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At least 307 records · Page 17

Evidence for Acid-Sulfate Alteration in the Pahrump Hills Region, Gale Crater, Mars

The Pahrump Hills region of Gale crater is a approximately 12 millimeter thick section of sedimentary rock in the Murray formation, interpreted as the basal geological unit of Mount Sharp. The Mars Science Laboratory, Curiosity, arrived at the Pahrump Hills in September 2014 and performed a detailed six-month investigation of the sedimentary structures, geochemistry, and mineralogy of the area. During the campaign, Curiosity drilled and delivered three mudstone samples (targets Confidence Hills, Mojave 2, and Telegraph Peak) to its internal instruments, including the CheMin XRD/XRF.

Rampe, E. B.↗

Oxychlorine Detection in Gale Crater, Mars and Implications for Past Environmental Conditions

The Sample Analysis at Mars (SAM) instrument on the Mars Science Laboratory (MSL) rover Curiosity has analyzed 3 scooped samples and 15 drilled samples since landing in 2012. Oxychlorine compounds (perchlorate/chlorate) were detected in the first 9 drilled samples but have not been detected in the last 6, starting with the Oudam sample in the Hartmann’s Valley member of the Murray formation (Table 1). Scooped samples have all contained detectable oxychlorine. These results suggest that oxychlorine formation and preservation spans the geologic record on Mars but has not been uniform spatially or temporally.

Archer, P. D., Jr.↗

Saponite Dissolution Experiments and Implications for Mars

Phyllosilicates detected throughout the Noachian terrains of Mars provide ample evidence of water-rock interactions in its geologic past, and characterizing their formation would elucidate past environmental conditions on the martian surface. Previous work suggests that ferric smectite may have been deposited in the Noachian as ferroan (Fe2+) smectite and then subsequently oxidized after formation. This is further supported by the detection of trioctahedral saponite at the base of the stratigraphic section in Gale crater by CheMin and the gradual transition to dioctahedral ferric smectite up section. A better understanding of the dissolution behavior of saponites would therefore help us better interpret past water-rock interactions at Gale crater. However, smectite structures and compositions are variable and complex, and very few saponite dissolution rates exist in the literature. To further understand past water-rock interactions at Gale crater, we are reporting our results to date from dissolution experiments of Fe- and Mg- saponites under a range of conditions.

Luu, N. C.↗

Sulfate Mineral Formation from Acid-Weathered Phyllosilicates: Implications for the Aqueous History of Mars

Phyllosilicates on Mars are thought to have formed under neutral to alkaline conditions during Mars' earliest Noachian geologic era (approx. 4.1-3.7 Gya). Sulfate formation, on the other hand, requires more acidic conditions which are thought to have occurred later during Mars' Hesperian era (approx. 3.7-3.0 Gya). Therefore, regions on Mars where phyllosilicates and sulfates are found in close proximity to each other provide evidence for the geologic and aqueous conditions during this global transition. Both phyllosilicates and sulfates form in the presence of water and thus give clues to the aqueous history of Mars and its potential for habitability. Phyllosilicates that formed during the Noachian era may have been weathered by the prevailing acidic conditions that characterize the Hesperian. Therefore, the purpose of this study is to characterize the alteration products resulting from acid-sulfate weathered phyllosilicates in laboratory experiments. This study focuses on two phyllosilicates commonly identified with sulfates on Mars: nontronite and saponite. We also compare our results to observations of phyllosilicates and sulfates on Mars to better understand the formation process of sulfates in close proximity to phyllosilicates on Mars and constrain the aqueous conditions of these regions on Mars.

Craig, P. I.↗

Abstracts of the Annual Meeting of Planetary Geologic Mappers, Flagstaff, AZ, 2008

