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At least 307 records · Page 17

A model for studying the composition and chemical effects of stratospheric aerosols

We developed polynomial expressions for the temperature dependence of the mean binary and water activity coefficients for H2SO4 and HNO3 solutions. These activities were used in an equilibrium model to predict the composition of stratospheric aerosols under a wide range of environmental conditions. For typical concentrations of H2O, H2SO4, HNO3, HCl, HBr, HF, and HOCl in the lower stratosphere, the aerosol composition is estimated as a function of the local temperature and the ambient relative humidity. For temperatures below 200 K, our results indicate that (1) HNO3 contributes a significant mass fraction to stratospheric aerosols, and (2) HCl solubility is considerably affected by HNO3 dissolution into sulfate aerosols. We also show that, in volcanically disturbed periods, changes in stratospheric aerosol composition can significantly alter the microphysics that leads to the formation of polar stratospheric clouds. The effects caused by HNO3 dissolution on the physical and chemical properties of stratospheric aerosols are discussed.

Tabazadeh, Azadeh↗

Physical Models of Layered Polar Firn Brightness Temperatures from 0.5 to 2 GHz

We investigate physical effects influencing 0.5-2 GHz brightness temperatures of layered polar firn to support the Ultra Wide Band Software Defined Radiometer (UWBRAD) experiment to be conducted in Greenland and in Antarctica. We find that because ice particle grain sizes are very small compared to the 0.5-2 GHz wavelengths, volume scattering effects are small. Variations in firn density over cm- to m-length scales, however, cause significant effects. Both incoherent and coherent models are used to examine these effects. Incoherent models include a 'cloud model' that neglects any reflections internal to the ice sheet, and the DMRT-ML and MEMLS radiative transfer codes that are publicly available. The coherent model is based on the layered medium implementation of the fluctuation dissipation theorem for thermal microwave radiation from a medium having a nonuniform temperature. Density profiles are modeled using a stochastic approach, and model predictions are averaged over a large number of realizations to take into account an averaging over the radiometer footprint. Density profiles are described by combining a smooth average density profile with a spatially correlated random process to model density fluctuations. It is shown that coherent model results after ensemble averaging depend on the correlation lengths of the vertical density fluctuations. If the correlation length is moderate or long compared with the wavelength (approximately 0.6x longer or greater for Gaussian correlation function without regard for layer thinning due to compaction), coherent and incoherent model results are similar (within approximately 1 K). However, when the correlation length is short compared to the wavelength, coherent model results are significantly different from the incoherent model by several tens of kelvins. For a 10-cm correlation length, the differences are significant between 0.5 and 1.1 GHz, and less for 1.1-2 GHz. Model results are shown to be able to match the v-pol SMOS data closely and predict the h-pol data for small observation angles.

layered polar firn emission↗

Ares I Reaction Control System Propellant Feedline Decontamination Modeling

The objective of the work presented here is to quantify the effects of purge gas temperature, pressure, and mass flow rate on Hydrazine (Hz) decontamination rates of the Ares I Roll Control System and Reaction Control System. A survey of experts in this field revealed the absence of any decontamination rate prediction models. Three basic decontamination methods were identified for analysis and modeling. These include low pressure eduction, high flow rate purge, and pulse purge. For each method, an approach to predict the Hz mass transfer rate, as a function of system pressure, temperature, and purge gas mass flow rate, is developed based on the applicable physics. The models show that low pressure eduction is two orders of magnitude more effective than the high velocity purge, which in turn is two orders of magnitude more effective than the pure diffusion component of pulse purging of deadheads. Eduction subjects the system to low pressure conditions that promote the extraction of Hz vapors. At 120 F, Hz is saturated at approximately 1 psia. At lower pressures and 120 F, Hz will boil, which is an extremely efficient means to remove liquid Hz. The Hz boiling rate is predicted by equating the rate at which energy is added to the saturated liquid Hz through heaters at the tube outer wall with the energy removed from the liquid through evaporation. Boil-off fluxes were predicted by iterating through the range of local pressures with limits set by the minimum allowed pressure of 0.2 psia and maximum allowed wall temperature of 120 F established by the heaters, which gives a saturation pressure of approximately 1.0 psia. Figure 1 shows the resulting boil-off fluxes as a function of local eduction pressure. As depicted in figure 1, the flux is a strong inverse function of eduction pressure, and that minimizing the eduction pressure maximizes the boil-off flux. Also, higher outer wall temperatures lead to higher boil-off fluxes and allow for boil-off over a greater range of eduction pressures.

