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At least 307 records · Page 17

Cordon screen: A cordon-based congestion pricing policy evaluation method for U.S. cities

Global trends toward urbanization will exacerbate traffic congestion, delays in economic productivity, and air pollution issues for growing cities. Traffic congestion pricing is one method available to help ameliorate these concerns. New York City is on the verge of implementing a cordon-based traffic congestion pricing policy around its central business district. For budget-constrained municipalities, evaluating implementation of such policy could be costly. This article proposes a sketch-planning methodology, called Cordon Screen, for major U.S. cities to evaluate the net income, traffic mitigation, and avoided pollution emissions from cordon-based traffic congestion pricing. This method relies on national datasets and limited user-specific data inputs, along with a range of user-selectable assumptions informed by academic literature to deliver order-of-magnitude results. The numerous limitations of this method are acceptable for preliminary policy evaluation to determine if greater financial investment to obtain more accurate results is justified. The Denver metropolitan area is used to demonstrate Cordon Screen capabilities, with mid-range assumption results suggesting the policy is most effective at generating net income and increasing vehicle speeds on major interstates. For Denver, the policy is comparably less effective at reducing air pollution and increasing speeds on minor roadways. Validation against early implementation results from the London cordon are acceptable. Still, users should discount revenue generation projections. Choice of cordon area may be the most difficult obstacle when using the Cordon Screen. With refinement, Cordon Screen could serve as a low-cost, open-source planning evaluation tool for growing and congested U.S. cities.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Anomaly detection in PV systems using constrained low-rank and sparse decomposition

PV (photovoltaic) systems, also known as solar panel systems, play an essential role in the mitigation of greenhouse gas emissions and the promotion of renewable energy. Through the conversion of sunlight into usable energy, electricity is generated without emitting greenhouse gases and producing pollutants. Notwithstanding the evolutionary significance of PV systems, the occurrence of defects and anomalies in PV systems may result in diminished power output, consequently impeding the efficiency of the systems and potentially resulting in hazards in certain circumstances. Therefore, early detection of faults and anomalies in PV systems is imperative to guarantee the reliability, efficiency, and safety of the systems. In this article, we develop a signal decomposition for the purpose of anomaly detection in PV systems. The proposed methodology is grounded on the concept of low-rank and sparse decomposition, with consideration given to the signs of the decomposed low-rank and sparse components, as well as the smooth variations within and between periods in the mean signals. Through the implementation of Monte Carlo simulations, we showcase the efficacy of our proposed methodology in identifying anomalies of varying durations and magnitudes in PV systems. A case study is employed to validate the proposed methodology in detecting anomalies in real PV systems.

14 SOLAR ENERGY↗

Location generalizability of image-based air quality models

This paper is to be submitted at the IEEE/CVF Winter Conference on Applications of Computer Vision (WACV) Computer Vision for Earth Observation workshop. The full paper abstract is below: The ability to rapidly quantify atmospheric pollutants is important both for global emissions monitoring and for mitigating the adverse effects that follow a hazardous chemical release. In the aftermath of a chemical release, imagery is often the only available resource to assess local conditions. Recent work has demonstrated initial success in predicting particulate matter pollution from imagery; however, these results are tied to a specific site and do not generalize to new geographic locations. In this work, we seek to understand how easily deep learning models generalize to new locations in the context of image-based air quality assessments, targeting two distinct tasks: (1) broad measures of particulate matter pollution, and (2) the mass of a given chemical released in hazardous plumes. For the latter, we focus on sulfur dioxide, a toxic aerosol and a major component of particulate matter pollution caused by industrial fossil fuel consumption. To develop a model that operates in the widest possible range of environments, we test different training strategies, including the use of new geolocation foundation models. The best performing models achieve >80% accuracy when evaluating unseen imagery at previously seen sites, but we find significant drops in performance when evaluating imagery from unseen sites, at best 65%. Additionally, we present the public release of the National Parks Air Quality Index Dataset, a new medium-sized dataset that pairs imagery with sensor-based air quality measurements at 15 different national parks.

