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At least 307 records · Page 17

Field-Scale Lysimeter Studies of Glass and Cementitious Waste Forms at the Hanford Site - 20392

The Hanford site Integrated Disposal Facility (IDF) will receive waste forms from vitrification activities at the Hanford Waste Treatment and Immobilization Plant (WTP). The waste form inventory to be disposed of at the IDF will consist of vitrified low-activity waste (LAW) in glass forms and solidified (or encapsulated) secondary wastes in cementitious forms. The IDF is a near-surface burial facility located near Hanford's Waste Treatment and Immobilization Plant in the 200 East Area of the site's Central Plateau. An extensive set of laboratory experimental data has been collected to support IDF performance assessment calculations of the eventual degradation of waste forms and mobility of contaminants. This paper describes the start of a field experiment to generate waste-form performance data on a larger scale (tens of centimeters), over a longer duration (five years or more), and under field conditions representative of the IDF. Results from this study are expected to improve model descriptions of contaminant mobility, reduce uncertainties about the representativeness of laboratory results in the IDF performance assessment, improve stakeholder confidence in the safe disposal of treated waste at the IDF, and facilitate the adoption of informed facility designs with the potential to reduce operational costs. A lysimeter test facility near Hanford's 200 West Area has been repurposed to carry out long-term assessments of waste forms buried in sediments excavated from the IDF. The waste forms are buried in large drainage lysimeters, open caissons that are two meters in diameter and three meters deep. Waste forms are buried in up to six locations in each lysimeter. Samplers collect pore water and drainage water beneath the waste forms and air from the pore space adjacent to waste forms. Sensors measure temperature, soil water content, soil water tension, and drainage flux. One lysimeter containing cementitious waste forms and one containing glass waste forms have been completed, along with a control lysimeter (without waste forms). The cementitious waste forms are Cast Stone grout formulations using a liquid secondary waste simulant and a generic Hanford high-salt simulant, as well as a hydrated lime-based grout formulation using a liquid secondary waste simulant. Technetium-99 and iodine-127 were added as tracers to monitor contaminant mobility. Glass waste forms were fabricated in two formulations (LAWA44 and ORLEC28), with rhenium and molybdenum tracers to monitor waste form degradation. The predicted performance of the waste forms in the lysimeters was modeled prior to installation to determine waste form size, tracer concentration/activity, and locations of sensors and samplers. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Anti-buckling fatigue test assembly

An antibuckling fatigue test assembly is described for holding a metal specimen which is subjected to compression and to rapid cyclical heating and cooling while permitting visual observation. In an illustrative embodiment of this invention, the anti-buckling fatigue test apparatus includes first and second guide members between which the metal specimen is disposed and held, a heating assembly comprising a suitable heating source such as a quartz lamp and a reflecting assembly directing the heat onto the specimen, and a cooling assembly for directing a suitable cooling fluid such as air onto the specimen. The guide members each have a passage to permit the heat to be directed onto the specimen. An opening is provided in the reflecting assembly to permit visual inspection of that region of the specimen adjacent to the opening onto which the heat is directed.

Eichenbrenner, F. F.↗

STS-72 Flight Day 2

On this second day of the STS-72 mission, the flight crew, Cmdr. Brian Duffy, Pilot Brent W. Jett, and Mission Specialists Leroy Chiao, Daniel T. Barry, Winston E. Scott, and Koichi Wakata (NASDA), awakened to music from the motion picture 'Star Wars.' The crew performed a systems checkout, prepared for the retrieval of the Japanese Space Flyer Unit (SFU), tested the spacesuits for the EVA, and activated some of the secondary experiments. An in-orbit news interview was conducted with the crew via satellite downlinking. Questions asked ranged from the logistics of the mission to the avoidance procedures the Endeavour Orbiter performed to miss hitting the inactive Air Force satellite, nicknamed 'Misty' (MSTI). Earth views included cloud cover, several storm systems, and various land masses with several views of the shuttle's open cargo bay in the foreground.

