Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “HCN”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)

Continuum and spectral-line radio observations of the comets IRAS-Araki-Alcock and Sugano-Saigusa-Fujikawa obtained at a number of observatories during May and June, 1983, are compiled in tables and briefly characterized. The species NH3, H2O, CO, and HCN are considered in detail; visible-range observations of CN are compared; and the implications of the results and the experience gained in performing and coordinating the observations for the detection of important species in other comets, especially Halley's Comet, are explored.

Irvine, W. M.↗
NASA NTRS1984

Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 x 10 to the -6th W/sq m can be expected. This value is much lower than that for earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C2N2 produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 0.01, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.

Borucki, W. J.↗
NASA NTRS1985

Chemistry in dynamically evolving clouds

A unified model of chemical and dynamical evolution of isolated, initially diffuse and quiescent interstellar clouds is presented. The model uses a semiempirically derived dependence of the observed cloud temperatures on the visual extinction and density. Even low-mass, low-density, diffuse clouds can collapse in this model, because the inward pressure gradient force assists gravitational contraction. In contrast, previous isothermal collapse models required the low-mass diffuse clouds to be unrealistically cold before gravitational contraction could start. Theoretically predicted dependences of the column densities of various atoms and molecules, such as C and CO, on visual extinction in diffuse clouds are in accord with observations. Similarly, the predicted dependences of the fractional abundances of various chemical species (e.g., CO, H2CO, HCN, HCO(+)) on the total hydrogen density in the core of the dense clouds also agree with observations reported to date in the literature. Compared with previous models of interstellar chemistry, the present model has the potential to explain the wide spectrum of chemical and physical properties of both diffuse and dense clouds with a common formalism employing only a few simple initial conditions.

Tarafdar, S. P.↗
NASA NTRS1984

The high resolution submillimetre spectrum of the stratosphere

The structure of the stratospheric spectrum, measured with a resolution of 0.0033/cm unapodized in the 7-90/cm spectral interval is described. The spectra from measurements recorded on April 24, 1979 from a balloon-borne platform at about 39 km altitude launched from the National Scientific Balloon Facility of Palestine, TX are presented. The main spectroscopic constituents include a few strong and saturated lines due to the rotational spectrum of water vapor, to magnetic dipole transitions of oxygen, and to the rotational spectrum of ozone. It is shown that the lines of ozone prevent the positive identification of the contribution to the submillimeter spectrum of several minor constituents such as HF, HCl, HCN, HNO3, and N2O. The assignments which are possible in the spectra are revised.

Carli, B.↗
NASA NTRS1984

A balloon-borne microwave limb sounder for stratospheric measurements

The balloon-borne microwave limb sounder (BMLS) measures atmospheric thermal emission from millimeter wavelength spectral lines to determine vertical profiles of stratospheric species. The instrument flown to date operates at 205 GHz to measure ClO, O3, and H2O2. A 63 GHz radiometer will be added to test the technique for determining tangent point pressure from the MLS experiment on the upper atmosphere research satellite (UARS). Many additional species could also be measured by the BMLS. A radiometer at 270 GHz would provide measurements of HO2, NO2, HNO3, N2O, O-16O-18O-16, and HCN. With this addition, the BMLS can test the current theory of O3 photochemical balance in the upper stratosphere.

Waters, J. W.↗
NASA NTRS1984

Chemical evolution on the giant planets and Titan

The atmospheres of Jupiter, Saturn, Neptune and Uranus, and Titan are characterized chemically in a review of recent observational and theoretical investigations. Compositions are indicated in tables, and special emphasis is given to the formation of HCN on Jupiter, the differentiation of polar and equatorial zones in the Jovian atmosphere, the mechanisms responsible for the color of the Great Red Spot, and the possible origin of the N2-dominated atmosphere of Titan.

Caldwell, J.↗
NASA NTRS1985

Theoretical investigation of the interstellar CH3NC/CH3CN ratio

Calculations have been performed to determine the abundance ratio of the metastable isomer CH3NC to the stable isomer CH3CN in dense interstellar clouds. According to gas phase, ion-molecule treatments, these molecules are both synthesized via protonated ion precursors. A calculation has been made of the ratio of the formation rates of the protonated precursor ions, CH3NCH(+) and CH3CNH(+), synthesized via the radiative association reaction between CH3(+) and HCN, which is thought to be the dominant formation process of the two isomeric ions. The calculations, which involve both ab initio quantum chemistry and equilibrium determinations, lead to a predicted CH3NCH(+)/CH3CNH(+) formation rate ratio between 0.1 and 0.4. If this ratio is maintained in the neutral species formed from the precursor ions, theory predicts a sizable abundance for methyl isocyanide (CH3NC) and lends credence to its tentative observation.