Byler, Eleanor B. [BATTELLE (PACIFIC NW LAB)]↗

Durability Optimization of CO 2 Electrolyzers for Syngas Evolution

Recently, there has been an increased interest in mitigating anthropogenic CO 2 emissions through the electrochemical conversion of CO 2 into fuels and fuel feedstocks, including hydrogen gas (H 2 ), carbon monoxide (CO), and mixtures of the two to yield syngas. Commercial applications of these systems require high catalytic selectivity for the desired products, while exhibiting operational lifetimes exceeding thousands of hours. Advancements in this field have produced systems that display high selectivity of the desired products at faradaic efficiencies exceeding 95%. Despite the advancements made in CO 2 electrolysis, system durability remains a standing challenge in the field. CO 2 electrolyzer lifetimes are often limited by carbonate fouling, catalyst degradation, detrimental flooding of electrode microporous layers and anion exchange membrane (AEM) failures. In this report, a 5 cm 2 membrane electrode assembly (MEA) device is used to investigate potential failure modes and to optimize AEM CO 2 electrolyzer operation. Key findings of this study include the importance of CO 2 flow rate, use of a thin PiperION PTFE-reinforced membrane, optimizing compression to enhance contact under 40 in-lb compression, and the effect of more compressible, commercial iridium oxide anodes on system durability.

Abouremeleh, Mohammed H. [Lawrence Berkeley Nation↗

Spray Combustion and Soot Formation

Mitigating particulate matter (PM) emissions while simultaneously controlling nitrogen oxide and hydrocarbon emissions is critical for both gasoline and diesel engines. The problem is especially critical during cold-start cycles where aftertreatment devices are less effective. Understanding how liquid sprays and films form PM and designing to change the outcome requires advanced combustion concepts developed through joint experimental and computational efforts. However, existing spray and soot computational models are oversimplified and non-physical, and are therefore unable to reliably capture quantitative or even qualitative trends over a wide range of engine operating conditions. This task involves the development and application of advanced optical diagnostics and high-pressure gas and particle sampling/analysis in unique high-temperature, high-pressure vessels to investigate spray dynamics and soot formation with the objective of providing fundamental understanding about soot processes under relevant engine conditions to aid the development of improved soot models for commercial CFD codes

02 PETROLEUM↗

Adoption of Biofuels for the Marine Shipping Industry: A Long-Term Price and Scalability Assessment

One of the biggest challenges in the 21st Century is transforming the transportation sector into a low carbon-based sustainable industry, including maritime shipping. Bioenergy has an essential role in the transition to move maritime shipping toward carbon neutrality. Biomass-derived fuels can undoubtedly play a crucial role in the future of marine propulsion that as renewable alternatives can offer potential synergistic benefits when blended with petroleum fuels. With inherently zero- or low-sulfur and renewable carbon sources, biofuels will help mitigate marine shipping sulfur emissions, improve overall emission profiles, and enable the decarbonization transition. As biofuel for marine propulsion is still at its nascent stage, knowledge gaps exist, including the life cycle environmental impacts, compatibility of biofuel blending with conventional marine fuels, scalability, and cost. This study assessed the biofuel availability and cost aspects for marine use and was supported by the U.S. Department of Transportation’s Maritime Administration (MARAD) Office of Environment to project the long-term price and annual biofuel production capacity potential for marine propulsion in the United States. The study will shed light on the prospect of biofuel adoption for the maritime shipping industry.