Topics discussed include: Merging of the USGS Atlas of Mercury 1:5,000,000 Geologic Series; Geologic Mapping of the V-36 Thetis Regio Quadrangle: 2008 Progress Report; Structural Maps of the V-17 Beta Regio Quadrangle, Venus; Geologic Mapping of Isabella Quadrangle (V-50) and Helen Planitia, Venus; Renewed Mapping of the Nepthys Mons Quadrangle (V-54), Venus; Mapping the Sedna-Lavinia Region of Venus; Geologic Mapping of the Guinevere Planitia Quadrangle of Venus; Geological Mapping of Fortuna Tessera (V-2): Venus and Earth's Archean Process Comparisons; Geological Mapping of the North Polar Region of Venus (V-1 Snegurochka Planitia): Significant Problems and Comparisons to the Earth's Archean; Venus Quadrangle Geological Mapping: Use of Geoscience Data Visualization Systems in Mapping and Training; Geologic Map of the V-1 Snegurochka Planitia Quadrangle: Progress Report; The Fredegonde (V-57) Quadrangle, Venus: Characterization of the Venus Midlands; Formation and Evolution of Lakshmi Planum (V-7), Venus: Assessment of Models using Observations from Geological Mapping; Geologic Map of the Meskhent Tessera Quadrangle (V-3), Venus: Evidence for Early Formation and Preservation of Regional Topography; Geological Mapping of the Lada Terra (V-56) Quadrangle, Venus: A Progress Report; Geology of the Lachesis Tessera Quadrangle (V-18), Venus; Geologic Mapping of the Juno Chasma Quadrangle, Venus: Establishing the Relation Between Rifting and Volcanism; Geologic Mapping of V-19, V-28, and V-53; Lunar Geologic Mapping Program: 2008 Update; Geologic Mapping of the Marius Quadrangle, the Moon; Geologic Mapping along the Arabia Terra Dichotomy Boundary: Mawrth Vallis and Nili Fossae, Mars: Introductory Report; New Geologic Map of the Argyre Region of Mars; Geologic Evolution of the Martian Highlands: MTMs -20002, -20007, -25002, and -25007; Mapping Hesperia Planum, Mars; Geologic Mapping of the Meridiani Region, Mars; Geology of Holden Crater and the Holden and Ladon Multi-Ring Impact Basins, Margaritifer Terra, Mars; Geologic Mapping of Athabasca Valles; Geologic Mapping of MTM -30247, -35247 and -40247 Quadrangles, Reull Vallis Region of Mars; Geologic Mapping of the Martian Impact Crater Tooting; Geology of the Southern Utopia Planitia Highland-Lowland Boundary Plain: First Year Results and Second Year Plan; Mars Global Geologic Mapping: Amazonian Results; Recent Geologic Mapping Results for the Polar Regions of Mars; Geologic Mapping of the Medusae Fossae Formation on Mars (MC-8 SE and MC-23 NW) and the Northern Lowlands of Venus (V-16 and V-15); Geologic Mapping of the Zal, Hi'iaka, and Shamshu Regions of Io; Global Geologic Map of Europa; Material Units, Structures/Landforms, and Stratigraphy for the Global Geologic Map of Ganymede (1:15M); and Global Geologic Mapping of Io: Preliminary Results.

Bleamaster, Leslie F., III↗

Mars brine formation experiment

Evaporites, particularly carbonates, nitrates, and sulfates, may be major sinks of volatiles scavenged from the martian atmosphere. Mars is thought to have once had a denser, warmer atmosphere that permitted the presence of liquid surface water. The conversion of atmospheric CO2 into carbonate is hypothesized to have degraded the martian climate to its present state of a generally subfreezing, desiccated desert. The rate for such a conversion under martian conditions is poorly known, so the time scale of climate degradation by this process cannot be easily evaluated. If some models are correct, carbonate formation may have been fast at geological time scales. The experiments of Booth and Kieffer also imply fast (10(exp 6) - 10(exp 7) yr) removal of the missing CO2 inventory, estimated to be 1 - 5 bar, by means of carbonate formation. The timing of formation of many of the fluvial features observed on Mars is, in large part, dependent on when and how fast the atmosphere changed. A knowledge of the rate at which carbonates and nitrates formed is also essential for assessing the probability that life, or its chemical precursors, could have developed on Mars. No previous experiments have quantitatively evaluated the rate of solution for a suite of mobile anions and cations from unaltered minerals and atmospheric gases into liquid water under Mars-like conditions. Such experiments are the focus of this task.

Moore, Jeffrey M.↗

Facies Analysis and Depositional Environments of the Upper Cambrian Eau Claire Formation in Central and Northern Illinois

The Cambrian Eau Claire Formation is a confining unit for geologic carbon dioxide (CO2) storage, and potentially a confining unit for hydrogen storage, within the underlying Mount Simon Sandstone in the Central and Northern Illinois Basin. However, extensive regional studies on lateral continuity, environment of deposition, and depositional fabric of the Eau Claire Formation in the Illinois Basin are minimal compared to studies of the underlying Mount Simon Sandstone. This study presents an integrated facies analysis using sedimentological, stratigraphic, ichnological, and mineralogical data to interpret the depositional environments of the Eau Claire Formation, emphasizing the dynamic nature of sedimentary systems. By combining core analyses, thin-section analysis, facies interpretation from geophysical logs, and regional stratigraphic framework interpretation, this work provides insights into the integrated depositional framework across diverse depositional environments. These findings suggest that the Eau Claire Formation in the Central and Northern Illinois Basin was deposited in a shallow marine environment, ranging from tidal flats to offshore settings. Its mixed siliciclastic-carbonate succession was primarily controlled by relative sea-level change.

