, etc.) conducted before launch. The space sector has witnessed tremendous growth within the past decade—not only from government agencies but also entrants from the private sector. Future growth in the capabilities of Earth observation, deep space, and planetary surface missions using miniaturized spacecraft platforms can only be sustained by innovations in the design of remote sensors and other sub-systems. Active metasurface optics with enhanced tunability and reconfigurability continues to redefine the boundaries of optical science [3]. The introduction of PCM technology and associated optical devices will help to accelerate the adoption of new architectures for reduced size, weight, power, and cost (SWaP-C) platforms in space.Here we introduce results obtained from the MISSE-14 mission related to space qualification of PCM-based optic devices and constituent materials. We then discuss our recent work developing active integrated photonic devices and metasurface optics based on PCMs for space applications. This includes tunable and reconfigurable optical metasurface devices to support NASA space communication and LIDAR applications. PCMs are quickly becoming interesting photonics materials but questions related to mission suitability remain, particularly in regard to key properties like figures-of-merit (FOM, Δn/Δk), glass forming temperatures, and phase transition speeds. This talk will describe efforts to afford researchers the ability to have access to cost-effective data on exposure-induced changes to PCM fundamental physical and optical properties to assess their utility for space applications. The MISSE-14 sample exposure campaign allows a complete understanding of the limitations of the PCMs for various space-based electronic and optoelectronic applications.

Chalcogenide Phase change material↗

Thermal Cycle and Capacitance Testing of Mezzo Industries Phase Changer Material Heat Capacitor

Effective Thermal management is essential for the safety and performance of human spacecraft, especially during long-duration missions with fluctuating heat loads. Phase Change Material (PCM) heat exchangers offer a compact, efficient solution by storing and releasing thermal energy through latent heat during phase transitions. This allows PCM systems to buffer transient thermal loads without immediate heat rejection, reducing the need for oversized radiators – particularly critical during ascent and re-entry when radiators are stowed. By maintaining stable temperatures in crew cabins and equipment bays, PCM technology enhances crew comfort, protects sensitive systems, and supports long-term mission sustainability with minimal mass and volume impact. A phase change material heat capacitor prototype, designed and built under a NASA Small Business Innovation Research grant by Mezzo Technologies, utilizes a laser welding microtube manufacturing process that promises increased reliability and performance over current manufacturing methods like brazing. This heat exchanger was tested through coolant thermal cycling within the expected flow rates and temperature range of the Orion spacecraft, the crewed spacecraft taking NASA astronauts to the moon under the Artemis Program. The useful heat storage capacitance was measured and compared to Orion spacecraft requirements.

Active Thermal Control Systems↗

Salt Hydrate Eutectic Mixtures for Near-ambient Thermal Energy Storage Applications

In this work, we synthesized and characterized Na2SO4.10H2O – Na2CO3.10H2O eutectic salt hydrate phase change material (PCM) using Differential Scanning Calorimetry (DSC), Attenuated total reflectance infrared spectroscopy (ATR-IR), and X-ray Diffraction (XRD) techniques. The eutectic point of the PCM mixture was predicted based on binary eutectic effect and ion exchange theory. The XRD and ATR-IR results indicate that the eutectic PCM mixture was formed based on only physical mixing without chemical interaction. Moreover, DSC results showed that the eutectic concentration is 50wt% Na2SO4.10H2O – 50wt% Na2CO3.10H2O with melting temperature of 25.18°C and melting enthalpy of 187.46 J/g. Also, 78% of melting enthalpy was recoverable after 10 melt/freeze cycles. This eutectic mixture has the potential to be used in building thermal comfort applications.

Gluesenkamp, Kyle↗

Experimental Evaluation of Thermal Storage Performance of a Dual-Purpose Underground Thermal Battery

A geothermal heat pump (GHP) system is an energy-efficient building heating and cooling technology with great potential for reducing energy consumption and decarbonization. However, applications of GHP are still limited due to the high cost, of which 30% is related to the cost of installing the conventional vertical bore ground heat exchangers, which are usually installed in boreholes 60 meters deep. A dual-purpose underground thermal battery (DPUTB) has been developed to offer a low-cost ground heat exchanger with a built-in thermal storage capacity. The DPUTB innovatively integrates a shallow-bore ground heat exchanger (the outer tank), which can be installed in a borehole less than 6 m deep, with thermal energy storage (TES) (the inner tank). DPUTB has the potential to reduce the cost of a ground source heat pump system while allowing shifting the electric demand of the building served by the GHP system from peak to off-peak hours of the electric grid by charging and discharging the thermal storage. A lab-scale (1:125 in volume) DPUTB prototype was built. Phase change material (PCM) was added to increase the thermal storage capacity and maintain the supply water temperature from the TES within the desired range for direct cooling operation during the discharge period. As PCMs are critical to the TES performance of the DPUTB, this study compared the influence of different PCMs (including salt hydrate and organic PCMs) on the discharge performance of the DPUTB. The thermal State of Charge (SoC) of the DPUTB was used to compare the performance resulting from using different PCMs. Test results indicate that the organic PCM (Methyl Laurate) outperforms salt-hydrate PCMs due to a lower melting temperature and a narrower melting temperature range during the phase change process. The results of this study provide a guide for PCM selection and the optimal design of DPUTB.