09 BIOMASS FUELS↗

Lehigh University Industrial Assessment Center (Final Technical Report for the Period 2016 to 2021)

This is the final technical report summarizing the activities Industrial Assessment Center at Lehigh University sponsored by the Department of Energy for the period September 1, 2016 till September 30, 2021. During this period, the Industrial Assessment Center at Lehigh University was successful in training numerous energy engineers of the future, and helped many manufacturing plants in New Jersey and Eastern Pennsylvania. The center and its activities helped save a great deal of energy, related fuel costs and along the way mitigated tons of CO2 emissions. The report covers many of the numerical details related to the center activities. The Industrial Center at Lehigh University is one of the most successful ones and this is made evident by the statistics included as part of this report and best center award bestowed upon the center.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Quantitative Risk Assessment (Topical Report)

Carbon capture, utilization, and storage (CCUS) in geological formations plays a key role in mitigating anthropogenic CO 2 emissions and achieving the aggressive goal of net-zero greenhouse gas emissions. Quantitative risk assessment is crucial for ensuring the safety and reliability of geologic carbon storage (GCS) by evaluating CO 2 migration in subsurface, forecasting potential leakage and induced seismicity risks, and optimizing operational and monitoring plans. We present the use, progress, and research trends of risk assessment from the Southwest Regional Partnership on Carbon Sequestration (SWP) as an example of large-scale CCUS projects in North America. The information provided in this report can help readers understand the significance of risk and uncertainty assessment and apply them effectively in large-scale CCUS projects.

42 ENGINEERING↗

Combustion of petroleum-based transportation fuels and their blends with biofuels: a new approach for developing surrogates and understanding the effects of blending

Accurate and versatile reaction mechanisms are necessary to simulate combustion of transportation fuels blended with biofuels for improving fuel efficiency, reducing fuel consumption and mitigating the formation and emissions of combustion products harmful to the atmosphere. This project involved a combined effort of simulation and experimentation of liquid fuel burning using a combustion configuration amenable to numerical modeling with a level of detail not previously achieved for blends of biofuels with gasoline certification and surrogate fuels. The configuration of an isolated droplet burning under conditions where gas transport arises solely from fuel evaporation was selected as the platform for experiments and numerical modeling. The spherical symmetry and one-dimensional gas transport that results enabled simulating the droplet burning process with an precedented level of detail. Processes associated with unsteady gas and liquid transport, formation of particulate and gaseous products, radiation, multicomponent phase equilibrium at the droplet surface and moving boundary effects from droplet evaporation, were incorporated in a single numerical framework. The numerical model was based on the open source code OPENSmoke++ (OS) adapted to incorporate the effects noted above. In addition to simulation, an experimental design was developed for the isolated droplet configuration to acquire the data needed for validating the numerical model. Several broad accomplishments of the project were the following: demonstrating generally excellent agreement between measured and simulated combustion parameters for the fuel blends examined that included mixtures of heptane and isobutanol as a model system, and surrogates comprised of up to seven miscible components mixed with ethanol or isobutanol as representative biofuel additives; using a new approach to validate reaction mechanisms of biofuel blends which incorporated fuel evaporation into the process along with developing an experimental design for acquiring data to compare with simulations; and showing that a wealth of information could be obtained on the combustion physics of biofuels from experiments requiring volumes on the order of only nanoliters at a time thus opening the way to evaluating biofuels synthesized by new processes early in development.

02 PETROLEUM↗

Assessing root–soil interactions in wetland plants: root exudation and radial oxygen loss

Abstract. Plant rhizosphere processes, such as root exudation and root oxygen loss (ROL), could have significant impacts on the dynamics and magnitude of wetland methane fluxes and other biogeochemical processes but are rarely measured directly. Here, we measure root exudation and ROL from Schoenoplectus americanus and Spartina patens, two plants that have had opposite relationships between biomass and methane flux in field experiments (positive in S. patens, negative in S. americanus). We found contrasting rates of ROL in the two species, with S. americanus releasing orders of magnitude more oxygen (O2) to the soil than S. patens. At the same time, S. patens exuded high amounts of carbon to the soil, and much of the rhizosphere carbon pool was reduced compared to exudates from other wetland species. This work suggests that the relative inputs of O2 and carbon to the rhizosphere vary significantly between wetland plant species, potentially with major consequences on biogeochemical cycling, and highlights the importance of understanding how plant rhizosphere processes mediate soil biogeochemistry at a community level. As global change drivers continue to affect wetlands, future research should consider how feedbacks from plant rhizosphere processes may exacerbate or mitigate coastal wetland methane emissions.