58 GEOSCIENCES↗

Data Format and Descriptions for the Alabama Carbon Storage: Data Sharing and Engagement Project

The Alabama Carbon Storage: Data Sharing and Engagement (ACS-DSE) project seeks to develop publicly accessible geologic carbon storage models and data across the southern Gulf Coastal Plain of Alabama. The public online platform developed for this project will include geologic, geophysical, infrastructure, and other relevant datasets and geologic models of the study area. Datasets, model surfaces (e.g. structural contour maps, isolith maps, porosity maps), and infrastructure data (e.g. offshore pipelines, field boundaries) will be downloadable in commonly used file formats. The anticipated primary geologic datasets are well headers, formation tops, average reservoir properties, and core analyses; these will be available as commaseparated values (CSV) text files and MS Excel workbooks. Geophysical logs will be available in Log ASCII Standard (LAS) file format. Modeled surfaces, such as structure contour maps, will be available in ArcGIS formats and text files. Infrastructure data will be available as ArcGIS shapefiles. This document provides information on the data sources and attributes of the datasets.

01 COAL, LIGNITE, AND PEAT↗

Experimental Characterization of Hydrogen Diffusion in Shale Rocks for Geologic Storage Applications

As global energy systems undergo a transition to cleaner alternatives, geologic hydrogen storage has emerged as a promising solution for large-scale energy storage. A critical factor in determining the feasibility of this approach is the effectiveness of caprock formations, such as shale, in preventing hydrogen migration. This study investigates the diffusion behavior of hydrogen through shale to assess its suitability as a caprock for geologic hydrogen storage. Using a novel double-seal core holder design and a through-diffusion apparatus, hydrogen diffusion was measured through shale rock from the Eagle Ford and Wolfcamp Formations under dry conditions. These measurements were complemented by microstructural and mineralogical analyses using low-pressure nitrogen adsorption and X-ray diffraction. The effective diffusion coefficient of hydrogen in these shale caprocks ranged from 2.51 × 10 –8 to 9.85 × 10 –8 m 2 /s. Notably, we observed that the diffusion behavior was more related to the pore network structure and could not be attributed to differences in the total pore volume between shale types alone. Here, to further understand the role of pore network complexity, a fractal pore model was developed to correlate tortuosity with the fractal dimension of the pore structure (a measure of pore network complexity). The proposed model closely matched tortuosity values obtained from diffusion experiments, outperforming existing theoretical tortuosity–porosity correlations. These findings provide key quantitative parameters needed to assess the feasibility of geologic hydrogen storage as well as insights that can be applied to hydrogen storage in a range of geologic formations.

08 HYDROGEN↗

Geologic Map of the Meskhent Tessera Quadrangle (V-3), Venus: Evidence for Early Formation and Preservation of Regional Topography

The area of the Meskhent Tessera quadrangle (V-3, 50-75degN, 60-120degE, Fig. 1) corresponds to a transition zone from the uplands of Ishtar Terra to the west to the lowlands of Atalanta Planitia to the east. The topographic configuration, gravity signature, and presence of large tesserae in Ishtar Terra are consistent with extensive areas of thickened crust and tectonically stabilized lithosphere representing ancient and now extinct regimes of mantle convection. The gravity and topographic characteristics of Atalanta Planitia have been cited as evidence for large-scale mantle downwelling. Thus, the region of Meskhent Tessera quadrangle represents an important sample for the study of the regional history of long-wavelength topography (highlands, midlands, and lowlands), interaction between the downwelling and areas of thickened crust/lithosphere, formation of associated tectonic features, and emplacement of volcanic plains.

Ivanov, M. A.↗

Abstracts of the Annual Meeting of Planetary Geologic Mappers, Flagstaff, AZ, 2010