Source record↗

C/sic Life Prediction for Propulsion Applications

Accurate life prediction is critical to successful use of ceramic matrix composites (CMC). The tools to accomplish this are immature and not oriented toward the behavior of carbon fiber reinforced silicon carbide (C/SiC), the primary system of interest for many reusable and single mission launch vehicle propulsion and airframe applications. This paper describes an approach and process made to satisfy the need to develop an integrated life prediction system that addresses mechanical durability and environmental degradation of C/SiC. Issues such as oxidation, steam and hydrogen effects on material behavior are discussed. Preliminary tests indicate that steam will aggressively remove SiC seal coat and matrix in line with past experience. The kinetics of water vapor reaction with carbon fibers is negligible at 600 C, but comparable to air attack at 1200 C. The mitigating effect of steam observed in fiber oxidation studies has also been observed in stress rupture tests. Detailed microscopy of oxidized specimens is being carried out to develop the oxidation model. Carbon oxidation kinetics are reaction controlled at intermediate temperatures and diffusion controlled at high temperatures (approximately 1000 C). Activation energies for T-300 and interface pyrolytic carbon were determined as key inputs to the oxidation model. Crack opening as a function of temperature and stress was calculated. Mechanical property tests to develop and verify the probabilistic life model are very encouraging except for residual strength prediction. Gage width is a key variable governing edge oxidation of seal coated specimens. Future efforts will include architectural effects, enhanced coatings, biaxial tests, and LCF. Modeling will need to account for combined effects.

Levine, Stanley R.↗

C/SIC Life Prediction for Propulsion Applications

Accurate life prediction is critical to successful use of ceramic matrix composites (CMC). The tools to accomplish this are immature and not oriented toward the behavior of carbon fiber reinforced silicon carbide (C/SiC), the primary system of interest for many reusable and single mission launch vehicle propulsion and airframe applications. This paper describes an approach and progress made to satisfy the need to develop an integrated life prediction system that addresses mechanical durability and environmental degradation of C/SiC. Issues such as oxidation, steam and hydrogen effects on material behavior are discussed. Preliminary tests indicate that stream will aggressively remove SiC seal coat and matrix in line with past experience. The kinetics of water vapor reaction with carbon fibers is negligible at 600 C, but comparable to air attack at 1200 C. The mitigating effect of steam observed in fiber oxidation studies has also been observed in stress rupture tests. Detailed microscopy of oxidized specimens is being carried out to develop the oxidation model. Carbon oxidation kinetics are reaction controlled at intermediate temperatures and diffusion controlled at high temperatures (approx. 1000 C). Activation energies for T-300 and interface pyrolytic carbon were determined as key inputs to the oxidation model. Crack opening as a function of temperature and stress was calculated. Mechanical property tests to develop and verify the probabilistic life model are very encouraging except for residual strength prediction. Gage width is a key variable governing edge oxidation of seal coated specimens. Future efforts will include architectural effects, enhanced coatings, biaxial tests, and LCF. Modeling will need to account for combined effects.

Levine, Stanley R.↗

Characterization of the indoor far-field aerosol transmission in a model commercial office building

As businesses gradually reopen and employees return to work, the potential spread of SARS-CoV-2 and its variants through airborne transmission via the heating, ventilation, and air-conditioning (HVAC) systems of commercial building raises concerns. Since the general practice in commercial buildings is to use low-efficiency air filters and given that indoor air is generally recycled, the degree to which cross-zone aerosol transmission occurs is of interest. To quantify the cross-zone aerosol transmission, experiments were conducted using a synthetic test aerosol in the five zones on the first floor of a model commercial office building at the Oak Ridge National Laboratory. Because the synthetic aerosol was tagged with fluorescent salt, the aerosol generated from the source zone can be distinguished from the background aerosols due to its unique fluorescent signal. Data from cross-zone campaigns showed that submicron-aerosol transmission was higher than the micron aerosols. In campaigns with doors closed, the submicron aerosol transmission was less than 16% and less than 11% for micron aerosol transmission. Finally, opening the interior doors that connecting different zones can significantly enhance the aerosol transmission for zones at the close proximity to the source, but has less impact on those farther away.

