Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “HUMIDITY”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Mitigation of PtCo/C Cathode Catalyst Degradation via Control of Relative Humidity

Maintaining the high performance of proton-exchange membrane fuel cells (PEMFC) over the course of its lifetime is a key enabling factor for its successful commercialization as a primary power source in zero-emission transportation applications. In this context, it is important to mitigate the degradation of PtCo-alloy based cathode catalysts used for oxygen reduction reaction (ORR). PtCo-alloy catalysts exhibit high activity at beginning-of-life (BOL) which tends to decrease during operation due to loss of electrochemical surface area (ECSA) and dissolution-contamination related effects of the Co-alloying component. Here, we demonstrate the use of relative humidity (RH) of the inlet gases as a controllable parameter to mitigate the degradation of PtCo-alloy catalyst degradation. We employ a catalyst-specific voltage cycling accelerated stress test (AST) durability protocol as a function of inlet RH to degrade PtCo catalysts. A series of in situ electrochemical diagnostics and ex situ characterizations have been carried out to investigate the catalyst layer characteristics at end-of-test (EOT). Our results show that at sub-saturated conditions of durability protocol operation, PtCo catalyst sustains higher EOT H 2 /air performance due to better retention of ECSA and smaller impact of Co 2+ dissolution/contamination.

25 ENERGY STORAGE↗
DOE OSTI2023

Electrospun Nanofiber Electrodes for High and Low Humidity PEMFC Operation

MEAs with nanofiber mat electrodes containing Pt/C catalyst and Nafion binder were fabricated and evaluated. The electrodes were prepared by electrospinning a solution of catalyst powder, salt-form Nafion (with Na + , Li + , or Cs + as the sulfonic acid counterion), and a carrier polymer of either polyethylene oxide or poly(acrylic acid). The carrier polymer was extracted prior to MEA testing by a hot water soaking step. The resulting fibers were 15%–17% porous, with a core–shell-like morphology (a coating of primarily Nafion on the fiber surface). MEAs with anode/cathode catalyst loadings of 0.1 mg Pt cm −2 each and a Nafion 211 membrane produced high power at both high and low relative humidity (RH) conditions in H 2 /air fuel cell tests, e.g., a maximum power density of 919 mW cm −2 at 100% RH and 832 mW cm −2 at 40% RH for a test at 80 °C and 200 kPa abs . The presence of nm-size pores within the fibers trapped water via capillary condensation during low RH feed gas testing, thus maintaining a high proton conductivity of the Nafion binder in the anode and cathode while minimizing/eliminating ionic isolation of catalyst particles in low water content, poorly conductive binder.

25 ENERGY STORAGE↗
DOE OSTI2023

Relative-Humidity Dependence of Electrochemically Active Surface Area in Porous Carbon Catalyst Layers

Polymer-electrolyte fuel cells (PEFCs) utilize porous catalyst layers (CLs) formed of carbon supports on which Pt particles are deposited and ionomer films are distributed. Carbon supports themselves have varying degrees of porosity, where high-surface-area carbon (HSC) supports possess nanometer-sized interior pores that are suitable for Pt nanoparticle deposition but prevent deleterious ionomer penetration. However, this requires protons to transport through water pathways inside the pores. To understand the generation of such pathways, we examine the various mechanisms of water uptake by PEFC CLs, and the subsequent impact of water uptake on Pt utilization through developing a multiphysics model of the water wetting phenomena as a function of relative humidity. The model details water uptake via ionomer absorption, capillary condensation in the hydrophilic pores, and surface adsorption using molecular potential that account for various water and surface dipole interactions. The results quantify how mesoporous carbons with highly hydrophilic pores increase Pt utilization through the development of wetted layers, which at the same time enable optimized gas-transport pathways. It also demonstrates the impact of pore-size distribution (PSD) and physical and chemical parameters on the water uptake phenomena, allowing for future CL particle and structure optimization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Quantitative form and fit of N95 filtering facepiece respirators are retained after dry and humid heat treatments for coronavirus deactivation