Topics covered include: Detailed Analysis of the Intra-Ejecta Dark Plains of Caloris Basin, Mercury; The Formation and Evolution of Tessera and Insights into the Beginning of Recorded History on Venus: Geology of the Fortuna Tessera Quadrangle (V-2); Geologic Map of the Snegurochka Planitia Quadrangle (V-1): Implications for the Volcanic History of the North Polar Region of Venus; Geological Map of the Fredegonade (V-57) Quadrangle, Venus: Status Report; Geologic Mapping of V-19; Geology of the Lachesis Tessera Quadrangle (V-18), Venus; Comparison of Mapping Tessera Terrain in the Phoebe Regio (V-41) and Tellus Tessera (V-10) Quadrangles; Geologic Mapping of the Devana Chasma (V-29) Quadrangle, Venus; Geologic Mapping of the Aristarchus Plateau Region on the Moon; Geologic Mapping of the Lunar South Pole Quadrangle (LQ-30); The Pilot Lunar Geologic Mapping Project: Summary Results and Recommendations from the Copernicus Quadrangle; Geologic Mapping of the Nili Fossae Region of Mars: MTM Quadrangles 20287, 20282, 25287, 25282, 30287, and 30282; Geologic Mapping of the Mawrth Vallis Region, Mars: MTM Quadrangles 25022, 25017, 25012, 20022, 20017, and 20012; Evidence for an Ancient Buried Landscape on the NW Rim of Hellas Basin, Mars; New Geologic Map of the Argyre Region of Mars: Deciphering the Geologic History Through Mars Global Surveyor, Mars Odyssey, and Mars Express Data; Geologic Mapping in the Hesperia Planum Region of Mars; Geologic Mapping of the Meridiani Region of Mars; Geologic Mapping in Southern Margaritifer Terra; Geology of -30247, -35247, and -40247 Quadrangles, Southern Hesperia Planum, Mars; The Interaction of Impact Melt, Impact-Derived Sediment, and Volatiles at Crater Tooting, Mars; Geologic Map of the Olympia Cavi Region of Mars (MTM 85200): A Summary of Tactical Approaches; Geology of the Terra Cimmeria-Utopia Planitia Highland Lowland Transitional Zone: Final Technical Approach and Scientific Results; Geology of Libya Montes and the Interbasin Plains of Northern Tyrrhena Terra, Mars: First Year Results and Second Year Work Plan; Mars Global Geologic Mapping Progress and Suggested Geographic-Based Hierarchal Systems for Unit Grouping and Naming; Progress in the Scandia Region Geologic Map of Mars; Geomorphic Mapping of MTMS -20022 and -20017; Geologic Mapping of the Medusae Fossae Formation, Mars, and the Northern Lowland Plains, Venus; Volcanism on Io: Results from Global Geologic Mapping; Employing Geodatabases for Planetary Mapping Conduct - Requirements, Concepts and Solutions; and Planetary Geologic Mapping Handbook - 2010.

Bleamaster, Leslie F., III↗

Nationwide cost and capacity estimates for sedimentary basin geothermal power and implications for geologic CO 2 storage

Sedimentary basins are naturally porous and permeable subsurface formations that underlie approximately half of the United States. In addition to being targets for geologic CO 2 storage, these resources could supply geothermal power: sedimentary basin geothermal heat can be extracted with water or CO 2 and used to generate electricity. The geothermal power potential of these basins and the accompanying implication for geologic CO 2 storage are, however, understudied. Here, we use the Sequestration of CO 2 Tool (SCO2T PRO ) and the generalizable GEOthermal techno-economic simulator (genGEO) to address this gap by a) estimating the cost and capacity of sedimentary basin geothermal power plants across the United States and b) comparing those results to nationwide CO 2 sequestration cost and storage potential estimates. We find that across the United States, using CO 2 as a geothermal heat extraction fluid reduces the cost of sedimentary basin power compared to using water, and some of the lowest cost capacity occurs in locations not typically considered for their geothermal resources (e.g., Louisiana, South Dakota). Additionally, using CO 2 effectively doubles the sedimentary basin geothermal resource base, equating to hundreds of gigawatts of new capacity, by enabling electricity generation in geologies that are otherwise (with water) too impermeable, too thin, too cold, or not deep enough. We find there is competition for the best sedimentary basin resources between water- and CO 2 -based power, but no overlap between the lowest-cost resources for CO 2 storage and CO 2 -based power. In this way, our results suggest that deploying CO 2 -based power may increase the cost of water based systems (by using the best resources) and the cost of CO 2 storage (by storing CO 2 in locations that otherwise may not be targeted). As such, our findings demonstrate that determining the best role for sedimentary basins within the energy transition may require balancing tradeoffs between competing priorities.