60 APPLIED LIFE SCIENCES↗

Effect of cultural conditions on the seed-to-seed growth of Arabidopsis and Cardamine - A study of growth rates and reproductive development as affected by test tube seals

The effects of test tube seals on the growth, flowering, and seed pod formation of Arabidopsis thaliana (L.) Heynh., mouse ear cress, and Cardamine oligosperma Nutt, bitter cress, are studied in order to assess the conditions used in weightlessness experiments. Among other results, it is found that the growth (height) and flowering (date of bud appearance) were suppressed in mouse ear cress in tubes sealed with Saran. Seed pod formation which occurred by day 45 in open-to-air controls, was still lacking in the sealed plants even up to day 124. The growth and flowering of bitter cress were also suppressed by the Saran seal, although up to day 55 the Saran-sealed plants were taller. It is suggested that atmospheric composition was the cause of the suppression of growth, flowering, and seed pod development in these plants, since the mouse ear cress renewed their growth and then set seed pods after the Saran seal was ruptured.

Hoshizaki, T.↗

Assessing MMOD Impacts on Seal Performance

The elastomer seal needed to seal in cabin air when NASA s Crew Exploration Vehicle is docked is exposed to space prior to docking. While open to space, the seal might be hit by orbital debris or meteoroids. The likelihood of damage of this type depends on the size of the particle. Our campaign is designed to find the smallest particle that will cause seal failure resulting in loss of mission. We will then be able to estimate environmental risks to the seal. Preliminary tests indicate seals can withstand a surprising amount of damage and still function. Collaborations with internal and external partners are in place and include seal leak testing, modeling of the space environment using a computer code known as BUMPER, and hypervelocity impact (HVI) studies at Caltech. Preliminary work at White Sands Test Facility showed a 0.5 mm diameter HVI damaged areas about 7 times that diameter, boring deep (5 mm) into elastomer specimens. BUMPER simulations indicate there is a 1 in 1440 chance of getting hit by a particle of diameter 0.08 cm for current Lunar missions; and 0.27 cm for a 10 year ISS LIDS seal area exposure.

deGroh, Henry C., III↗

WBS 4.2.1.31 Integrated Life Cycle Sustainability Analysis

The main objective of this project (following the 2017 BETO Program Peer-Review) is to provide BETO with a coherent methodology and modeling framework based on life cycle (LCA) and economic input-output analysis, tested and vetted with stakeholders, to better understand the effects of an expanding U.S. bioeconomy at specific levels including economic dimensions such as jobs, gross domestic product (value added), and environmental criteria such as air pollutant emissions, water and land use, ecotoxicity, and others. This supports a 2019 milestone in the BETO MYP and simultaneously addresses a gap previously identified in the BETO program and highlighted, e.g., by BETO Program Peer Reviewers in 2015 and 2017. To fill in this gap, NREL started collaborating with developers of the national level U.S. Environmentally-Extended Input-Output (USEEIO) model in FY18. This peer-reviewed, open source model is based on publicly available data, and developed and maintained by U.S. EPA where it has been the basis for EPA's Sustainable Material Management analyses and program. Also, USEEIO was initially designed for use with EPA's Tool for the Reduction and Assessment of Chemicals and Other Environmental Impacts (TRACI). It aligns well with similar efforts including the Federal LCA Commons and the Sustainable Acquisition Program at the Department of Defense (DoD). In FY18, NREL convened stakeholders from federal agencies, universities, and private sector entities to identify and form a common understanding of (1) models describing the U.S. economy and how to build off of them, (2) a bioeconomy definition for the next modeling steps, (3) the (sub)sectors that can/should be used in the framework, and (4) opportunities for collaboration and data sharing. NREL then created a first order model by disaggregating, i.e., separating the economic activities associated with and attributed to a selected product of the bioeconomy: corn ethanol. Corn ethanol is well studied and has a significant amount of public, validated economic industry information. This is important as disaggregation is a critical step in creating a representative and accurate framework. Corn ethanol served as a validation test case for the method and framework. By the end of FY18, the team was able to generate several scenarios for corn ethanol on national and selected regional levels providing results on the absolute and relative (Megajoule) effects in several environmental and economic impact categories. A second objective of the project is to inform BETO's strategic decision making, specifically its sustainability research portfolio, by engaging in, evaluating, and synthesizing selected global multi-year activities from the perspectives of a variety of complex multilateral and multi-stakeholder processes that pertain to bioenergy. This helps to (1) identify gaps, barriers, and critical areas for future BETO bioenergy and sustainability assessments; (2) identify opportunities and challenges to a sustainable U.S. bioeconomy; and (3) contribute to and disseminate BETO information to and from major global bioenergy and sustainability efforts. This project's work with multilateral organizations ensures that U.S. science-based viewpoints are considered and helps to balance the influence of the large number of countries with the same centralized philosophy. This engagement builds a more solid foundation for sustainable biomass and bioenergy systems in the U.S. and in the world. Working with multi-lateral, international platforms including IEA Bioenergy, Global Bio-Energy Partnership (GBEP), and their partner organizations also allows engagement with important stakeholders including policy makers, industry, NGOs, and academia.