Defrees, D. J.↗
NASA NTRS1985

Detection of interstellar CCD

The first detection of interstellar CCD has been obtained in the N = 3-2, J = 7/2-5/2 line at 216.3732 GHz towards the Kleinman-Low nebula. An abundance ratio CCD/CCH of 0.045 is found, indicating in this molecule a deuterium enhancement similar to that found for HNC, but an order of magnitude higher than for HCN. Negative results towards DR 21(OH), NGC 2264, L 134N, TM Cl, Rho OphB2, and IRC 10216 rule out a stronger D enhancement for CCD than for other deuterated molecules in these sources. Predictions of currently developed ion-molecule reaction schemes are consistent with the CCD line detected and the negative results.

Combes, F.↗
NASA NTRS1985

Microwave limb sounder for stratospheric measurements

The balloon-borne Microwave Limb Sounder (BMLS) measures atmospheric thermal emission from millimeter wavelength spectral lines to determine vertical profiles of stratospheric species. The instrument flown to data operates at 205 BHz to measure ClO, O3, and H2O2. A 63 GHz radiometer is added to test the technique for determining tangent point pressure from the MLS experiment on the Upper Atmosphere Research Satellite (UARS). Many additional species is also measured by the BLMS. A radiometer at 270 GHz would provide measurements of HO2, NO2, HNO3, N2O, 16O18O16O, and HCN. With this addition the BMLS can test the current theory of O3 heavy ozone photochemical balance in the upper stratosphere.

Waters, J. W.↗
NASA NTRS1986

Characterization of biogenic elements in interplanetary dust particles

Those particles that were designated cometary are aggregates of amorphous materials including carbon, iron-magnesium silicates, sulfides, metal and trace amounts of unusual phases. Most aggregates are carbon-rich with major and minor element abundances similar to a fine grained matrix of carbonaceous chondrites. Several particles were analyzed by a laser microprobe. The negative ionic species identified to date include carbon clusters, protonated carbon clusters, CN-, HCN-, CNO-, PO2-, PO3-, S-, S2- asnd OH-. These species are similar to those observed in cometary spectra and they support the assumption that organic materials are present. The occurance of phosphate ions suggests the presence of apatite or whitlockite. Cometary particle characteristics may indicate that the component grains represent primitive unaltered dust whose overall properties are extremely similar to altered primitive dust in carbonaceous chondrites.

Bunch, T. E.↗
NASA NTRS1985

The photochemistry of the early atmosphere

The composition of the earth's present atmosphere is described. The formation of the earth from the coalescence and accretion of the refractory elements of the solar nebula is examined. Two possible compositions of the prebiological paleoatmosphere, which are a reducing atmosphere of CH4, NH3, and H2 or a mildly reducing atmosphere of H2O, CO2, and N2, and their photochemistry are analyzed. General photochemical and chemical processes are reviewed. The use of the coupled continuity-transport equation to calculate the vertical distribution of each species is discussed. A study of the photochemical process of CH4 and NH3 reveals that the reducing atmosphere could not possibly exist. An analysis of the photochemistry and chemistry of the H2O, CO2, and N2 atmosphere reveals that the photodissociation of H2O and CO2 results in a prebiotic source of O2, H2CO, and HCN, which are the components for the evolution of photosynthetic organisms and a strongly oxidizing atmosphere. The reactions which produce O2 and H2CO from H2O and CO2, and the relation between H2O and CO2 concentrations and O2 levels are investigated. The formation of O3 photochemically from O2 is explained.

Levine, J. S.↗
NASA NTRS1987

Atlas of Absorption Lines from 0 to 17900 Cm (sup)-1

Plots of logarithm (base 10) of absorption line strength versus wavenumber from 0 to 17900/cm(sup)-1 are shown for the 28 atmospheric gases (H2O, CO2, O3, N2O, CO, CH4, O2, NO, SO2, NO2, NH3, HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, H2CO, HOCl, N2, HCN, CH3Cl, H2O2, C2H2, C2H6, PH3), which appear in the 1986 Air Force Geophysics Laboratory high-resolution transmission molecular absorption data base (HITRAN) compilation, and for O(P-3), O-18 isotopic ozone, and HO2 from the 1984 JPL compilation in the 0- to 200/cm(sup)-1 region, and infrared solar CO lines at 4500 K. Also shown are plots of logarithm (base 10) of approximate infrared absorption cross sections of 11 heavy molecules versus wavenumber. The cross-section data cover 700 to 1800/cm(sup)-1 and are included as a separate data file in the 1986 HITRAN database.