Re-use of filtering facepiece respirators (FFRs, commonly referred to as N95s) normally meant for single use only is becoming common in healthcare facilities due to shortages caused by the COVID19 pandemic. Here we report that mouse hepatitis virus (MHV) initially seeded on FFR filter material is inactivated (6 log reduction as measured by 50% tissue culture infective dose (TCID50)) after dry heating at 75 °C for 30 minutes. We also find that the quantitative fit of FFRs after heat treatment at this temperature, under dry conditions or at 90% relative humidity, is not affected by single or ten heating cycles. Previous studies have reported that the filtration efficiency of FFR filters is not negatively impacted by these heating conditions. These results suggest that thermal inactivation of coronaviruses is a potentially rapid and widely deployable method to re-use N95 FFRs in emergency situations where reusing FFRs is a necessity and broad-spectrum sterilization is unavailable. However, we also found that a heat source that emits radiation (e.g., an exposed heating element) results in rapid qualitative degradation of the FFR. Finally, we discuss differences in the results reported here and other recent studies investing heat as a means to recycle FFRs and suggest that overall wear time and donning/doffing cycles are important factors that need to be considered.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Understanding the temperature and humidity dependence of the SiPM characteristics

A miniature version of the ICAL experiment at the India-based Neutrino Observatory, the mini-ICALis in operation at the IICHEP, Madurai. The commissioning work of a Cosmic Muon Veto detector (CMVD)on top of the mini-ICAL is continued using extruded plastic scintillators with embeddedWLS fibers and the SiPM as a photo-transducer. The CMVD is being built to study thefeasibility of a cosmic muon veto for a shallow-depth neutrino experiment. The SiPM is calibratedusing an ultrafast LED driver andthe same calibration techniques will be used during the data taking period with a simplified LED in thesame readout PCB. An experimental setup wasdesigned to characterise the SiPMs in a temperature controlled environment. The readout electronicsinvolves trans-impedance amplifiers and a voltage followers of combined gain 1.24 mV/$\mu$A and adigital storage oscilloscope for the data collection with a minimal distortion of SiPM signal.Various characteristics of the Hamamatsu SiPM (S13360-2050VE), e.g. signal shape, optically correlatedand uncorrelated noise, recovery time etc were studied as a function of $V_{ov}$, number of photoelectrons,the ambient temperature and the humidity. This paper will cover the details of those results.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Impact of Humidity and Temperature on the Stability of the Optical Properties and Structure of MAPbI3, MA0.7FA0.3PbI3 and (FAPbI3)0.95(MAPbBr3)0.05 Perovskite Thin Films

In situ real-time spectroscopic ellipsometry (RTSE) measurements have been conducted on MAPbI3, MA0.7FA0.3PbI3, and (FAPbI3)0.95(MAPbBr3)0.05 perovskite thin films when exposed to different levels of relative humidity at given temperatures over time. Analysis of RTSE measurements track changes in the complex dielectric function spectra and structure, which indicate variations in stability influenced by the underlying material, preparation method, and perovskite composition. MAPbI3 and MA0.7FA0.3PbI3 films deposited on commercial fluorine-doped tin oxide coated glass are more stable than corresponding films deposited on soda lime glass directly. (FAPbI3)0.95(MAPbBr3)0.05 films on soda lime glass showed improved stability over the other compositions regardless of the substrate, and this is attributed to the preparation method as well as the final composition.