09 BIOMASS FUELS↗

A novel 3-D pulsating heat pipe module for high heat-flux applications

This study proposed a novel pulsating heat pipes (PHP) for high-flux thermal module. According to the open literature, the maximum value of the heat flux is 23.7 W∙cm –2 handled by PHP, which is far behind industry requirements. Therefore, the present study proposes a novel 3D PHP suitable for high heat-flux applications. The PHP were experimentally tested for different working fluids, including methanol and water. Furthermore, the experiments were performed to analyze the influence of various operating parameters, such as filling ratio (25–60%), heat load (100–800 W), and air flow rate 100–250 cubic feet per minute (CFM). In this work, the results showed that this PHP can sustain a heat flux up to 70 W∙cm –2 with the maximum case temperature under 80 °C, which is approximately three times higher than the available literature. Furthermore, the performance of the PHP module was compared against the commercial module with wicked heat pipe. The PHP exhibited about 7% higher heat dissipation compared to the commercial module. Since the proposed module uses simple copper tubes in its construction over the wicked structure used in commercial module, the novel 3D PHP module provides additional economic and mass production capability.

3D pulsating heat pipe↗

Performance evaluation of Space Shuttle SRB parachutes from air drop and scaled model wind tunnel tests

The aerodynamic performance characteristics have been determined for the Space Shuttle Solid Rocket Booster drogue, main, and pilot parachutes. The performance evaluation on the 20-degree conical ribbon parachutes is based primarily on air drop tests of full scale prototype parachutes. In addition, parametric wind tunnel tests were performed and used in parachute configuration development and preliminary performance assessments. The wind tunnel test data are compared to the drop test results and both sets of data are used to determine the predicted performance of the Solid Rocket Booster flight parachutes. Data from other drop tests of large ribbon parachutes are also compared with the Solid Rocket Booster parachute performance characteristics. Parameters assessed include full open terminal drag coefficients, reefed drag area, opening characteristics, clustering effects, and forebody interference.

Moog, R. D.↗

An investigation of the use of discharge valves and an intake control for improving the performance of N.A.C.A. Roots type supercharger

This report presents the results of an analytical investigation on the practicability of using mechanically operated discharge valves in conjunction with a manually operated intake control for improving the performance of N. A. C. A. Roots type superchargers. These valves, which may be either of the oscillating or rotating type, are placed in the discharge opening of the supercharger and are so shaped and synchronized with the supercharger impellers that they do not open until the air has been compressed to the delivery pressure. The intake control limits the quantity of air compressed to engine requirements by permitting the excess air to escape from the compression chamber before compression begins. The percentage power saving and the actual horsepower saved were computed for altitudes from 0 to 20,000 feet. These computations are based on the pressure-volume cards for the conventional and the modified roots type superchargers and on the results of laboratory tests of the conventional type. The use of discharge valves shows a power saving of approximately 26 per cent at a critical altitude of 20,000 feet. In addition, these valves reduce the amplitude of the discharge pulsations and increase the volumetric efficiency. With slow-speed roots blowers operating at high-pressure differences even better results would be expected. For aircraft engine superchargers operating at high speeds these discharge valves increase the performance as above, but have the disadvantages of increasing the weight and of adding a high-speed mechanism to a simple machine. (author)

Schey, Oscar W↗

Atomization of liquid fuels. Part II

This report describes the design and operation of a nozzle to inject fuel into an engine. The design of the nozzle is open, without any compulsory or automatic stop-valve. The fuel injection is regulated simply by the pressure and the adjustment of the fuel pump.