Park, J. H.↗
NASA NTRS1986

Variations in the HCN/HNC abundance ratio in the Orion molecular cloud

Observations of the rare isotopes of HCN and HNC have been used to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio HCN/HNC decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. The kinetic temperature in the regions studied is determined from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways that those in the general instellar cloud material.

Goldsmith, Paul F.↗
NASA NTRS1986

Dust grains and gas in the circumstellar envelopes around luminous red giant stars

Far-infrared color-color diagrams have been constructed for over 100 of the brightest evolved stars in the IRAS Point Source Catalog. The diagrams are used to deduce average values of the dust grain emissivity index (p) between 12 and 100 microns. Grains in C-rich and O-rich environments have similar values of p between 12 and 25 microns and between 60 and 100 microns, but between 25 and 60 microns p is larger by approximately 0.4 for the O-rich stars. Dust grains in envelopes around S-type stars seem to have 25 to 60 micron emissivities more nearly like grains in O-rich rather than C-rich environments. CO and HCN emissions from various stars are used to reclassify several stars as oxygen or carbon rich.

Zuckerman, B.↗
NASA NTRS1986

Detections of C-13-substituted C3H2 in astronomical sources

The more abundant C-13-substituted variant of the new interstellar ring molecule, C3H2, has been detected in TMC-1 and Sgr B2, and a tentative detection has been made in IRC + 10216. The fractional abundance relative to H2 is 1-2 x 10 to the -8th in TMC-1, a value similar to that of HCN. In Sgr B2, the C-12 species shows a self-absorbed profile and the relative abundance of C3H2 is about an order of magnitude less than in TMC-1. In IRC + 10216, the fractional abundance of C3H2 is an order of magnitude greater than that in TMC-1.

Madden, Suzanne C.↗
NASA NTRS1987

Infrared observations of circumstellar molecules

A current listing of IR observations of circumstellar molecules is presented. These observations were performed using Fabry-Perot, Fourier transform, and laser heterodyne spectroscopy. The most abundant species were CO, SiO, and HCN, while trace species included NH3, CH4, SiH4, and CS. Among the undetected species were H2, HCl, and CH2.

Betz, Albert↗
NASA NTRS1986

Current status of the prebiotic synthesis of small molecules

Experiments designed to simulate conditions on the primitive earth and to demonstrate how the organic compounds that made up the first living organisms were synthesized are described. Simulated atmospheres with CH4, N2, NH3, and H2O were found to be most effective for synthesis of small prebiotic molecules, although atmospheres with H2, CO, N2, and H2O, and with H2, CO2, N2, and H2O also give good yields of organic compounds provided the H2/CO and H2/CO2 ratios are above 1 and 2, respectively. The spark discharge (which is a good source of HCN) and UV light are also important. Reasonable prebiotic syntheses were worked out for the amino acids that occur in proteins (with the exception of lysine, arginine, and histidine), and for purines, pyrimidines, sugars, and nicotinic acid. Many of the molecules that have been produced in these simulated primitive-earth experiments are found in carbonaceous chondrites.

Miller, Stanley L.↗
NASA NTRS1987

Comets and life

Some of the chemical species which have been detected in comets include H2O, HCN, CH3CN, CO, CO2, NH3, CS, C2 and C3. All of these have also been detected in the interstellar medium, indicating a probable relationship between interstellar dust and gas clouds and comets. Laboratory experiments carried out with different mixtures of these molecules give rise to the formation of the biochemical compounds which are necessary for life, such as amino acids, purines, pyrimidines, monosaccharides, etc. However, in spite of suggestions to the contrary, the presence of life in comets is unlikely. On the other hand, the capture of cometary matter by the primitive earth is considered essential for the development of life on this planet. The amount of cometary carbon-containing matter captured by the earth, as calcualted by different authors, is several times larger than the total amount of organic matter present in the biosphere (10 to the 18th g). The major classes of reactions which were probably involved in the formation of key biochemical compounds are discussed. The tentative conclusions are that: (1) comets played a predominant role in the emergence of life on earth, and (2) they are the cosmic connection with extraterrestrial life.

Oro, J.↗