Near UV based LED fabricated with K2Ba3Si8O20:Eu2+ and energy transfer between Ce3+ and Eu2+
Highlights: • A kind of novel green-emitting phosphor K{sub 2}Ba{sub 3}Si{sub 8}O{sub 20}:Ce{sup 3+},Eu{sup 2+} has been prepared. • Energy transfer in this host is systematically investigated and their origins are to be revealed. • Commission on illumination value as well as thermal luminescence quenching properties are studied. • Results indicate that the phosphor can be served as a potential green emitting phosphor candidate for LED devices. - Abstract: K{sub 2}Ba{sub 3}Si{sub 8}O{sub 20}:Eu{sup 2+} as a new green-emitting phosphor was prepared and studied in this article. This material showed powerful absorption in near ultraviolet-visible regions from 350 to 450 and its green-emitting band peaked at 502 nm. Its photoluminescence emitting intensity affected by concentrations of K{sub 2}Ba{sub 3}Si{sub 8}O{sub 20}:Ce{sup 3+} and K{sub 2}Ba{sub 3}Si{sub 8}O{sub 20}:Eu{sup 2+} was also studied and consequently verified to be a dipole–dipole interaction. Effective energy transfer was observed in Ce{sup 3+},Eu{sup 2+} co-doped K{sub 2}Ba{sub 3}Si{sub 8}O{sub 20} phosphor, and the transfer efficiency was also obtained from the decay lifetime. The K{sub 2}Ba{sub 3}Si{sub 8}O{sub 20}:Eu{sup 2+} phosphor combined with a 380 nm near-UV chip was demonstrated to produce a diode which emitted green light. This article indicates that the phosphor prepared in this work could be used in manufacturing of white light-emitting diodes.