FUELS - TESTS↗

Active Control of Rotating Stall Demonstrated for a Multistage Compressor With Inlet Distortion

Aircraft compressors can suffer debilitating consequences as a result of rotating stall and surge events caused by inlet distortions. This is particularly true of aircraft during takeoff, when the compressor is operating at peak performance close to the surge line. Significant research has been conducted by the NASA Glenn Research Center in the area of compressor stability enhancement through active and passive control methods. Most recently, an experiment was conducted at the Wright Patterson Air Force Base Research Laboratory on a two-stage fan with inlet guide vanes and inlet distortion. In this joint Small Business Innovation Research effort between Scientific Systems and Glenn, control of rotating stall was demonstrated in a multistage transonic fan. This twostage fan with inlet guide vanes was tested under clean and distorted inlet conditions. The compressor was also configured with a circumferential distortion screen capable of 180 of distortion and with 14 high-velocity injectors upstream of the first rotor. Twelve of these injectors could oscillate up to frequencies of 450 Hz. The additional two injectors were located next to each other and were used in concert with each other as a single, on/off, high-authority actuator. In a first test of injection in this multistage environment, 12 of the valves were opened 50 percent of their full stroke to assess steady injection through the compressor. This baseline injection is shown in the compressor characteristic of the following figure, and stall margin improvements are tracked from this baseline condition. The compressor was then tested with clean inlet conditions using 12 injectors and active control. Pressure disturbances were tracked before rotating stall, and a constant gain control scheme reduced the stalling mass flow by 10.8 percent over the baseline. With the distortion screen present in the inlet, a pole-zero cancellation control scheme was used to achieve a 6.4-percent decrease in stalling mass flow. These improvements also are shown in the figure. In a final experiment, actively controlled, high-frequency injection from the 12 valves was used in conjunction with the high-authority actuators. In this test, the stalling mass flow of the compressor was reduced by 27 percent as indicated in the graph. These results were obtained by injecting less than 2 percent of the total compressor throughflow into the rotor tip region via 14 injection ports. These results mark the first successful demonstration of actively controlled air injection as a stall-control strategy for multistage compressors operating at speeds typical of an actual gas turbine engine. A goal of continuing research is to determine the combination of air-injection parameters and control strategies that are most effective in providing stall control for both clean and distorted inlet flow conditions for multistage environments. Other goals include the demonstration of stall control at many locations along the core compressor and development and application of active stall control strategies that will be integral flightworthy components of onboard engine hardware.

VanSchalkwyk, Christian↗

Improved Fuel Cell Chemical Durability of an Heteropoly Acid Functionalized Perfluorinated Terpolymer-Perfluorosulfonic Acid Composite Membrane

Commercial proton exchange membrane heavy-duty fuel cell vehicles will require a five-fold increase in durability compared to current state-of-the art light-duty fuel cell vehicles. We describe a new composite membrane that incorporates silicotungstic heteroply acid (HPA), α -K 8 SiW 11 O 40 ▪13H 2 O, a radical decomposition catalyst and when acid-exchanged can potentially conduct protons. The HPA was covalently bound to a terpolymer of tetrafluoroethylene, vinylidene fluoride, and sulfonyl fluoride containing monomer (1,1,2,2,3,3,4,4-octafluoro-4-((1,2,2-trifluorovinyl)oxy)butane-1-sulfonyl fluoride) by dehydrofluorination followed by addition of diethyl (4-hydroxyphenyl) phosphonate, giving a perfluorosulfonic acid-vinylidene fluoride-heteropoly acid (PFSA-VDF-HPA). A composite membrane was fabricated using a blend of the PFSA-VDF-HPA and the 800EW 3M perfluoro sulfonic acid polymer. The bottom liner-side of the membrane tended to have a higher proportion of HPA moieties compared to the air-side as gravity caused the higher mass density PFSA-VDF-HPA to settle. The composite membrane was shown to have less swelling, more hydrophobic properties, and higher crystallinity than the pure PFSA membrane. The proton conductivity of the membrane was 0.130 ± 0.03 S cm −1 at 80 °C and 95% RH. Impressively, when the membrane with HPA-rich side was facing the anode, the membrane survived more than 800 h under accelerated stress test conditions of open-circuit voltage, 90 °C and 30% RH.