Pasch, James J.↗

Estimation of surface temperature in remote pollution measurement experiments

A simple algorithm has been developed for estimating the actual surface temperature by applying corrections to the effective brightness temperature measured by radiometers mounted on remote sensing platforms. Corrections to effective brightness temperature are computed using an accurate radiative transfer model for the 'basic atmosphere' and several modifications of this caused by deviations of the various atmospheric and surface parameters from their base model values. Model calculations are employed to establish simple analytical relations between the deviations of these parameters and the additional temperature corrections required to compensate for them. Effects of simultaneous variation of two parameters are also examined. Use of these analytical relations instead of detailed radiative transfer calculations for routine data analysis results in a severalfold reduction in computation costs.

Gupta, S. K.↗

Saturn's microwave spectrum: Implications for the atmosphere and the rings

Measurements of Saturn's disk temperature are compiled to determine the planet's microwave spectrum from 1 mm to 100 cm wavelength. The data were adjusted to conform with a common flux density scale. A model of Saturn's rings is used to remove the effects of the rings from the atmospheric component at centimeter and decimeter wavelengths. Theoretical spectra for a number of convective atmospheric models were computed and compared with the observed spectrum. Radiative-convective models with approximately solar composition and with an effective temperature of approximately 89 K are in good agreement with the observations. The agreement between the observed and theoretical spectra is a strong indication that gaseous ammonia is present in Saturn's atmosphere. A good fit to the data is obtained with an ammonia mixing ratio of approximately 5 x 10,0001. A comparison of the millimeter wavelength data with the best-fitting atmospheric spectrum indicates that the thermal component of the ring brightness temperature near 1 mm wavelength is approximately 25 k.

Klein, M. J.↗

Annual variation in temperature and composition of the thermosphere and upper mesosphere

A three-dimensional circulation model, including UV (O2 dissociation) and EUV sources, is used to study the wind field and the effects of temperature and composition on annual thermospheric variations. The results are compared to those of OGO-6 and AE-C. Within an 800-1200 K temperature range, summer to winter temperature variation is studied as a function of solar activity. It is found that the model correctly predicts H, He, O, N2, O2, and Ar measurements. It is suggested that a small winter maximum in mesospheric temperature is caused by large-scale circulation induced by EUV heating. This effect, however, is masked by the energy released in O2 dissociation. The annual temperature amplitude and the winter oxygen bulge are noted to increase with increasing solar activity, whereas the winter helium bulge is noted to decrease with enhanced exospheric return flow. It is felt that the dependence of the F2 region winter anomaly on solar activity may be significantly affected by the solar activity effect in atomic oxygen.

Mayr, H. G.↗

Remote sensing of the Martian surface

Researchers investigated the physical properties of the Martian surface as inferred from a combination of orbiting and earth-based remote sensing observations and in-situ observations. This approach provides the most detailed and self-consistent view of the global and regional nature of the surface. Results focus on the areas of modeling the diurnal variation of the surface temperature of Mars, incorporating the effects of atmospheric radiation, with implications for the interpretation of surface thermal inertia; modeling the thermal emission from particulate surfaces, with application to observations of the surfaces of the Earth, Moon, and Mars; modeling the reflectance spectrum of Mars in an effort to understand the role of particle size in the difference between the bright and dark regions; and determining the slope properties of different terrestrial surfaces and comparing them with planetary slopes derived from radar observations.

Jakosky, Bruce M.↗

Model-based prognostics for batteries which estimates useful life and uses a probability density function

This invention develops a mathematical model to describe battery behavior during individual discharge cycles as well as over its cycle life. The basis for the form of the model has been linked to the internal processes of the battery and validated using experimental data. Effects of temperature and load current have also been incorporated into the model. Subsequently, the model has been used in a Particle Filtering framework to make predictions of remaining useful life for individual discharge cycles as well as for cycle life. The prediction performance was found to be satisfactory as measured by performance metrics customized for prognostics for a sample case. The work presented here provides initial steps towards a comprehensive health management solution for energy storage devices.