54 ENVIRONMENTAL SCIENCES↗

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH 4 ) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH 4 are continuing to increase, making CH 4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO 2 ). Assessing the relative importance of CH 4 in comparison to CO 2 is complicated by its shorter atmospheric lifetime, stronger warming potential, and atmospheric growth rate variations over the past decade, the causes of which are still debated. Two major difficulties in reducing uncertainties arise from the variety of geographically overlapping CH 4 sources and from the destruction of CH 4 by short-lived hydroxyl radicals (OH). To address these difficulties, we have established a consortium of multi-disciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Towards an improved representation of carbonaceous aerosols over the Indian monsoon region in a regional climate model: RegCM

Mitigation of carbonaceous aerosol emissions is expected to provide climate and health co-benefits. The accurate representation of carbonaceous aerosols in climate models is critical for reducing uncertainties in their climate feedback. In this regard, emission fluxes and aerosol life cycle processes are the two primary sources of uncertainties. Here, we demonstrate that the incorporation of a dynamic ageing scheme and emission estimates that are updated for the local sources improves the representation of carbonaceous aerosols over the Indian monsoon region in a regional climate model, RegCM, compared with its default configuration. The respective mean black carbon (BC) and organic carbon (OC) surface concentrations in 2010 are estimated to be 4.25 and 10.35 µg m -3 over the Indo-Gangetic Plain (IGP) in the augmented model. The BC column burden over the polluted IGP is found to be 2.47 mg m -2 , 69.95 % higher than in the default model configuration and much closer to available observations. The anthropogenic aerosol optical depth (AOD) increases by more than 19 % over the IGP due to the model enhancement, also leading to a better agreement with observed AOD. The respective top-of-the-atmosphere, surface, and atmospheric anthropogenic aerosol short-wave radiative forcing are estimated at -0.3, -9.3, and 9.0 W m -2 over the IGP and -0.89, -5.33, and 4.44 W m -2 over Peninsular India (PI). Our results suggest that the combined effect of two modifications leads to maximum improvements in the model performance in regions where emissions play a dominant role.

54 ENVIRONMENTAL SCIENCES↗

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH4 continue to increase, making CH4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO2). The relative importance of CH4 compared to CO2 depends on its shorter atmospheric lifetime, stronger warming potential, and variations in atmospheric growth rate over the past decade, the causes of which are still debated. Two major challenges in reducing uncertainties in the atmospheric growth rate arise from the variety of geographically overlapping CH4 sources and from the destruction of CH4 by short-lived hydroxyl radicals (OH). To address these challenges, we have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations). For the 2008–2017 decade, global methane emissions are estimated by atmospheric inversions (a top-down approach) to be 576 Tg CH4/yr (range 550–594, corresponding to the minimum and maximum estimates of the model ensemble). Of this total, 359 Tg CH4/yr or ∼ 60 % is attributed to anthropogenic sources, that is emissions caused by direct human activity (i.e. anthropogenic emissions; range 336–376 Tg CH4/yr or 50 %–65 %). The mean annual total emission for the new decade (2008–2017) is 29 Tg CH4/yr larger than our estimate for the previous decade (2000–2009), and 24 Tg CH4/yr larger than the one reported in the previous budget for 2003–2012 (Saunois et al., 2016). Since 2012, global CH4 emissions have been tracking the warmest scenarios assessed by the Intergovernmental Panel on Climate Change. Bottom-up methods suggest almost 30 % larger global emissions (737 Tg CH4/yr, range 594–881) than top-down inversion methods. Indeed, bottom-up estimates for natural sources such as natural wetlands, other inland water systems, and geological sources are higher than top-down estimates. The atmospheric constraints on the top-down budget suggest that at least some of these bottom-up emissions are overestimated. The latitudinal distribution of atmospheric observation-based emissions indicates a predominance of tropical emissions (∼ 65 % of the global budget, < 30° N) compared to mid-latitudes (∼ 30 %, 30–60° N) and high northern latitudes (∼ 4 %, 60–90° N). The most important source of uncertainty in the methane budget is attributable to natural emissions, especially those from wetlands and other inland waters. Some of our global source estimates are smaller than those in previously published budgets (Saunois et al., 2016; Kirschke et al., 2013). In particular wetland emissions are about 35 Tg CH4/yr lower due to improved partition wetlands and other inland waters. Emissions from geological sources and wild animals are also found to be smaller by 7 Tg CH4/yr by 8 Tg CH4/yr, respectively. However, the overall discrepancy between bottom-up and top-down estimates has been reduced by only 5 % compared to Saunois et al. (2016), due to a higher estimate of emissions from inland waters, highlighting the need for more detailed research on emissions factors. Priorities for improving the methane budget include (i) a global, high-resolution map of water-saturated soils and inundated areas emitting methane based on a robust classification of different types of emitting habitats; (ii) further development of process-based models for inland-water emissions; (iii) intensification of methane observations at local scales (e.g., FLUXNET-CH4 measurements) and urban-scale monitoring to constrain bottom-up land surface models, and at regional scales (surface networks and satellites) to constrain atmospheric inversions; (iv) improvements of transport models and the representation of photochemical sinks in top-down inversions; and (v) development of a 3D variational inversion system using isotopic and/or co-emitted species such as ethane to improve source partitioning.