Wang, Lingshi↗

Techno-Economic Analysis of Dynamic Building Envelopes Comprising Phase Change Materials and Switchable Insulations: Preprint

Integrating phase change materials (PCMs) in building envelopes is a recognized technique to reduce the space heating/cooling loads and provide load shedding and shifting capacity. However, PCM benefits have been found to reduce dramatically with increase in the insulation requirements. Dynamic building envelopes that can alter their thermal resistance based on the indoor and outdoor conditions can effectively harness free ambient heating/cooling, thereby greatly enhancing the benefits of the PCM-integrated envelope in managing thermal loads. In this study, we examine various combinations of PCMs and switchable insulations and compare their combined impact on heat flow through the building envelope. Using numerical analysis, we investigate the PCM- and switchable insulation-integrated building walls, calculate the potential energy saving benefits compared to the conventional static walls, and finally perform technoeconomic analysis to estimate the acceptable cost of the technology under various payback period scenarios.

dynamic building envelopes↗

Techno-Economic Analysis of Dynamic Building Envelopes Comprising Phase Change Materials and Switchable Insulations

Integrating phase change materials (PCMs) in building envelopes is a recognized technique to reduce the space heating/cooling loads and provide load shedding and shifting capacity. However, PCM benefits have been found to reduce dramatically with increase in the insulation requirements. Dynamic building envelopes that can alter their thermal resistance based on the indoor and outdoor conditions can effectively harness free ambient heating/cooling, thereby greatly enhancing the benefits of the PCM-integrated envelope in managing thermal loads. In this study, we examine various combinations of PCMs and switchable insulations and compare their combined impact on heat flow through the building envelope. Using numerical analysis, we investigate the PCM- and switchable insulation-integrated building walls, calculate the potential energy saving benefits compared to the conventional static walls, and finally perform techno-economic analysis to estimate the acceptable cost of the technology under various payback period scenarios.

dynamic building envelopes↗

MUSiC: Critical Experiment with Bare Highly Enriched Uranium Shells Benchmark

The measurements of the Uranium Subcritical and Critical (MUSiC) experiment were performed from December 2020 through April 2021. The purpose of the experiment was to test a variety of multiplicity detection systems for a large range of multiplication values and to see how well they perform as the k eff of the MUSiC series of experiments approached the delayed critical window. Out of the ten configurations that were studied, two of them were super critical and were recently approved as benchmarks and they will be included in the International Criticality Safety Benchmark Evaluation Project (ICBESP) handbook. For each of the two experiments, uncertainties were evaluated six categories: (1) critical measurement, (2) mass, (3) composition, (4) positioning, (5) dimensions, and (6) temperature. The largest contribution to the overall uncertainty in each of the cases was due to the uncertainties in the dimensions of the HEU Rocky Flats shells. Simplified detailed models were created with an average bias of -130.5 pcm due to the removal various components surrounding the experiment. For MCNP6.2 models using ENDF-VIII.0 neutron cross section data, the average difference between the calculated and benchmark k effs was -54 pcm for the detailed model and -102 pcm for the simplified model.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Investigation of the Impact of TSL Data Libraries and Geometry Variations on the MSRE Benchmark

The increasing demand for green, low-carbon energy solutions has amplified the focus on advanced nuclear reactor technologies. Among these, Molten Salt Reactors (MSRs) have been spotlighted because of their special features. Historically, Oak Ridge National Laboratory (ORNL) started the Molten Salt Reactor Experiment (MSRE) in 1956. Later, ORNL and the University of California, Berkeley (UCB) jointly developed the MSRE benchmark. This was then reviewed by the International Reactor Physics Experiment Evaluation Project (IRPhEP) committee and added to their 2019 handbook. In the current study, the benchmark model was recreated via the Serpent code. The calculated effective multiplication factor was 1.02087 ± 0.00019, which gives a deviation of about 2000 pcm compared to the benchmark/experimental result. At North Carolina State University (NCSU), recent evaluations were conducted on thermal scattering cross sections for molten salt FLiBe and 20% porous nuclear graphite, anticipated for incorporation in the ENDF/B-VIII.1 library. The influences of these thermal scattering law (TSL) data and geometry changes on the multiplication factor were examined using the ENDF/B-VII.1 and ENDF/B-VIII.0 libraries. Introducing the TSL data for FLiBe and 20% porous graphite resulted in an effective multiplication factor of +270 pcm compared to the reference value obtained with ENDF/B-VII.1 in this study. The adjustment of the reactor vessel dimensions resulted in decrease of -448 pcm in the calculated effective multiplication factor.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