CPG↗

CO 2 Storage Site Screening Platform Development and CO 2 Storage Resource Analysis in SECARB Offshore Reservoirs Using SAS Viya

A major goal of the SECARB Offshore Partnership (DE-FE0031557) is to screen deep saline aquifers and hydrocarbon reservoirs in the central Gulf of Mexico for CO 2 sequestration and CO 2 -enhanced oil and gas recovery (EOR/EGR) and estimate the corresponding CO 2 storage resources for select reservoirs. CO 2 storage potential associated with offshore CO 2 -EOR is considerable and likely represents “low hanging fruit” for near-term CO 2 storage given the in-place infrastructure in the region. It is for these reasons that this assessment focuses on oil and gas fields. To this end, three major objectives have been completed and include (1) managing geological data derived from different sources, (2) building a reservoir screening platform for CO 2 storage, and (3) ranking the reservoirs based on the estimated CO 2 storage resources. The SAS ® Viya platform was used for data management and analytics. The Viya platform is a cloud service platform that provides data integration, data management, quick analytics, data visualization, machine learning functions, and application programming interfaces (APIs) for multi-programming languages. Different sources of data containing geologic information, reservoir properties, and EOR/EGR information were collected, cleaned, formatted, and loaded into the SAS ® Viya platform for evaluation. The major geological characteristics of both shelf and deep-water areas of the central Gulf were examined and compared to define the appropriate reservoir screening criteria. Next, a CO 2 storage site screening system was built in the SAS ® Viya platform with the pre-defined criteria. Finally, the CO 2 storage resources of the screened reservoirs were calculated and reported at the BOEM field level to identify fields with the highest estimated CO 2 storage resource. The fields with the largest total estimated CO 2 storage resource are located in the Mississippi Canyon protraction area. Due to proximity to the Mississippi Delta (indicative of less infrastructure) and large estimated CO 2 storage resources, future development activities may wish to focus efforts in the Mississippi Canyon protraction area.

02 PETROLEUM↗

Relative chronology of Martian volcanoes

Impact cratering is one of the major geological processes that has affected the Martian surface throughout the planet's history. The frequency of craters within particular size ranges provides information about the formation ages and obliterative episodes of Martian geologic units. The Barlow chronology was extended by measuring small craters on the volcanoes and a number of standard terrain units. Inclusions of smaller craters in units previously analyzed by Barlow allowed for a more direct comparison between the size-frequency distribution data for volcanoes and established chronology. During this study, 11,486 craters were mapped and identified in the 1.5 to 8 km diameter range in selected regions of Mars. The results are summarized in this three page report and give a more precise estimate of the relative chronology of the Martian volcanoes. Also, the results of this study lend further support to the increasing evidence that volcanism has been a dominant geologic force throughout Martian history.

Landheim, R.↗

Coupled Hydromechanical Modeling of Induced Seismicity From CO 2 Injection in the Illinois Basin

Injection of CO 2 for geologic carbon sequestration into deep sedimentary formations involves fluid pressure increases that engage hydromechanical processes that can cause seismicity by activation of existing faults. In this work, we use a coupled multiphase fluid flow and geomechanical simulator to model spatiotemporal fluid pressure and stress changes in order to study the poroelastic effect of CO 2 injection on faults in crystalline basement rock below the injection zone. The seismicity rate along features interpreted to be basement faults is modeled using Dieterich's rate-and-state earthquake nucleation model. The methodology is applied to microseismicity detected during CO 2 injection into the Mount Simon formation during the Illinois Basin—Decatur Project. The modeling accurately captures an observed reduction in seismicity rate when the injection in the second well was into a slightly shallower zone above the base of the Mount Simon formation. Moreover, the modeling shows that it is important to consider poroelastic stress changes, in addition to fluid pressure changes for accurately modeling of the observed seismicity rate.

58 GEOSCIENCES↗

Acyl silicates and acyl aluminates as activated intermediates in peptide formation on clays

Glycine reacts with heating on dried clays and other minerals to give peptides in much better yield than in the absence of mineral. This reaction was proposed to occur by way of an activated intermediate such as an acyl silicate or acyl aluminate analogous to acyl phosphates involved in several biochemical reactions including peptide bond synthesis. The proposed mechanism has been confirmed by trapping the intermediate, as well as by direct spectroscopic observation of a related intermediate. The reaction of amino acids on periodically dried mineral surfaces represents a widespead, geologically realistic setting for prebiotic peptide formation via in situ activation.

White, D. H.↗

Significant achievements in the Planetary Geology Program

Developments reported at a meeting of principal investigators for NASA's planetology geology program are summarized. Topics covered include: constraints on solar system formation; asteriods, comets, and satellites; constraints on planetary interiors; volatiles and regoliths; instrument development techniques; planetary cartography; geological and geochemical constraints on planetary evolution; fluvial processes and channel formation; volcanic processes; Eolian processes; radar studies of planetary surfaces; cratering as a process, landform, and dating method; and the Tharsis region of Mars. Activities at a planetary geology field conference on Eolian processes are reported and techniques recommended for the presentation and analysis of crater size-frequency data are included.

Head, J. W.↗