methane budget↗

Drought-Tolerant Succulent Plants as an Alternative Crop Under Future Global Warming Scenarios in Sub-Saharan Africa

Globally, we are facing an emerging climate crisis, with impacts to be notably felt in semiarid regions across the world. Cultivation of drought-adapted succulent plants has been suggested as a nature-based solution that could: (i) reduce land degradation, (ii) increase agricultural diversification and provide both economic and environmentally sustainable income through derived bioproducts and bioenergy, (iii) help mitigate atmospheric CO 2 emissions and (iv) increase soil sequestration of CO 2 . Identifying where succulents can grow and thrive is an important prerequisite for the advent of a sustainable alternative ‘bioeconomy’. Here, we first explore the viability of succulent cultivation in Africa under future climate projections to 2100 using species distribution modelling to identify climatic parameters of greatest importance and regions of environmental suitability. Minimum temperatures and temperature variability are shown to be key controls in defining the theoretical distribution of three succulent species explored, and under both current and future SSP5 8.5 projections, the conditions required for the growth of at least one of the species are met in most parts of sub-Saharan Africa. These results are supplemented with an analysis of potentially available land for alternative succulent crop cultivation. In total, up to 1.5 billion ha could be considered ecophysiologically suitable and available for succulent cultivation due to projected declines in rangeland biomass and yields of traditional crops. These findings may serve to highlight new opportunities for farmers, governments and key stakeholders in the agriculture and energy sectors to invest in sustainable bioeconomic alternatives that deliver on environmental, social and economic goals.

agriculture↗

Concept Design of Active Shielding for Dynamic Wireless Charging of Light-duty EV

Dynamic wireless charging of electric vehicles is a flexible and state of the art charging technology with the potential capability of enabling fully automated in-motion charging. With charging power increasing to more than 100 kW for light duty vehicles, electromagnetic field (EMF) emission becomes a critical challenge. Due to the high costs of ferrite materials, this paper proposes an active shielding solution with multiple canceling coils installed on the ground side to supplement ferrite passive shielding to ensure electromagnetic safety. Two canceling coils are designed on two sides of the ground side coil. The canceling coils are small in size and 180 degree opposite in phase to the ground coil. Simulation and modeling shows that the canceling coils can reduce EMF emission from 37.2 µT to 18.2 µT at 0.8 m during 100 kW operation with only 2.5% of ground side current flowing in the canceling coils. These results have been preliminarily verified by inductance measurements and magnetic field measurement at 1.1 m distance without canceling coils. By further increasing the canceling coils’ currents to 4%, EMF emission can also be mitigated at 200 kW, although the canceling coils’ shape, position, and phase angle can be further optimized to improve the three-dimensional field distribution.