Saha, Bhaskar↗

Rotational and vibrational nonequilibrium effects in rarefied, hypersonic flow

Results are reported for an investigation into the methods by which energy transfer is calculated in the Direct Simulation Monte Carlo method. Description is made of a recently developed energy exchange model that deals with the translational and rotational modes. A new model for simulating the transfer of energy between the translational and vibrational modes is also explained. This model allows the vibrational relaxation time to follow the temperature dependence predicted by the Landau-Teller theory at moderate temperatures. For temperatures in excess of about 8000K the vibrational model is extended to include an empirical result for the relaxation time. The effect of introducing these temperature dependent collision numbers into the DSMC technique is assessed by making calculations representative of the stagnation streamline of a hypersonic space vehicle. Both thermal and chemical nonequilibrium effects are included while the flow conditions have been chosen such that ionization and radiation may be neglected. The introduction of these new models is found to significantly affect the degree of thermal nonequilibrium observed in the flowfield. Larger, and more widely ranging, differences in the results obtained with the different energy exchange probabilities are found when a significant amount of internal energy is included in the calculation of chemical nonequilibrium.

Boyd, Iain D.↗

Modeling Creep Effects in Advanced SiC/SiC Composites

Because advanced SiC/SiC composites are projected to be used for aerospace components with large thermal gradients at high temperatures, efforts are on-going at NASA Glenn to develop approaches for modeling the anticipated creep behavior of these materials and its subsequent effects on such key composite properties as internal residual stress, proportional limit stress, ultimate tensile strength, and rupture life. Based primarily on in-plane creep data for 2D panels, this presentation describes initial modeling progress at applied composite stresses below matrix cracking for some high performance SiC/SiC composite systems recently developed at NASA. Studies are described to develop creep and rupture models using empirical, mechanical analog, and mechanistic approaches, and to implement them into finite element codes for improved component design and life modeling

Lang, Jerry↗

Infrared emission from isolated dust clouds in the presence of very small dust grains

Models of the effects of small grain-generated temperature fluctuations on the IR spectrum and surface brightness of externally heated interstellar dust clouds are presently constructed on the basis of a continuum radiation transport computer code which encompasses the transient heating of small dust grains. The models assume a constant fractional abundance of large and small grains throughout the given cloud. A comparison of model results with IRAS observations indicates that the observed 12-25 micron band emissions are associated with about 10-A radius grains, while the 60-100 micron emission is primarily due to large grains which are heated under the equilibrium conditions.

Lis, Dariusz C.↗

Supersonic flow calculation using a Reynolds-stress and an eddy thermal diffusivity turbulence model

A second-order model for the velocity field and a two-equation model for the temperature field are used to calculate supersonic boundary layers assuming negligible real gas effects. The modeled equations are formulated on the basis of an incompressible assumption and then extended to supersonic flows by invoking Morkovin's hypothesis, which proposes that compressibility effects are completely accounted for by mean density variations alone. In order to calculate the near-wall flow accurately, correction functions are proposed to render the modeled equations asymptotically consistent with the behavior of the exact equations near a wall and, at the same time, display the proper dependence on the molecular Prandtl number. Thus formulated, the near-wall second order turbulence model for heat transfer is applicable to supersonic flows with different Prandtl numbers. The model is validated against flows with different Prandtl numbers and supersonic flows with free-stream Mach numbers as high as 10 and wall temperature ratios as low as 0.3. Among the flow cases considered, the momentum thickness Reynolds number varies from approximately 4,000 to approximately 21,000. Good correlation with measurements of mean velocity, temperature, and its variance is obtained. Discernible improvements in the law-of-the-wall are observed, especially in the range where the big-law applies.

Sommer, T. P.↗

Methane, Carbon Monoxide, and Ammonia in Brown Dwarfs and Self-Luminous Giant Planets

We address disequilibrum abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based 1D atmospheric chemistry model. Our approach is to use the full kinetics model to survey the parameter space with effective temperatures between 500 K and 1100 K. In all of these worlds equilibrium chemistry favors CH4 over CO in the parts of the atmosphere that can be seen from Earth, but in most disequilibrium favors CO. The small surface gravity of a planet strongly discriminates against CH4 when compared to an otherwise comparable brown dwarf. If vertical mixing is like Jupiter's, the transition from methane to CO occurs at 500 K in a planet. Sluggish vertical mixing can raise this to 600 K; clouds or more vigorous vertical mixing could lower this to 400 K. The comparable thresholds in brown dwarfs are 1100±100 K. Ammonia is also sensitive to gravity, but unlike CH4/CO, the NH3/N2 ratio is insensitive to mixing, which makes NH3 a potential proxy for gravity. HCN may become interesting in high gravity brown dwarfs with very strong vertical mixing. Detailed analysis of the CO-CH4 reaction network reveals that the bottleneck to CO hydrogenation goes through methanol, in partial agreement with previous work. Simple, easy to use quenching relations are derived by fitting to the complete chemistry of the full ensemble of models. These relations are valid for determining CO, CH4, NH3, HCN, and CO2 abundances in the range of self-luminous worlds we have studied but may not apply if atmospheres are strongly heated at high altitudes by processes not considered here (e.g., wave breaking).