36 MATERIALS SCIENCE↗
DOE OSTI2020

A global model–measurement evaluation of particle light scattering coefficients at elevated relative humidity

The uptake of water by atmospheric aerosols has a pronounced effect on particle light scattering properties, which in turn are strongly dependent on the ambient relative humidity (RH). Earth system models need to account for the aerosol water uptake and its influence on light scattering in order to properly capture the overall radiative effects of aerosols. Here we present a comprehensive model–measurement evaluation of the particle light scattering enhancement factor f(RH), defined as the particle light scattering coefficient at elevated RH (here set to 85 %) divided by its dry value. The comparison uses simulations from 10 Earth system models and a global dataset of surface-based in situ measurements. In general, we find a large diversity in the magnitude of predicted f(RH) amongst the different models, which can not be explained by the site types. Based on our evaluation of sea salt scattering enhancement and simulated organic mass fraction, there is a strong indication that differences in the model parameterizations of hygroscopicity and model chemistry are driving at least some of the observed diversity in simulated f(RH). Additionally, a key point is that defining dry conditions is difficult from an observational point of view and, depending on the aerosol, may influence the measured f(RH). The definition of dry also impacts our model evaluation, because several models exhibit significant water uptake between RH = 0 % and 40 %. The multisite average ratio between model outputs and measurements is 1.64 when RH = 0 % is assumed as the model dry RH and 1.16 when RH = 40 % is the model dry RH value. The overestimation by the models is believed to originate from the hygroscopicity parameterizations at the lower RH range which may not implement all phenomena taking place (i.e., not fully dried particles and hysteresis effects). This will be particularly relevant when a location is dominated by a deliquescent aerosol such as sea salt. Our results emphasize the need to consider the measurement conditions in such comparisons and recognize that measurements referred to as dry may not be dry in model terms. Recommendations for future model–measurement evaluation and model improvements are provided.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Developing A Custom-Built Metal Aerosol Processing Chamber: Analysis of Aerosol Coagulation at Low Humidities

We have developed an intermediate size (906 L) aerosol processing chamber, and this work reports on the design and initial characterization of dry aerosol experiments. Specifically, we are determining wall-loss and coagulation correction factors using the observed size distribution measurements for surrogates of common aerosol classes: sodium chloride, sucrose, and biomass burning aerosol smoke. Results show that, on average, sodium chloride, sucrose, and smoke wall-loss rates converge to similar values on relatively short time scales (< 1 h). The fitted coagulation correction factor, W C -1 , for smoke particles (1.23 ± 0.312), indicates that on average they adhere to each other more than sodium chloride (0.969 ± 0.524) and sucrose (1.16 ± 1.38). The relative uncertainty is high for the coagulation correction, but it is consistent with our Monte Carlo error analysis. This study lays the foundation for future experiments at elevated humidity and supersaturation conditions to characterize the influence of particle shape on coagulation and cloud parameters.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

University of Kentucky measurements of wind, temperature, pressure and humidity in support of LAPSE-RATE using multisite fixed-wing and rotorcraft unmanned aerial systems

In July 2018, unmanned aerial systems (UASs) were deployed to measure the properties of the lower atmosphere within the San Luis Valley, an elevated valley in Colorado, USA, as part of the Lower Atmospheric Profiling Studies at Elevation – a Remotely-piloted Aircraft Team Experiment (LAPSE-RATE). Measurement objectives included detailing boundary layer transition, canyon cold-air drainage and convection initiation within the valley. Details of the contribution to LAPSE-RATE made by the University of Kentucky are provided here, which include measurements by seven different fixed-wing and rotorcraft UASs totaling over 178 flights with validated data. The data from these coordinated UAS flights consist of thermodynamic and kinematic variables (air temperature, humidity, pressure, wind speed and direction) and include vertical profiles up to 900 m above the ground level and horizontal transects up to 1500 m in length. These measurements have been quality controlled and are openly available in the Zenodo LAPSE-RATE community data repository (https://zenodo.org/communities/lapse-rate/, last access: 23 July 2020), with the University of Kentucky data available at https://doi.org/10.5281/zenodo.3701845 (Bailey et al., 2020).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1967

Fluidic oscillator used as humidity sensor

Fluidic oscillator measures the humidity of the hydrogen stream leaving a hydrogen-oxygen fuel cell. The instrument provides continuous readings with a certain speed of response.

Prokopius, P. R.↗