25 ENERGY STORAGE↗

Impact of sub-core scale heterogeneity on CO2/brine multiphase flow for geological carbon storage in the Minnelusa sandstone

CO2 geological storage in deep saline aquifers is a mitigation option for CO2 emissions due to its large storage capacity and immediate accessibility. Accurately determining the CO2-brine relative permeability curves is key to the evaluation of CO2 injectivity and sweep efficiency in reservoir simulation as well as the CO2 injection in the field. This study highlights the remarkable effects of sub-core scale heterogeneity on the CO2-brine multiphase flow properties of the Minnelusa Sandstone in Wyoming. Two unsteady state CO2-brine drainage experiments were performed on the two samples. The first sample exhibits slanted laminated structure, while the second one represents a more homogeneous sandstone system. The CO2 saturation distributions during drainage reveals that the main variation in multiphase flow properties of two core samples were attributed to the porosity distribution that leads to the capillary pressure heterogeneity. Assisted history matching was used to obtain the respective relative permeability curves, which suggests heterogeneity-dependent behavior. In addition, sensitive and uncertainty analyses indicate that physical and petro-physical properties of low-porosity and low-permeability bedding layers exert marked effects on CO2 front breakthrough time and brine production. The results presented in this study help to gain insight into the CO2-brine multiphase flow properties in heterogeneous sandstones and can pave the way for the upscaling of CO2 migration and field-scale simulation accurately. This work is funded under the Department of Energy CarbonSAFE program (awards DE-FE0031624 DE0031891).

Kou, Zuhao↗

Challenging Common Assumptions of Thick-Wall Chamber Dynamics in Inertial Fusion Systems using MOOSE

As an increasing number of companies look toward commercial Inertial Fusion Energy (IFE) designs, there is a pressing need to understand the physics of thick-wall chamber gas dynamics. The thick liquid wall approach implements a renewable wall to mitigate the fusion target emissions, thereby reducing the radiation damage rate and significantly extending the lifetime of chamber structures, leading to increased plant availability and reduced waste streams in comparison to dry wall chamber designs. It is necessary, however, to assess the critical performance and safety aspects of these systems. For example, it is crucial to predict (1) where the mass ablated from the liquid walls will vent, which determines the placement of condensing surfaces; (2) debris propagation up the beam lines, which provides essential information for design and protection requirements; (3) peak pressures and impulse on chamber walls, which affect chamber structural design; and (4) momentum transfer to the liquid jets, which constrains the shape and positioning of the jets. In turn, the chamber design and its liquid walls affect shielding requirements, material activation, and tritium fuel cycle. Currently available simulation tools, however, are unable to accurately capture key thick-wall chamber dynamics. Significant assumptions are often made to simplify the system and reduce computational cost and modeling capability needs, but the impact of these assumptions on simulation predictions has not been evaluated. For example, no three-dimensional simulations can be found in the open literature to evaluate gas venting and momentum transfer to the jets with simulations using two-dimensional domains to represent complex three-dimensional geometries. Moreover, limited studies have been dedicated to jet breakup due to both turbulence and neutron heating, and no studies have been found that evaluate how jet breakup can impact shock-jet interaction. Furthermore, effects of radiative heat transfer have rarely been included for the hydrodynamic phase of shock propagation, and integration of proper equations of state in shock dynamics codes has been mostly exploratory. In this study, we use the flexible, high-fidelity Multiphysics Object-Oriented Simulation Environment (MOOSE) to model these complex phenomena and inform design and safety studies. Capabilities to model thick-wall chamber gas dynamics are being developed, and the impact of the assumptions listed above (i.e., two-dimensional vs three-dimensional, absence of jet breakout, no radiative heat transfer, and ideal gas behavior) are being quantified.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