Planets and satellites↗

Detection of the SO2 atmosphere on Io with the Hubble Space Telescope

Observations of the trailing hemisphere of Io made with the Faint Object Spectrograph of the Hubble Space Telescope (HST) in March 1992 have resulted in the first detection of atmospheric SO2 absorption bands in the ultraviolet. These observations represent only the third positive means of detection of what is widely believed to be Io's primary atmospheric constituent. Below approximately 2130 A the geometric albedo of the satellite is dominated by SO2 gas absorption band signatures, which have been analyzed using models that include the effects of optical thickness, temperature, and spatial distribution. The disk-intergrated HST data cannot resolve the spatial distribution, but it is possible to define basic properties and set constraints on the atmosphere at the time of the observations. Hemispheric atmospheres with average column density N = 6 - 10 x 10(exp 15)/sq sm and T(gas) = 110 - 500 K fit the data, with preference for temperatures of approximately 200 - 250 K. Better fits are found as the atmosphere is spatially confined, with a limit of approximately 8% hemispheric areal coverage and N approximately equal to 3 x 10(exp 17)/sq cm with colder 110 - 250 K temepratures. A dense (N greater than or equal to 10(exp 16)/sq cm), localized component of SO2 gas, such as that possibly associated with active volcanoes, can generate the observed spectral constrast only when the atmosphere is cold (110 K) and an extended component such as Pele is included. The combination of a dense, localized atmosphere with a tenuous component (N less than 10(exp 16)/sq cm, either patchy or extended) also fits the data. In all cases the best fit models imply a disk-averaged column density larger than exospheric but approximately 10 - 30 times less than the previous upper limit from near-UV observations.

Ballester, G. E.↗

Formation and evolution of luminous supersoft X-ray sources

Luminous supersoft X-ray sources, with characteristic luminosities of approximately 10(exp 38) ergs/s and temperatures, kT, of approximately 35 eV, have been established as a new and distinct class of X-ray source through recent Roentgen Satellite (ROSAT) observations. Several possible physical models have been proposed for these sources. One promising scenario (van den Heuvel et al. 1992) involves mass transfer, which is unstable on a thermal timescale, from a main-sequence or subgiant donor star onto the surface of a white dwarf. For a narrow range of accretion rates, steady nuclear burning of the accreted matter can take place. This process can provide the high luminosities and the correct range of temperatures observed in the supersoft sources. However, given the limited range of mass transfer rates that are consistent with this phenomenon, it is far from obvious that a sufficient population of such systems exists in galaxies such as our own, M31, and the Magellanic Clouds, in order to account for the large number of supersoft sources which can be inferred from present observations. This work addresses the population question in detail, through a Monte Carlo simulation of the formation and evolution of such systems, which starts with zero-age primordial binaries. In order to evolve into close binary systems which contain a white dwarf component and a companion transferring mass at a rate within the requisite narrow range, a binary system must undergo a specific progression of evolutionary steps. We find that a sufficient subset of our initial binaries evolve to become systems with the requisite properties, so that they can account for the population of supersoft sources that is inferred from observations. In particular, we find that there should be more than 1000 systems in the Galaxy today with properties that very closely match those of the observed supersoft sources. From our models, we find expected luminosities, white dwarf effective temperatures, and orbital periods in the ranges of 10(exp 37) - 10(exp 38) ergs/s, (1-5) x 10(exp 5) K, and 8 hr-1.4 days, respectively. The masses of the white dwarf and donor star are expected to lie in the range of 0.7-1.05 solar mass and 1.3-2.7 solar mass. Finally, we discuss the role that supersoft X-ray sources may play as the progenitors of Type Ia supernovae, and estimate the rate of production via this channel.

Rappaport, S.↗