08 HYDROGEN↗

The Dual-Axis Radiographic Hydrodynamic Test Facility Capability eXpansion (DCX) Strategy

The Dual-Axis Radiographic Hydrodynamic Test (DARHT) facility is a vital and important part of the Nation’s nuclear security enterprise. The Department of Energy/National Nuclear Security Administration (DOE/ NNSA) Stockpile Stewardship Management Plan (SSMP) identifies DARHT as a weapons mission critical facility along with the need to modernize DARHT to support weapons modernization efforts. With more than two decades of operations, DARHT has a storied history. Conceived in the 1970s, constructed in the 1990s, and operational since 2000, DARHT has advanced from open-air hydrodynamic experiments (hydros) to foam-confined hydros, to vessel-confined hydros, and in 2022, the 75 th hydro was successfully completed. Radiography has advanced from a single-axis, single-pulse system to a dual-axis, multi-pulse capability to variable fields of view (VFV) on both accelerators. The culmination of these experiences, accomplishments, and advancements has brought us to a very important question: What do the next two decades at DARHT look like? The world is not the same place it was in the 1990s when construction at DARHT was in progress. Evolving threats, an expanding mission, and technology changes necessitate adaptation. The 2018 Nuclear Posture Review (NPR) states that the nuclear weapons infrastructure has suffered the effects of age and underfunding with no margin for further delay in recapitalizing the physical infrastructure. To adapt, the aging facility, accelerators, vessels, and detector systems require improvements to ensure DARHT remains the Nation’s hydrodynamic data foundation for stockpile certification, safety, surety, and global security threats.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Performance, Combustion and Emissions Evaluation of Liquid Phase Port-Injected LPG on a Single Cylinder Heavy-Duty Spark Ignited Engine

Liquefied petroleum gas (LPG), like many other alternative fuels, has witnessed increased adoption in the last decade, and its use is projected to rise as stricter emissions regulations continue to be applied. However, much of its use is limited to dual fuel applications, gaseous phase injection, light-duty passenger vehicle applications, or scenarios that require conversion from gasoline engines. Therefore, to address these limitations and discover the most efficient means of harnessing its full potential, more research is required in the development of optimized fuel injection equipment for liquid port and direct injection, along with the implementation of advanced combustion strategies that will improve its thermal efficiency to the levels of conventional fuels. This paper focuses on the development of a liquid phase port-injection system for LPG, the design of a reference piston, and the baseline evaluation of the performance, combustion, and emissions characteristics of a single cylinder research engine to establish a benchmark comparable to existing LPG engines. A sweep of start of injection (SOI) timing is performed by injecting liquid LPG at several closed and open intake valve timings, which demonstrates no significant variation in engine performance, but accounts for a 10% reduction in bsCO with the optimal SOI timing. Spark timing sweep demonstrates the 50% burn crank angle location related to maximum brake torque (MBT) point with a brake thermal efficiency (BTE) of ~34% for the tested load case. The effect of equivalence ratio is also presented with optimal SOI timing at MBT condition. The engine starts exhibiting knocking combustion at 140kPa intake manifold air pressure (IMAP) with a peak torque of 253Nm and a 5% reduction in brake specific fuel consumption compared to the naturally aspirated scenario.

Fosudo, Toluwalase↗

The Prevention of Ice Formation on Gasoline Tank Vents

This investigation was conducted in the refrigerated wind tunnel at the Langley Memorial Aeronautical Laboratory, Langley Field, Va., to determine a suitable method for preventing the formation of ice on the vents of airplane gasoline tanks. Tests were made on a variety of vent forms arranged in a number of different orientations relative to the direction of the air stream. Both the size of the tube and its orientation were found to be of great importance. Small tubes, under equal circumstances, were found to freeze over far more rapidly than large ones. Tubes pointing downstream, or shielded in other ways, appear to be perfectly immune against this hazard. A tube 3/4 inch in diameter with the opening pointing downstream is finally recommended as being the safest choice of gas tank vent.

Theodorsen, Theodore↗